Lec 04
Lec 04
Motivation
• Improve understanding of the process =⇒ steady-state and transient
conditions.
Models Classification
A Simple Example
We will start with the general material balance equation:
( ) ( ) ( ) S1 S2
rate of mass rate of rate of x1 x2
= −
accumulation mass in mass out w1 w2
d(ρV )
= w1 + w2 − w (2)
dt x
Applying to component A:3 w
3
Assuming well-mixed conditions (low
d(ρVx ) viscosity, adequate agitation)
= x1 w1 + x2 w2 − xw (3)
dt
Solving this model gives us connections between the different vari-
ables: x vs. V, x vs. (x1 , x2 ), and so on.
0 = w̄1 + w̄2 − w̄
x
Some Principles
All models are wrong, but some are useful.
( ) ( ) ( ) rate of
rate of component i rate of rate of
= − + component i
accumulation component i in component i out
produced
(5)
( ) ( ) ( )
rate of energy rate of energy in rate of energy out
= −
accumulation by convection by convection
net rate of heat
net rate of work
+ addition to the system + performed on the system
from the surroundings by the surroundings
(6)
dUint
= −∆ w Ĥ + Q
(8)
dt
dV 1
= ( w1 + w2 − w ) (9)
dt ρ
dx w w
= 1 ( x1 − x ) + 2 ( x2 − x ) (10)
dt Vρ Vρ
dx w w
= 1 ( x1 − x ) + 2 ( x2 − x )
dt Vρ Vρ
400 200
= (0.4 − x ) + (0.75 − x )
2 × 900 2 × 900
dx
3 = 3.1 − x
dt
This is a first-order linear ODE. The initial condition
is given in the previous part (x̄ = 0.5). Solving the
equation:
e) For all the above cases, plot x (t) and the normalized
response for x defined as:
x ( t ) − x (0)
x (t) =
x ( ∞ ) − x (0)
d
0.6
x (t)
b
0.5
c
0.4
0 5 10 15 20 25
Time (min)
The normazlized curves can be found by calculating
x (∞) for each case. For example, for (b):
∞ ∞
e−
x (t → ∞) = 0.5 e−
+ 0.517(1 − ) = 0.517
0.5
0
0 5 10 15 20 25
Time (min)
The interesting observation here is that the normalized
response has the same time behavior for all cases. This
is because the characteristic time (ρV/w) was kept
constant for all cases (= 3 s).