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Assignment 3

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Assignment 3

Copyright
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Total μL Pb2+ added Absorbance at 490 Corrected 0.

500
nm wavelength absorbance 0.450
0.0 0.227 0.227
0.400
6.0 0.256 0.255
0.350
12.0 0.286 0.284
0.300

Absorbance
18.0 0.316 0.313
24.0 0.345 0.341 0.250
30.0 0.370 0.365 0.200
36.0 0.399 0.392 0.150
42.0 0.425 0.416 0.100
48.0 0.445 0.435 0.050
54.0 0.448 0.436 0.000
60.0 0.449 0.436 0.0 10.0 20.0 30
70.0 0.450 0.435
80.0 0.447 0.430

equivalence point, μL
initial volume, μL 2025
0.500
0.450
0.400
0.350
0.300
0.250
0.200
0.150
0.100
0.050
0.000
0.0 10.0 20.0 30.0 40.0 50.0 60.0 70.0 80.0 90.0
Total μL Pb2+ added

54.0
Unknown, mL Standart, mL Final volume, mL Emission intensity 1000
10.00 0.00 100.0 309
900
10.00 5.00 100.0 452 f(x) = 30.14 x + 305
10.00 10.00 100.0 600 800
10.00 15.00 100.0 765 700
10.00 20.00 100.0 906
600
y=mx+b 500
m= 30.14
400
b= 305
300
30.14 305
200
dm= 0.426301927433285 5.22111099288265
0.9994001967953 6.74042530804499 100
4998.64049889949 3 0
227104.9 136.3 0.00 5.00
1000

900
f(x) = 30.14 x + 305
800

700

600

500

400

300

200

100

0
0.00 5.00 10.00 15.00 20.00 25.00
0.88
1.48
0.94
1.12
1.03
1.40
1.14

<x>= 1.14
s= 0.224828
m= 1

Detection limit 0.67 ng/l


Quantitative limit 2.25 ng/l

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