JEE MAIN PAPER

CLASS 12th IIT SCHOOL VIJAY BATCH

Time : 3 Hours Maximum Marks : 100

PART – 1 : MATHEMATICS
• This question paper contains two sections, section A & B.
• Section A contains 20 Single choice questions (SCQs) with four options (A),(B),(C),(D) out of
which only one option is correct.
• Section B contains 5 Integer Type questions, out of which candidate have to attempt only 5
questions.

Section-I
• This Section contain 20 questions (Q.No. 1 to Q.No. 20)
• Answer to each question in Section A will be evaluated according to the following marking
scheme:
Full Marks : ⁡+𝟒 for correct answer
Zero Marks : 0 If the question is unanswered;
Negative Marks : −𝟏 for incorrect answer

1
cos⁡ x π
1. If ∫ 2 dx = f(x)(1 + sin6 ⁡ x)λ + c, where c is a constant of integration, then λf (3 ) is
sin3 ⁡ x(1+sin6 ⁡ x)3

equal to:
9 9
(A) ⁡ − 8 (B) 8

(C) 2 (D) -2
dx
2. The integral ∫ 8 6 is equal to: (where C is a constant of integration)
(x+4)7 (x−3)7
1
x−3 −7
(A) − (x+4) +C
3
1 x−3 7
(B) ⁡ 2 (x+4) +C
1
x−3 7
(C) (x+4) + C
13
1 x−3 − 7
(D) − 13 (x+4) +C
dθ
3. If ∫ = λtan⁡ θ + 2log e ⁡ |f(θ)| + C where C is constant of integration, then the
cos2 ⁡ θ(tan⁡ 2θ+sec⁡ 2θ)

ordered pair (λ, f(θ)) is equal to:

(A) (−1,1 − tan⁡ θ) (B) (−1,1 + tan⁡ θ)
(C) (1,1 + tan⁡ θ) (D) (1,1 − tan⁡ θ)

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x
4. If ∫ sin−1 ⁡ (√1+x) dx = A(x)tan−1 ⁡(√x) + B(x) + C, where C is a constant of integration, then the

ordered pair (A ( x ), B ( x ) ) can be :

(A) (x + 1, −√x)
(B) (x − 1, −√x)
(C) (x + 1, √x)
(D) (x − 1, √x)
1
5. The integral ∫ 4 dx is equal to (where C is a constant of integration)
√(x−1)3 (x+2)5
5
3 x+2 4
(A) ( ) +c
4 x−1
1
3 x+2 4
(B) ( ) +c
4 x−1
1
4 x−1 4
(C) ( ) +c
3 x+2
5
4 x−1 4
(D) ( ) +c
3 x+2
(x2 +1)ex d3 f
6. ∫ dx = f(x)ex + C, where C is a constant, then dx3 at x = 1 is equal to :
(x+1)2
3
(A) − 4
3
(B) 4
3
(C) − 2
3
(D) 2
dy
7. If y = y(x) is the solution of the differential equation, ey (dx − 1) = ex such that y(0) = 0, then

y(1) is equal to
(A) log e 2
(B) ⁡2e
(C) 2 + log e 2
(D) 1 + log e 2
dy
8. Let y = y(x) be a solution of the differential equation, √1 − x 2 dx + √1 − y 2 = 0, |x| < 1. If
1 √3 1
y (2) = , then y ( ) is equal to:
2 √2
1 √3
(A) − (B) −
√2 2

1 √3
(C) (D)
√2 2

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9. The differential equation of the family of curves, x 2 = 4b(y + b), b ∈ R is
(A) ⁡xy ′′ = y ′
(B) x(y ′ )2 = x + 2yy ′
(C) ⁡x(y ′ )2 = x − 2yy ′
(D) ⁡x(y ′ )2 = 2yy ′ − x
dy xy
10. If dx = x2+y2 ; y(1) = 1; then a value of x satisfying y(x) = e is:

(A) √3e
1
(B) √3e
2

(C) √2e
e
(D)
√2
x
11. Let f: (a, b) → R be twice differentiable function such that f(x) = ∫a g(t)dt for a differentiable
function g(x). If f(x) = 0 has exactly five distinct roots in (a, b), then g(x)g ′ (x) = 0 has at least:
(A) seven roots in (a, b)
(B) five roots in (a, b)
(C) three roots in (a, b)
(D) twelve roots in (a, b)
2
12. The value of α for which 4α∫−1 e−α|x| dx = 5, is:
(A) ⁡log e ⁡ 2
(B) log e ⁡ √2
4
(C) ⁡log e ⁡ (3)
3
(D) ⁡log e ⁡ (2)
2 dx
13. If I = ∫1 √2x3 −9x2 +12x+4
, then:
1 1 1 1
(A) 6 < I2 < 2 (B) 8 < I2 < 4
1 1 1 1
(C) 9 < I2 < 8 (D) 16 < I2 < 9
2π xsin8 ⁡ x
14. The value of ∫0 dx is equal to:
sin8 ⁡ x+cos8 ⁡ x

(A) 2π (B) 4π
(C) 2π2 (D) π2
π
15. ∫−π |π − |x||dx is equal to :
π2
(A) π2 (B) 2

(C) √2π2 (D) 2π2

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1 1
16. If I1 = ∫0 (1 − x 50 )100 dx and I2 = ∫0 (1 − x 50 )101 dx such that I2 = αI1 then α equal to :
5050
(A) 5049
5050
(B) 5051
5051
(C) 5050
5049
(D) 5050

17. Let the function, f: [−7,0] → R be continuous on [−7,0] and differentiable on (−7,0). If f(−7) =
−3 and f ′ (−7) = −3 and f ′ (x) ⩽ 2, for all x ∈ (−7,0), then for all such functions f, f(−1) + f(0)
lies In the interval
(A) [−6,20]
(B) (−∞, 20]
(C) (−∞, 11]
(D) [−3,11]

18. Let f(x) be a polynomial of degree 5 such that x = ±1 are its critical points. If limx→0 (2 +
f(x)
) = 4, then which one of the following is not true?
x3

(A) f(1) − 4f(−1) = 4

(B) ⁡x = 1 is a point of maxima and x = −1 is a point of minimum of f.
(C) f is an odd function.
(D) x = 1 is a point of minima and x = −1 is a point of maxima of f.
π π
19. Let f(x) = xcos−1 ⁡(sin⁡(−|x|)), x ∈ (− 2 , 2 ), then which of the following is true?
π
(A) f ′ (0) = − 2
π π
(B) ⁡f ′ is decreasing in (− 2 , 0) and increasing in (0, 2 )

(C) ⁡f is not differentiable at x = 0

π π
(D) f ′ is increasing in (− 2 , 0) and decreasing in (0, 2 )

20. Let P(h, k) be a point on the curve y = x 2 + 7x + 2, nearest to the line, y = 3x − 3. Then the
equation of the normal to the curve at P is :
(A) x + 3y − 62 = 0
(B) x − 3y − 11 = 0
(C) x − 3y + 22 = 0
(D) x + 3y + 26 = 0

4
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Section-II
• This Section contain 5 questions (Q.No. 21 to Q.No. 25) whose answer to be filled as
numerical value
• Answer to each question in Section B will be evaluated according to the following marking
scheme:
Full Marks : ⁡+𝟒 for correct answer
Zero Marks : 0 If the question is unanswered;
Zero Marks : 𝟎 for incorrect answer

sin⁡ x 2tan⁡ x−1

21. ∫ ⁡ sin3⁡ x+cos3⁡ x dx = αlog e ⁡ |1 + tan⁡ x| + βlog e ⁡|1 − tan⁡ x + tan2 ⁡ x| + γtan−1 ⁡ ( )+C
√3

When C is constant of integration, then the value of 18(α + β + γ2 ) is

2 k
22. If the integral ∫0 ||x − 1| − x|dx = 2 then k is equal to :
dy
23. If the solution of the differential equation dx + ex (x 2 − 2)y = (x 2 − 2x)((x 2 − 2)e2x ) satisfies

y(0) = 0, then the value of y(2) is ⁡

24. The number of distinct real roots of the equation 3x 4 + 4x 3 − 12x 2 + 4 = 0 is
25. If the angle made by the tangent at the point (x0 , y0 ) on the curve x = 12(t + sin⁡ tcos⁡ t), y =
π π
12(1 + sin⁡ t)2 , 0 < t < 2 , with the positive x-axis is 3 , then y0 is equal to

5
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PART – 2 : PHYSICS

• This question paper contains two sections, section A & B.

• Section A contains 20 Single choice questions (SCQs) with four options (A),(B),(C),(D) out of
which only one option is correct.
• Section B contains 5 Integer Type questions, out of which candidate have to attempt only 5
questions.

Section-I
• This Section contain 20 questions (Q.No. 1 to Q.No. 20)
• Answer to each question in Section A will be evaluated according to the following marking
scheme:
Full Marks : ⁡+𝟒 for correct answer
Zero Marks : 0 If the question is unanswered;
Negative Marks : −𝟏 for incorrect answer

sin⁡ i
26. In the figure shown sin⁡ r is equal to:

μ22
(A) μ
3 μ1
μ
(B) μ3
1
μ3 μ1
(C) μ22

(D) none of these

27. A transparent cylinder has its right half polished so as to act as a mirror. A paraxial light ray is
incident from left, that is parallel to principal axis, exits parallel to the incident ray as shown.
The refractive index n of the material of the cylinder is:

(A) 1.2 (B) 1.5

(C) 1.8 (D) 2.0

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28. A convex lens is cut into two parts in different ways that are arranged in four manners, as
shown. Which arrangement will give maximum optical power?

(A) (B)

(C) (D)

29. A ray of light travelling in air is incident at grazing incidence on a slab with variable refractive
1/2
index, n (y) = [ky 3/2 + 1] where k = 1 m−3/2 and follows path as shown in the figure. What
is the total deviation produced by slab when the ray comes out.

(A) 60∘ (B) 53∘

(C) sin−1 ⁡(4/9) (D) no deviation at all
30. An astronomical telescope has an angular magnification of magnitude 5 for distant objects. The
separation between the objective and the eye-piece is 36 cm and the final image is formed at
infinity. The focal length f0 of the objective and fe of the eye-piece are
(A) f0 = 45 cm and fe = −9 cm
(B) f0 = 50 cm and fe = 10 cm
(C) f0 = 7.2 cm and fe = 5 cm
(D) fo = 30 cm and fe = 6 cm
31. A and B are two concentric hollow spheres. If A is given a charge Q while B is earthed as shown
in figure.

(A) A and B both will have the same charge densities

(B) the potential inside A and outside B will zero
(C) the electric field between A and B is non zero
(D) the electric field inside A and outside B is non zero.

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32. Two positive point charges each of magnitude 10C are fixed at positions A⁡&⁡B at a separation
2d = 6 m. A negatively charged particle of mass m = 90gm⁡& charge of magnitude 10 × 10−6 C
is revolving in a circular path of radius 4 m in the plane perpendicular to the line AB and
bisecting the line AB. Neglect the effect of gravity. If the angular velocity of the particle is ω.
Then the value of ω (in rad/sec) is:

(A) 100 (B) 200 (C) 300 (D) 400

33. The electric potential decreases uniformly from 180 V to 20 V as one moves on the X-axis from
x = −2 cm to x = +2 cm. The electric field at the origin:
(A) must be equal to 40 V/cm.
(B) may be equal to 40 V/cm.
(C) may be less than 30 V/cm.
(D) may be less than 40 V/cm.
34. The magnitude of electric field intensity at point (2,0,0) due to a dipole of dipole moment,
⃗ = î + √3ĵ kept at origin is [ where k = 1/4π ∈0 ] :
P
√13k √13k √7k √7k
(A) (B) (C) (D)
8 4 8 4

35. The figure shown represents the electric field between two large metal plates. Which of the
graphs given in figure represents the force on a positive charge as it moves from point P
towards plate B ?

(A) (B)

(C) (D)

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36. The capacitors A and B are connected in series with a battery as shown in the figure. When the
switch S is closed and the two capacitors get charged fully, then-

(A) The potential difference across the plates of A is 4V and across the plates of B is 6 V
(B) The potential difference across the plates of A is 6 V and across the plates of B is 4 V
(C) The ratio of electric energies stored in A and B is 2: 3
(D) The ratio of charges on A and B is 3: 2
37. In the circuit shown in fig. C1 = 2C2 . Capacitor C1 is charged to a potential of V. The current in
the circuit just after the switch S is closed is

(A) 0
2V
(B) R

(C) Infinite
V
(D) 2R
38. Two identical capacitors 1 and 2 connected in series to a battery as shown in fig. Capacitor 2
contains a dielectric slab of dielectric constant k as shown. Q1 , and Q2 are the charges stored in
the capacitors. Now the dielectric slab is removed and the corresponding charges are Q′1 and
Q′2 . Then

Q′ k+1
(A) Q1 =
1 k

Q′ k+1
(B) Q2 =
2 2

Q′ k+1
(C) Q2 =
2 2k

Q′1 k
(D) =
Q1 2

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39. A current loop consists of two identical semicircular parts each of radius R, one lying in the x −
y plane and the other in x − z plane. If the current in the loop is i. The resultant magnetic field
due to the two semicircular parts at their common centre is
μ i
(A) 2√2R
0

μ i
(B) 2R
0

μ i
(C) 4R
0

μ0 i
(D)
√2R

40. If the angular momentum of electron is j then its magnetic moment will be –
eJ
(A) m
eJ
(B) 2m

(C) eJ 2m
2m
(D) eJ

41. A particle of charge per unit mass α is released from origin with a velocity v
⃗ = v0 î in a uniform
⃗ = −B0 k̂. If the particle passes through (0, y, 0) then y is equal to
magnetic field B
2v0
(A) − B
0α
v0
(B) B0 α
2v0
(C) B
0α
v
(D) − B 0α
0

42. The spokes of a wheel are made of metal and their lengths are of one metre. On rotating the
wheel about its own axis in a uniform magnetic field of 5 × 10−5 tesla normal to the plane of
the wheel, a potential difference of 3.14mV is generated between the rim and the axis. The
rotational velocity of the wheel is-
(A) 63rev./s
(B) 50rev./s
(C) 31.4rev./s
(D) 20rev./s

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43. A conducting rod AB of length l = 1 m is moving at a velocity v = 4 m/s making an angle 30∘
with its length. A uniform magnetic field B = 2T exists in a direction perpendiuclar to the plane
of motion. Then

(A) VA − VB = 8 V
(B) VA − VB = 4V
(C) VB − VA = 8V
(D) VB − VA = 4V
44. The graph between the current and the time for an inductance coil is shown below. Which of
the following graph show the voltage-time variation –

(A) (B)

(C) (D)

45. In the figure six lines of emission spectrum are shown. Which of them will be absent in the
absorption spectrum.

(A) 1,2,3 (B) 1, 4, 6

(C) 4,5,6 (D) 1,2,3,4,5,6

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Section-II
• This Section contain 5 questions (Q.No. 21 to Q.No. 25) whose answer to be filled as
numerical value
• Answer to each question in Section B will be evaluated according to the following marking
scheme:
Full Marks : ⁡+𝟒 for correct answer
Zero Marks : 0 If the question is unanswered;
Zero Marks : 𝟎 for incorrect answer

46. In the photoelectric experiment, if we use a monochromatic light, the I - V curve is as shown. If
work function of the metal is 2eV, estimate the power of light used. (Assume efficiency of photo
emission = 10−3 %, i.e. number of photoelectrons emitted are 10−3 % of number of photons
incident on metal.)

47. A charge particle q 0 of mass m0 is projected along the y-axis at t = 0 from origin with a velocity
V0 . If a uniform electric field E0 also exists along the x-axis, then the time at which debroglie
mv
wavelength of the particle becomes half of the initial value is √K qE 0. Then K = ?
0

48. If the mass of proton = 1.008a.m.u. and mass of neutron = 1.009a. m. u. then binding energy
per nucleon for ⁡4 Be9 (mass = 9.012amu) would be K MeV. Then K =?
49. The resistance of an ammeter is 13Ω and its scale is graduated for a current upto 100 A. After
an additional shunt has been connected to this ammeter it becomes possible to measure
currents upto 750 A by this meter. The value of shunt resistance is in ohm
50. In a photoelectric effect experiment, stopping potential changes by 30volt if we change
frequency of the radiation. Then the magnitude of change in the frequency is: (h =
6 × 10−34 J − s) k × 1015 s −1 then k = ?

12
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PART – 3 : CHEMISTRY

• This question paper contains two sections, section A & B.

• Section A contains 20 Single choice questions (SCQs) with four options (A),(B),(C),(D) out of
which only one option is correct.
• Section B contains 5 Integer Type questions, out of which candidate have to attempt only 5
questions.

Section-I
• This Section contain 20 questions (Q.No. 1 to Q.No. 20)
• Answer to each question in Section A will be evaluated according to the following marking
scheme:
Full Marks : ⁡+𝟒 for correct answer
Zero Marks : 0 If the question is unanswered;
Negative Marks : −𝟏 for incorrect answer

51. Find the solubility product of copper (II) iodate, Cu(IO3 )2, by iodometric titration in an acidic
solution. 26 ml of 0.1 M sodium thiosulphate solution is needed to titrate 20 ml of saturated aq.
Solution Cu(IO3 )2
(A) 4.0 × 10−6 (B) 1.0 × 10−6
(C) 8.8 × 10−6 (D) 1.0 × 10−4

52. The Ziegler-Natta catalyst used for polymerisation of ethene and styrene is
TiCl4 + (C2 H5 )3 Al, the catalysing species (active species) involved in the polymerisation is
(A) TiCl4 (B) TiCl3
(C) TiCl2 (D) TiCl
53. Which of the following compounds will provide a tertiary alcohol on reaction with excess of
CH3MgBr followed by hydrolysis?

(A) (B)

(C) (D)

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54. The molar volume of X(𝑙)(d = 0.9 g/ml) increases by a factor of 3000 as it vaporises at 27∘ C
and that of Y(𝑙)(d = 0.88 g/ml) increases by a factor of 8000 at 27∘ C. A miscible liquid solution
of X and Y at 27∘ C has a vapour pressure of 50 torr. Find the mole fraction of Y in solution is
[Given: R = 0.082 atm/L/mol/K; Molar mass of X = 75; Molar mass of Y = 88 ]
(A) 0.48
(B) 0.52
(C) 0.62
(D) 0.247
55. Which of the following compound is responsible for catching fire spontaneously in Holme's
signal?
(A) P2 H4 (B) PH3 (C) C2 H4 (D) All of these
56. The major product ‘P’ formed in the given reaction is

(A) (B)

(C) (D)

57. The equilibrium constant for the reaction CO(g) + H2 O(g) ⇌ CO2 ( g) + H2 ( g) is 3 at 500 K . In
a 2 litre vessel 60 gm of water gas [equimolar mixture of CO(g) and H2 ( g) ] and 90 gm of steam
is initially taken. What is the equilibrium concentration of H2 ( g) at equilibrium (mole/L)?
(A)2.15
(B)1.75
(C)1.20
(D)2.55

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58. A chloride dissolves appreciably in cold water. When placed on a platinum wire in Bunsen
flame, no distinctive color is noticed. Which one is cation?
(A) Mg 2+ (B) Ba2+ (C) Na+ (D) Ca2+
59. Diethyl ether and air gives ether hydroperoxide. The mechanism of the reaction is
(A)Nucleophilic substitution (B) Free radical addition
(C) Free radical substitution (D) None of the above
60. If last line of Lyman series of H-atom has wavelength 𝜆1 Å and 2nd line of Balmer series has
wavelength 𝜆2 Å then :
16 9
(A) 𝜆 = 𝜆
1 2

16 3
(B) 𝜆 = 𝜆
2 1

4 1
(C) 𝜆 = 𝜆
1 2

16 3
(D) 𝜆 = 𝜆
1 2

61. Borax is converted into crystalline boron by the following steps:

X Δ Y
Borax ⟶ H3 BO3 ⟶ B2 O3 ⟶ B
X and Y are respectively:
(A) HCl, Mg (B) HCl, C (C) C, Al (D) HCl, Al
62. In the give Reaction sequence

Which of the following pairs are correct

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63. Choose the INCORRECT statements among the following :
(A) On decreasing pressure at the equilibrium H2 O(s) ⇌ H2 O(𝑙), more ice will be formed
(B) At equilibrium, if K p = 1, then ΔG∘ < 1
(C) For the reaction 2SO2 ( g) + O2 ( g) ⇌ 2SO3 ( g), K p is less than K c ⁡ at 25∘ C
(D) Data for the given reaction N2 O4 ( g) ⟶ 2NO2 ( g); ΔH = 54 kJ, Ea (forward) = 57.2 kJ
Then activation energy for the reverse reaction is 3.2 kJ
64. In a polythionic series (H2 Sn O6 ) if [n = 4]. Which of the following option is incorrect?
(A) Absolute oxidation state of S is +5 as well as zero.
(B) Number of S-S linkage are three
(C) It has sp3 sulphur atom.
(D) It has only non-polar bonds.
65. The decreasing order of ease of alkaline hydrolysis for the following esters is

I. II.

III. IV.

(A)III > II > IV > I (B) III > II > I > IV

(C) IV > II > III > I (D) II > III > I > IV
66. Which of the following condition are correct for a binary solution, in which the solute as well as
the solvent are liquid? [Liquid Solution-M]
(A) C6 H6 and C6 H5 CH3 ΔHsolution > 0; ΔVsolution = 0
(B) CH3 COCH3 and CHCl3 ΔHsodution < 0; ΔVsolotion < 0
(C) H2 O and HClΔHsolution > 0; ΔVsolution < 0
(D) H2 O and C2 H5 OHΔHsolution < 0; ΔVsolution > 0

67. The stability of dihalides of Si, Ge, Sn, and Pb increases steadily in the sequence:
(A) PbX2 < SnX2 < GeX2 < SiX2
(B) GeX2 < SiX2 < SnX2 < PbX2
(C) SiX2 < GeX2 < PbX2 < SnX2
(D) SiX2 < GeX2 < SnX2 < PbX2

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68. Which of the following method is not useful for the synthesis of ether

(A) CH2Br + HO NO2 ⎯⎯⎯→

aq.NaOH

(B) C2H5ONa + (CH3)2SO4 ⎯→

(C) CH3ONa + CH3CH2OSO2 CH3 ⎯→

(D) (CH3)3CBr + CH3CH2ONa⎯→

69. For the reaction

2ClF3 ( g) ⇌ Cl2 ( g) + 3 F2 ( g)

1
log⁡ K eq v/s (where temperature is in K ) curve is obtained as following
T

Which of the following change will increase the concentration of Cl2 in an equilibrium mixture
of Cl2 , F2 &ClF3 :
(A) Addition of inert gas at constant pressure
(B) Decrease in temperature at constant volume
(C) Addition of cataslyst at equilibrium
(D) Removal of F2 ( g) at equilibrium

70. Assume that the decomposition of HNO3 can be represented by the following equation
4HNO3 ( g) ⇌ 4NO2 ( g) + 2H2 O( g) + O2 ( g)
and that at a given temperature 400 K and pressure 30 atm the reaction approaches
equilibrium. At equilibrium partial pressure of HNO3 is 2 atm . Calculate K C in (mol/L)3 at 400
K.
(Use R = 0.08 atm − L/mol. K )
(A)28 (B)35
(C)30 (D) 32

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 JEE MAIN PAPER
CLASS 12th IIT SCHOOL VIJAY BATCH

Section-II
• This Section contain 5 questions (Q.No. 21 to Q.No. 25) whose answer to be filled as
numerical value
• Answer to each question in Section B will be evaluated according to the following marking
scheme:
Full Marks : ⁡+𝟒 for correct answer
Zero Marks : 0 If the question is unanswered;
Zero Marks : 𝟎 for incorrect answer

71. A certain buffer solution contains equal concentration of X − and HX . The K b for X − is 10−10. The
pH of the buffer is

72. How many atomic orbitals are involved in hybridization - of [Co(NH3 )6 ]2+ ?
73. In the trimer structure of SO3, calculate the sum of S–O–S, S–S bonds and total number of lone
pair present.
74. In the given reaction sequence
O O
(i) NaOBr
C – C – C – CH3 Product (P)
(ii) H2O/H+
H3C CH3 (iii) 

Total number of double bond equivalent present in product (P) is

75. A compound (X) reacts with thionyl chloride to give a compound (Y). (Y) reacts with Mg to form
a Grignard reagent, which is treated with acetone and the product is hydrolysed to give 2-
methyl-2-butanol. Total number of carbon atoms are presents in compound (X) is

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