Obtaining capillary pressure curves from resistivity measurements in low-permeability sandstone
Obtaining capillary pressure curves from resistivity measurements in low-permeability sandstone
Obtaining capillary pressure curves from resistivity measurements in low-permeability sandstone
A R T I C L E I N F O A B S T R A C T
Keywords: The increasing global demand for energy necessitates exploring and developing low-quality prospects, e.g., low-
Tight reservoirs permeability reservoirs, which contain substantial hydrocarbon resources and have the potential to fill the gap in
Partially-saturated media the energy markets. Typically, modeling fluid flow using reservoir simulators requires capillary pressure curves
Fractal theory
as an input. Nonetheless, laboratory capillary pressure measurements in low-permeability samples are time-
Genetic algorithm
Resistivity modeling
consuming and challenging. On the contrary, resistivity measurements are easier to perform in the laboratory
Capillary pressure modeling and offer a different prospect for obtaining capillary pressure curves. This paper proposes a new approach for
obtaining capillary pressure curves from resistivity measurement in low-permeability sandstone using fractal
theory and genetic algorithm. First, the fractal pore system is characterized as tortuous square and triangular
capillaries to account for angular pores. Afterward, the drainage process is simulated to develop an innovative
electrical resistivity model in fully and partially saturated porous media. Next, the genetic algorithm matches
laboratory-measured resistivity data and obtains the developed model parameters. Afterward, the matched pa
rameters are adopted in the drainage capillary pressure model to generate capillary pressure curves. The pro
posed model’s reliability is verified by analyzing the prediction results of eighteen sandstone core samples.
Furthermore, the developed model performance is compared with different models from the literature, and the
results indicated its superiority in predicting capillary pressure curves.
* Corresponding author.
E-mail address: [email protected] (M. Saafan).
https://doi.org/10.1016/j.petrol.2022.111297
Received 9 May 2022; Received in revised form 27 October 2022; Accepted 26 November 2022
Available online 14 December 2022
0920-4105/© 2022 Elsevier B.V. All rights reserved.
M. Saafan et al. Geoenergy Science and Engineering 221 (2023) 111297
saturation have equal power-law exponents. Li and Williams (2007) modeling the mixed-wet conditions. Although the capillary bundle
demonstrated that Szabo’s model is inaccurate in several cases, espe model is a simplistic approach to modeling realistic reservoir rocks, it
cially for low permeability core samples. Moreover, the authors derived allows studying the influence of different parameters on the resulting
a power-law fractal model that correlates capillary pressure and re capillary pressure behavior and deriving analytical expressions to be
sistivity index. Their model outperformed in low-permeability samples. included in reservoir simulators. The drainage process is simulated, and
Mahmoud and Abdelgawad (2013) proposed a method for determining the electrical resistivity of partially saturated fractal porous media is
the capillary pressure profile in the transition zone using resistivity log modeled. Then, analytical fractal models are derived for characterizing
data. The predicted capillary pressure curves provided a good match capillary pressure and electrical resistivity. The genetic algorithm is
with the laboratory-measured curves in medium permeability carbon utilized to adjust the parameters of the developed resistivity model by
ate, i.e., 100–250 md, and low permeability sandstone, i.e., less than 60 minimizing the error between the model results and laboratory-
md. Tan (2018) introduced a Pc/Rt versus Sw plot defined by an expo measured resistivity. Afterward, the adjusted parameters are utilized
nential function with four fitting coefficients. The fitting coefficients for in the drainage capillary pressure model to obtain the capillary pressure
each core are determined and related to permeability. Afterward, the curve. Finally, experimental measurements of eighteen samples are
established relationships are employed to compute the log-based capil utilized to validate the proposed method and compare its performance
lary pressure using resistivity, water saturation, and permeability logs. with different models from the literature.
Lately, Li et al. (2019) performed additional experiments at room tem The paper is organized as follows. Section 2 summarizes the sample
perature to support Li and Williams’ power-law model. The findings preparation and the different laboratory measurements. Moreover, it
showed that power-law model works effectively in many tested core details the pore system representation and simulates the drainage pro
samples. Moreover, the authors correlated the power-law model expo cess to derive fractal models for capillary pressure and electrical re
nent with rock permeability. sistivity. Also, the suggested procedures for obtaining drainage curves
Many theoretical investigations have been limited to predicting from resistivity measurements are detailed. Section 3 examines the
porous media’s flow characteristics in the homogeneous microstructures developed models’ outcomes and illustrates the validation process.
while failing in heterogeneous microstructures. The limitation is Furthermore, the developed model performance is compared with
attributable to the complex pore structure with tortuous flow paths, different models from the literature. Section 4 provides the conclusions
creating uncertainty in the flow distribution throughout the media (Yu, and recommendations for future works.
2008). On the other hand, fractal theory was introduced to characterize
complex and irregular geometries in nature and represent the middle 2. Samples and methods
ground between linear geometry and complete chaos (Mandelbrot,
1982). Subsequently, experimental measurements demonstrated that 2.1. Samples
the porous media microstructures are fractal (Katz and Thompson,
1985). Recently, several researchers adopted the fractal theory to Eighteen low-permeability sandstone samples are cut from cores
characterize the pore structure of low permeability sandstone (Dong obtained from the Jurassic lower Safa sandstones, a member of the
et al., 2021; Lu and Liu, 2021; Shao et al., 2017). Moreover, fractal Khatatba formation in Faghur Basin located in the Western Desert of
theory can help analyze porous media’s petrophysical properties, i.e., Egypt. Fig. 1 shows the generalized stratigraphic column of the Faghur
permeability, capillary pressure, and electrical properties (Saafan et al., Basin (Edress et al., 2022). Generally, Lower Safa reservoir consists of
2022b; Saafan and Ganat, 2020). For example, Wei et al. (2015) derived fine to medium-grained moderate to well-sorted sandstones character
a fractal expression from modeling electrical conductivity in fully ized by large reservoir quality differences.
saturated porous media and compared it to Archie’s equation. Cai et al.
(2018) suggested a leaf vein network and studied the electrical prop 2.2. Experiments
erties of porous media. Later, Rembert et al. (2020) derived a fractal
model to evaluate fully saturated porous media’s formation factor and The experimental work starts with cleaning core plugs by hot soxhlet
electrical conductivity. Moreover, they establish a relationship between using toluene and drying in a conventional oven to remove any fluids.
electrical conductivity and transport characteristics, e.g., permeability. Then the samples’ dry weights are recorded. After that, the samples are
The available methods for obtaining capillary pressure from re saturated by putting them in a vacuum desiccator with brine. The
sistivity measurements have the following limitations: samples’ fully saturated weight is recorded, and the porosity is calcu
lated. Afterward, the liquid permeameter is used to measure the
1) They correlated the capillary pressure and resistivity using equations permeability of the core plugs. Then, the fully saturated sample re
with fitting coefficients. Those coefficients must be determined in sistivity, R0, is measured at ambient conditions. The porous plate
advance by fitting laboratory data of capillary pressure and re apparatus is used to obtain the drainage Pc - Sw curve. At each desa
sistivity, then correlating them with petrophysical properties such as turation step, the plugs are removed and weighed to calculate the water
permeability. Consequently, those correlations are not universal and saturation. Also, the value of resistivity, Rt, is measured. The plugs are
applicable only to cores from the same formation. returned to the porous plate, and the air pressure is increased. Fig. 2
2) Li et al. (2019) only verified the power-law relation between capil illustrates the detailed work flow of the experimental steps.
lary pressure and resistivity. Although the authors correlated the
model exponent with permeability, they never verified its ability to 2.3. Pore system representation
predict capillary pressure from resistivity measurements.
3) The fractal electrical conductivity models are limited to fully- Irregular pore walls characterize the pore structure of porous media.
saturated porous media and should be developed in partially- As a result, polygons such as triangles and squares are more appropriate
saturated media. for modeling pore geometry than circles (Mason and Morrow, 1991).
Moreover, polygons permit the retention of the wetting phase in invaded
This study proposes a new method to obtain capillary pressure curves capillary corners. The dimensionless pore shape factor, G, is used to
from resistivity measurements based on fractal theory and genetic al define pore morphology and is obtained from the pore’s area (A) and
gorithm. The pore system is represented using the capillary bundle perimeter (P) as:
model with separate bundles of tortuous fractal square and triangular
A
capillaries. Using capillaries with polygon cross-sections allow the G= (1)
P2
wetting phase to be retained in the corners of invaded tubes, hence
2
M. Saafan et al. Geoenergy Science and Engineering 221 (2023) 111297
Fig. 1. Generalized stratigraphic column of the Faghur Basin (Edress et al., 2022).
This work utilizes the capillary bundle model proposed by Saafan Patzek equations (Patzek and Silin, 2001). Suppose the corner-half an
et al. (2022a, 2022b), which represents the pore system as tortuous gles satisfy 0 < β1 ≤ β2 ≤ β3 ≤ π/2, then the minimum and maximum
triangular and square capillaries (Fig. 3). values of β2 for a given G is:
The radii of capillary inscribed circles change sinusoidally (Fig. 4) to { [ ( √̅̅̅ ) ]}
account for the existence of pores and throats. The inscribed circle’s 2 cos− 1 − 12 3 G 4π
β2,min = tan − 1
√̅̅̅ cos + (4)
radius at a distance x is given as: 3 3 3
( ) [ ( )]
2π x 2π x { [ ( √̅̅̅ )]}
r(x) = R + r sin = R 1 + a sin (2) 2 cos− 1 − 12 3 G
λ λ β2,max = tan − 1
√̅̅̅ cos (5)
3 3
Where R is the average capillary inscribed radius, r is the oscillation
In this paper, β2 is set to:
amplitude, λ is the wavelength, and a is the cross-sectional restriction
factor (0 ≤ a ≤1). The capillary’s cross-sectional area at a distance x is β2,min + β2,max
β2 = (6)
represented by: 2
r2 (x) R2
[ ( )]2
2π x Then, β1 and β3 are calculated as:
A(x) = = 1 + a sin (3) ( )
4G 4G λ 1 1 tan β2 + 4G
β1 = − β2 + sin− 1 sin β2 (7)
Each corner-half angle of a square capillary is π/4. For a triangular 2 2 tan β2 − 4G
capillary, the corner-half angles (β1, β2, and β3) are obtained using the
3
M. Saafan et al. Geoenergy Science and Engineering 221 (2023) 111297
dN = − Df RDmax
f
R− Df − 1
dR (10)
Based on the work of Wheatcraft and Tyler (1988) and (Yu and
Cheng, 2002), Saafan and Ganat (2021) proposed a tortuous length
equation to eliminate the fractal models’ reliance on straight capillary
length, L0. The tortuous length, Lt, is expressed as:
Lt = 21− Dt
R1− Dt
L0 (11)
where Across is the cross-sectional of the capillary bundle model and Rmin
is the smallest pore radius.
Mandelbrot (1982) developed the fractal theory to describe complex Where σow is the oil-water interfacial tension, θr is the receding contact
geometries in nature and represent the middle ground between linear angle, and C is:
geometry and complete chaos. In a fractal porous medium, the number ∑ n {
cos(θr + βi ) (π )}
of capillaries (N) with radii larger than or equal to R is expressed as (Yu C= cos θr − − θ r − βi (14)
sin βi 2
and Li, 2002): i=1
( )D
Rmax f where n is the number of corners satisfying:
N= (9)
R π
βi < − θ r (15)
2
where Rmax is the largest pore radius, and Df is the pore fractal
4
M. Saafan et al. Geoenergy Science and Engineering 221 (2023) 111297
Fig. 5. Change of fluids configuration during primary drainage (Saafan and Ganat, 2021).
The second integration in Eq. (18) defines the water volume left in
Fig. 6. A simplified view of the residual water on the walls of
invaded capillary.
the invaded capillaries’ corners and is evaluated as:
∫
Rmax ∫
Rmax
The cross-sectional area occupied by the remaining water is calcu vwr (− dN) = Awr Lwall (− dN) (22)
lated by: R R
Awr = C r2 (16) where Lwall is the length of the capillary wall, which represents the
length of a sinusoidally varying curve. Fig. 6 shows a simplified repre
where r is the radius of the arc meniscus between the two phases, which
sentation of the remaining water on a straight capillary wall. Lwall is
is computed as follows:
calculated for tortuous capillary as (Appendix A):
σ ow √̅̅̅̅̅̅̅̅̅̅̅̅̅ (√̅̅̅̅̅̅̅̅̅̅̅̅̅)
r= (17) √̅̅̅̅̅̅̅̅̅̅̅̅̅ ( )
Pc a2 + 1 a2 2− Dt a2 + 1 a
Lwall = E Lt = 2 E √ ̅̅̅̅̅̅̅̅̅̅̅̅̅ R1− Dt L0
π/2 a2 + 1 π a2 + 1
The water volume remaining in the pore system at a given Pc is
calculated as (Saafan and Ganat, 2021): (23)
∫R ∫
Rmax
Where E is the complete elliptical integral of the second kind and is
√̅̅̅̅̅̅̅̅̅̅̅̅̅̅
Vw = vp (R) (− dN) + vwr (− dN) (18) calculated at a/ a2 + 1. Using Eq. (23), Eq. (22) is evaluated as:
Rmin R
√̅̅̅̅̅̅̅̅̅̅̅̅ ( a ) (σ )2 ( 1− Df − Dt )
∫
Rmax
22− Dt a2 +1 E √̅̅̅̅̅̅̅ ̅ C Pow Df L0 RDmax
f
Rmax − R1− Df − Dt
where R is the average radius of the smallest capillary that will be a2 +1 c
vwr (− dN)= ( )
invaded at a given Pc and is obtained from re-arranging Eq. (13) as: π 1− Df − Dt
R
( √̅̅̅̅̅̅̅̅̅̅̅̅̅̅̅̅̅̅̅̅̅ ) (24)
σ ow cos θr 4GC
R= 1+ 1 − (19)
(1 − a)Pc cos2 θr The water saturation remaining in the pore structure, which com
prises two separate bundles of capillaries (m = 2), at given Pc is:
R determined by Eq. (19) satisfies:
{
Rmin if R < Rmin
R= (20)
Rmax if R > Rmax
( )
⎧ ⎡ 3− D f i − Dt i 3− D − Dt i ⎤⎫
⎪ Ri − Rmini f i ⎪
⎪
⎪ ⎪
⎪
⎪ ⎢ ( ) + ⎥⎪
⎪
⎪
2 ⎨
⎢ 4 Gi 3 − Df i − Dt i ⎥⎪
⎪
∑ Df i ⎢ ⎥⎬
1− Dt i
2 Df i Rmax ⎢
i⎢ √̅̅̅̅̅̅̅̅̅̅̅̅̅ ( ) ( )2 ( ⎥
)⎥
i=1⎪
⎪ ⎢ 2 a2 + 1 E √̅̅̅̅̅̅̅̅̅̅̅̅̅a σ ow 1− D − D 1− Df i − Dt i ⎥⎪
⎪
⎪
⎪ ⎣ Ci Rmaxi f i t i − Ri ⎦⎪
⎪
∑
2 ⎪
⎪ a2 + 1 Pc ⎪
⎪
Vwi ⎩ ( ) ⎭
π (1 + 0.5a2 ) 1 − Df i − Dt i
Sw = i=1 = ⎧ [ ]⎫ (25)
∑2
2 ⎨Df i Rmaxi i Rmaxi i
Df 3− Df − Dt i 3− Df − Dt i
− Rmin i ⎬
Vp i ∑ i
i=1 2Dt i +1 Gi (3− Df i − Dt i )
i=1 ⎩ ⎭
5
M. Saafan et al. Geoenergy Science and Engineering 221 (2023) 111297
3 ΔV Across Across Rw
∑ κw (1 − a2 )2 R1+Dt Rt = = ( )3 ( )
= (28) I L0 ⎧ ⎡ 1− a2 2 R1+Dt i − Df i − R1+Dt i − Df i
i mini
⎤⎫
capillary
23− Dt G L0 ⎪
⎪ ( ) + ⎪
⎪
⎪
⎪ ⎢ ⎥⎪
⎪
⎪
⎪ ⎢ 2Gi 1+Dt i − Df i ⎥⎪
⎪
⎪ ⎥⎪
For partially saturated capillary, i.e., invaded capillary, Aw is given ∑⎨ −
2
D f
⎢ ( )
⎢ 2 ( ) ⎥
⎬
by Eq. (16), and the electrical flow path length is Lwall. Recalling Awr is 2 Dt i D R i
f i maxi ⎢ σ ow D ti − D fi − 1 D ti − D fi − 1 ⎥
i=1⎪
⎪ ⎢ π Ci Rmaxi − Ri ⎥⎪
⎪ ⎢ ⎥⎪
⎪
independent on R, Eq. (26) is expressed as: ⎪
⎪
⎪
Pc
⎣ √̅̅̅̅̅̅̅̅̅̅̅ ( a )( ⎦⎪
⎪
⎪
⎪
⎩ ) ⎪
⎭
∫ Lwall 2
∑ a +1 E √̅̅̅̅̅̅̅̅̅̅̅ Dt i − Df i − 1
1 κw Cr2
(29)
2
= κw Cr2 = a +1
capillary 0 dx Lwall (36)
Using Eqs. (17) and (23), Eq. (29) is represented as: Where Rw is the pore-water resistivity (Rw = 1/κw ). The developed re
( )2 sistivity model in Eq. (36) can be written in terms of porosity using Eq.
∑ πκw C σPowc (12) as:
= √̅̅̅̅̅̅̅̅̅̅̅̅̅ ( a ) (30)
capillary 22− Dt a2 + 1 E √̅̅̅̅̅̅̅ ̅ R1− Dt L0 ⎧ ( )⎫
2 ⎨ Df i Rmaxi i Rmaxi i ⎬
2 Df 3− Df − Dt i 3− Df − Dt i
a +1 − Rmin i
2
∑ i
(1 + 0.5a )
From Ohm’s law, the electric current flowing through each capillary Rw i=1 ⎩ 2Dt i +1 Gi (3− Df i − Dt i ) ⎭
due to a voltage difference ΔV is defined as: Rt = × ( ) 3
( )
φ ⎧ ⎡ 1 − a2 2 R1+Dt i − Df i − R1+Dt i − Df i ⎤⎫
∑ ⎪ i mini
⎪
i(R) = ΔV (31) ⎪
⎪
⎪
⎪ ⎢
(
2 Gi 1 + Dt i − Df i
) + ⎪
⎥⎪
⎪
⎪
capillary ⎪
⎪ ⎢ ⎥⎪
⎪
∑2 ⎨ ⎢ ( ) ⎥⎬
D fi ⎢ 2( ) ⎥
2− D Df i Rmaxi ⎢ σow ⎥
The total current flowing through the pore system at a given pressure
t i Dt i − Df i − 1 Dt i − Df i − 1
i=1 ⎪
⎪ ⎢ π Ci Rmaxi − Ri ⎥⎪
⎪ ⎢ Pc ⎥⎪
⎪
is obtained by adding the electric currents through all the capillaries as: ⎪
⎪
⎪ ⎣ √̅̅̅̅̅̅̅̅̅̅̅̅ ) ⎪
⎦⎪
⎪
⎩ 2
( a ( ) ⎪
⎪
⎭
a + 1 E √̅̅̅̅̅̅̅̅̅̅̅̅ Dt i − Df i − 1
∫R ∫
Rmax 2
a +1
I= i(R) (− dN) + iwr (R)(− dN) (32) (37)
Rmin R
The first term in Eq. (32) defines the current flowing through unin 2.5. Proposed method
vaded capillaries and is evaluated using Eqs. (10), (28), and (31) as:
( ) This section illustrates the method of obtaining drainage capillary
pressure curves from resistivity measurements. The pore structure is
3 Df 1+D − D
∫R ΔVκw (1 − a2 )2 Df Rmax R1+Dt − Df − Rmin t f
i(R) (− dN) = ( ) (33) characterized as two bundles of tortuous capillaries with square and
23− Dt G L0 1 + Dt − Df
Rmin triangular geometries. Generally, the shape factor of a triangle varies
from zero for a slit-shaped triangle to 0.0481 for the equilateral triangle
The second term in Eq. (32) defines the current flowing through the
(Oren et al., 1998). The shape factor of triangular pores is set to 0.024, i.
corners fluids of invaded pores and is evaluated using Eqs. (10), (30),
e., the median value of slit-shaped and equilateral triangles. Moreover,
and (31) as:
the pore fractal dimension of each bundle is calculated as (Yu and Li,
2002):
ln(φ)
Df = 2 − (38)
ln(Rmin /Rmax )
Table 1 Table 1 provides a rule of thumb for estimating Rmin/Rmax using the
Empirical range of Rmin/Rmax as function permeability of the rock sample. The lower the permeability, the
permeability. broader range of the pore size.
K (md) Rmin/Rmax Thomas et al. (1968) correlated the threshold pressure with porosity,
<0.5 10− 6 - 10− 5 permeability, surface tension, and formation resistivity factor as:
0.5–5 10− 5 - 10− 4 √̅̅̅̅̅̅̅̅̅̅
5–50 10− 4 - 10− 3 0.1461 × 10− 3 σ 1000
PT = √̅̅̅̅̅ (39)
>50 10–3 ko F φK
6
M. Saafan et al. Geoenergy Science and Engineering 221 (2023) 111297
where PT is the threshold pressure, F is the formation resistivity factor, 3. Results and discussions
and ko is the shape factor that varies between 2 and 3. A little error is
introduced by using ko value between 2 and 3 since it is raised to the one- This section shows a comparative analysis of validating the proposed
half power, and in this work, ko is set to 2.5. Also, Eq. (39) yielded results model. The model results are compared with the experimental data and
between +50% and − 70% error lines compared to laboratory mea the results of other literature models. Table 3 displays the measured
surements (Thomas et al., 1968). porosity, permeability, and fully saturated resistivity of the eighteen
There are nine unknowns in Eqs. (37), which are Rmax1, Rmax2, Rmin1, core samples. The porosities range from 6.8% to 15.8% and perme
Rmin2, Dt1, Dt2, Df1, Df2, and a. Rmax1 and Rmax2 are determined using the abilities from 0.36 to 63 mD. Also, the samples’ drainage capillary
threshold pressure of each pore set, i.e., PT1 and PT2, using Eq. (19). pressure curves and resistivity measurements are displayed in Fig. 8 and
Afterward, Rmin1 and Rmin2 are obtained using Rmin1/Rmax1 and Rmin2/ Fig. 9.
Rmax2 from Table 1. Then, the pore fractal dimensions, i.e., Df1 and Df2,
are calculated from Eq. (38), which require the porosity of each bundle. 3.1. Comparisons with laboratory measurements
As the sample porosity is measured, the porosity of one set is utilized to
calculate the other. Therefore, eight parameters are required to calculate The steps shown in Fig. 7 are employed to obtain the capillary
resistivity, which are PT1, PT2, Rmin1/Rmax1, Rmin2/Rmax2, Dt1, Dt2, φ1, and pressure curves for the eighteen core samples using resistivity mea
a. surements. The MAPE is calculated and displayed in Table 4. The MAPE
The genetic algorithm (GA) is employed to adjust the eight param of the eighteen core samples ranges between 2.4% and 39.4%, with a
eters and minimize the error between the results of the fractal resistivity median of 11.3%. Moreover, the mean MAPE is 13.3%, with one stan
model and laboratory-measured resistivity. The GA optimization steps dard deviation of 9.8%.
are summarized as follows: Fig. 10 depicts the calculated versus laboratory-measured drainage
water saturation of the eighteen core samples with an error factor of
1. Generate a random initial population of individuals, utilizing the ±0.1. From the preceding analysis, the proposed method of obtaining
search space limits of the eight parameters shown in Table 2. drainage capillary pressure curves using resistivity measurements yields
2. Calculate the fitness of each individual. The fitness function is rep a good match with laboratory measurements.
resented by the mean absolute percentage error (MAPE) between the
calculated and laboratory-measured resistivity.
3.2. Comparisons with literature models
N ⃒ ⃒
100 ∑ ⃒Rt model − Rt laboratory ⃒
MAPE = ⃒
⃒
⃒
⃒ (40) The suggested approach for obtaining capillary pressure curves from
N i=1 Rt laboratory
resistivity measurements is compared with three different models from
the literature, i.e., Kwon and Pickett (1975) (Appendix B), Pittman
3. Select two individuals for crossover, and with a crossover probability (1992) (Appendix C), and Li et al. (2019). Li et al. correlated the
of 0.7, exchange strings and create two offsprings. dimensionless capillary pressure to the resistivity index. However, they
4. With a mutation probability of 0.01, randomly change genes in the did not introduce a way to calculate the capillary entry pressure.
offspring. Therefore, we utilize Eq. (39) to obtain the entry pressure and calculate
5. Place the resulting individuals in the new population. Li et al.’s capillary pressure curves. Fig. 11 graphically compares the
6. Repeat steps 3–5 until the new population size is obtained. calculated drainage curves of the eighteen core samples from our pro
7. Replace the existing population of chromosomes with the new posed and literature models.
population. Known and Pickett’s model calculates the capillary pressure for
8. Repeat steps 2–7 until the stopping condition is reached. water saturation from 0.3 to 0.9. Consequently, we only calculate the
9. Determine the eight parameters, i.e., PT1, PT2, Rmin1/Rmax1, Rmin2/ MAPE in the mentioned water saturation range to have a representative
Rmax2, Dt1, Dt2, φ1, and a, of the fittest individual. comparison between different models. The MAPE of the computed
capillary pressure from the various models is summarized in Table 5.
The optimized model parameters are then utilized in the capillary The best-performing model, i.e., the lowest MAPE, is highlighted in bold
pressure model, i.e., Eq. (25), to generate the drainage Pc - Sw curve. for each sample. The proposed model outperforms the literature models
Fig. 7 displays the detailed methodology for obtaining capillary pressure for fourteen samples of the eighteen, i.e., S1, S4, S6 – S12, and S14 – S18.
curves from resistivity measurements, and the steps are as follows: On the other hand, the Known and Pickett model outperforms for
samples S2, S3, and S13. While Pittman’s model only outperforms for
1. Calculate PT from Eq. (39). sample S5. Moreover, Li et al.’s model has a high MAPE compared to
2. Determine the range of Rmin/Rmax from Table 1. other models, attributed to the dependency of their model on the
7
M. Saafan et al. Geoenergy Science and Engineering 221 (2023) 111297
Fig. 7. Flow chart of obtaining the drainage capillary pressure curve from resistivity data.
8
M. Saafan et al. Geoenergy Science and Engineering 221 (2023) 111297
Table 3
Porosity, permeability, and fully saturated resistivity of the eighteen core plugs.
Sample φ (%) K R0 (Ω. Sample φ (%) K R0 (Ω.
(md) m) (md) m)
9
M. Saafan et al. Geoenergy Science and Engineering 221 (2023) 111297
Fig. 11. Calculated capillary pressure curves from our proposed model and literature models versus laboratory measurements.
10
M. Saafan et al. Geoenergy Science and Engineering 221 (2023) 111297
Fig. 12. Box and whisker plot of MAPE for the different models.
Declaration of competing interest
Data availability
Nomenclature
11
M. Saafan et al. Geoenergy Science and Engineering 221 (2023) 111297
Consider a curve (Fig. A1) that varies sinusoidally according to the following equation:
y = a sin x (A.1)
The length of the arc, ds, connecting two points as in Fig. A2 is approximated using Pythagoras theorem:
√̅̅̅̅̅̅̅̅̅̅̅̅̅̅̅̅̅̅̅̅̅̅
( )2
√̅̅̅̅̅̅̅̅̅̅̅̅̅̅̅̅̅̅̅̅̅̅̅̅̅̅̅
dy
ds ≈ (dx)2 + (dy)2 = 1 + dx (A.2)
dx
where dx and dy represent the horizontal distance and the vertical height of the right-angled triangle.
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M. Saafan et al. Geoenergy Science and Engineering 221 (2023) 111297
The integration of the infinitely small distances for the distance between x = 0 and x = X is:
√̅̅̅̅̅̅̅̅̅̅̅̅̅̅̅̅̅̅̅̅̅̅
( )2
∫X ∫X
dy
L= ds = 1+ dx (A.3)
0 0 dx
dy
= a cos x (A.4)
dx
Using Eq. (A.4), the length of the arc given by Eq. (A.3) is expressed as:
∫ X √̅̅̅̅̅̅̅̅̅̅̅̅̅̅̅̅̅̅̅̅̅̅̅̅̅̅
L= 1 + a2 cos2 x dx (A.5)
0
where E represents a complete elliptical integral of the second kind evaluated at k as:
∫ π2 √̅̅̅̅̅̅̅̅̅̅̅̅̅̅̅̅̅̅̅̅̅̅̅̅̅
E(k) = 1 − k2 sin2 θ dθ (A.8)
0
MATLAB is used to evaluate E using the following command line, [~,E] = ellipke (k). As shown in Fig. A3, the value of E changes from E(0) = π/2 to
E(1) = 1. Hence, for a = 0, E(1) = 1 and the length of the elliptical curve L equals X.
Fig. A.3. Evaluation of the complete elliptical integral of the second kind.
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M. Saafan et al. Geoenergy Science and Engineering 221 (2023) 111297
For in the Sw in the range from 30% to 90%, a relation between Pc and k/φ was presented as follows:
Pc = A(K/φ)− B
(B.1)
where Pc is mercury-air capillary pressure from measurement on cores, K is air permeability (md), and φ is porosity (%). The empirical
values for A and B are shown in Table B1.
Table B.1
Empirical values of A and B (Kwon and Pickett, 1975).
Sw (%) Log A B
30 2.18 − 0.407
40 1.97 − 0.455
50 1.81 − 0.468
60 1.67 − 0.452
70 1.56 − 0.446
80 1.47 − 0.440
90 1.36 − 0.428
The empirical equations for determining pore aperture radii in μm corresponding to various mercury saturations are shown in Table C1.
Table C.1
Pore aperture radii corresponding to various mercury satura
tions (Pittman, 1992).
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