Copper (Nearly) : Vo (B + 2a)
Copper (Nearly) : Vo (B + 2a)
L,
D6.5
2) 8.5
5. 3) 7.5 4) 10
An ideal gas
undergoes process
a in
which the coefficient volume
varies with absolute expansion of gas y
temperature asy= Let C' be the molar
heat capacity in this
process and Cp. are molar specific heats at
then constant pressure and volume respectively
I) C=3C +2R 2) C= 2C +2R 3) C=Cy + 2R
Al an altitude of about 12.5km the
4) C =C +R
21.8K Pa. The amount ofH, gas (intemperature is around-55°C and the pressure is around
kilograms) to be put in a balloon to fill it to 2000m?
at that altitude is 25
R:
R= SI units
3
l) 96 2) 69 3) 50 48
When a thermodynamic system of ideal gas is taken from
state a' to state b` as shown
in the figure. along the path a ’c’b 60J of
heat flows into the system and 30J of work
done by gas. If internal energy values at a and d are
respectively 2J and 24J then the ratio
of heat absorbed in the process a -dand d- bis (Also
given thal work done by thesystem
when it is taken along a ’d’b is 10J)
2gx02000
(2-5
P C
3) 2 4)8
Page 2
D8.
One mole of
and volume areideal mnono
respectively atomic
(Given y= 5/3 and 3 =
gas is
10$ Nm andcompressed
6 litres.
Theadifinal
abatically. The initial
9. 1)957J
A
6.19).The change in inlernal energyvolunme
2) + 957)
of
of the gas ispressure
2 litres
barometer gives wrong reading 3) 619)
At a
gas in
4) - 319J
pressure
of Hg P=75Smm llg thebecause some air is present above the
740mmn
shows barometer
the
the
mercury
I) 784mm
level barometer
is 736mm. the
shows 748mm. and at mercury colunn.
actual length of the preSsure
10,
The
2) 760mm baromeler tube aboe
magnitude of
ideal gas by 30°C amount of work done in
3) 764mm
4) 755nmm
the increasing temperature of one mole ol an
if it the
have their own expands under
is (R = 8.31 SI condition V«TIS (where
l) 166.2J meanings)
2) 186.2J units) individual letters
. Two moles of 3) 146.2J
diatomic gas is taken thorough the
and T is absolute 4) 165J
the amount of temperature of gas. If its process PT =const where P is
|) 2RT.
vork done by the system is temperature increases from T, K topressure
2) 3RT, 21, K
12. A vertical 3) 8RT,
cylinder
parts. The two partscontains movable friction less piston fART,
upper and lower
are filled with ideal gas and at separating the cy linder into two
becomes portions is 5:3. cquilibrium. the
3:2. Then the ratio of When the temperature of systen isratio of volunes of
is number of moles in the upper to that in doubled the ratio
the lower porion
l) 26:35
2) 35:26
13. Two 3) 35:19
identical vessels A and B contain one 4) 25:19
P, and that in B is
P'. The r.m.s
mole ofO each. The pressure in
velocity of vessel A is
The vessel A is at rest and
B is moving wih molecules in both the
vessels arc cqual
following is correct. constant speed V., then which ol the
Imole l mole
of O, of O,
Vessel A Vessel B
2.
2)14P,, 3) 1.1P,V,
D2.5Pl,
insulated cylinder into two parts of volumes V
I$. A ueightless piston di ides a themally atmospheres are contined to the part with
and 3V. 2 moles of ideal gas at pressure P=2
evacuated.The piston is now released and
olume V. The remainder of the cylinder is
cylinder. The piston is now pressured back
the gas evpands to fill the entire space of the
V = Ilitre y= 3/2then the increase in
to the initial position. Given latm = 10 pascal
internal energy of gas in their process is
2) 300 J 3) 100 J 4) 400 J
D200 J
where T is absolute temperature of gas then
a|6. IfC for an ideal gas is taken as G =3+2T
the equation for adiabatic process for this gas is
) T' =const 2) Te =const
3) 1RT2T =cOISt 4) T'c =const
takes t, seconds to cool from 90°C
17. A bucket full of water (hot) is placed in a room. Water 70°Cto 60°C
ti seconds to cool from
to 80°C. t seconds to cool from 80°C to 70°C and
then
2) 1 =1) =3 3) >14 >i; 4) 1 <Ih =l;
The air temperature is
el8. In a 1Om deep lake the bottom is at constant temperature 4°C.
constant at -4°C. The thermal conductivity of ice is 3 times that of water. Neglecting
expansion of water on freezing the maximum thickness of ice will be
)7.5m 2)6m 3) 5m 4) 2.5m
19. A c linder filled with apiston which can slide without friction contains one mole of an
ideal gas. The walls of the cy linder and piston are adiabatic. The cylinder contains a
resistance R = 2000 2 which is connected to a capacitor of capacitance C= 75mF.
640
Initially the PD across capacitor is V and switch S is open. When S is closed for
3
(2.5 In4) minutesthe gas expands isobarically and its temperature increases by 72K. Heat
Page 4
loss through wire is negligible and R=8.3 Slunits. The approximate values of workdone
by gas and the increment in the internal energy of' gas are respectively
Po.
1) 2) 30 20 20
3) 4)
s(P,A +Mg) 5(P,4+ Mg) 5(P,A +Mg) 5(P,4- Mg)
21. 2 grams of steam at 100°C is mixed with 5gm of ice at -40°C in an ideal calorimeler. The
final temperature of system will be (Given L of' steam = 500 cal gm.
Sice = 0.5Cal / gm° C, S wvater = 1Cal / gm° C,L ice = 80Cal / gm)
I) 0°C 2) 100°C . 3) 80°C 4)50°C
22. A smooth partition divides a horizontal cylinder into two equal part. with one part
containing H: gas at STP and the other part contains vacuum. Initially the partition is held
in position and the walls of cylinder are adiabatic. If the partition is removed then gas
fills the whole cylinder, then which of the following are correct.
A) The work done by the gas is zero.
B)The internal energy of gas is constant i.e. doesn't change.
C) The pressure of gas decreases.
1) Only A is correct 2) Only B is corect
3) Only A&B are correct 4) A. B.Call are correci
2x Page 5
Rushike in ihe tigure shoWn apiston divdes ylindrical container into tvO equal parts, ls
nart cmtains I moie of He gas nd the right prt contains 2 moles of 0: gas.
iemperture and pressures in he lett and right chambers are as
The in:a:
shown. The pislon *
gases mix
nallk otinder are adiabaic. Aier removal of piston the
and the final pressure bccOmes homogencously
2 mole of
He
Po. lo 2
13P) 3) 12P 4)
Mgx 12 13 13
Iour identical samples of same poly atomic idcal gas undergo addition of same amount
PI'=C,P=C, Py'=C
of heat under tour difterent processes namely P = C .
where individual letters have their own meanings and ' is constant. Final internal
energy i} be maximum for sample which has undergone.
2) P 2 -C 3) P= 4) PV2=c
2* The tigure shows the variation of intermal energy wih density pof one mole of an ideal
mone atom ic gas. The wOrk done in the process is
B
2U
2p, Sp, P
Page 6
He
2P,
P,
I 2, '
28. An ideal monoatomic gas undergoes an isobaric process. Then the ratio of and
P-V indicator diagram of Imole of an idealgas is as shown inthe figure. The maximum
temperature between A and Bis
PA
2P
P
2.1R
w
RHATAYAAT ACIDEN INDIA 3-202! Srl'ERo0_Jee-Main GT\IO 0 b
CHEMISTRY Max Marks: 100
(SINGLE CORRECT ANSWER TYPE)
con be
oo-o ()
O-o0. (2)
here xk . and k. are the rate cOnstuts
which of uie following 1s
Assumng stead stare appruNnation for reacton intermediate
Comect.
k,k, [o, K,
Co3)
)- 0 2) -9]_.
[O.j-<o,)
4) - ) , *k[o,}'
3) dt
3) TeOF,
2) TFIT 4) FFTF
Page
INDIA
SRI CHAITANYA IIT ACADEMY, 23-03-2022 Sr.sPLR60 Jee-Nlain GI\-01_Q.1"
35 Which of the lollowing statement(s) is'are coec?
)The atomic and ionic radii of alkaline carth metals are smaller than those of the
corresponding alkali metals in the same perods.
ii) Second ionisation cnthalpies ofthe alkaline carth metals are smaller than those of the
corresponding alkali metals.
(ip) Compounds of alkaline carth metals are more extensivelh hy drated than those of alkali
metals
-radius
Atomic
A B E
Sec: Sc.SUPERG0
Page 12
SRICHAITANYAIIT GIM-01 Q.P
ACADEMY, INDA 2303-2022 Sr.s PERo0 Jee-Main
Consider the tollow ing scheme.
'NH,
(A)
NH
OH
NH.
(B)
hich psitions are aetivatedfor coupling reaction in acidic andbasic media respectively?
in A and Bin B 2) x in A and a in B
)
CH,-=cH, CD, -Ü-CD,
OD
CH, --CH,D 4)
CD, =C-CD;
3)
41. Ghcerol is obtained from propylene (CH,CH =CH,) by using the following reagents:
I.C,'at773K) II. Na,CO; III. HOCI IV. NaOH
psoh
1) In acidic solutions. protons coordinate with ammonia molecules foming NH; ions and
NH, molecules are not available.
H
H H
H
HCI
CH,
) Enantiomers 2) Diastereomers
same compound
Structuralisomers 4) Two molecules of the
is compressed to half of its initial volume and simultaneously
49. hen one mole of an ideal gas
change in entropy IS
heated to IW ice its initial temperature irreversibly. the respcctively)
constant pressure and volume
Co andC are molar heat capacities of gas at
1) C In 2 4) (C, -R) In 2
3) R In 2
2) C, In 2
used to removing oil on hand
Which of the follow ing is micellar system
I) Sodium stearate - water 2) Rubber + benzene
to nearest integer
Report magnitude of E"|Hg;/Hg) in volts
/F= 0.06
(iven that E"(Ie* /Fet|=0.77V. 2.303RT
to first decimal
Report the valuc after rounding off
cquivalent of C,H,ONa in ethanol, only one
52. I: 2. 4dichloropentane is treated with one
pentenes (including
HCicliminated to give chloro pentene How many different chloro
iurcoomers) would be formed?
Page 15
ACADEMY, INDIA 23-03-2022 Sr.S PER60 Jee-Main GTM-01 Q.P
SRI CHAITANYA IIT
53. Ahydrocarbon (X) contains 91.3% carbon and 8.8% hydrogen. Xon chlorination using
CL/hv gives compound Yand with Cl,/AICI, gives three isomeric monochloro
substituted products of Y(considering major as well as minor products). Total maximum
number of atoms present on one of possible planes of Xis ab.
(a+b) is.... Here a and bare integers and acan be zero)
54. Alomic number of Cr is 24. Onc of the ions of the metal in aqueous solution has a magnetic
moment 4.9 BM. What is the difference in the number of electrons of the ion with clockwiSC
andanticlockwise self-spins in ground state of aqucous ion?
55. Oxidation state of nickel in the compound formed during purification of nickel in vapour
phase refining is...
RCONH, +XNaOH+Br, ’ RNH, +2NaBr +Na,C0, +H,0
Number of moles of NaOH used in above Hoffman's bromamide reaction per mole of the
amide is..4.
57. Ametal Mof molar mass 96 gm/mole reacts with fluorine to form a salt that can be
represented by empirical formula MF,. Inorder to determine x. a41.20gm of the sample of
the salt is dissolved in 100gm of water and its boiling point was determined to be 374,38K.
If degree of dissociation of salt is 10what is value of x? Given
K,(water)=0.512K kg/mole.
58. For atriprotic acid H,A,K4, is 10.K, is I0 and Ku, is l0-".Requisite moles of NaOHare
added to 0.1 molar H,4 to form maximum H4 At what pH (to nearest integer). this
would occur ?
59. How many grams of sucrose (mol. Wt. =342) should be dissolved up to the ncarest integer
in 100gm water in order to produce a solution with 105°C difference betwcen the treezing
point &boiling point temperature at I atm?
(Unit: k, =2 Kkg mol", k, =0 SK kgmol' )
60, Atiny spherical ball of water-soluble solute is dropped in Iliure of water. Mass of ball is
gim and molecular mass of solute is 125u. Decerease in surface area due to dissolutionfollows
Ist order of half-life period l sec. and after2 sec. molarity of solution is 10, Find the
value of x.
Quetlos Eoh question ur4optionn () (), (3) ot (4) for ity amwer, oul
Max Marks: 100
scheme +4 for
corect aniwer Oi not
of whlch ONLY ONE optlon con be
The atemptd ond-I
cqulion otpair olngular in all other oses.
l() passing througlh (|, I) satislics -=x'+\y +y´. then the curve is
ds
1)
2) x= ytan( fns)
2) 7 4) 5
l6
Itthe tangent at a point4cos . to the cllipse 16x' +lly = 256 is also a tangent
Page 17
scCIAITANYA IT ACADEMY, INDIA 23-03-2022 SrsP.R60 Jer-Main G10 9.P
I(.y. z) be an arbitrary point lying on aplane Pwhich passes through the point 42. 0. 0).
(0. 42. 0) and (0, 0, 42). then the value of expresion
y-19 -12
(y-19)'(-12)' (x-1j(-12) (x-1I'(y -19) 14-)(y-19)7-12)
1) 0 3) 39 4) 45
lun'x
The valuc of the integral -dx is
x+1+ 2x
30
2) 4)
8
68. Aclass has 20 students. Ateacher makes certain viit to the z00 along with 2students fron
the class. TIhe tcacher visits z00 with allpossible selections of 2students cxactly once. Fnd
the number of takes teacher makes vísit to the zoo more than any particular student.
If the cquation of plane through straicht ine y+2 and perpendicular to the planc
2 -3
I)a 2) b 3)c
Sec:Sr.SUPERG0 P'agc 18
+n
SRICHAIYANYA T
ACADEMY,INDIA 23-03-2022_ Sr SPRG0 Jee-Main GIMO 0.P
tnskler the ntegral | d.Whcre (] denotes the, 2reatest integer less than or
Cqual to lhen the valuc ot / iN cqual to
2) 45 (e ) 4) 9e + )
The arca of the triangle formed by cordinate axes and tangent at vertex to thc parabola,
whose focus is (. 4) and langents are x= (0, 1=0 IS sq. units
2) 3 3)6 4)4
2) 0 3) 2 4) -1
"5. Let thc lenghs of intercepts on x-axis and y-axis made by the circle
-y-ax -2ay -c=0. (a< 0)be 2V2 and 2V5. respectively. Then the shortest distance
irom origin to a tangent to this circle which is perpendicular to the line x + 2y = 0.
Scquad to
2) \7 3)V6 4) V10
Area bounded hy the lines 7x 5y + 3 -0. l6x +y= 14. 13x =2y +17 is
2
2) 3) 3
2 v3
Page 19
SRICIHAITANYA IIT ACADEMY, INIIA 23-03-2022 Sr.st iPEPG0 Jee-Main (,I \11 ).!
2x
(independent of n). Then the sum of all possible valucs ofx
X
77. Given I(x)sin .sin
) {0. I. 2. 3} 2) {1.2. 3} 3) 0. 2, 3}
79. Consider arcctangle ABCD having 5, 7, 6. 9points in the interior of the line scgments AB.
CD, BC, DA respctively. Let a be the number of triangles having these points from
ditferent sides as vertices and ß be the number of quadrilaterals having these points from
different sides as vertices. Then (ß-a) is cqual to :
a' b
|80. The minimum distance of the curve -=1 form origin is (a. b>0)
2
I) a-b| 2) la +b 3) ab 4) a'+b
(NUMERICAL VALUE TYPE)
Section-l contalns 10 Numericol Value Type questios. Amempt any 5 questions only. Art 5
otempted questiom will be considered if more than 5
questlons attempted. The Answer should be within 0to 9999. Hthe Answer is in Decimal then round off to the nearest
Integer valve Exomple ie. if am wer
Is above 10 ond less than 10.5 round off is 10 and If answer s from 10.5 and less thon ll rond of is 11).
Marking sheme: +4 for corret onswer, 0 if not atempt ond -1 in all other cases.
25-|2.3
3 4
+..... +
24
Then s is
|+
Sec. Sr.SUPERGU
Jee-Main GTM-41 ).P
SRI CHAITANYA IIT ACADEMY, INDIA 23-03-2022 Sr.sUPERG0
complex variables) then the minimum valuc
82.
|4|(-)z, +(1+i)z, 8/2.(Z.Za
= are
of 2-z s 1
is
II a and b are any two unit vectors. then the minimum vaue o
84.
Let e*x(4x° +4x'+ 5x +I}dx ex(x)
= +e. Then r(0) is
found to be
unknown colors. A ball is drawn at random from itand is
A bag contain 5 balls of
balls is
white. The probability that bag contains onlywhite
-1)(x²-2)(x'-3.x-20) is
86. The coefficient of x210 in the expression (x
87. If a,ß are roots of the quadratic
equation x- bx + c= 0(b.c e R) such that
Consider the function f(x)= lim cos then the number of solution of equation
Im.
+og
Dog
Sec: Sr.SUPERGO Page 21