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Chemistry: A Molecular Approach, Second Cdn. Ed. (Tro)
Chapter 6 Thermochemistry
2) Which of the following signs on q and w represent a system that is doing work on the
surroundings as well as losing heat to the surroundings?
A) q = - , w = -
B) q = +, w = +
C) q = -, w = +
D) q = +, w = -
E) None of these represent the system referenced above.
Answer: A
Diff: 1 Type: MC Var: 1 Page Ref: 6.3
3) Which of the following signs on q and w represent a system that is doing work on the
surroundings as well as gaining heat from the surroundings?
A) q = +, w = -
B) q = -, w = +
C) q = +, w = +
D) q = -, w = -
E) None of these represent the system referenced above.
Answer: A
Diff: 1 Type: MC Var: 1 Page Ref: 6.3
1
Copyright © 2017 Pearson Canada, Inc.
5) Calculate the change in internal energy (ΔU) for a system that is giving off 45.0 kJ of heat and
is performing 855 J of work on the surroundings.
A) 44.1 kJ
B) -44.1 kJ
C) -45.9 kJ
D) 9.00 × 102 kJ
E) -9.00 × 102 kJ
Answer: C
Diff: 1 Type: MC Var: 1 Page Ref: 6.3
2
Copyright © 2017 Pearson Canada, Inc.
10) Identify the unit of heat capacity.
A) J °C-1
B) J g-1 °C-1
C) J mol-1 °C-1
D) g °C-1
E) mol °C-1
Answer: A
Diff: 1 Type: MC Var: 1 Page Ref: 6.4
12) A piece of iron (C = 0.449 J g-1 °C-1 and a piece of gold (C = 0.128 J g-1 °C-1) have
identical masses. If the iron has an initial temperature of 498 K and the gold has an initial
temperature of 298 K, which of the following statements is TRUE of the outcome when the two
metals are placed in contact with one another? Assume no heat is lost to the surroundings.
A) Since the two metals have the same mass, the final temperature of the two metals will be 398
K, exactly halfway between the two initial temperatures.
B) Since the two metals have the same mass, but the specific heat capacity of gold is much
smaller than that of iron, the final temperature of the two metals will be closer to 298 K than to
498 K.
C) Since the two metals have the same mass, the thermal energy contained in the iron and gold
after reaching thermal equilibrium will be the same.
D) Since the two metals have the same mass, the thermal energy contained in each metal after
equilibrium will be the same.
E) None of the above is true.
Answer: D
Diff: 1 Type: MC Var: 1 Page Ref: 6.4
13) Which of the following substances (with specific heat capacity provided) would show the
greatest temperature change upon absorbing 100.0 J of heat?
A) 10.0 g Ag, CAg = 0.235 J g-1 °C-1
B) 10.0 g H2O, = 4.184 J g-1 °C-1
C) 10.0 g ethanol, Cethanol = 2.42 J g-1 °C-1
D) 10.0 g Fe, CFe = 0.449 J g-1 °C-1
E) 10.0 g Au, CAu = 0.128 J g-1 °C-1
Answer: E
Diff: 2 Type: MC Var: 1 Page Ref: 6.4
3
Copyright © 2017 Pearson Canada, Inc.
14) Which of the following (with specific heat capacity provided) would show the smallest
temperature change upon gaining 200.0 J of heat?
A) 50.0 g Al, CAl = 0.903 J g-1 °C-1
B) 50.0 g Cu, CCu = 0.385 J g-1 °C-1
C) 25.0 g granite, Cgranite = 0.79 J g-1 °C-1
D) 25.0 g Au, CAu = 0.128 J g-1 °C-1
E) 25.0 g Ag, CAg = 0.235 J g-1 °C-1
Answer: A
Diff: 2 Type: MC Var: 1 Page Ref: 6.4
15) Calculate the amount of heat (in kJ) required to raise the temperature of a 79.0 g sample of
ethanol from 298.0 K to 385.0 K. The specific heat capacity of ethanol is 2.42 J g-1 °C-1.
A) 57.0 kJ
B) 16.6 kJ
C) 73.6 kJ
D) 28.4 kJ
E) 12.9 kJ
Answer: B
Diff: 2 Type: MC Var: 1 Page Ref: 6.4
16) Calculate the amount of heat (in kJ) necessary to raise the temperature of 47.8 g benzene by
57.0 K. The specific heat capacity of benzene is 1.05 J g-1 °C-1.
A) 1.61 kJ
B) 16.6 kJ
C) 2.59 kJ
D) 2.86 kJ
E) 3.85 kJ
Answer: D
Diff: 2 Type: MC Var: 1 Page Ref: 6.4
17) Determine the specific heat capacity of an alloy that requires 59.3 kJ to raise the temperature
of 150.0 g alloy from 298 K to 398 K.
A) 4.38 J °C-1
B) 2.29 J °C-1
C) 3.95 J °C-1
D) 2.53 J °C-1
E) 1.87 J °C-1
Answer: C
Diff: 2 Type: MC Var: 1 Page Ref: 6.4
4
Copyright © 2017 Pearson Canada, Inc.
18) A sample of copper absorbs 43.6 kJ of heat, resulting in a temperature rise of 75.0 °C.
Determine the mass (in kg) of the copper sample if the specific heat capacity of copper is 0.385 J
g-1 °C-1.
A) 1.51 kg
B) 6.62 kg
C) 1.26 kg
D) 7.94 kg
E) 3.64 kg
Answer: A
Diff: 2 Type: MC Var: 1 Page Ref: 6.4
19) Determine the final temperature of a gold nugget (mass = 376 g) that starts at 398 K and
loses 4.85 kJ of heat to a snowbank when it is lost. The specific heat capacity of gold is 0.128 J
g-1 °C-1.
A) 133 K
B) 398 K
C) 187 K
D) 297 K
E) 377 K
Answer: D
Diff: 3 Type: MC Var: 1 Page Ref: 6.4
20) A balloon is inflated from 0.0100 L to 0.500 L against an external pressure of 10.00 bar.
How much work is done in joules? (100 J = 1 L bar)
A) -49.0J
B) 49.0 J
C) 0.490 J
D) -0.490 J
E) -490 J
Answer: E
Diff: 3 Type: MC Var: 1 Page Ref: 6.4
5
Copyright © 2017 Pearson Canada, Inc.
22) Calculate the change in internal energy (ΔU) for a system that is giving off 25.0 kJ of heat
and is changing from 12.00 L to 6.00 L in volume at 1.50 bar. (Remember that 100 J = 1 L bar)
A) +25.9 kJ
B) -16.0 kJ
C) -25.9 kJ
D) -24.1 kJ
E) 937 kJ
Answer: D
Diff: 2 Type: MC Var: 1 Page Ref: 6.5
23) Calculate the change in internal energy (ΔU) for a system that is absorbing 35.8 kJ of heat
and is expanding from 8.00 to 24.0 L in volume at 1.00 bar. (Remember that 100 J = 1 L bar)
A) +51.8 kJ
B) -15.8 kJ
C) -16.6 kJ
D) -29.3 kJ
E) +34.2 kJ
Answer: E
Diff: 2 Type: MC Var: 1 Page Ref: 6.5
24) A 6.55 g sample of aniline (C6H5NH2, molar mass = 93.13 g ) was combusted in a
bomb calorimeter. If the temperature rose by 32.9 °C, use the information below to determine the
heat capacity of the calorimeter.
A) 97.3 kJ
B) 38.9 kJ
C) 5.94 kJ
D) 6.84 kJ
E) 12.8 kJ
Answer: D
Diff: 3 Type: MC Var: 1 Page Ref: 6.5
6
Copyright © 2017 Pearson Canada, Inc.
25) Calculate the internal energy change, ΔrU, for the combustion of 29.3 g of vitamin C
(C6H8O6, molar mass = 176.124 g mol-1) if the combustion inside a bomb calorimeter, Ccal =
8.31 kJ °C-1, causes a temperature change from 21.5 °C to 68.3 °C.
A) -1.78 × 103 kJ mol-1
B) -2.34 × 103 kJ mol-1
C) -6.03 × 103 kJ mol-1
D) -9.19 × 102 kJ mol-1
E) -1.67 × 102 kJ mol-1
Answer: B
Diff: 3 Type: MC Var: 1 Page Ref: 6.5
26) Calculate the internal energy change, ΔrU, for the combustion of 9.467 g of L-alanine
(C3H7NO2, molar mass = 89.094 g mol-1) if the combustion inside a bomb calorimeter, Ccal =
7.83 kJ °C-1, causes a temperature change from 24.7 °C to 46.1 °C.
A) -1.58 × 103 kJ mol-1
B) 6.14 × 103 kJ mol-1
C) -3.48 × 103 kJ mol-1
D) -8.60 × 102 kJ mol-1
E) 3.84 × 103 kJ mol-1
Answer: A
Diff: 3 Type: MC Var: 1 Page Ref: 6.5
27) Calculate the internal energy change, ΔrU, for the combustion of 6.9261 g of diethylene
glycol (C4H10O3, molar mass = 106.120 g mol-1) if the combustion inside a bomb calorimeter,
Ccal = 13.84 kJ °C-1, causes a temperature change from 22.8 °C to 34.0 °C.
A) -4.39 × 103 kJ mol-1
B) -9.16 × 102 kJ mol-1
C) -2.37 × 103 kJ mol-1
D) 4.39 × 103 kJ mol-1
E) 1.18 × 103 kJ mol-1
Answer: C
Diff: 3 Type: MC Var: 1 Page Ref: 6.5
7
Copyright © 2017 Pearson Canada, Inc.
28) A chemist wishes to calibrate a bomb calorimeter, so he combusts 7.529 g of D-galactose,
ΔcombustionU = -15.48 kJ g-1, which causes a temperature change from 26.38 °C to 34.60 °C.
What should the chemist report for the value of Ccal?
A) 24.34 kJ °C-1
B) 8.009 kJ °C-1
C) 14.18 kJ °C-1
D) 16.67 kJ °C-1
E) 9.170 kJ °C-1
Answer: C
Diff: 3 Type: MC Var: 1 Page Ref: 6.5
29) A chemist wishes to calibrate a bomb calorimeter, so she combusts 5.58 g of 4-pentenoic
acid, ΔcombustionU = -26.77 kJ g-1, which causes a temperature change from 23.4 °C to 38.9
°C. What should the chemist report for the value of Ccal?
A) 6.10 kJ °C-1
B) 17.5 kJ °C-1
C) 28.7 kJ °C-1
D) 9.64 kJ °C-1
E) 7.61 kJ °C-1
Answer: D
Diff: 3 Type: MC Var: 1 Page Ref: 6.5
30) A 21.8 g sample of ethanol (C2H5OH) is burned in a bomb calorimeter according to the
following reaction. If the temperature rises from 25.0 °C to 62.3 °C, determine the heat capacity
of the calorimeter. The molar mass of ethanol is 46.07 g .
A) 4.99 kJ °C-1
B) 5.65 kJ °C-1
C) 63.7 kJ °C-1
D) 33.1 kJ °C-1
E) 15.7 kJ °C-1
Answer: E
Diff: 3 Type: MC Var: 1 Page Ref: 6.5
8
Copyright © 2017 Pearson Canada, Inc.
31) A 4.98 g sample of aniline (C6H5NH2, molar mass = 93.13 g ) was combusted in a
bomb calorimeter with a heat capacity of 4.25 kJ . If the temperature rose from 29.5 °C to
69.8 °C, determine the value of U for the combustion of aniline.
A) +7.81 × 103 kJ mol-1
B) -3.20 × 103 kJ mol-1
C) +1.71 × 103 kJ mol-1
D) -1.71 × 103 kJ mol-1
E) -7.81 × 103 kJ mol-1
Answer: B
Diff: 3 Type: MC Var: 1 Page Ref: 6.5
32) A 2.38 g sample of phenol (C6H6O, molar mass = 94.11 g ) was combusted in a bomb
calorimeter with a heat capacity of 6.65 kJ . If the temperature increased from 23.8 °C to
35.4 °C, determine U for the combustion of phenol.
A) -8.19 × 103 kJ mol-1
B) -5.81 × 103 kJ mol-1
C) 4.87 × 103 kJ mol-1
D) -3.05 × 103 kJ mol-1
E) 2.41 × 103 kJ mol-1
Answer: D
Diff: 3 Type: MC Var: 1 Page Ref: 6.5
33) An 8.21 g sample of glycerol (C3H8O3, molar mass = 92.0938 g ) was combusted in a
bomb calorimeter with a heat capacity of 10.61 kJ . If the temperature increased from 22.1
°C to 36.0 °C, determine U for the combustion of glycerol.
A) -4.38 × 103 kJ mol-1
B) 3.65 × 103 kJ mol-1
C) 2.18 × 103 kJ mol-1
D) -2.18 × 103 kJ mol-1
E) -1.65 × 103 kJ mol-1
Answer: E
Diff: 3 Type: MC Var: 1 Page Ref: 6.5
34) Calculate the amount (mass) of acetic acid (C2H4O2, molar mass = 60.052 g mol-1) that
causes a bomb calorimeter with a heat capacity of 8.43 kJ °C-1 to have a temperature increase
from 24.5 °C to 36.8 °C. The DrU for the combustion of acetic acid is -874.2 kJ mol-1.
A) 6.18 g
B) 7.12 g
C) 2.18 g
D) 9.66 g
E) 8.68 g
Answer: B
Diff: 3 Type: MC Var: 1 Page Ref: 6.5
9
Copyright © 2017 Pearson Canada, Inc.
35) Calculate the amount (mass) of acetaldehyde (C2H4O, molar mass = 44.0526 g mol-1) that
causes a bomb calorimeter with a heat capacity of 12.91 kJ °C-1 to have a temperature increase
from 27.8 °C to 41.7 °C. The DrU for the combustion of acetaldehyde is -1166.9 kJ mol-1.
A) 6.77 g
B) 8.67 g
C) 4.29 g
D) 7.30 g
E) 5.55 g
Answer: A
Diff: 3 Type: MC Var: 1 Page Ref: 6.5
36) A bomb calorimeter with a heat capacity of 13.9 kJ °C-1 has an initial temperature of 21.9
°C. If 5.00 g of propanal (C3H6O, molar mass = 58.0791 g mol-1, DrU = -1822.7 kJ mol-1 for
combustion) is combusted, calculate the final temperature of the calorimeter.
A) 26.1 °C
B) 16.7 °C
C) 33.2 °C
D) 43.1 °C
E) 34.0 °C
Answer: C
Diff: 3 Type: MC Var: 1 Page Ref: 6.5
37) The temperature rises from 25.00 °C to 29.00 °C when 3.50 g of sucrose undergoes
combustion in a bomb calorimeter. Calculate U for the combustion of sucrose in kJ
sucrose. The heat capacity of the calorimeter is 4.90 kJ . The molar mass of sugar is 342.3 g
.
A) -1.92 × 103 kJ mol-1
B) 1.92 × 103 kJ mol-1
C) -1.23 × 103 kJ mol-1
D) 2.35 × 104 kJ mol-1
Answer: A
Diff: 3 Type: MC Var: 1 Page Ref: 6.5
10
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38) A 12.8 g sample of ethanol (C2H5OH) is burned in a bomb calorimeter with a heat capacity
of 5.65 kJ . Using the information below, determine the final temperature of the calorimeter
if the initial temperature is 25.0°C. The molar mass of ethanol is 46.07 g .
A) 53.4 °C
B) 28.1 °C
C) 111 °C
D) 85.7 °C
E) 74.2 °C
Answer: D
Diff: 3 Type: MC Var: 1 Page Ref: 6.5
39) A 35.6 g sample of ethanol (C2H5OH) is burned in a bomb calorimeter according to the
following reaction. If the temperature rose from 35.0 °C to 76.0°C and the heat capacity of the
calorimeter is 23.3 kJ , what is the value of U°? The molar mass of ethanol is 46.07 g
.
40) A 6.55 g sample of aniline (C6H5NH2, molar mass = 93.13 g ) was combusted in a
bomb calorimeter with a heat capacity of 14.25 kJ . If the initial temperature was 32.9 °C,
use the information below to determine the value of the final temperature of the calorimeter.
U° = -1.28 × 104 kJ
A) 257 °C
B) 46.6 °C
C) 96.1 °C
D) 41.9 °C
E) 931 °C
Answer: C
Diff: 3 Type: MC Var: 1 Page Ref: 6.5
11
Copyright © 2017 Pearson Canada, Inc.
41) Given w = 0, an endothermic reaction has which of the following properties?
A) +ΔH and -ΔU
B) -ΔH and +ΔU
C) +ΔH and +ΔU
D) -ΔH and -ΔU
Answer: C
Diff: 1 Type: MC Var: 1 Page Ref: 6.6
12
Copyright © 2017 Pearson Canada, Inc.
45) Using the following equation for the combustion of octane, calculate the heat of reaction for
100.0 g of octane. The molar mass of octane is 114.33 g .
A) 4.82 × 103 kJ
B) 4.82 kJ
C) 9.64 × 103 kJ
D) 1.26 × 104 kJ
Answer: A
Diff: 3 Type: MC Var: 1 Page Ref: 6.6
46) How much energy is required to decompose 765 g of PCl3 according to the reaction below?
The molar mass of PCl3 is 137.32 g and may be useful.
A) 2.31 × 103 kJ
B) 4.33 × 103 kJ
C) 6.72 × 103 kJ
D) 1.68 × 103 kJ
E) 5.95 × 103 kJ
Answer: D
Diff: 3 Type: MC Var: 1 Page Ref: 6.6
47) How much energy is evolved during the reaction of 48.7 g of Al according to the reaction
below? Assume that there is excess Fe2O3.
A) 415 kJ
B) 207 kJ
C) 241 kJ
D) 130 kJ
E) 769 kJ
Answer: E
Diff: 3 Type: MC Var: 1 Page Ref: 6.6
13
Copyright © 2017 Pearson Canada, Inc.
48) How much energy is evolved during the formation of 98.7 g of Fe according to the reaction
below?
A) 753 kJ
B) 1.51 × 103 kJ
C) 4.20 × 103 kJ
D) 482 kJ
E) 241 kJ
Answer: A
Diff: 3 Type: MC Var: 1 Page Ref: 6.6
49) According to the following reaction, how much energy is required to decompose 55.0 kg of
Fe3O4? The molar mass of Fe3O4 is 231.55 g .
A) 1.10 × 106 kJ
B) 2.38 × 102 kJ
C) 2.66 × 105 kJ
D) 1.12 × 103 kJ
E) 3.44 × 104 kJ
Answer: C
Diff: 3 Type: MC Var: 1 Page Ref: 6.6
50) Using the following thermochemical equation, determine the amount of heat produced per kg
of CO2 formed during the combustion of benzene (C6H6).
14
Copyright © 2017 Pearson Canada, Inc.
51) Using the following thermochemical equation, determine the amount of heat produced from
the combustion of 24.3 g benzene (C6H6). The molar mass of benzene is 78.11 g
A) 3910 kJ C6H6
B) 1950 kJ C6H6
C) 977 kJ C6H6
D) 40.1 kJ C6H6
E) 0.302 kJ C6H6
Answer: C
Diff: 3 Type: MC Var: 1 Page Ref: 6.6
52) Using the following equation for the combustion of octane, calculate the amount of moles of
carbon dioxide formed from 100.0 g of octane. The molar mass of octane is 114.33 g . The
molar mass of carbon dioxide is 44.0095 g .
A) 18.18 moles
B) 6.997 moles
C) 14.00 moles
D) 8.000 moles
E) 10.93 moles
Answer: B
Diff: 3 Type: MC Var: 1 Page Ref: 6.6
53) Using the following equation for the combustion of octane, calculate the amount of moles of
oxygen that reacts with 100.0 g of octane. The molar mass of octane is 114.33 g . The
molar mass of carbon dioxide is 44.0095 g .
A) 18.18 moles
B) 6.997 moles
C) 14.00 moles
D) 8.000 moles
E) 10.93 moles
Answer: E
Diff: 3 Type: MC Var: 1 Page Ref: 6.6
15
Copyright © 2017 Pearson Canada, Inc.
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Veärin veetään apaja.
Tuop' on Vanha Väinämöinen,
Itse noin sanoiksi virkko:
"Onkos tarvis tarpojia,
Varsin puun pitelejiä?"
Sisarekset vastoavat:
"On tarvis tarpojia,
Varsin puun pitelejiä."
Tuop' on Vanha Väinämöinen
Hongan rannalta hotasi,
Poajen porkaksi panoovi,
Tarpo nuotan tappuraksi,
Veen velliksi sekotti.
Niin tuli Lohi punanen,
Jot' on vasten nuotta tehty.
Vaan ei kärsi käsin ruveta
Ilman kirjo-kinttahitta,
Eli rauta-rukkasitta.
Tuop' on Vanha Väinämöinen
Nouti kirjo-kinttahansa,
Haki rauta-rukkasensa,
Itse noin sanoiksi virkko:
"Vieris veitsi taivosesta,
"Puukko pilvestä putoa,
Peä kulta, terä hopio,
Peäp' on Väinösen kätehen,
Kärki Luojan kukkarohon,
Puhota lohi punanen!"
Toisin.
(Sotkamosta.)
Sikaliskon Synty.
(Paavolasta.)
Poika viiään
Keskelle Simon saloa.
Pah' on pojan siellä olla:
Simon salot kuivettuvat,
Mehtä-miehet vanhanevat. —
Poika viiään
Koivu-pökkölön kottiin,
Lahon kannon kartanoon;
Siell' on hyvä ollaksesi,
Lempi liekasellaksesi; —
Päivä paistaa lämpymästi; —
Siellä toukaksi tuleepi,
Sikaliskoksi sikesi. — — —
Maon Sanat.
(Paavolasta.)
Toisin.
(Paavolasta.)