Jaipur region
Jaipur region
Jaipur region
CLASS- XI
SUBJECT- CHEMISTRY
Set-c
General Instructions:
SECTION-A
1 Which one will have maximum numbers of water 1
molecules? (A)18 molecules of water
(B)1.8 grams of water
(C) 18 grams of water
(D) 18 moles of water
2 ……………. is the mass percentage of carbon in 1
carbo dioxide?
3 The second ionisation enthalpies of Na, Mg, Al and Si are in the order: 1
…………….
(a) 40 ℃
(b) 94 ℃
(c) 93.3 ℃
(d) 30 ℃
2+ +
(c) OO –< O
2 2
<2
2+ – +
(d) O2 < O2 < O2
14 Assertion (A) : Atoms with completely filled and half-filled subshells are stable. 1
Reason (R) : Completely filled and un-filled subshells have the
energy.
15 Assertion : BF3 molecule has zero dipole moment. 1
Reason :B is electronegative and B–F bonds are
polar in nature.
SECTION-B
17 What is the molar concentration of sugar C12H22O11 if it’s 2gm are dissolved in 2
enough water to make final volume 2L
18 (i)Calculate the number of electrons which will together weigh 5 gram. 1+1
(ii) Calculate the mass and charge of one mole of electrons.
19 (i) A photon of wavelength 4 × 10-7 m strikes on metal surface ; the work function of the 1
metal being 2.13 eV. Calculate (i) the energy of the photon,
(ii) the kinetic energy of the emission 1
27 An element X with atomic number 112 has been recently predicted. Its
electronic configuration is :
[Rn] 5f146d107s2
. Predict 1
i. its group 1
ii. block in which this element would be placed 1
iii. IUPAC name and symbol.
28 In a reaction 3
A +2 B → AB2
(vi)3gm of A +5 gm of B
SECTION-D
29 Read the passage given below and answer the following questions:
Hybridisation helps us to understand the geometry of molecules. This is because hybridized orbitals
are directed in space in some preferred direction to have stable arrangement , which determine the
geometry. The presence of lone pairs in addition to bond pairs distort the geometry due to repulsion.
c) Give shape of the molecule having four bond pairs and one lone pair . 1
SECTION-E
31 a.The bromine atom possesses 35 electrons that contain 6 electrons in 2p orbital, 6 electrons in 3p 1
orbital and 5 electrons in 4p orbital. Which of these electrons experiences the lowest effective
nuclear charge?
b. The arrangement of the orbitals is based upon the energy based on the (n+l ) value. The lower the
value of the (n+l ), the lower energy found. For orbitals with equal values of (n+l), the orbital with 1
the lower value of n will have the lower energy.
1. Based upon the above-given information, arrange the following orbitals in the increasing order of
their energy
(a) 1s, 2s, 3s, 2p
1
(b) 4s, 3s, 3p, 4d
λ(A) = 300 nm
1
λ(B) = 300 μm
λ(c) = 3 nm
λ (D) 30 A°
d. The Balmer series in the hydrogen spectrum corresponds to the transition from n1 = 2 to n2 =
3,4,………. This series lies in the visible region. Calculate the wave number of lines associated by the
transition in the Balmer series if the electron moves to n = 4 orbit. (RH= 109677 cm-1) 1
32 1. The net enthalpy change for the reaction is the amount of energy needed to break all the bonds 2
from the reactant molecules minus the amount of energy needed to form all the bonds in the
product molecules. What will be the enthalpy change for the given reaction?
2
H2(g) + Br2(g) → 2HBr(g)
Given that the Bond energy of the H2, Br2 and HBr is 435 kJ mol-1, 192 kJ mol-1, as well as 368
kJ mol-1, respectively.
2. Expansion of the gas in the vacuum is called free expansion. Calculate the work done as well as
the change in the internal energy if 1 litre of the ideal gas expands isothermally into a vacuum
until the total volume is 5 litres?
3. Entropy on boiling of egg ………………whereas curding of milk…………….
1
(a) Which of the two compounds will have intermolecular hydrogen bonding and which compound is 2
expected to show intramolecular hydrogen bonding.
1
(b) Which of the above two compounds will show lower melting point. Why?
(c) Solubility of compounds in water depends on power to form hydrogen
2
bonds with water. Which of the above compounds will form hydrogen bond
with water easily and be
more soluble in it