28-11-2024

1001CJM202023240010 JM

PART-1 : PHYSICS

SECTION-I

1) Two long parallel wires are at a distance 2d apart. They carry steady equal currents flowing out of
the plane of the paper, as shown in figure. The variation of the magnetic field B along the line XX' is
given by :-

(A)

(B)

(C)

(D)

2) A particle of charge –q & mass m enters a uniform magnetic field B (Perpendicular to paper
inwards) at P with a speed V0 at an angle α & leaves the field at Q with speed V at angle β as shown

then :-

(A) α = β

(B)
(C)
Particle remains in field for time
(D) All of above

3) Two long current carrying thin wires, both with current I, are held by the insulating threads of
length L and are in equilibrium as shown in the figure, with threads making an angle 'θ' with the
vertical. If wires have mass λ per unit length then the value of I is :-

(g = gravitational acceleration)

(A)

(B)

(C)

(D)

4) A current carrying loop is placed in a uniform magnetic field in four different orientations, I,II, III
& IV. Arrange them in the decreasing order of potential Energy

(A) I > III > II > IV

(B) I > II >III > IV
(C) I > IV > II > III
(D) III > IV > I > II

5) A loop carrying current 'I' lies in the x-y plane as shown in the figure. The unit vector is coming
out of the plane of the paper. The magnetic moment of the current loop is :
(A)

(B)

(C)

(D)

6) A square loop ABCD carrying a current i, is placed near and coplanar with a long straight

conductor XY carrying a current I, the net force on the loop will be :-

(A)

(B)

(C)

(D)

7) A battery is connected between two points A and B the circumference of a uniform conducting
ring of radius r and resistance R. One of the arcs AB of the ring subtends an angle θ at the centre.
The value of the magnetic induction at the centre due to the current in the ring is:

(A) zero, only if θ = 180º

(B) zero for all values of θ
(C) proportional to 2 (180º– θ)
(D) inversely proportional to r

8) In the circuit shown below, the key K is closed at t = 0. The current through the battery is :-
(A) 5 A at t = 0 and 7 A at t = ∞
(B) 3 A at t = 0 and 1 A at t = ∞
(C) 1 A at t = 0 and 3 A at t = ∞
(D) 2 A at t = 0 and 6 A at t = ∞

9) The r.m.s. value in time T of potential difference V shown in the figure is :-

(A)

(B) V0

(C)

(D)

10) In an a.c. circuit V and I are given by

V = 100 sin (100 t) volts
I = 100 sin (100t + π/3) mA
The power dissipated in the circuit is

(A) 104 watt

(B) 10 watt
(C) 2.5 watt
(D) 5.0 watt

11) The figure shows a LCR network connected to 300 V a.c. supply. The circuit elements are such
that R = XL = XC = 10Ω. V1, V2 and V3 are three a.c. voltmeters connected as shown in the figure.
Which of the following represents the correct set of readings of the voltmeters ?

(A) V1 = 100 V, V2 = 100 V, V3 = 100 V

(B) V1 = 150 V, V2 = 0 V, V3 = 150 V
(C) V1 = 300 V, V2 = 100 V, V3 = 100 V
(D) V1 = 300 V, V2 = 300 V, V3 = 300 V

12) In a circuit L, C and R are connected in series with an alternating voltage source of frequency f.
The current leads the voltage by 45°. The value of C is :-

(A)

(B)

(C)

(D)

13) Figure (a) shows a conducting loop being pulled out of a magnetic field with a speed v. Which of
the four plots shown in figure (b) may represent the power P delivered by the pulling agent as a

function of the speed v.

(A) A
(B) B
(C) C
(D) D

14) Consider the situation shown in the figure. The wire AB is sliding on the fixed rails with a
constant velocity. If the wire AB is replaced by semi circular wire, the magnitude of the induced

current will :-

(A) Increase
(B) Remain the same
(C) Decrease
Increase or decrease depending on whether the semicircle bulges towards the resistance or
(D)
away from it

15) A conducting rod PQ of length L = 1.0 m is moving with a uniform speed v = 20 m/s in a uniform
magnetic field B = 4.0 T directed into the paper. A capacitor of capacity C = 10 μF is connected as

shown in figure. Then

(A) qA = + 800 μC and qB = –800 μC

(B) qA = –800 μC and qB = + 800 μC
(C) qA = 0 = qB
charge stored in the capacitor
(D)
increases

16) An electromagnetic wave with frequency ω and wavelength λ travels in the +y direction. Its
magnetic field is along +x axis. The vector equation for the associated electric field (of amplitude E0)
is :-

(A)

(B)

(C)

(D)

17) The decreasing order of wavelength of infrared, microwave, ultraviolet and gamma rays is :

(A) microwave, infrared, ultraviolet, gamma rays

(B) gamma rays, ultraviolet, infrared, microwaves
(C) microwaves, gamma rays, infrared, ultraviolet
(D) infrared, microwave, ultraviolet, gamma rays

18) Electromagnetic wave of intensity 1400 W/m2 falls on metal surface on area 1.5 m2 is completely
absorbed by it. Find out force exerted by beam.

(A) 14 × 10–5 N
(B) 14 × 10–6 N
(C) 7 × 10–5 N
(D) 7 × 10–6 N

19) A point source of electromagnetic radiation has an average power output of 800 W. The
maximum value of electric field at a distance 3.5 m from the source will be –

(A) 25.2 V/m

(B) 62.6 V/m
(C) 72.5 V/m
(D) 80.7 V/m

20) An electromagnetic wave of frequency 1 × 1014 hertz

0
is propagating along z-axis. The amplitude of electric field is 4 V/m. If ε = 8.8 × 10–12 , then
average energy density of electric field will be :

(A) 35.2 × 10–10 J/m3

(B) 35.2 × 10–11 J/m3
(C) 35.2 × 10–12 J/m3
(D) 35.2 × 10–13 J/m3

SECTION-II

1) Considering magnetic field along the axis of a circular loop of radius 1 meter, at what distance

from the centre of the loop the magnetic field is times of its value at the centre ?

2) The mid points of two small magnetic dipoles of length d in end-on positions, are separated by a
distance x, (x >> d). The force between them is proportional to x–n where n is :-

3) The magnetic field in a certain region of space is given by = 3.14 × 10–2 T. A proton is shot
into the field with velocity
= (2 × 106 + 4 × 106 ) m/s. The proton follows a helical path in the field. The distance moved by
proton in the x-direction during the period of one revolution in the yz-plane will be
(Mass of proton = 1.6 × 10–27 kg)

4) A long solenoid has 100 turns/meter and a current of 3.5 A is flowing through it. If it is filled with
material of relative permeability (μr = 20) then magnetic field within the solenoid will be xπ × 10–4,
find x?

5) The network shown in the figure is a part of a complete circuit. If at a certain instant the current

i is 5 A and is decreasing at the rate of 103 A/s then VB – VA is (in volt)

PART-2 : CHEMISTRY

SECTION-I

1) If RH is the Rydberg constant for hydrogen, then wave number of the first line in the Lyman series
is :-
(A) 2RH

(B)

(C)

(D)

2) The number of photons of light, having wave number 'x' in 10J of energy is :-

(A) 10 hcx

(B)

(C)

(D) None of these

3) In an atom, the total number of electrons having quantum numbers n = 4, |mℓ| = 1 and ms = – is
:

(A) 6
(B) 2
(C) 10
(D) 3

4) The orbital angular momentum of an electron in a single electron system is . Which of the
following angular momentum value (s) are not possible for this electron in Bohr orbit.

(A)

(B)

(C)

(D)

5) In a reaction, n1A + n2B → m1C + m2D , 5M of reactant A are allowed to react with 3M of reactant
B. After 5 second, the concentration of A was found to be 4M. Rate of decomposition A and rate of
formation of D respectively :-

(A)

(B)
(C)

(D)

6) For the reaction, following data is given

The temperature at which K1 = K2 is :-

(A) 1000 K
(B) 2000 K
(C) 868.4 K
(D) 434.22 K

7) Which of the following pair contains isostructural species ?

(A)
(B) SO2, CO2
(C) PF3, BF3
(D)

8) Select incorrect statement :-

σ π π
(A) In N2 molecule, the energy of 2pz is more than 2px and 2py
– +
(B) C2, CN and NO are diamagnetic
+ – + –
(C) Among N2 , N2 and N2 , the stability order in N2 > N2 > N2
(D) He2 molecule does not exist as the effect of bonding and anti-bonding orbitals cancel each other

9) An element (X) forms compounds of the formula XCl3, X2O5 and Ca3X2 but does not for XCl5.
Predict element (X) :

(A) B
(B) Al
(C) N
(D) P

10) Which of the following statement is wrong ?

(A) d-orbital taking part in dsp2 is

3
(B) d-orbital taking part in sp dis dxy.
(C) d-orbitals taking part in sp3d2 are and
(D) d-orbitals taking part in sp3d3 are ,dxy and

11) Which order of dipole moment is correct ?

(A) CCl4 < CH3Cl < CH2Cl2 < CHCl3

(B) CH3Cl > CH3F > CH3Br > CH3I
(C) BF3 > NH3 > NF3
o-dichlorobenzene < m-dichlorobenzene
(D)
< p-dichloro benzene

12) Which of the following compound has highest lattice energy ?

(A) CaF2
(B) Al2O3
(C) AlF3
(D) Na2S

13) Select the reaction in which co-ordinate bond is not formed in product side :

+ +
(A) H2O + H → H3O
(B) CO + BF3 → OCBF3
(C) Ca+2 + O–2 → CaO
– –
(D) BF3 + F → BF4

14) Match List -I with List II:

List - I List - II
Mechanism steps Effect

(A) (I) – E effect

(B) (II) – R effect

(C) (III) + E effect

(D) (IV) + R effect

Choose the correct answer from the options given below :

(A) (A) – (IV), (B) – (III), (C) – (I), (D) – (II)
(B) (A) – (III), (B) – (I), (C) – (II), (D) – (IV)
(C) (A) – (II), (B) – (IV), (C) – (III), (D) – (I)
(D) (A) – (I), (B) – (II), (C) – (IV), (D) – (III)

15) What will be the decreasing order of basic strength of the following conjugate bases ?

> OH > R > CH3CO

(A)

(B) R >–OH > CH3CO >

(C) –OH > R > CH3 CO >

–
> R > OH > CH3CO
(D)

16) The correct stability order of the following resonance structures of CH3 –CH = CH–CHO is

(A) II > III > I

(B) III > II > I
(C) I > II > III
(D) II > I > III

17) Which of the following molecule/species is most stable?

(A)

(B)

(C)

(D)

18) The ascending acidity order of the following H atoms is

(A) C < D < B < A
(B) A < B < C < D
(C) A < B < D < C
(D) D < C < B < A

19) Correct order of stability of carbanion is

(A) c > b > d > a

(B) a > b > c > d
(C) d > a > c > b
(D) d > c > b > a

20) The correct sequence of acidic strength of the following aliphatic acids in their decreasing order
is :
CH3CH2COOH, CH3COOH, CH3CH2CH2COOH, HCOOH

(A) HCOOH > CH3COOH > CH3CH2COOH > CH3CH2CH2COOH

(B) HCOOH > CH3CH2CH2COOH > CH3CH2COOH > CH3COOH
(C) CH3CH2CH2COOH > CH3CH2COOH > CH3COOH > HCOOH
(D) CH3COOH > CH3CH2COOH > CH3CH2CH2COOH > HCOOH

SECTION-II

1) For a first order reaction, time required for 99.0% completion is 'x' times for the time required for
the completion of 90% of the reaction then value of 'x' is ?

2) How many of the following have one unpaired electron ?

KO2, O2[BF4], K2O2, O2, N2, NO2, B2H6

3) How many of the following orders are correct?

(i) NaF < MgF2 < AlF3 (order of lattice energy)
(ii) BeCl2 < MgCl2 < CaCl2 < SrCl2 < BaCl2
(order of covalent character)
(iii) BeCO3 < MgCO3 < CaCO3 < SrCO3 < BaCO3
(order of thermal stability)
(iv) LiH > NaH > KH > RbH > CsH
(order of thermal stability)
(v) LiCl > NaCl > KCl > RbCl > CsCl
(order of melting point)
(vi) Li2CO3 < Na2CO3 < K2CO3 < Rb2CO3 < Cs2CO3
(order of solubility in water)

4) Total number of aromatic compounds among the following compounds is _______.

5) Among the following, total number of meta directing functional groups is :
(Integer based)
– OCH3, –NO2, –CN, –CH3 –NHCOCH3,
– COR, –OH, – COOH, –Cl

PART-3 : MATHEMATICS

SECTION-I

1) The function

ƒ(x) = {2(t – 1) (t – 2)3 + 3(t – 1)2 (t – 2)2} dt

attains its maximum at x is equal to :-

(A) 1
(B) 2
(C) 3
(D) 4

2) The function f(x) = sin4 x + cos4 x increases, if :-

(A) 0 < x < π/8

(B)

(C)

(D)

3) If ϕ(x) = f(x) + f(2a – x) and

f"(x) > 0, a > 0, 0 ≤ x ≤ 2a, then :-

(A) ϕ(x) increases in (a, 2a)

(B) ϕ(x) increases in (0, a)
(C) ϕ(x) decreases in (a, 2a)
(D) None

4) A spherical balloon is expanding. If at any instant rate of increase of its volume is 16 times of rate
of increase of its radius, then its radius at that instant, is
(A)

(B)

(C)

(D)

5) The maximum and minimum values of sin 2x–x are

(A) 1, –1

(B)
,

(C)
,
(D) do not exist

6) Let
the set of values of b for which f(x) have greatest value at x = 1 is given by :

(A) 1 ≤ b ≤ 2
(B) b = {1, 2}
(C) b ∈ (–∞, –1)

(D)

7) Let f"(x) > 0 ; ∀ x ∈ R and

g(x) = f(2 – x) + f(4 + x) ; then g(x) is increasing in -

(A) (–∞, –1)

(B) (–∞, 0)
(C) (–1, ∞)
(D) (–∞, ∞)

8) The global maximum value of

f(x) = log10(4x3 – 12x2 + 11x – 3), x ∈ [2, 3], is :-

(A)
– log103
(B) 1 + log10 3
(C) log103

(D)
log103
9) If maximum & minimum value of function ƒ(x) = x3 – 6x2 + 9x + 1 ∀ x ∈ [0,2] are M & m
respectively, then value of M – 2m is :

(A) 3
(B) 2
(C) –1
(D) 0

10) The primitive function of the function

is :-

(A)

(B)

(C)

(D) None of these

11)

(A)

(B)

(C)

(D)

12) is equal to

(A) tan–1 (tanx + cotx) + C

(B) tan–1 (cotx – tanx) + C
(C) tan–1 (tanx – cotx) + C
(D) tan–1 (cot x) + C

13) equals
(where C is integration constant)

(A)
(B)

(C)

(D)

14) If , then equals:-

(A)

(B)

(C)

(D) None of these

15) The values of , where [ · ] denotes the greatest integer function, is :-

(A)

(B)

(C)

(D) None of these

16)

The area (in sq. units) of the region

{(x, y) : y2 ≥ 2x and x2 + y2 ≤ 4x, x ≥ 0, y ≥ 0} is :-

(A)

(B)

(C)

(D)

17) Let f(x) = min. for all x ≤ 1. Then the area bounded by y = f(x) and the
x-axis is :-

(A)
sq. units
(B)
sq. units

(C)
sq. units

(D)
sq. units

18) Let y = y(x) satisfies the differential equation

, then
y(x) is given by

(A)

(B)

(C)

(D)

19) A curve passes through the point . Let the slope of the curve at each point (x, y) be

. Then the equation of the curve is :

(A)

(B)

(C)

(D)

20) If
then Sum of a, b, c is equal to :

(A) 7
(B) 8
(C) 0
(D) 1

SECTION-II
1) If the maximum value of
is λ then the value of is :

2) Let f : R → R be a differentiable function such that f(2) = 6, f'(2) = , then is :

3) The area enclosed by the curve xy2 = 4(2 – x) and y-axis is λ square unit, then the value of
8 cos (2014 λ) is equal to

4) If a curve y = f(x) is given by passing through (–2, 3) meets the line L = 0 at (3, y)

then ; value of P + A = ?

5) Evaluate :
 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. B D D C B A B C C C D B D B A D A D B C

SECTION-II

Q. 21 22 23 24 25
A. 1 4 4 28 15

PART-2 : CHEMISTRY

SECTION-I

Q. 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45
A. C C A A D D D C C B B B C A B B A A D A

SECTION-II

Q. 46 47 48 49 50
A. 2 3 4 1 4

PART-3 : MATHEMATICS

SECTION-I

Q. 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 69 70
A. A B A B B D C B A C D C A A B C D B A A

SECTION-II

Q. 71 72 73 74 75
A. 6 18 8 -37 8
 SOLUTIONS

PART-1 : PHYSICS

1)

2) α = β

PQ = 2R sin α

3)
consider balance of unit length
T cos θ = λg .....(i)
T sin θ = F .....(ii)

, = L sin θ

4)

5)
 6) F =

7)

i1R1 = i2R2 = ε
i1(2π – θ) = i2(θ)
So Bat centre = 0

8) at t = 0 'L' behaves as open circuit at t = ∞ as short circuit

9)

10) Pav = Vrms irms cos ϕ

11) VR = iR, VL = iXL = VC = iXC

12)

13) P = Fv = il B × v

∴ P ∝ v2

14)

Since effective length will be same hence there will be no change.

15)

qA= + (Bℓv) C
= (4) (1) (20) (10 × 10–6) = 800μC

qB = –qA = –800μC
16) Propagation is along

18) F =

19) Intensity of electromagnetic wave given is by

= = 62.6 V/m

20) Average energy density of electric field

= 35.2 x 10–12 J/m3

21)

x2 = R2
x=±R ∴x=1

22) F =

23) p = V11T

24)

B = µ0µRni
 25)

VA – VB = iR – E – L
= 5 × 1 – 15 – 5 × 10–3 × 103 = – 15 volts

PART-2 : CHEMISTRY

26) Given : Energy level (n) = 2,

We know that wave number in Lyman series

27)

n= = .

28)

n = 4, |mℓ| = 1, ms =

Total no. of electron having n = 4, |mℓ| = 1 &

ms = – =6

29) Orbital angular momentum

=
ℓ=3=F

mvr = 4f, 5f, 6f ............ Possible

For F-subshell n =3 not possible

30) = 0.2 mol lit–1 sec–1

31)

K1 = K2 (given)
 or
on taking log of both side
loge10 =

2.303 × log1010 =

T= kelvin

32)

Species Shape

Pyramidal

Trigonal planar

SO2 'v'- shape

CO2 Linear

Tetrahedral

33) Order of stability :-

N2 > N2+ > N2–

34) 'N' can form NCl3, N2O5 and Ca3N2 but not NCl5 .

35) In sp3d hybridisation, participates.

36) Correct order of dipole moment :

CCl4 < CHCl3 < CH2Cl2 < CH3Cl
BF3 < NF3 < NH3
O-dichlorobenzene > m-dichlorobenzene
> p-dichlorobenzene

37)

lattice energy
Al2O3 has highest U0 among these four because it has highest value of |z+|. |z–|

38) In this reaction ionic bond is formed.

39)

40) Strong acid have weak conjugate base

Acidic strength :
H–Cl > CH3COOH > H2O > R–OH
Conjugate base strength :
Cl– < CH3COO– < < RO–

41)

Stability order III > II > I

42) it is aromatic species

 43)
Stability of conjugate base ∝ acidic strength
C<D<B<A

44) As we know compound (d) is aromatic and the compound (a) is anti-aromatic. Hence
compound (d) is most stable and compound (a) is least stable among these in compound (b)
and (c) carbon atom of that positive charge is sp3 hybridised they on the basis of angle strain

theory compound (c) is more stable than compound (b).

45) CH3CH2COOH, CH3COOH, CH3CH2CH2COOH, HCOOH

The correct order is :
HCOOH > CH3COOH > CH3CH2COOH
> CH3CH2CH2COOH

46)

Apply : kt = ln

47)

Species Number of unpaired e–

K+O2– 1

O2+[BF4]– 1

2K+ O2–2 0

O2 2

N2 0

NO2 1

B2H6 0

48)

Correct order are :

(i), (iii), (iv), (vi)

49)
 50)

–NO2, – C ≡ N, –COR, –COOH

are meta directing.

PART-3 : MATHEMATICS

51) ƒ'(x) = 2(x – 1) (x – 2)3 + 3(x – 1)2 (x – 2)2

= (x – 1) (x – 2)2 {2(x – 2) + 3(x – 1)}
= (x – 1) (x – 2)2 (5x – 7)

sign change of ƒ'(x) from +ve to –ve at x = 1

∴ Maximum at x = 1

52) ∵ f (x) = sin4 x + cos4 x

∴ f '(x) = – sin 4x
∵ f '(x) > 0
⇒ – sin 4x > 0
⇒ sin 4x < 0
(2n + 1)p < 4x < (2n + 2)p

For n = 0,

Now,

∴ f(x) is increasing in

53) ϕ'(x) = f '(x) + f '(2a – x)

given, f"(x) > 0, ⇒ f '(x) is increasing function, if
x < 2a – x ⇒ x < a
f '(x) < f '(2a – x)
⇒ ϕ(x) < 0
∴ ϕ(x) decreases in (0, a)
and if x > 2a – x ⇒ x > a
f '(x) > f '(2a – x) ⇒ f'(x) > 0
∴ ϕ(x) increases in (a, 2a)

54)

55) Let f(x) = sin2x – x

f '(x) = 2cos 2x – 1
f "(x) = –4sin 2x
Now f '(x) = 0 ⇒ 2cos 2x – 1 = 0

⇒ x = np ± , n = 0, 1, 2......

⇒ x= , , , – ,........

But f" = –2 <0

⇒ x= is a max. point
Also

⇒ x= is a min. point

Hence one max. value = =

one min. value = =–

But it is not three in given alternatives. Hence by alternate position another min. point is –
so one min. value.

56)
5 ≥ –2 + log2 (b2 – 2)
log2 (b2 – 2) ≤ 7
b2 ≤ 27 + 2
b2 ≤ 130
∴ b2 – 2 > 0
∴ 2 < b2 ≤ 130

57) f"(x) > 0; ∀x∈R ⇒ f'(x) is increasing ∀x∈R

g'(x) = – f'(2 –x) + f'(4 + x)
If g'(x) > 0 ⇒ f' (4 + x) > f' (2 – x)
⇒ (4 + x) > (2 – x)
⇒ 2x > – 2 ⇒ x > –1
⇒ x∈(–1, ∞)

58) Let g(x) = 4x3 – 12x2 + 11x – 3

∴ g'(x) = 12x2 – 24x + 11
= 12(x – 1)2 – 1
> 0 for x Î [2, 3]
Thus, g(x) is increasing in [2, 3].
f(x)max = f(3) = log10(4.27 – 12.9 + 11.3 – 3)
= 1og10(30) = 1 + log103
59)
∴ M = 5 and m = 1
M – 2m = 3

60) Primitive function means indefinite integral

∴ Primitive function of f(x)

(say)

Put

or

Then

61)

62)

I=

⇒I=
(where t = tan x)

⇒I=
⇒ I = tan–1 + C = tan–1(tanx – cotx) + C

63)

64) Putting x2 = t, 2xdx = dt, we get

65) = Area of the shaded region

66)

=π– . = π – 8/3
67)
Required area = shaded region

68)

Hence,

So,

69)

Put = v or y = vx

∴v+x

⇒
⇒ sin (y/x) = ℓn x + c
Passes (1, π/6) ∴ c = 1/2

∴ sin (y/x) = ℓnx +

70) Put sinx =

& cos x =

71) y = 7 cos2x + 6 sinx cos x – sin2x

= 3sin 2x + 4 cos 2x + 3
The maximum value of y is 8

Also

72)
D'L rule

= 4.63· =18

73)

Put x = 2 sin2 θ

Then, cos (2014 × 4π) = 1

∴ 8×1=8

74)

⇒
It passes through (–2, 3)

⇒ =2+C

∴ Curve is
It also passes through (3, y)

75) Note that |cos x| is a periodic function with period p. Hence the given integral.

I=4