Electron Chem 1H
WS Keys
4-1 Apply – Understanding Wave Motion
1. A
4-1 R & R – Radiant Energy
1. 3.00x108
2. Frequency
3. 5.04x1014
4. Particles
5. Frequency
6. Longer than
7. Red
8. Infrared (IR)
9. Short
10. Amplitude
11. Radio waves
12. Microwaves
13. Infrared radiation (IR)
14. Red
15. Orange
16. Yellow
17. Green
18. Blue
19. Indigo
20. Violet
21. Ultraviolet radiation (UV)
22. X-rays
23. Gamma rays
4-2 Apply – Photoelectric Effect
1. A
4-2 R&R – Quantum Theory
1. T
2. F, small
3. F, more
4. T
5. F, electrons
6. F, Compton
7. F, radio
8. T
9. T
10. F, particle
11. A ramp represents continuous change, and a stairway
represents quantized change.
12. No, E of red light is not high enough for photoelectric effect.
By increasing intensity, one is increasing the number of
photons w the same E.
13. A
14. B
15. C
16. B
17. A
18. C
19. A
20. B
4-3 Apply – Heisenberg Uncertainty Principle
1.
4-3 R&R – Another Look at the Atom
1. Line (or emission)
2. Matter waves
3. Momentum (or velocity)
4. Bohr
5. Energy level (or orbit)
6. Higher
7. Radiation (light)
8. Wavelike
9. B
10. B
11. A
12. Continuous spectrum contains all of the colors; line
emission spectrum contains only certain colors of light
corresponding to energy level changes.
13. The mass of the baseball is too big. Wave effects are
inversely proportional to the mass of the object.
14. n=1 inner circle, n=2 next circle, n=3 outer circle
15. Inner circle is g.s.
16. Outer two circles are e.s.
17. Draw an arrow from electron to either n=2 or n=3
4-4 Apply – Atomic Orbitals
1.
a. 9 pins/78.5 cm2 = ? pins/cm2 0.115
b. 11 pins/ 236 cm2 = 0.0466
c. 0.0425
d. 0.0458
e. 0.0203
2. % = pins in circle/ total pins x 100% = 9/100 x100 = 9%
11%
20%
36%
24%
3. 1st ring has the highest density of pins
4th ring has the highest probability of finding a pin
Because the smallest area is ring 1, and more pins are located
in ring 4
4. 22.5cm = r, A = πr2, A = (3.14)(22.52) = 1590 cm2
4-4 R &R – A New Approach to the Atom
1. Orbital
2. Electron density
3. Quantum number
4. Pauli exclusion principle
5. Quantum-mechanical model
6. Principal energy levels
7. Electron spin
8. b
9. b
10. c
11. b
12. c
13. c
14. The E of an electron is quantized; electrons exhibit
wavelike behavior; it is impossible to know the exact
position and momentum of an electron at any given time.
15. The contour represents the surface of an orbital w/in
an electron can be found 90% of the time.
16. 1, 2
17. 3, 6
18. 5, 10
19. 7, 14
4-5 PP – Electron Configurations
1.
a. 1s22s22p63s23p64s1, 1 unpaired electron
b. 1s22s22p63s23p64s23d7, 3 unpaired electron
2. nitrogen
3.
a. 1s22s22p63s23p2, 2 unpaired electrons
b. 1s22s1, 1 unpaired electron
4. Phosphorus
5.
a. 1s22s22p63s23p64s23d10 4p65s24d105p66s24f145d7, 3 unpaired
electron
b. 1s22s22p63s23p64s23d104p4, 2 unpaired electron
6. Scandium
7.
a. 1s22s22p63s23p64s23d10 4p65s24d105p66s24f145d106p3, 3
unpaired electron
b. 1s22s22p63s23p64s23d3, 3 unpaired electron
8. Cadmium
9.
a. 1s22s22p63s23p4, 2 unpaired electron
b. 1s22s22p63s23p64s23d10 4p65s24d105p66s24f145d10, no unpaired
electrons
10. osmium
4-5 R&R – Electron Configurations
1. T
2. F, electrons
3. F, lowest
4. T
5. F, most
6. T
1s 2s 2p 3s 3p 4s
7. Mg: ↑↓ ↑↓ ↑↓ ↑↓ ↑↓ ↑↓
8. O: ↑↓ ↑↓ ↑↓ ↑_ ↑_
9. Al: ↑↓ ↑↓ ↑↓ ↑↓ ↑↓ ↑↓ ↑_ __ __
10. Ar: ↑↓ ↑↓ ↑↓ ↑↓ ↑↓ ↑↓ ↑↓ ↑↓ ↑↓
11. Sc: ↑↓ ↑↓ ↑↓ ↑↓ ↑↓ ↑↓ ↑↓ ↑↓ ↑↓ ↑↓
3d
↑_ __ __ __ __
12. P: ↑↓ ↑↓ ↑↓ ↑↓ ↑↓ ↑↓ ↑_ ↑_ ↑_
13. Ca
14. Si
15. V
16. Br
17. Ne
18. Aufbau – electrons one at a time lowest E level available:
Pauli – max two electrons per orbital w/ opposite spins:
Hund – maximum number of unpaired (one electron in each
equal E orbital before second electron)
