Other Items: Scope References Additional Literature Gas Distributors
Other Items: Scope References Additional Literature Gas Distributors
CONTENTS
Section Page
SCOPE ............................................................................................................................................................2
REFERENCES ................................................................................................................................................2
SAMPLE CALCULATIONS...........................................................................................................................10
GRID JET PENETRATION....................................................................................................................10
HEAT TRANSFER COEFFICIENTS .....................................................................................................10
NOMENCLATURE ........................................................................................................................................14
TABLES
Table 1 ............................................................................................................................................7
Table 2 ............................................................................................................................................8
FIGURES
Figure 1 Gas Distributor Types........................................................................................................15
Figure 2 Grid Stability ......................................................................................................................16
Figure 3 Effect of Transfer Surface and Fluid Bed Temperature on Bed Emissivity........................17
Figure 4 Heat Transfer Coefficient Maldistribution Factors..............................................................17
Revision Memo
12/02 Corrections and minor updates.
SCOPE
This section covers other fluid solids design items such as gas distributors and heat exchangers used to extract heat from
fluidized beds. Distributor types, stability criteria, pressure drop and jet penetration are included. Heat exchanger design and
heat transfer between gas and particles are described.
REFERENCES
1. Shaw, D. F., R. G. Nichols, Refractory Lined Regenerator Grid for Fluid Catalytic Cracking Units, EE.41E.86, April, 1986.
2. Merry, J. M. D., AlChE Journal 21, 507 (1975).
3. Zenz, F. A., Bubble Formation and Grid Design, I Chem E Symposium Series No. 30 (1968).
4. Zilora, S. J., Design Considerations for Steam Generating Coils Located in an FCCU Regenerator, EE.45E.82, May 3, 1982.
5. Design Practices Section IX, Heat Exchange Equipment.
6. Vreedenberg, H. A., Chem. Eng. Science, 9, 52 (1958).
7. Baskakov, A. P., et al., Powder Technology, 8, 273 *73.
8. Exxon Research and Engineering Company, “Industrial Application of Fluidized Bed Combustion, Indirect Fired Process
Heaters, Final Report," U. S. Dept. of Energy, September 30, 1980.
9. Botterill, J. S. M., “Fluid-Bed Heat Transfer," p. 237, Academic Press, London, 1975.
10. Kothari, A. K., M. S. Thesis, Illinois Institute of Technology, Chicago (1967).
ADDITIONAL LITERATURE
1. Baker, C. L. et. al., Fluid Coker Design Notes (Rev. 1), 83 HOP 51, March 14, 1983.
2. Luckenbach, E. C., Design Notes, Catalytic Cracking, Unissued draft report to M. G. Bienstock, Dec. 21, 1989. Available
from the Catalytic Cracking Section, Exxon Engineering.
3. Montiero, F. M., FCCU Maintenance Guide, EE.44E.84, June 1984 with updates.
4. Danielsen, A. M., Flexicoker/Fluid Coker Maintenance Guide, Manual EEEEE-9, December, 1988 with updates.
➧ 5. Mobil FCC Design Guide and Technology Inventory, EE.31E.2002
GAS DISTRIBUTORS
DISTRIBUTOR TYPE
Selection of a gas distributor type is often dependent on specific process characteristics. Several types are shown in Figure 1.
➧ The perforated plate grid (Figure 1a) is probably the most widely used in hExxon commercial scale equipment. It is relatively
cheap and simple to fabricate and maintain, and it should always receive consideration.
For use at very high temperatures, an insulated grid (Figure 1b) may be used. The insulated grid requires that cool gases be
passed up through the grid in order to keep temperatures of structural metal in the plenum at acceptable levels. Grid metal
temperature differentials and stresses are much lower than in unlined grid plates. Three or four in. (75 to 100 mm) of refractory
are placed on the top of the grid. Grid holes are on the order of 3/8 to 1/2 in. (9.5 to 12.5 mm). The grid holes are surrounded by
metal shrouds (pipe stubs) whose length equals the refractory thickness. The diameter of the shrouds is small enough to contain
the expanding gas jet issuing from the grid holes. This is necessary to prevent erosion of the refractory near the gas outlets and
also minimize solids attrition at those points. Erosion and attrition are caused by clockwise recirculating eddies detaching from
the expanding jet, which pull in bed solids and scour the top surface of the grid near the gas outlet holes. The diameter of the
shrouds is calculated from:
H
≥ 5 .2 Eq. (1)
D − do
GRID STABILITY
A grid is said to be stable when gas is passing upward through all grid holes and solids are not sifting down through any grid
holes. When this condition occurs, all parts of the bed above the grid will be fluidized, and the bed is also said to be stable. An
unstable bed has slumped or unfluidized zones. Therefore, an important consideration in the design of a large grid is to ensure
sufficient grid pressure drop for good gas distribution and stable bed operation. One approach to calculating grid pressure drop
necessary for stability is shown in Figure 2. The pressure drop through a grid hole will increase with gas velocity. However,
pressure drop through the bed immediately above that hole will decrease as gas preferentially channels through the hole,
because the density of the bed decreases as gas flow increases. Therefore, local grid and bed conditions will move to the
minimum in the total pressure drop curve in Figure 2 by stopping gas flow through some of the holes. In order for the grid to be
stable, total pressure drop through a grid hole plus the bed above the hole must increase as gas flow starts to channel
preferentially. This will halt the channeling by forcing gas to flow through other grid holes as well. A simplified case is instructive.
➧ Assuming that the bed is bubbling freely, pressure drop through the bed is given by:
−3
−3 10 gρ mf H
∆P b = 10 gHρ = (kPa) Eq. (2m)
U − U mf
1+
UB
where: ∆Pb = The pressure drop through the bed (psi), (kPa)
ρ = The fluidized bed density (lb/ft3), (kg/m3)
H = The fluidized bed height (ft), (m)
ρmf = The minimum fluidized bed density (lbs/ft3), (kg/m3)
U = The gas velocity (ft/s), (m/s)
Umf = The minimum fluidization velocity (ft/s), (m/s)
UB = The bubble rise velocity (ft/s), (m/s)
2 2
➧ g = The acceleration due to gravity (32.2 ft/s )(9.81 m/s )
➧ gc = 2
The gravitational conversion factor [(32.2 ft/s ) (lb mass/lb force)]
for stable grid operation. A grid operated at too low a pressure drop will redistribute the gas flow so that some of the holes are
inoperative and the remainder satisfy the criterion. Exxon practice is to maintain grid pressure drops of 25% to 40% of bed
pressure drop to keep all holes active.
Unstable bed conditions are most likely to occur during turndown and certain startup operations when flow rates and grid ∆P are
low. If this occurs, it is usually seen as high temperatures below the grid due to solids sifting, uneven ∆P measurements, and
possibly high solids losses through internal cyclones. The high losses occur if cyclone diplegs terminate in slumped bed zones.
If this happens, the solids in the diplegs back up into the cyclone and make it inoperative. Grid chimneys can be placed on a
small fraction of grid holes to assure that those holes will remain active during low flow conditions. Those holes will remain active
since the bed ∆P above the chimneys is less than that above the remaining grid holes. To prevent cyclone dipleg flooding, it is
recommended that chimneys be placed over half of the grid holes in the vicinity of each dipleg termination. The holes with
chimneys should be alternated with plain holes to minimize re-start problems in the event of loss of fluidizing gas. Chimney ID
should be the same as grid hole ID with a 6:1 chimney length/ID ratio. Chimneys are particularly recommended for grids through
which both gas and solids flow. Startup problems are more likely since only gas is passed through the grid during startup and the
pressure drop is therefore very low. Chimneys can also be used for gas flow only grids, but the need is less than for the gas plus
solids flow design.
INTRODUCTION
In some fluids solids processes, heat must be extracted from a fluidized bed to maintain temperature of the bed within certain
limits or to recover energy from the bed. Examples are in fluidized bed combustion or in FCC regenerators operating under
conditions of high coke yield. Heat exchange was also used in the past in Fluid Hydroforming regenerators. Heat can be
removed by tubular heat exchangers immersed in the fluidized beds or by circulating the solids between the process vessel and
another vessel containing the heat exchanger. The immersed heat exchanger is discussed in this section. It has been used in
Exxon installations in the past, is reliable, but has the disadvantage of not being able to vary the rate of heat removal from the
bed. External heat exchange systems can control the rate of heat removal by controlling the circulation rate. Consult
Engineering Equipment and Environmental Department for further information.
Heat exchanger design technology for fluid solid systems is also available from vendors. UOP has licensed a number of external
dense phase coolers which are reported to be operating satisfactorily. Similar systems are available from Air Products/HRI.
Other vendor systems are also available, but less is known about operating experience and reliability. These include a dilute
phase cooler from Kellogg and a flow through system from UOP. Consult Process Engineering Department if vendor designs are
to be considered.
Immersed heat exchangers are usually cooled by a forced circulation water system. Parallel cooling circuits are used in the
event of tube failure. Other systems which have been used are steam/atomized water and a natural convection circulation
system. The forced circulation system is generally recommended.
−0.3 0.44
é h d ù é Cp µg ù é Gdtoρp (1 − ε) ù
ê c to ú ê ú = 0.66 ê ú Eq. (7m)
ëê k g ûú ëê k g ûú ëê ρg µg ε ûú
where: hc = The bed side convective heat transfer coefficient (Btu/hr ft2 °F), (W/m2K)
dto = The tube outside diameter (ft), (m)
Kg = The thermal conductivity of the gas (Btu/hr ft °F), (W/mK)
Cp = The heat capacity of the solids (Btu/lb °F), (J/kgK)
➧ G = The gas superficial mass flux (lbs/ft2s), (kg/m2s)
µg = The gas viscosity (lbs/ft s), (kg/ms)
ε = The bed voidage fraction
ρg = The gas density (lb/ft3), (kg/m3)
ρp = The solids particle density (lb/ft3), (kg/m3)
This equation is claimed to correlate data to within ± 40%.
Gdp ρp
For coarser and heavier particles, i.e., > 2550 :
ρg µg
−0.3 0. 3
éh d ù é Cpµg ù é Gd ρ µ 2g ù
to p
ê c to ú ê3600 ú = 420 ê x 3 2 ú Eq. (8c)
êë k g úû êë k g úû ê ρg µg dp ρp g úû
ë
−0.3 0.3
é h d ù é Cpµg ù é Gd ρ µg2 ù
to p
ê c to ú ê ú = 420 ê x 3 2 ú Eq. (8m)
ëê k g ûú êë k g ûú ê ρg µg dp ρpg ú
ë û
where: hr = The radiant heat transfer coefficient (Btu/hr ft2 °F), (W/m2 K)
Tb = The average bed temperature (°R), (K)
Ts = The surface temperature of the tubes (°R), (K)
εb = The bed emissivity
The bed emissivity, εb, is obtained from Figure 3 which relates the emissivity to bed and tube surface temperatures.
Inclusion of radiant heat transfer usually adds about 20% to the value of the convective coefficient for bed temperatures in
the range of 1200 to 1400°F (920 to 1030 K).
For those cases where heat is being removed from the combustion of coke on catalyst in an FCC regenerator and steam is
being generated in the tubes, the following overall heat transfer coefficients, Uo, should be used instead of Equation (7) or
(8).
TABLE 1
CUSTOMARY UNITS
Ug 1 2 3 1 2 3 1 2 3
Uo 69 78 83 58 66 71 49 56 60
METRIC UNITS
TABLE 2
Uo 80 88 450 500
where: hp = The gas to particle heat transfer coefficient (Btu/hr ft2 °F), (W/m2 K)
dp = The weight mean particle diameter (ft), (m)
kg = The thermal conductivity of the gas (Btu/hr ft °F), (W/mK)
ρg = The gas density (lb/ft3), (kg/m3)
Ug = Gas superficial velocity (ft/s), (m/s)
µg = Gas viscosity (lb/ft s), (kg/ms)
The correlation is good to within about ± 50%
SAMPLE CALCULATIONS
é ρg do ù
0.3 é éV2 ù
0.2 ù
L ê1.3
= 5. 2 ê ú ê o ú − 1ú
ê ú
do ëê ρp dp ûú êë
êë g do úû
úû
é 0.44 x 0.042 ù
0.3
é é 100 2 ù
0.2
ù
= 5.2 ê −4 ú
ê1.3 ê ú − 1ú
ë101 x 1.84 x 10 û êë ë 32.2 x 0.042 û úû
= 35
L = 35 x 0.042 = 1.5 ft
= 7.85
L = 7.85 x 0.042 = 0.33 ft
• Calculate
G dp ρp 0.24 x 1.84 x 10 −4 x 101
=
ρg µg 0.07 x 2.5 x 10 −5
= 2600
− 0.3
é hc x 0.375 ù é 0.2 x 2.5 x 10 −5 ù
ê ú ê3600 ú
ë 0.04 û êë 0.04 úû
( )
0.3
é 0.24 x 0.375 x 101 2.5 x 10 −5
2
ù
= 420 ê x ú
êë 0.04 x 2.5 x 10
−5
1.84 x 10 −
(4 3 2
)
(101) x 32.2 úû
hc = 324 Btu/hr ft2 °F
Decrease hc by 10% to account for bundling effect
hc = 324 x 0.9 = 292 Btu/hr ft2 °F
hr =
(
1.71 x 10 −9 εb Tb 4 − Ts 4 )
Tb − Ts
=
(
1.71 x 10 −9 x 0.6 1760 4 − 1260 4 )
1760 − 1260
= 15 Btu/hr ft2 °F
• Calculate gas to particle heat transfer coefficient, hp, using Equation (10)
Given: U = 3.5 ft/s
1.3
hp dp é dp ρ g U ù
= 0.03 ê ú
kg êë µg úû
1. 3
hp x 1.84 x 10 −4 é 1.84 x 10 − 4 x 0.07 x 3.5 ù
= 0.03 ê ú
0.04 êë 2.5 x 10 −5 úû
∆tlm =
(1300 − 100 ) − (1300 − 490 )
ln
(1300 − 100 )
(1300 − 490 )
= 990°F
3. Obtain Uo
From Table 1, Uo = 71 Btu/hr ft2
If hto were calculated from Equations (8) and (9), using properties of particles and solids from previous samples, and using
1000, 600, and 200 for inside coefficient, wall coefficient and fouling factor, respectively, Uo would be about 90 Btu/hr ft2 °F,
about 25% greater.
Use Uo = 71 Btu/hr ft2 °F for conservative estimate.
4. Calculate heat transfer surface area, coil length
Q
A =
Uo ∆tlm
4 x 10 −6
=
71 x 990
= 57 ft2
57 ft 2
L =
1.047 ft 2 / ft
= 54 ft
5. Estimate internal velocity
Btu 1
Vapor rate = 4 x 106 x
hr 871 Btu / lb steam
= 4590 lbs/hr
Liquid rate for 25/1 L/V weight ratio
= 25 x 4590
= 115,000 lbs/hr
ft 3 hr
Velocity = 5840 x x 0.0884 ft 2
hr 3600 s
= 18 ft/s
Since velocity is less than 20 ft/s, design is satisfactory.
NOMENCLATURE
A = Grid hole area, ft2 (m2)
æ ö
➧ C = ç lb
çs ft f /in.÷÷ (s kPa m/kg)
ç lbm ÷
è ø
Cp = Heat capacity of solids, Btu/lb°F (J/kg K)
D = Shroud inside diameter, ft (m)
do = Grid hole diameter, ft (m)
dp = Average particle diameter, ft (m)
dto = Heat transfer tube outlet diameter, ft (m)
G = Gas or solids mass flux, lbs/ft2s (kg/m2s)
➧ g = Acceleration due to gravity, (32.2 ft/s2)(9.81 m/s2)
H = Fluidized bed height, shroud height, ft (m)
hc = Bed side convective heat transfer coefficient, Btu/hr ft2°F (W/m2K)
hp = Gas to particle heat transfer coefficient, Btu/hr ft2°F (W/m2K)
hr = Radiant heat transfer coefficient, Btu/hr ft2°F (W/m2K)
hto = Sum of bed side and radiant heat transfer coefficients, Btu/hr ft2°F (W/m2K)
kg = Thermal conductivity of gas, Btu/hr ft°F (W/mK)
L = Grid jet penetration length, ft (m)
L/V = Liquid to vapor ratio
Q = Gas flow rate through grid, ft3/s (m3s)
Tb = Average bed temperature, °R (K)
Ts = Surface temperature of heat transfer tubes, °R (K)
U, Ug = Superficial gas velocity, ft/s (m/s)
UB = Bubble rise velocity, ft/s (m/s)
Umf = Superficial gas velocity at minimum fluidization, ft/s (m/s)
Uo = Overall heat transfer coefficient, Btu/hr ft2°F (W/m2K)
Vo = Grid hole velocity, ft/s (m/s)
∆Pb = Bed pressure difference, lbs/in.2 (kPa)
∆Pg = Grid pressure difference, lbs/in.2 (kPa)
∆t = Temperature difference °F (°C)
∆tlm = Log mean temperature difference, °F (°C)
ε = Voidage fraction
εb = Bed emissivity
µg = Gas viscosity, lb/ft s (kg/ms)
ρ = Fluid bed density, lbs/ft3 (kg/m3)
ρa = Density of mixture flowing through grid, lbs/ft3 (kg/m3)
ρg = Gas density, lb/ft3 (kg/m3)
ρmf = Fluid bed density at minimum fluidization, lbs/ft3 (kg/m3)
ρp = Solids particle density, lbs/ft3 (kg/m3)
FIGURE 1
GAS DISTRIBUTOR TYPES
D
Refractory
g. Pipe Grid
DP6DF01
FIGURE 2
GRID STABILITY
Umf
Unstable Stable
Pressure Drop
FIGURE 3
EFFECT OF TRANSFER SURFACE AND FLUID BED TEMPERATURE ON BED EMISSIVITY
0.9
600°C
1110°F
700°C
1290°F
0.8 800°C
1470°F
900°C
1650°F
Bed Emissivity, Eb
0.7
1000°C
1830°F
0.6
0.5
Lines of Constant
Fluid Bed Temperature
0.4
0.3
300 400 500 600 700 800 900 1000 (°C)
570 750 930 1110 1290 1470 1650 1830 (°F)
FIGURE 4
HEAT TRANSFER COEFFICIENT MALDISTRIBUTION FACTORS
2.0
Maldistribution Factor
1.5
Bed Temperature Range 525 – 1550°F
(275 – 840°C)
1.0
1.0 1.5 2.0 2.5 3.0 3.5 4.0 4.5 5.0 5.5 6.0
DP6DF04 Ratio of Superficial Gas Velocity to Superficial Minimum Fluidization Velocity, U/Umf