GREEN PARK EDUCATIONAL INSTITUTIONS, NAMAKKAL

XII CBSE - CHEMISTRY – WORKSHEET

3. CLASSIFICATION OF ELEMENTS AND PERIODICITY IN PROPERTIES

Choose the correct answer :

1. Anomalous pair among the following is 8. Pauling’s electronegativity is based on
1) Boron – silicon 1) Electron affinity (EA)
2) Beryllium – indium 2) Ionization potential (IP)
3) Aluminium – gallium 3) Both IP and EA
4) Cobalt – nickel 4) Bond energies
2. Identify the correctly matched set among the 9. The atomic numbers of the second inner
following transition series lie in the range of
1) Sc – d-block – transition element 1) 88 to 101 2) 89 to 102
2) La – d-block – inner transition element
3) 90 to 103 4) 91 to 104
3) Cl – f-block – transition element
10. Symbol for the element with atomic number
4) Al – d-block – transition element
114 is
3. In the isoelectronic species the ionic radii (Ao)
of N3–, O2– and F– are respectively. 1) Uup 2) Uuq
3) Uun 4) Uut
1) 1.36, 1.71, 1.40 2) 1.36, 1.40, 1.71
3) 1.71, 1.40, 1.36 4) 1.71, 1.36, 1.40 11. Second ionization energy among Li, Be, B and
4. Element in periodic table with electronic C is lowest for
configuration as [Ar]3d54s1 belongs to 1) Li 2) Be
1) IA, s-block 2) VIA, d-block 3) B 4) C
3) VIB, s-block 4) VIB, d-block 12. The electronegativity of an element is 1.0 on
5. If the ionization potential of Na is 5.48 eV, the Pauling scale. Its value on Mulliken’s
then I.P of ‘K’ will be scale will be
1) 4.34 eV 2) 5.68 eV 1) 2.8 2) 1
3) 10.88 eV 4) 5.48 eV 3) 2.0 4) 1.5
6. Generally the ionization potential in a period 13. Which of the following configuration is
increases, but there are some exceptions. The associated with the biggest jump between first
one which is not an exception is and second ionization energy?
1) Be & B 2) N & O 1) 1s22s22p5
3) Mg & Al 4) Na & Mg 2) 1s22s22p63s1
7. In which of the following process maximum 3) 1s22s22p4
energy is released?
4) 1s22s22p3
1) O(g) + e– → O(g)
−
14. Ionization energy of F- ion is 320 kJ/mole. The
2) O − –
+e → O 2− electron gain enthalpy of fluorine atom would
(g ) (g)
be
3) S(g) + e– → S(g)
−

1) -320 kJ/mole 2) -160 kJ/mole

−1
4) S(g) + e– → S(g)
2−
3) +320 kJ/mole 4) +160 kJ/mole
 2
15. If the element (M) has successive ionization 21. Element with Z = 83 belongs to which block?
potential values as 5.98, 18.82, 28.44 and 1) s 2) p
−2
119.96 eV, then its formula with SO 4 ion is 3) d 4) f
1) MSO4 2) M2SO4 22. Match the following
3) M3(SO4)2 4) M2(SO4)3 List – I List – II
16. Aqueous solutions of two compounds M-O-H (Element) (Nature of element)
and M′-O-H have been prepared in two A) Sodium I) Noble gas
different beakers. If the electronegativity of B) Argon II) Halogen
M = 3.0, M′=1.72, O = 3.5 and H = 2.1, Then C) Chromium III) Alkali metal
the solutions respectively are D) Chlorine IV) Inner transition element
1) Acidic, acidic 2) acidic, basic V) Transition element
3) basic, basic, 4) basic, acidic The correct match is
1) A-III, B-I, C-V, D-II
17. Which of the following is correctly matched?
2) A-III, B-I, C-II, D-V
1) Fe > Fe+2 > Fe+3 – size
3) A-IV, B-II, C-III, D-I
2) O > O- > O-2 – size
4) A-III, B-IV, C-I, D-II
3) N > C > O – I.E
23. The element having outer electronic
4) N > C > O – E.A
configuration (n-1)d2ns2, n = 4 belong to --- of
18. Match the column-I with column-II and select
the periodic table
the correct answer by the given code.
1) group 12, period 4
Column-I Column-II 2) group 3, period 3
(Atoms) (Properties) 3) group 4, period 4
A) He p) High electronegativity
4) group 4, period 3
B) F q) More electropositive
24. The law of triad is applicable to a group of
C) Rb r) Strongest reducing agent
1) Cl, Br, I 2) Cl, N, O
D) Li s) Highest ionization energy
3) Na, K, Rb 4) H, O, N
1) A-s, B-q, C-r, D-p
25. Mendeleev left gaps for unknown elements
2) A-p, B-s, C-q, D-r
Gallium, Germanium and given their
3) A-s, B-p, C-r, D-q
respective names as
4) A-s, B-p, C-q, D-r
1) Eka – boron and Eka – carbon
19. Which of the following elements obey
2) Eka – aluminium and Eka – carbon
Newland’s octave rule?
3) Eka – aluminium and Eka – silicon
1) Na, K, Rb 2) F, Cl, Br
4) Eka – boron and Eka silicon
3) Be, Mg, Ca 4) B, Al, Ga
26. Lanthanum and lanthanides belong to _____
20. The group in the periodic table that contains
and _____ blocks respectively
the elements in all the different physical states
1) d and f
at room temperature is
2) d and d
1) 15 2) 1
3) f and f
3) 17 4) 14
4) f and d
 3
27. Column – I Column – II +
1) N (g) + e− → N (g)
(Atomic number (IUPAC symbol) 2) O(g) + e − → O (g)
−

of elements) −1
A) 105 P) Uun 3) S(g) + e − → S−(g)2
+
B) 107 Q) Uns 4) Na (g) + e− → Na (g)
C) 109 R) Unp 34. The correct order of electron gain enthalpy
D) 110 S) Une for the halogens
1) A-R, B-P, C-S, D-Q
1) F > Cl > Br > I 2) I > Br > Cl > F
2) A-P, B-R, C-S, D-Q
3) Cl > F > Br > I 4) Br > F > Cl > I
3) A-R, B-Q, C-S, D-P
35. If the ionization potential of an element is x,
4) A-Q, B-R, C-S, D-P
electron affinity is y and electronegativity Z
28. The correct increasing order of first ionization
then which of the following relation is correct
enthalpy is :
1) 2Z – Y – X = 0 2) 2X – Y – Z = 0
1) Li < Be < B < C < N < O < F
3) 2Y – X – Z = 0 4) All the above
2) Li < B < Be < C < O < N < F
36. Which ion has greatest radius in the following
3) Li < B < Be < C < N < O < F
1) H– 2) F–
4) Li < Be < B < C < O < N < F
3) Br– 4) I–
29. Zr and Hf have similar atomic radii because of
37. Covalent radius of ‘Cl’ is 99 pm. Select best
1) belongs to same group
representation of Cl2 molecule
2) diagonal relationship
3) lanthanide contraction
4) having similar chemical properties 1) 2)
30. Which of the following pairs are isoelectronic
species?
1) Ca+2 & K+ 2) P–3 & S–2
3) Both (1) and (2) 4) Na+ & K+ 3) 4)
31. The ions O–2, F–, Na+, Mg+2 and Al+3 are
isoelectronic then their radii shows
1) an increase from Na+ to Mg+2 38. Which of the following are the correct order
2) an increase from F– to O–2 of ionization energy?
3) an increase from F– to Na+ a) Be+ > Be b) Be > Be+
4) an increase from O–2 to Mg+2 c) C > Be d) B > Be
32. The first four successive ionization energies of 1) b & c 2) c & d
an element X are 200, 800, 1327 & 9100 3) a & c 4) none of these
kJ/mole respectively. Find the formula of its 39. If the ionization potential and electron affinity
oxide of an element is 18.4 and 4.15 eV respectively.
1) X2O3 2) XO Then the electronegativity of an element is
3) X2O4 4) XO2 (according to Pauling)
33. Which of the following cases electron gain 1) 4.02 2) 3.87
enthalpy is positive? 3) 1.34 4) 2.82
 4
40. In which of the following is not correct 47. Which of the following set of oxides is
according to the property written against it amphoteric nature?
1) C < N < O < F : Increasing non-metallic 1) CO, NO, N2O 2) SO3, SO2, Cl2O7
character 3) Al2O3, ZnO, BeO 4) Na2O, MgO, BaO
2) Sr < Ca < Mg < Be : Increasing metallic 48. The period number in the long form of the
character periodic table is equal to
3) B < C < O < N : Increasing first ionization 1) magnetic quantum number of any element
energy of the period.
4) Li < Na < K < Rb : Increasing in atomic 2) atomic number of any element of the
radius period.
41. The correct order of acidic nature of the 3) maximum Principal quantum number of
oxides of chlorine is any element of the period.
1) Cl2O < ClO2 < Cl2O6 < Cl2O7 4) maximum Azimuthal quantum number of
2) ClO2 < Cl2O < Cl2O6 < Cl2O7 any element of the period.
3) Cl2O < ClO2 < Cl2O7 < Cl2O6 49. Which one of the following statements related
4) Cl2O7 < Cl2O6 < ClO2 < Cl2O to the modern periodic table is incorrect?
42. Consider the elements Al, P, Cl the correct
1) The p-block has 6 columns, because a
decreasing order of Non-metallic character
maximum of 6 electrons can occupy all the
1) Cl > Al > P 2) Cl > P > Al orbitals in a p-subshell.
3) Al > P > Cl 4) P > Al > Cl 2) The d-block has 8 columns, because a
43. Which of the following sets of oxides is basic maximum of 8 electrons can occupy all the
in nature orbitals in a d-subshell.
1) Na2O, Al2O3, BaO 3) Each block contains a number of columns
2) Na2O, MgO, BaO equal to the number of electrons that can
3) Al2O3, ZnO, Na2O occupy that subshell.
4) N2O, Al2O3, BaO
4) The block indicates value of Azimuthal
44. The most electro positive element is?
quantum number (l) for the last subshell
1) Na 2) Cu that received electrons in building up the
3) Cs 4) Ca electronic configuration.
45. What property of oxygen atom is represented
50. Which of the following is generally true
by the equation O(g) + e– → O(g)
−
regarding effective nuclear charge (Zeff) :
1) electronegativity 1) It increases on moving left to right in a
2) first electron gain enthalpy period.
3) first ionization energy 2) It remains almost constant on moving top to
4) electropositivity bottom in a group.
46. According to diagonal relationship, Li is 3) For isoelectronic species, as Z increases,
shows diagonal relationship with Zeff decreases.
1) Na 2) Al 4) Both (1) and (2)
3) Mg 4) Si
 5
51. Which can have both +ve and –ve oxidation 58. Considering the elements B, Al, Mg, and K,
states in their compounds the correct order of their metallic character is :
1) F 2) I 1) B > Al > Mg > K
3) Na 4) Al 2) Al > Mg > B > K
52. The oxidation state of nitrogen varies from : 3) Mg > Al > K > B
1) –3 to + 5 2) 0 to +5 4) K > Mg > Al > B
3) –3 to 1 4) +3 to +5 59. Which one of the following arrangements
53. In which of the following elements, +3 represents the correct order of electron gain
oxidation state is more stable than +5 ? enthalpy (with negative sign) of the given
1) P 2) As atomic species ?
3) N 4) Bi 1) Cl < F < S < O
54. Which of the following is correct order of 2) O < S < F < Cl
stability : 3) S < O < Cl < F
1) Tl3+ > Bi3+ 2) PbO2 > PbO 4) F < Cl < O < S
2+ 2+ 60. Assertion : F atom has a less negative
3) BiI5 < BiF5 4) Sn = Ge
55. Which one of the following statements is electron affinity than Cl atom.
incorrect in relation to ionisation enthalpy ? Reason : Additional electrons are repelled
1) Ionization enthalpy increases for each more effectively by 3p electrons in Cl atom
successive electron. than by 2p electrons in F atom.
2) The greatest increase in ionization enthalpy 1) Both Assertion and Reason are true, and
is experienced on removal of electron from Reason is the correct explanation of
core of noble gas configuration. Assertion.
3) End of valence electrons is marked by a big 2) Both Assertion and Reason are true, but
jump in ionization enthalpy. Reason is not correct explanation of
4) Removal of electron from orbitals bearing Assertion.
lower n value is easier than from orbitals 3) Assertion is true but Reason is false.
having higher n value. 4) Assertion is false but Reason is true.
56. The first ionisation enthalpies of Na, Mg, Al 61. Assertion : The first ionization energy of Be
and Si are in the order : is greater than that of B.
1) Na < Mg > Al < Si Reason : 2p orbital is lower in energy than 2s.
2) Na > Mg > Al > Si 1) Both Assertion and Reason are true and
3) Na < Mg < Al < Si Reason is the correct explanation of
4) Na > Mg > Al < Si Assertion.

57. The order of electron gain enthalpy 2) Both Assertion and Reason are true but
(magnitude) of O, S and Se is Reason is not correct explanation of
Assertion.
1) O > S > Se 2) S > Se > O
3) Assertion is true but Reason is false.
3) Se > S > O 4) S > O > Se
4) Assertion is false but Reason is true.
 6
62. The size of the iso-electronic species Cl–, Ar 3) lesser nuclear charge and greater first
and Ca2+ is affected by :  ionization enthalpy
1) Effective nuclear charge 4) greater nuclear charge and greater first
2) Principal quantum number of valence shell ionization enthalpy
3) azimuthal quantum number of valence shell 65. The electron gain enthalpy (in kJ/mol) of
4) electron-electron interaction in the outer fluorine, chlorine, bromine and iodine,
orbitals respectively are :
63. The element having greatest difference 1) –296, –325, –333 and –349
between its first and second ionization 2) –333, –349, –325 and –296
energies, is 3) –349, –333, –325 and –296
1) Ba 2) K 4) –333, –325, –349 and –296
3) Ca 4) Sc 66. The acidic, basic and amphoteric oxides,
64. In comparison to boron, beryllium has : respectively, are :
1) greater nuclear charge and lesser first 1) Na2O, SO3, Al2O3
ionization enthalpy. 2) N2O3, Na2O, Al2O3
2) lesser nuclear charge and lesser first 3) Cl2O, CaO, P4O10
ionization enthalpy 4) MgO, Cl2O, Al2O3