26-10-24_Jr.IPL-IC_ Jee-Main_WTM-13_Key & Sol's (2)

SRI CHAITANYA IIT ACADEMY, INDIA 26-10-24_Jr.
IPL-IC_ Jee-Main_WTM-13_Key & Sol's
Sri Chaitanya IIT Academy.,India.

 A.P  T.S  KARNATAKA  TAMILNADU  MAHARASTRA  DELHI  RANCHI
A right Choice for the Real Aspirant
ICON Central Office - Madhapur - Hyderabad
SEC: Jr. IPL-IC JEE-MAIN Date: 26-10-2024
Time: 09.00Am to 12.00Pm WTM -13 Max. Marks: 300
KEY SHEET
PHYSICS
1) 4 2) 3 3) 3 4) 2 5) 2
6) 2 7) 4 8) 1 9) 4 10) 4
11) 2 12) 2 13) 2 14) 2 15) 3
16) 3 17) 1 18) 3 19) 2 20) 1
21) 2 22) 2 23) 6 24) 4 25) 7
26) 1 27) 19 28) 8 29) 40 30) 12
CHEMISTRY
31) 2 32) 4 33) 4 34) 4 35) 1
36) 2 37) 2 38) 4 39) 4 40) 2
41) 2 42) 2 43) 3 44) 4 45) 2
46) 3 47) 4 48) 2 49) 1 50) 1
51) 189 52) 2 53) 182 54) 6 55) 710
56) 0 57) 4 58) 6 59) 4 60) 2
MATHEMATICS
61) 4 62) 1 63) 2 64) 1 65) 4
66) 2 67) 4 68) 3 69) 3 70) 2
71) 2 72) 2 73) 2 74) 2 75) 3
76) 1 77) 2 78) 3 79) 1 80) 2
81) 8 82) 6 83) 130 84) 16 85) 25
86) 8 87) 2 88) 10 89) 15 90) 79
Sec: Jr. IPL-IC Page 1

SRI CHAITANYA IIT ACADEMY, INDIA 26-10-24_Jr.IPL-IC_ Jee-Main_WTM-13_Key & Sol's
SOLUTIONS
PHYSICS
1. When particle executing S.H.M moves from
2 A 
A A  
T 2  4 2A
 to  it takes S  Vmax    
2 2 4 T 
4
T
1
2. Potential energy = kx 2
2
1 2 1 2
Kinetic energy = kA  kx
2 2
According to given condition
1 2 1 2 1 2 A2 A
kx  kA  kx  k 2 x 2  kA 2  x 2  x
2 2 2 2 2
x  Asin  wt  δ 
A
At t  0, x 
2
3. A 1
 Asinδ   sin δ
2 2
π
δ
6
4. Criteria of SHM:
Acceleration at any instant is directly proportional to the displacement of the body from
the mean position and is always in opposite direction of the displacement.
a∝-x
a=-mω2x
Hence, SHM is not a uniformly accelerated motion as acceleration varies with

displacement.
Velocity in SHM is given as, v  ω A 2  x 2
Hence, velocity is non-uniform in SHM.
Both statements are true, but reason is not the correct explanation of the assertion.
5. Conceptual
6. A pseudo force F = ma is acting on the block towards left. Since magnitude of the force is
constant, therefore, maximum elongation of the spring will be equal to 2ma/K.
For equilibrium/mean position, elongation of the spring should be equal to ma/K and the
2ma ma ma
amplitude of oscillations will be, A   
K K K
1
7. TE  KA2
2
Here K & A are constants hence TE is also constant.
8. From y = Asin wt
9. In simple harmonic motion y=asinωt and v=aωcosωt
y2 v2
from this we have 2  2 2  1 , which is an equation of ellipse.
a a
10. Conceptual
11. a=-ω2x⇒a∝x ⇒FR∝x
V  ω A 2  x 2 ⇒Vmax=Aω (at mean position) ⇒|amax|=ω2A (at extreme position)
12. For a simple harmonic motion,
Displacement equation: x=A sinωt
Velocity equation: v=Aω cosωt
Acceleration equation: a=-Aω2 sinωt
Here, all are varying with time.
Hence, assertion is true.
In a non-viscous medium, damping force is zero. So, energy loss is zero. Hence, the total
energy will be constant.
Reason is true.
Energy conservation does not clarify about the changing nature of velocity and
acceleration of the particle performing SHM.
Hence, both (A) and (R) are true and (R) is the correct explanation of (A).
13. ω2=α
 
2
T

14. At A: v= 0 i.e, particle is at extreme position. At B: v is maximum i.e., particle is at mean

position, so acceleration of particle is zero.
At C: v =0 and after some time its velocity is negative. Hence, particle is at x = +A i.e.,
acceleration of particle is maximum in negative direction.
k 1
15. ω . so, ω 
m m
ω2 m1 1 1
  
ω1 m2 2 2
16. By using concept of phasor diagram. Particle starts from π/6.
x=Acos(ωt+ϕ)
x=r cos(ωt+π/6)

3m
T1  2π
2k
m
17. T2  2π
3k
3m
2π
T1 2k  3

T2 m 2
2π
3k
1 1
P.E 
2 2

m 2 x 2 ; K  E  m 2 A 2  x 2 
18.
1
T.E  m 2 A 2
2
At x = 0 (mean position), the P. E is minimum, the K.E is maximum.
At x = A (extreme position), the P. E is maximum, the K.E is minimum.
Total energy is conserved in SHM.
19. m = 2 kg; F=(8–2x)N
A) at equilibrium F = 0 so, x = 4 m
B) Because it released from extreme position amplitude A = 6 - 4 = 2 m
C) F=8−2x ⇒F−8=−2x⇒k=2 ⇒mω2=k=2 ⇒ω2=1⇒T=2π s

T 2π π
Time taken from x = 2 to x = 4 (extreme to mean position) t    s
4 4 2
1 1
D) Energy, E  kA2   2  22  4 J
2 2
π
E) As the particle has started its motion from +ve extreme, phase constant,  
2
1
20. v max  A ; a max  ω2 A; TE  m 2 A 2
2
21. In figure (1) force constant is ka=k
k k k
In figure (2) force constant is kb   [∵ they are joined in series]
kk 2
M 1
Time period of spring T  2 T 
K k
Tb k k
  a   2
Ta kb k
2
22. Fmax = mω2A = 10 × 10–3 × 102 × 0.5 ⇒Fmax = 0.5 N
23. Let say x=Asinωt
At t=0, x=0
A A 
Put x    A sin t  t 
2 2 6
2 t  T
  t 
T 6 12
T 2 1
Time taken to travel from mean position to half amplitude is , so  s
12 12 6
2
1 1  A 1 1  1
24. P m 2 y 2  m 2     m 2 A2   E
2 2 m 4 2  4
x  4
d2 y 4π 2 2π 2π
25. 49 2
 4π 2
y  0  ω   rad / s  T   7s
dt 49 7 ω
m
26. T  2π T m
k
T2 m3 2 m3 4 m3

      4m  m  3  m  1
T1 m 1 m 1 m
th th
5 1 1
27. of oscillation     of oscillation
8  2 8
  2  7  2  7T
    t ,    t,   t,t 
6  T  6  T  12

28. T = t1+t2+t3+t4=2+2+2+2=8sec
T
 4sec  T  8sec
2
29. Given, F = -25 x

Compare with F = - Kx
K = 25 N/m
K
Angular frequency of oscillation ω 
M
25
ω  10rad / s
0.25
Maximum speed of particle Vmax=Aω ⇒4=A(10) ⇒A=0.4m=40cm
30. A = 0.06 m
T = 3.14 s
 2π  2  3.14
Vmax  Aw  A    0.06   0.12 m / s  12 cm / s
 T  3.14
CHEMISTRY
1
A g   Bg  C g 
2
31. Initial : Pi 0 0
α
At eq.: Pi 1  α  Pi  α Pi
2
Now, equilibrium pressure
 
   1 
P  Pi   1   PA   P
 2  1
 
 2 
   α 
 α   
PB    PPC   2  P
α α
 1   1 
 2  2

1
P 2  PB
K  c
PA
3 1
α2p2
K 1
(2  α) 1  α 
2
1
SO3  g   SO2  g   O2  g  : K c  4.9  102
2
32. 2 SO2  g   O2  g   2 SO3
1 1 106
K  2 
1
  0.000416  10 4  416
 
c 2
Kc 49 103 2401
H 2C 2 O 4  H   HC2 O 4 K a1
33. H 2C 2 O 4  H   C2 O 42  K a 2
H 2C 2 O 4  2H   C 2 O 24 K a 3  K a1  K a 2
K P  KC ( RT )Δn
Δn  nP  nR
34.  1
 1  1  
 2
1

2
K P  KC ( RT )1/ 2
KP 1

KC RT
35. PCl5=5 mole
Ar=4 mole
9  0.82  610
PTotal   4.5atm
100
5  4.5 4  4.5
PPCl5   2.5; PAr  2
9 9
PCl5  PCl3  Cl2

2.5  P P
Ptotal  2.5  P  P  P  PAr  6
P  1.5
1.5 1.5
Kp   2.25
1

36. Conceptual
X  Y ; K1  1.0
Y  Z ; K 2  2.0
Z  W ; K 3  4.0
37.
____________________
X  W K  K1  K 2  K3
 1 2  4  8
38. Conceptual
H 2  I 2  2 HI
39.
g g g
Same vessel = V same
No. of molecules same i.e. No. of moles same
Conc. is same Δ x=0
 K P  KC
[ HI ]2 e2
KC   1
 H 2   I2  e  e
 K p  K c  x  101  10 101  1
 x  10
40. More H-bonds⇒More viscous
41.
42.
43.

44. 2-butyne with Na/liq NH3 gives trans alkene
2-butyne with pd/Baso4 gives cis alkene.
45. If both (A) and (R) are true but (R) is not the correct explanation of (A)
46. A →Q; B→R,T; C→P;D→P
47. Both Assertion and Reason are true and Reason is correct explanation of Assertion.
Markovnikoff product
48.
49. Statement I and II are correct.

Tertiary alkanes can be oxidized to alcohol by treating with KMnO4.
50. BH 2  N2  2.NH3
 NH 3 eq
2
K eq 
 H 2 eq  N3 eq
3
51. On reaction, 2SO2(g)+O2(g)⟶2SO3(g)

Given values are : p SO  45kPa, pO  530 Pa  0.53kPa
3 2
p SO2  45kPa
2
 p SO g 
Now, K p   3  
2
 p SO g    pO 
 2     2
On putting given values, we get,
(45) 2 2025 1
 Kp     1.886
(45)  0.53 2025  0.53 0.53
2
 188.6  10 2  189
Hence, the equilibrium constant, Kp = 189.

H 2 O  H 2  12 O 2
52. 1 0 0
x
1 x x
2
1
 x 2
x  
k P  2  103  2
1 x
xx 1/2
2  103  1  x  1
2
2 2  103  x 3/ 2
3
103  x 3/2
22
23 106  x 3
x  2  102
%x  2
A  B  C  D
53. Initially, 1 1 1 1
At equilibrium, 1  x 1 x 1 x 1 x
2
 1 x 
KC   
 1 x 
2
 1 x 
100   
 1 x 
1 x
 10
1 x
9
x
11
Moles of D  1  x
9 20
 1 
11 11
 1.818  181.8  102  181.8  102
 182  102 M
k r 102
54. AB  CD
k j 103
k2 = 10
Δ10  2.303RT by k  8.3  103  300  2.3  5.72  6kg

N 2O4  2 NO2
1 mol 0
55.
1  0.5  mol 0.5  2mol
0.5 mol 1 mol
2
 1 
  1
1.5  1 100
kP     = 1.33
 0.5  0.75 75
 1
 1.5 
G 0   RT nk P
G 0   RT  2.3 log k P  8.31 300  ln 1.33  710.45J / mol 710J / mol
56.
57.
No. of stereoisomers = 4
58. .Shows both geometrical and optical isomerism, Total

alkenes =4
. Shows only geometrical isomerism Total alkenes = 2
4 + 2 = 6 alkenes
59.
60. Two products are possible.

MATHEMATICS
 1 3   84 3   1  1  2  π π π
tan 1    sec    tan 1 
1
61.   sec   663
 3 3   
 63 3   3  3
62.
 e1/ x  e 1/ x 
f  x   x  1/ x 1/ x 
e e 
 1  e 2/ x   1 0 
RHL  lim  lim x  2/ x 
 0 0
x 0 x 0
 1 e   1 0 
 e2/ x  1 
LHL  lim  lim x  2/ x 0
x 0 x 0
 e 1 
 LHL  RHL  f  0   f is continuous at x  0
 1  e 2/ x 
x 0
1  e 2/ x 
 
f 1 0  lim
x 0

x0
1
 e 2/ x  1 
x  2/ x 0
e 1
 
f 1 0  lim
x 0

x0
 1
f1 0   f 0 
 1 
f is not differentiable at x  0
63.
x2  4x  2
   
2 2
 1 x 2  4 x  2  x 2  3
x 3
2
   
2 2
 x2  4x  2  x2  3  0
1
 2x 2
 4 x  5   4 x  1  0  4 x  1  0  x  
4
64.

sin h 1x  log x  1  x 2 

f  x   log x  1  x 2 
 
 1 x2  x  1 x2  x 
f   x   log   
1 x  x
2 
 
 log 
 1 x2  x2 
 x  1 x 
2

  log 
1
 x  1 x 
2

2

   log x  1  x  f  x 
f is odd function
π
65. tan 1 x  x  1  sin 1 x 2  x  1 
4
Domain, x(x+1)≥0
0≤x2+x+1≤1
So, only when x2+x=0, equation will be defined.
x=0,−1
π
At x  0, tan 1 0  sin 1 1 
2
π
x  1, tan 1 0  sin 1 1 
2
∴ No solution
66. f(x)=|x-1|+|x+1|
1  x  1  x if x  1

f  x   1  x  1  x if 1  x  1
x  1  x  1 if x  1

2x ; if x  1

f  x   2 ; if 1  x  1
2x ; if x  1

lim f  x   lim f  x   f  x   f is continuous at x
x 1 x 1
 1lim f  x   lim f  x   f 1  2

x 1 x 1
 
 f is continuous at x  1f 1 1  2, f 1 1  0 
   
f 1 1  0, f 1 1  2
 f is not differentiable at x  1,1
x2 x2
67.  0 also x 2
 x 2
 1  1
x2 1 x2 1
Range of f  x    4 sin 1  0  , 4sin 1 1   0, 4π / 2   0, 2π 
68.
 1 x2 
cosec h 1    k tan h 1x
 x 
 
 1 x2 
cosec h 1  y
 x 
 
1 x2
cosec hy 
x
Tan hy = x
y  tan h 1x
 1  x2 
cosec h 1    tan h 1x
 x 
 
K=1
4 4
69. Let tan 1    tan  
3 3
 3 2   3 3 2 4
E  cos 1  cos   sin   cos 1    · 
 10 5   10 5 5 5 
 9 8   25  1 
 cos 1     cos 1    cos 1   
 50 25   50  2 3
 p sin x  q e  x  rx 3 : x0
f  x   p sin x  qe x  r x  
3
70.
p sin x  qe  rx :x  0
x 3
f 1  x    p cos x  qe  x  3rx 2  p  q
 at x 0 
1
f 0    p cos x  q e
 x
 3rx 2 z at x  0  p  q
f is differentiable if -p-q=p+q ⇒p+q=0 and r can be any real number

50
 1 
71. Given, tanr 1
1
 2p
 2r 
Now,  tan 1  
2

 1  4r  1 
2
  2r  1   2r  1 
  tan 1      tan  2r  1  tan  2r  1
1 1
 
1  2r  1 2r  1  
  
 tan 1 3  tan 1 1  tan 1 5  tan 1 3  tan 1 101  tan 1 99 
 101  1   50 
 tan 1 101  tan 1 1  tan 1    tan 1  
 1  101   51 
50 50
 tan 1  p  tan p 
51 51
2 3 1

2 3 tan h  tan h 1
72. P1 : tan h  , tan h  tan h  α  β    3 5  15 
3 5 1  tan h tan h 1  2 3 9 9
3 5 15

P2 : sin h cos h 1 3  sin h 1 7 
    50  7  
sin h log 3  8  log
sin h  log  3  8  50  7  

log 3 8  50  7  
 log 3 8  50  7 
e e
2
 3  8   
50  7  3  8  50  7 
2

2 21  400 
2
21  20
41

 2 3
P3 : tan h  tan h 1  tan h 1 
 3 5
 2  3
tan h  tan h 1   tan h  tan h 1 
 3  5
 2  3
1  tan h  tan h 1  tan h  tan h 1 
 3  5
2 3

3 5  19
2 3 21
1
35
P2 >P3  P1
 5 
Let A  tan  2 tan 1    sin 1    .....  i 
3
73.
 5  13
 
2x
Now, using 2 tan 1 x  tan 1
1 x2
 3   6 
 2    
3 5  30   15 
2 tan 1    tan 1    2   tan 1  5   tan 1    tan 1  
5
   3  9
 1  16
  8
1     25 
 5 
Let sin 1    θ, then sin θ 

5 5
 13  13
5
5
sin θ 13  5 5
 tan θ    13  θ  tan 1    sin 1  
1  sin θ
2 2 12  12   13 
5
1   13
 3
From Eq. (i),
  15 5 
   
  15   5  8 12  
A  tan  tan 1    tan 1     tan  tan 1 
 8  12     1   15  5   
   8  12   
      
  55  
 1  24    1 55  4   220  220
 tan  tan     tan  tan  tan  tan 1 
  21    21    21  21
  96  

x : x 1

f  x   2  x : 1 x  2
74. 2  3x  x 2 :x  2

lim f  x   lim f  x   1
x 1 x 1
lim f  x   lim f  x   0
x  2 x 1
F(x) is a continuous function
   
f 1 1  1, f 1 1  1  f is not differentiable at x  1
f  2   1, f  2   1  f is differentiable at x  2
1  1 
75. A : 2cos h3 cos h5
2cos hx cos hy=cos h(x+y)+cos h(x-y) =cos h8+cos h2

 4 77  77 4
76. Given, sin 1  cos 1  tan 1  0 0    13  sin 1  tan 1  cos 1
17 5 36 17   36
  5
A B
  77  4   36  3 
sin 1  sin  A  B   sin A cos B  cos A sin B            8
17 17 85  5   85  5 
 sin 1  sin    cos 1 cos   3  8  8  2  
2 2
cosec hx  ec hx  x
 x x
e e x
e e
77. I) x x
2e  2e  2e  2e
x x
4e  x
   2e  x cosec h2x
e 2x  e 2x e2x  e 2x
1  tan hx
II)  cos 2x  sin h2x
1  tan hx
1
1  cos 
III) log e (cot )  log 
θ 2
  tan h 1  cos 
2  1  cos 
log  x  1  x 2  2x 
 
IV) log  x  1   x  1  1
2
 
cos h 1  x  1
e x  e x 1
78.    
log 2  5  log 3  10  x  e x  6  2 10  3 5  50  cosh  x  
2

 12  2 50
2


79.
 a a  a a 
tan 1  2 1  ..  tan 1  2022 2021 
 1  a1a 2   1  a 2021a 2022 
 tan 1 a 2  tan 1 a1  ..  tan 1  a 2022   tan 1  a 2021 
π
 tan 1  a 2022   tan 1 a1  tan 1  a 2022  
4
π π
  cot 1  a 2022    a1  1
2 4
π π
  cot 1  a 2022    cot 1  2022 
4 4
80. We know that
 |x-a| is not differentiable at x=a,

 Cos|x| is differentiable everywhere.
 Sin|x-a| is not differentiable at x=a
 |(x-a)(x-b)| is not differentiable at x=a, x=b
The given function is f  x   x  1 cos x  2  2sin x  1   x  3 x 2  5x  4
This can be written as f  x   x  1 cos  2  x   2sin  x  1   x  3  x  1 x  4 
Observing the above function, the function is not differentiable at x=1,4
Therefore, the number of points where the function is not differentiable is 2.
      
 cos  4  4   1   cos  1 
81. tan 1      tan 1 4
   
 sin   sin
 4   4 
 1 2  
tan 1    
 1  8
Therefore, k=8
82.
π π 
θ , x  log cot   θ e x  cot 750  2  3
6 4 
sin hx 
ex  ex 2 3  2  3
 

2 3
 3

2 2 2
sin x  3
2 3 sin x  6
2
83. 
 x  sin 2 tan 1    1  2
and
1 4 1 3
y  sin  tan 1   sin  cos 1 
2 3 2 5
 3
 1 
y  sin  sin 1 5   sin  sin 1 1   1
2   
  5 5
 
 
Given that y2=1−x

1 2
 1  1   2  5  5 2  10  2 2  5  2  0
5 1  2
1
  2,
2
1
 16 3  16  23  16 
aS 23
= 130
84.
sin x cos hy  cos
3
cos x sinhy  sin , tan x 
4
sin x cosh y  cos x sin h 2 y  1
2 2 2
2 2
3 4
5
 2

  1  sin h y    sin h y  1
5
2
9  9 16 
    sin h 2 y  1
25  25 25 
9 16
sin h 2 y  1  
25 25
85. f(x)=[a+13 sinx]=a+[13sinx]
We know that for f(x)=[n+psinx] (p is a prime),
No.of non- differentiable points in (0,π) =2p – 1 = 25

86.
 1

sech 2  tan h 1   cosech 2 cot h 1 3
 2

 1

1  tan h 2  tanh 1   cot h 2 cot h 1 3  1
 2

2
1
1      3  1
2
2
1
9
4
35
 8.75
4
Now [k ]  8
87.
9 x 2 12 x  4
Given, f  x   x 2  2 x  3 .e
f  x    x  3 x  1 .e 3 x  2
2
 x  3 x  1 .e3 x  2 ; x   3,  
2
f  x   {   x  3 x  1 .e 3 x  2 ; x   1,3

2
 x  3 x  1 .e3 x 2 ; x  , 1

2
Hence at x=−1,3 f(x)=0
Clearly, non−differentiable at x=−1 & x=3.
88.
14
Given cos hx  and sin hx  cos
3
14 4 2
sin  1  cos 2 θ  1  sin h 2 x  1  cos h 2 x  1  2      15 sin   10
9 9 3
89.
1
x;x  2

f  x   ax 2  2b; 2  x  2
 1
 ; x  2
 x
1
Continuous at x = 2   4a  2b
2
1
Continuous at x = -2   4a  2b
2
Since, it is differentiable at x = 2
L.H .D  R.H .D
1
  2ax
x2
1 1 3
  4a  a  and b 
4 16 8
90.
 1
f  x   4 2x  3  9  x    12  x  20
 2
x   20, 20 
1
f(x) is not Differentiable at x=I∈{−19,−18,…..0,…19}=39 at x  I  , f  x  Non
2
differentiable at  ,  , ,  ,  , , ,  = 40
39 37 3 1 1 39
 2 2 2 2 2 2
3
Check at x 
2
3
Discontinuous at x 
2
No. of points of non-differentiability = 79

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SRI CHAITANYA IIT ACADEMY, INDIA 26-10-24_Jr.

IPL-IC_ Jee-Main_WTM-13_Key & Sol's

Sri Chaitanya IIT Academy.,India.

Sec: Jr. IPL-IC Page 1

According to given condition

Hence, SHM is not a uniformly accelerated motion as acceleration varies with

Velocity in SHM is given as, v  ω A 2  x 2

Hence, velocity is non-uniform in SHM.

Here K & A are constants hence TE is also constant.

9. In simple harmonic motion y=asinωt and v=aωcosωt

11. a=-ω2x⇒a∝x ⇒FR∝x

V  ω A 2  x 2 ⇒Vmax=Aω (at mean position) ⇒|amax|=ω2A (at extreme position)

12. For a simple harmonic motion,

Displacement equation: x=A sinωt

Velocity equation: v=Aω cosωt

Acceleration equation: a=-Aω2 sinωt

Here, all are varying with time.

Hence, assertion is true.

14. At A: v= 0 i.e, particle is at extreme position. At B: v is maximum i.e., particle is at mean

16. By using concept of phasor diagram. Particle starts from π/6.

Sec: Jr. IPL-IC Page 4

At x = 0 (mean position), the P. E is minimum, the K.E is maximum.

At x = A (extreme position), the P. E is maximum, the K.E is minimum.

Total energy is conserved in SHM.

19. m = 2 kg; F=(8–2x)N

C) F=8−2x ⇒F−8=−2x⇒k=2 ⇒mω2=k=2 ⇒ω2=1⇒T=2π s

23. Let say x=Asinωt

T2 m3 2 m3 4 m3

Sec: Jr. IPL-IC Page 6

29. Given, F = -25 x

Maximum speed of particle Vmax=Aω ⇒4=A(10) ⇒A=0.4m=40cm

Now, equilibrium pressure

Sec: Jr. IPL-IC Page 7

35. PCl5=5 mole

PCl5  PCl3  Cl2

Sec: Jr. IPL-IC Page 8

40. More H-bonds⇒More viscous

Sec: Jr. IPL-IC Page 9

46. A →Q; B→R,T; C→P;D→P

49. Statement I and II are correct.

51. On reaction, 2SO2(g)+O2(g)⟶2SO3(g)

Hence, the equilibrium constant, Kp = 189.

Sec: Jr. IPL-IC Page 11

58. .Shows both geometrical and optical isomerism, Total

. Shows only geometrical isomerism Total alkenes = 2

60. Two products are possible.

So, only when x2+x=0, equation will be defined.

 1lim f  x   lim f  x   f 1  2

Range of f  x    4 sin 1  0  , 4sin 1 1   0, 4π / 2   0, 2π 

f is differentiable if -p-q=p+q ⇒p+q=0 and r can be any real number

Sec: Jr. IPL-IC Page 16

Let sin 1    θ, then sin θ 

From Eq. (i),

Sec: Jr. IPL-IC Page 17

F(x) is a continuous function

75. A : 2cos h3 cos h5

2cos hx cos hy=cos h(x+y)+cos h(x-y) =cos h8+cos h2

 sin 1  sin    cos 1 cos   3  8  8  2  

Sec: Jr. IPL-IC Page 18

80. We know that