Ecss Q ST 70 01C
Ecss Q ST 70 01C
15 November 2008
Space product
assurance
Cleanliness and contamination
control
ECSS Secretariat
ESA-ESTEC
Requirements & Standards Division
Noordwijk, The Netherlands
ECSS‐Q‐ST‐70‐01C
15 November 2008
Foreword
This Standard is one of the series of ECSS Standards intended to be applied together for the
management, engineering and product assurance in space projects and applications. ECSS is a
cooperative effort of the European Space Agency, national space agencies and European industry
associations for the purpose of developing and maintaining common standards. Requirements in this
Standard are defined in terms of what shall be accomplished, rather than in terms of how to organize
and perform the necessary work. This allows existing organizational structures and methods to be
applied where they are effective, and for the structures and methods to evolve as necessary without
rewriting the standards.
This Standard has been prepared by the ECSS‐Q‐ST‐70‐01 Working Group, reviewed by the ECSS
Executive Secretariat and approved by the ECSS Technical Authority.
Disclaimer
ECSS does not provide any warranty whatsoever, whether expressed, implied, or statutory, including,
but not limited to, any warranty of merchantability or fitness for a particular purpose or any warranty
that the contents of the item are error‐free. In no respect shall ECSS incur any liability for any
damages, including, but not limited to, direct, indirect, special, or consequential damages arising out
of, resulting from, or in any way connected to the use of this Standard, whether or not based upon
warranty, business agreement, tort, or otherwise; whether or not injury was sustained by persons or
property or otherwise; and whether or not loss was sustained from, or arose out of, the results of, the
item, or any services that may be provided by ECSS.
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Change log
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Table of contents
1 Scope.......................................................................................................................8
4 Principles ..............................................................................................................16
5 Requirements........................................................................................................17
5.1 Cleanliness and contamination control programme ................................................. 17
5.1.1 General....................................................................................................... 17
5.1.2 Documentation ........................................................................................... 17
5.1.3 Contamination budget ................................................................................ 18
5.1.4 Contamination predictions .......................................................................... 18
5.1.5 Contamination prediction with respect to budget........................................ 19
5.1.6 Cleanliness and contamination process flow chart..................................... 19
5.2 Phases ..................................................................................................................... 20
5.2.1 Design ........................................................................................................ 20
5.2.2 MAIT ........................................................................................................... 22
5.2.3 pre-launch and launch ................................................................................ 23
5.2.4 Mission ....................................................................................................... 24
5.3 Environments ........................................................................................................... 25
5.3.1 Cleanrooms ................................................................................................ 25
5.3.2 Vacuum facilities......................................................................................... 33
5.3.3 Other facilities............................................................................................. 34
5.4 Activities ................................................................................................................... 34
5.4.1 Cleaning of hardware ................................................................................. 34
5.4.2 Cleanliness monitoring of space hardware................................................. 36
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5.4.3 Cleanliness verification............................................................................... 39
5.4.4 Packaging, containerization, transportation, storage.................................. 42
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Annex M (informative) Cleaning methods ............................................................72
M.1 Removal of particulate contamination ...................................................................... 72
M.1.1 Overview..................................................................................................... 72
M.1.2 Vacuum cleaning and wiping...................................................................... 72
M.1.3 Gas jet cleaning.......................................................................................... 72
M.1.4 Tapes and films trapping ............................................................................ 73
M.2 Removal of molecular contamination ....................................................................... 73
M.2.1 Overview..................................................................................................... 73
M.2.2 Mechanical cleaning ................................................................................... 73
M.2.3 Solvent and detergent cleaning .................................................................. 73
M.2.4 Films trapping ............................................................................................. 73
M.2.5 Gas jet cleaning.......................................................................................... 73
M.2.6 Plasma cleaning ......................................................................................... 74
M.2.7 Bakeout ...................................................................................................... 74
M.2.8 Ultra-violet-ozone cleaning ......................................................................... 74
Figures
Figure 5-1: Graphical representation of ISO-class concentration limits for selected ISO
classes................................................................................................................. 27
Figure C-1 : Cleanliness and contamination control process overview .................................. 51
Tables
Table 5-1: Outgassing criteria for materials in the vicinity of sensitive items around RT ....... 21
Table 5-2: Outgassing criteria for materials in the vicinity of sensitive items at
temperature below RT ......................................................................................... 21
Table 5-3: Outgassing criteria for materials in the vicinity of cryogenic surfaces................... 21
Table 5-4: Selected airborne particulate cleanliness classes for cleanrooms and other
controlled environment ........................................................................................ 28
Table 5-5: Correlation airborne and PFO for cleanrooms ...................................................... 29
Table G-1 : Classification system........................................................................................... 64
Table H-1 : Correlation between ideal class of IEST-STD-CC1246D and obscuration
factor.................................................................................................................... 66
Table I-1 : Examples of compatibility of various solvents with listed materials ...................... 68
Table J-1 : Commercially available solvents evaporation residue.......................................... 69
Table K-1 : Molecular contaminant content of some wipe materials ...................................... 70
Table L-1 : Effect of humidity on materials and components ................................................. 71
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Introduction
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1
Scope
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2
Normative references
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3
Terms, definitions and abbreviated terms
3.2.3 bakeout
activity of increasing the temperature of hardware to accelerate its outgassing
rates with the intent of reducing the content of molecular contaminants within
the hardware
NOTE Bakeout is usually performed in a vacuum
environment, but can be done in a controlled
atmosphere.
3.2.4 biocontamination
contamination of materials, devices, individuals, surfaces, liquids, gases or air
with viable particles
[ISO 14698‐1:2003, 3.1.4] [ISO 14698‐2:2003, 3.4]
3.2.5 cleaning
actions to reduce the contamination level
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3.2.8 cleanliness verification
activity intended to verify that the actual cleanliness conditions of the space
system, the cleanrooms or the vacuum chambers are in conformance with the
applicable specifications and other cleanliness requirements
3.2.9 cleanroom
room in which the concentration of airborne particles is controlled, and which is
constructed and used in a manner to minimize the introduction, generation and
retention of particles inside the room, and in which other relevant parameters,
e.g. temperature, humidity and pressure, are controlled as necessary
[ISO 14644‐6]
3.2.11 contaminant
any unwanted molecular or particulate matter (including microbiological
matter) on the surface or in the environment of interest, that can affect or
degrade the relevant performance or life time
3.2.12 contaminate, to
act of introducing any contaminant
3.2.16 fibre
particle with a length to diameter ratio of 10 or more
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3.2.17 FTIR spectrometer
analyser (chemical identification) of organic and inorganic contamination using
infrared wavelengths
3.2.21 monitoring
to perform routine, quantitative measurements of environmental parameters in
and around cleanrooms, clean zones, and other clean areas, including
contamination parameters
3.2.24 offgassing
evolution of gaseous products from a liquid or solid material into an
atmosphere
3.2.26 outgassing
evolution of gaseous species from a material, usually in vacuum
NOTE Outgassing also occurs in a higher‐pressure
environment.
3.2.27 particle
unit of matter with observable length, width and thickness
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3.2.29 particle size
apparent maximum linear dimension of a particle in the plane of observation as
observed with an optical microscope, or the equivalent diameter of a particle
detected by automatic instrumentation
NOTE The equivalent diameter is the diameter of a
reference sphere having known properties and
producing the same response in the sensing
instrument as the particle being measured.
3.2.30 particulate
of or relating to minute separate particles
3.2.32 plume
exhaust (molecules or particles) of thrusters and engines
3.2.33 purging
supply of clean gas to protect the critical hardware from contamination
3.2.38 venting
conveying unwanted gaseous products through an aperture
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3.2.41 witness sample
sample used to collect contaminants during exposure, usually in an
environmentally controlled area, and then analysed or measured
Abbreviation Meaning
ACS American Chemical Society
AIT assembly, integration and testing
AIV assembly, integration and verification
AO atomic oxygen
BOL beginning of life
CC contamination control
C&CCP cleanliness and contamination control plan
CRS cleanliness requirement specification
CVCM collected volatile condensable material
DIW deionised water
DML declared materials list
DOP dioctylphthalate
ECLS environmental control and life support
EGSE electrical ground support equipment
EMC electromagnetic compatibility
EOL end of life
EVA extra vehicular activity
FTIR Fourier transform infrared
GSE ground support equipment
HEPA high‐efficiency particulate air filter
ICC internal contamination control
IPA isopropyl alcohol
IR infrared
LEO low Earth orbit
MGSE mechanical ground support equipment
MLI multi layer insulation
MOC molecular contamination
MRR manufacturing readiness review
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4
Principles
The cleanliness and contamination control process is applied all along the
project life cycle, from the definition of the C&CCP programme during the early
phases (see clause 5.1) until its implementation during phases B, C, D, E and F
(see clause 5.2) through the systematic verification of the cleanliness
requirements baseline including: predictions through contamination modelling
and the establishment of agreed procedures (see clause 5.3 and 5.4) for:
environments control (see clause 5.3) packaging, containerization,
transportation and storage of the space system.
NOTE Figure C‐1 of Annex C gives an overview of an
example of a cleanliness and contamination process.
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5
Requirements
5.1.1 General
a. The supplier shall define and implement a cleanliness and contamination
control programme for each level of configuration.
NOTE 1 Surveys can also be made to determine the
contamination control requirements, based on
mission objectives and scenarios.
NOTE 2 The objective of this programme is, starting from
the mission performance requirements, to establish
cleanliness and contamination levels to be
achieved at different manufacturing, AIT and
mission stages.
NOTE 3 In general, the organization of regular workshops
dedicated to cleanliness and contamination control
for a specific programme is a good practice.
b. The supplier shall establish measures for the coordination and resolution
of cleanliness and contamination control issues among the parties
involved in the project.
5.1.2 Documentation
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c. The CRS should be prepared in collaboration with users and engineers
from the different disciplines.
NOTE Users can be, for example, experimenters or
scientists.
d. In case the CRS cannot be produced at an early stage of the design, a
cleanliness control policy document shall be used.
NOTE 1 The cleanliness control policy document gives the
correlation data between acceptable performance
losses and the contamination levels from library
search or from tests that are performed.
NOTE 2 The cleanliness control policy document can
become the CRS during the development of the
design.
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d. For each on ground activity, for launch and in‐orbit phases, the following
items shall be identified in the contamination prediction:
1. the seen environment,
2. the sensitive surfaces,
3. the duration of the exposure to this environment, and
4. the potential means of protection.
e. During all on ground activities, the contamination predictions shall be
consolidated with the results of molecular and particulate monitoring.
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5.2 Phases
5.2.1 Design
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i. The outgassing criteria for materials in the vicinity of sensitive items at
temperature below RT shall conform to Table 5‐2.
j. The outgassing criteria for materials in the vicinity of cryogenic surfaces
shall conform to Table 5‐3.
k. Volatile metals shall not be used.
NOTE 1 This is especially the case when the temperatures
are above room temperatures.
NOTE 2 Some metals such as cadmium and zinc have high
vapour pressures and deposit metallic films can
occur on adjacent surfaces.
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5.2.2 MAIT
5.2.2.1 Manufacturing
a. Personnel involved in the manufacturing of sensitive items shall be
trained with respect to the cleanliness control policy.
b. All elements manufactured in non‐controlled areas or under non‐clean
conditions shall be the object of a cleaning process until the cleanliness
requirements are met, before they are packaged for delivery.
c. Cleaning and packaging operations for all elements shall be processed
according to procedures approved by the customer for the specific
application/product.
d. Elements that can be cleaned after manufacturing shall be cleaned till the
cleanliness requirements are met.
e. For elements that cannot be cleaned after manufacturing, then
manufacturing and assembling areas shall meet the cleanliness level
requirements specification.
f. The conformity of the manufacturing facilities shall be verified during
MRR or TRR.
g. An audit of the manufacturing facilities shall be performed according to
ECSS‐Q‐ST‐10 clause 5.2.3 criteria.
h. An audits shall be held after problems have already occurred or as part
of a plan to establish if facilities and personnel are adequate.
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type of protection applied to critical hardware (e.g.
covers, shields and purging).
g. The conformity of the facilities shall be verified during MRR or TRR.
h. An audit of the integration facilities shall be performed according to
ECSS‐Q‐ST‐10 clause 5.2.3 criteria.
i. An audit shall be held after problems have already occurred or as part of
a plan to establish if facilities and personnel are adequate.
5.2.2.3 Testing
a. Involved personnel shall be trained with respect to the cleanliness policy.
b. For test centres, ECSS‐Q‐ST‐20‐07 shall apply.
c. The conformity of the facilities shall be verified during MRR or TRR.
d. An audit of the test facilities shall be performed according to ECSS‐Q‐ST‐10
clause 5.2.3 criteria.
e. An audit shall be held after problems have already occurred or as part of
a plan to establish if facilities and personnel are adequate.
5.2.3.1 General
a. Personnel involved in pre‐launch activities shall be trained with respect
to the cleanliness policy.
b. The space system shall be shipped to the launch base under clean
conditions as defined in the CRS and controlled by the C&CCP.
c. The potential contamination during launch preparation shall be also
controlled.
NOTE This can be done through the C&CCP or through
specific launch base procedures approved by the
project.
d. Contamination during launch shall be controlled through preventive
actions and specific design provisions.
NOTE Preventive actions can consist of cleaning and
purging of the fairing. Specific design provisions
can consist of shields controlling the
depressurization.
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b. The materials of the hardware in the vicinity of the space system shall
meet the same outgassing and surface‐cleanliness requirements as the
space system itself.
c. The building environment in which the spacecraft is put inside the
fairing shall be compatible with the spacecraft characteristics.
NOTE 1 Specific spacecraft design provisions can be
protection mechanisms used to limit the launch
contaminants, especially the “unknown” figure of
particle transfer during launch.
NOTE 2 A second design aspect is the location of the
contamination‐sensitive items with respect to the
position of thrusters and of pyrotechnics or other
contamination sources.
NOTE 3 The reflection by atmospheric molecules (i.e.
atmospheric scattering) or by outgassing
molecules (i.e. self‐scattering) can take place and
some form of modelling is of interest.
5.2.4 Mission
a. External contamination control during mission shall be done through
preventive actions, specific design provisions and operations.
NOTE 1 Preventive actions include materials selection (see
clause 5.5.3 in ECSS‐Q‐ST‐70‐02), bakeout (see
clause 5.4.3.2) and purging (see clause 5.4.3.3).
NOTE 2 Specific design provisions include the
implementation of heaters for decontamination of
sensitive surfaces, of shutters and baffles.
NOTE 3 Operations include shielding during dumping,
thrusters firing or venting,, decontamination of
sensitive surfaces through exposure to the Sun.
b. Fluids that can emerge to the exterior by leakage or intentional use of
valves shall be considered in the design and operational requirements of
system and equipment hardware.
c. A specific analysis shall be performed to ensure an optimum level of
detection, location and isolation techniques.
NOTE These fluids are originating from thermal,
environmental or life support systems or
subsystems or released due to crew activities
(nutrients, wastes), during maintenance and repair
and from experiments or payloads as well as the
propellant systems.
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5.3 Environments
5.3.1 Cleanrooms
5.3.1.3 Filters
a. In laminar flow cleanrooms, (HEPA) filters shall cover either one entire
wall or the entire ceiling, except when diffusion ceiling or wall systems
are used or when built‐in benches are included in the incoming air end of
the room.
b. Monitoring shall be done and any work with highly sensitive equipment
shall not be performed before the defined ISO class for the hardware has
been reached. as specified in the C&CCP for the following situations:
1. after the installation of new filters,
2. after “at rest “ period,
3. after stand by period.
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NOTE Due to the transitory pressure gradients,
contamination previously trapped by HEPA filters,
together with a reduction in the operating life of the
filters themselves can be released.
c. The air flow inside cleanrooms and independent HEPA filtering systems
shall be maintained during “at‐rest” periods, except for the maintenance
operations.
NOTE 1 For example, during filters replacement.
NOTE 2 Independent HEPA filtering systems can be like
those used for the laminar flow tents and benches.
NOTE 3 This is to avoid the risk of redistribution of
particles at restart of the flow.
NOTE 4 Exception can be made for independent HEPA
filtering systems that can work with a reduced air
flow rate during stand‐by periods.
d. In cases where a uniform and controlled molecular environment is
required, the filtering system shall be equipped with additional charcoal
filters positioned before the HEPA filters.
e. When charcoals filters are used, the initial charge shall be assessed on
installation and analysed regularly.
NOTE It can be useful to evaluate the charge in
contaminants of the filtering system which can
release its charge in contaminants trapped. in order
to be able to monitor the evolution and when a
failure occurs.
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larger than the considered particle size. Cn
is rounded to the nearest whole number,
using no more than three significant
figures.
N is the ISO classification number, which
does not exceed a value of 9. Intermediate
ISO classification numbers can be
specified, with 0,1 the smallest permitted
increment of N.
D is the considered particle size, in
micrometres.
0,1 is a constant, with a dimension of
micrometres.
NOTE 4 From the particle point of view, the number of
5 μm particles per given volume of air is much
more critical than the number of smaller particles,
since the fallout is mainly determined by particles
of 5 μm or larger. The cleanliness level of a
cleanroom can only be selected when the specified
obscuration factors for critical spacecraft surfaces
are known. The particle size 5 μm is often used as a
criterion, because for optical surfaces particles
larger than 5 μm are critical, whereas for bearings
and gears, particles in the range 10 μm to 40 μm
are more harmful.
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NOTE This can be done through the exposure of test
surfaces or samples to the environment and
counting the settled particles by appropriate
methods.
j. Air monitoring of class ISO 8 or better shall be achieved by means of light
scattering equipment.
k. Tests shall be performed to determine if leaks exceed the specified limits,
according to the filter characteristics:
1. in the filter media themselves,
2. in the bond between filter media and the interior of the filter
frame,
3. between filter frame gasket and filter bank supporting frames,
4. between supporting frames and walls or ceilings.
l. The cleanrooms shall have a monitoring function of the contamination
levels and the environmental parameters.
m. The cleanroom shall have an alarm function activated when warning
levels are exceeded.
NOTE 1 Those warning levels are usually defined well
below the out of specification limits in order to
prevent their exceedence.
NOTE 2 Environmental parameters are temperature,
relative humidity and differential pressure.
n. Planned corrective actions shall be initiated to re‐establish the nominal
conditions in the shortest possible time and to prevent recurrence.
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5.3.1.7 Surface molecular levels
a. Molecular deposits shall be monitored by exposure witness plates.
b. For actual measurements at least, two different witness plates shall be
placed in two different locations.
c. For each location, one of the two witness plates shall be analyzed at least
once month.
d. The other witness plate is cumulative and shall be analyzed after more
than one month.
e. These locations shall be selected in order to measure molecules in
significant points of the environment with at least one representative of
the empty cleanroom.
f. Molecular contamination in controlled environments shall not exceed
0,5 × 10‐7 g/cm2 during a continuous period of one week.
NOTE 1 In case of contamination sensitive equipment, a
lower level can be required, based on the
contamination budget (including exposure time).
NOTE 2 In a normal cleanroom (without charcoal filters)
levels can be achieved that are 10 to 100 times
better.
g. For those hardware items where the accumulation from the air becomes a
major issue, the use of charcoal filters as molecular contamination trap
should be considered.
NOTE Example of such a hardware are coated mirrors.
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b. Pressure shall decrease successively between the cleanroom, entrance
lock, anteroom and the surroundings.
c. The positive minimum pressure delta to be maintained shall be:
1. Between cleanroom and surrounding area; 1,2 mm H2O (12 Pa).
2. Between cleanroom and entrance lock; 0,5 mm H2O (5 Pa).
d. Pressure in all areas shall be monitored continuously
NOTE In order to take timely corrective actions in case of a
pressure drop.
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i. The cleanliness after the cleaning operations shall be verified by
inspection by means of UV or high intensity white light.
j. Any personnel involved in cleaning operations shall be trained and
informed about the criticality of a cleaning operation within a cleanroom.
k. Cleaning tools, solvents and gases that are used for cleaning purposes
shall be chosen not to have a detrimental effect on the hardware within
the cleanroom.
NOTE Cleanroom air of better than class ISO 8 is
transported in a close loop. Since only a limited
percentage of fresh air is fed to the loop, excessive
use of solvents offgassing into the air, even if not
flammable or toxic, can cause health problems.
l. When the level of contamination exceeds the cleanliness requirements
specification, corrective actions shall be taken.
NOTE The decision as to whether or not to clean depends
on the integration flow of the unit within the
cleanroom.
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NOTE This is to avoid contamination of those parts by
loose skin or natural skin oils.
k. All equipment shall be cleaned by dusting, vacuum suction, washing, or
other means suited to the equipment involved before being brought into
the area.
l. Exhaust systems for grinding, welding or soldering, machining or related
operations shall be installed.
m. Actions related to equipments items with cooling fans shall be identified
and mitigated in order to avoid contamination of critical hardware.
NOTE Equipments items with cooling fans are potential
contamination sources.
n. Personnel shall be instructed about the behaviour in a cleanroom.
o. Personnel movements to and from the cleanroom shall be kept to a
minimum.
p. Smoking, eating and drinking shall not be permitted in the cleanroom,
including the entering areas and air locks.
q. Local cleanroom instructions shall specify the amount of protective
clothing to be worn and shall reduce to the minimum the contaminant
transfer.
r. If air showers are used, only suitably clothed personnel shall be allowed
to enter.
s. Paper, pencils or erasers shall be kept outside the clean facilities. Only
special non‐shedding papers and ball‐points shall be used.
t. Cosmetics and medicaments that can produce contamination shall not be
used by any personnel.
NOTE In particular, eye make‐up, rouge, face powder and
hair spray.
u. Fingernail polish shall not be permitted in the area.
v. Before entering a cleanroom, hand lotions, creams or soap containing
lanolin to tighten skin particles shall be used.
w. Contact of hands with solvents shall be avoided.
NOTE Many solvents remove natural oils and cause
excessive skin peeling or flaking.
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and to collect the air for repressurization in a clean
area (preferably ISO class 5).
3. The regeneration of sorption pumps.
NOTE Sorption pumps can be e.g. cryopumps, zeolites, or
charcoal.
4. The cleaning of cold trap.
b. For a test in a vacuum facility, it shall be ensured that the item under test
does not pose any risk of contamination of the facility.
c. An approved declared material list (DML) of the hardware under test,
including the test adapter and all connections shall be provided.
NOTE Including, for example mechanical and electrical
connexions.
d. A pre‐test shall be performed to prove the cleanliness of the facility.
e. During the pre‐test, test equipment and cabling shall be included in the
facility.
f. During the pre‐test, pump down and repressurization sequences shall be
similar to the actual test.
NOTE In typical “clean” vacuum systems, a sensor (or a
critical surface) is not contaminated by more than
1 × 10‐7 g/cm2 during a blank test of 24 hours
duration. The sensor is normally at room
temperature, but, more stringent requirements can
be imposed, depending upon the budget allocation
for the equipment. In fact, for sensitive equipment,
0,3 × 10‐7 g/cm2, 24 hours (or 0,5 × 10‐7 g/cm2, week)
for a blank test is often specified.
5.4 Activities
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before the entry of the space system into the fairing,
or even just before closing the fairing.
b. The choice of the cleaning method shall be determined by the following
criteria:
1. The type of contaminants to be removed.
2. The physical or chemical nature of the item to be cleaned.
3. The actual on ground phase.
NOTE 1 Examples are provided in Annex M for removal of
both particulate and molecular contamination.
NOTE 2 The cleaning of some parts is particularly
important during the course of manufacture or
before processing (e.g. prior to bonding, painting,
vacuum, coating, welding and soldering).
NOTE 3 Any detrimental effect of cleaning is evaluated as
well as the order of the defined cleaning methods.
NOTE 4 For those items that are too delicate to withstand
cleaning, preventive contamination control is of
the utmost importance.
c. The cleaning procedures shall be mentioned in the process specification.
d. The cleaning procedures shall be validated by tests on representative
samples, or by experience from previous and similar projects, in which
they were validated.
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5.4.1.2.2 Cleaning fluids
a. The cleaning solvent shall be selected on the basis of its compatibility
with the material or item to be cleaned and its efficiency in removing
contaminants.
NOTE A compatibility table between materials and
solvents is given in Annex I.
b. Toxicity and flammability of solvents shall be evaluated (see MIL‐HDBK‐
406) and be compliant to the local law.
c. For precision cleaning, solvents of high purity shall be used (see Annex J).
d. The cleaning gas shall be free of oil and filtered to remove particulate
contamination according to the needs.
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method for the determination of the particle
contamination can also be microscopic counting
(manual or with the aid of an imaging recognition
software).
NOTE 5 Extraction methods can be performed by:
• tape lift, using sticky tapes (according to ECSS‐
Q‐ST‐70‐50);
• blowing and suction of air;
• washing of the surface of interest and counting
the particles in the washing fluid either directly
using a commercial instrument, or on a filter
after filtration of the liquid.
NOTE 6 The “visibly clean” level roughly corresponds to
an obscuration factor smaller than 300 mm2/m2.
c. When using ultra‐violet or “black light” (365 nm) lamps for inspection of
organic residues, the induced thermal and health effects shall be
assessed.
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absorption, the washing efficiency and the solvent
background. The NVR measurement is expressed
in mass per unit area and the residue can be used
for further analyses). Direct measurements can be
made in situ using quartz crystal microbalances
(QCM).
NOTE 4 Further analyses can be performed to characterize
molecular contamination (e.g. gas
chromatography, mass spectrometry, ultra‐violet
degradation, SEM).
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5.4.2.6 Contamination monitoring in space
a. Contamination of external surfaces should be monitored.
NOTE 1 particulate contamination can be measured by
light scattering (e.g. using the Sun or a laser as the
a light source) or using QCMs with a crystal
having a surface to which particles stick.
NOTE 2 Molecular contamination can be measured using
QCM located near a sensitive item and maintained
at the same temperature as the item or using a
mass spectrometer.
NOTE 3 Measurements of contamination in space are not
often made because the policy of cleanliness
control is based upon the basic principle of
achieving the lowest possible contamination levels
with existing knowledge and within the allocated
financial budgets. However, it is advisable to
implement an “in space contamination
monitoring” as part of the spacecraft
housekeeping. When appropriate sensor elements
are applied it is possible to predict design
life‐times at system, subsystem, component or
equipment levels.
b. For internal environments monitoring of particulate, molecular and
microbiological contamination shall be assessed.
5.4.3.1 General
a. The cleanliness verification activities shall be specified in the C&CCP.
b. The cleanliness verification shall include all the activities intended to
ensure that the actual cleanliness conditions of the space system, the
cleanrooms or the vacuum chambers conform to the applicable standards
or the applicable CRS (specific to a certain project).
c. The cleanliness verification shall make use of recognized methods for the
determination or the monitoring of the contamination levels.
d. The cleanliness verification of cleanrooms shall also include the
verification of the environmental parameters such as temperature,
relative humidity and the overpressure.
e. The cleanliness verification shall take place under one or more of the
following conditions:
1. At predetermined intervals, independently of the current activity,
to confirm the efficiency of the established cleanliness control
measures.
2. After the occurrence of an incident or anomaly that can have
influenced the cleanliness conditions of the space system or
cleanroom.
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3. Before the beginning of the ground (e.g. test campaign) or launch
activities, to confirm that the facilities and cleanrooms are conform
to the relevant C&CCP.
4. Before and after a test in a vacuum chamber.
f. A cleanliness declaration of conformity shall be delivered for space
hardware.
g. In case of nonconformance of an item, corrective actions shall be applied
and ECSS‐Q‐ST‐10‐09 shall apply.
5.4.3.2 Bakeout
a. When contamination predictions exceed the allocated contamination
budget, a bakeout shall be performed.
NOTE 1 The aim of the bakeout is:
• To improve the outgassing behaviour of a
material/item.
• To reduce the level of surface contamination
collected during processing or testing.
NOTE 2 Typical materials on which bakeout can be applied
are:
• Harness
• MLI
• Carbon and glass fibre components
• Glued, coated or potted materials.
b. The bakeout conditions (temperature, time, pressure) shall not have a
detrimental effect on the functionality of the material/item under
bakeout.
NOTE It is more efficient to perform a bakeout at the
lowest possible product level to allow reaching
higher bakeout temperature (i.e. to avoid
temperature constraints at higher assembly level)
c. The effectiveness of the bakeout shall be monitored by means of one the
following methods:
1. By using a QCM.
NOTE Eventually also a Residual Gas Analysis (RGA), as
already described in NOTE 3 of 5.4.2.3 “Molecular
contamination monitoring”.
2. By outgassing testing the material/item before and after the
bakeout.
NOTE 1 The second method is in general only practical for
materials and items containing a limited number
of materials.
NOTE 2 Other analytical methods can be considered but
their effectiveness is not yet be proven (e.g. in situ
optical methods).
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d. Independently of the chosen method, success criteria shall be established
and approved before starting the bakeout.
e. When the QCM monitoring or other in situ analytical methods are
chosen, a “stopping” criterion” shall be defined.
NOTE This “stopping” criterion is also a way to determine
if going further with the bakeout is worth or not.
For instance, this criterion can be based on the
change of the mass rate (i.e. on the second
derivative of the QCM frequency).
f. When outgassing testing methods are chosen, a “verification criterion”
shall be defined.
NOTE For instance, the “verification criterion” can be
based on the reduction of the outgassing potential.
g. The different outgassing mechanisms shall be used in the elaboration of
the stopping and verification criteria.
NOTE 1 Desorption and diffusion are examples of
outgassing mechanisms).
NOTE 2 In case of outgassing testing after the bakeout, a
certain time is necessary for reconditioning of the
material/item to consider the diffusion
phenomenon.
h. The background of the baking facility shall be determined before starting
the bakeout.
NOTE This can be done by using a QCM or molecular
witnesses. The use of QCM is preferred because it
provides the background of the chamber in function
of time whereas witness plates can only provide the
integrated value.
i. Independently of any stopping and verification criteria, the minimum
bakeout duration shall be 72 hours.
j. Baking time shall start when the material/item under baking has reached
the predefined bakeout temperature.
5.4.3.3 Purging
a. The purging shall be performed inside a cavity to maintain a constant
exchange of the gas present in the cavity.
NOTE 1 This exchange depends on the entry flow rate of
the gas and the total surface leaks.
NOTE 2 The aim of the purging is not only to protect the
critical hardware such as optics from
contamination by injecting a non‐ionized
high‐purity dry gas inside a cavity but also a way
for decontamination (e.g. removal of water for
dimensional stability of composite).
NOTE 3 The purging can be implemented at instrument or
spacecraft level during functional and performance
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tests at ambient conditions, during
repressurization after TB/TV and TV tests, during
all the phases without activities and during
storage, transport and pre‐launch phases up to the
final close of the fairing. (In case of an aborted
launch, purging can be not re‐installed).
b. The purity of the gas and the cleanliness of all the pipes shall be verified
before the first use of the purging system.
c. Filtering systems (both for MOC and PAC) shall be provided before the
gas comes into contact with the hardware.
d. The filtering capabilities shall be compatible with the relevant cleanliness
requirements.
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k. The design of the container shall facilitate easy cleaning and inspection of
its surfaces, avoiding any kind of dirt traps.
l. Small clean parts shall be double bagged in airtight envelopes during
storage or transportation outside controlled clean areas.
m. Bags for contamination‐sensitive items shall be flushed with dry nitrogen
or dry clean air and then sealed.
n. Only approved materials that were procured as cleaned films shall be
used.
o. Static sensitive items shall use metallized films.
p. Outer bags shall not enter controlled clean areas.
q. When used, desiccants shall be in bags that are clean and do not produce
particulate contamination.
r. Desiccants and humidity indicators shall be placed in the external
envelope.
s. Procedures shall be provided for packaging, containerization,
transportation and storage.
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Annex A (normative)
Cleanliness requirement specification
(CRS) - DRD
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<1> Introduction
a. The CRS shall give a general overview of the item to which the CRS
refers, describing sensitive items and contamination sources, in
consideration of:
1. possible impacts of contaminants on their physical or functional
characteristics;
2. possible effects of contamination on the performance;
3. their impact as potential sources of contamination.
b. The CRS shall specify the pressures (or other molecular fluxes) that can
be reached in connection with voltage breakdown, arcing, corona
discharges, multipaction, opening time of shutters and ejection time of
covers.
<3> Contaminants
a. The CRS shall describe all possible contamination sources to be analysed
and the maximum acceptable emissions.
NOTE For example: Materials outgassing, lubricants
escaping from bearings, wear particles from moving
parts, terrestrial contaminants such as dust, plume
contaminants from thrusters and engines, leaks
from fuel systems and from hermetically sealed
components, dumps and EVA, co‐passengers,
fairing and equipment bay items of the launcher.
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b. The CRS shall specify the chemical nature of the contaminants listed
under <3>a. with their vapour pressures or relevant condensation
conditions.
c. The CRS shall specify the transport mechanisms of the potential
contaminants from the sources under <3>a. to the contamination sensitive
items or areas to be considered in the contamination analysis.
NOTE For example: direct flux, reflected flux, ambient
scatter, self‐scatter and creeping.
d. The CRS shall specify the contamination environment to be applied for
design.
NOTE For example, molecular column density, maximum
molecular deposition on the sensitive items.
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Annex B (normative)
Cleanliness and contamination control
plan (C&CCP) - DRD
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<1> Introduction
a. The C&CCP shall contain description of the purpose, objective, content
and the reason prompting its preparation.
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<7.6> Responsibilities
a. Responsibility and authority shall be assigned for the implementation of
the cleanliness and contamination control tasks.
b. The C&CCP shall describe responsibilities for:
1. Hardware inspections
2. Cleanrooms and facilities
3. Contamination monitoring (hardware).
<8> Forms
a. The C&CCP shall define the forms that are used to document the
cleanliness and contamination control activities defined by the C&CCP.
b. As minimum, the following forms shall be defined:
1. PAC and MOC measurement report.
2. Cleanliness declaration of conformity (see ECSS‐Q‐ST‐20).
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Annex C (informative)
Cleanliness and contamination control
process overview
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Annex D (informative)
Guidelines for general cleanliness and
contamination control
D.1 General
Contamination control cannot be applied effectively without an understanding
of the contaminant, the contaminant source and the detrimental effect that the
contaminant has.
The known causes of failure and degraded performance of space elements
attributed to contamination, including their sources, are given in this Standard.
When they are not known, tests and analyses can be performed (e.g. outgassing
rates as a function of time, chemical composition of outgassing products,
condensation rates or degradation as result of radiation).
The results of these tests and analyses can be used to calculate expected
contamination levels and their subsequent effects if other relevant parameters
are known.
Preventive cleanliness control is becoming more important as space systems
become more sophisticated and mission durations are extended.
A problem frequently encountered in space technology is the lack of data
enabling a good correlation between contaminant levels and mission
performance requirements.
NOTE This kind of information can be available in the
mass production areas of electronics and precision
mechanical devices.
D.2.1.1. On ground
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can therefore be protected from them right up to the final preparation at the
launch site.
Nevertheless, a considerable quantity of particulate contaminants are produced
or released during all on ground phases of the space system, especially during
testing activities.
NOTE Test facilities can be inside cleanrooms, but are
basically not clean and can loosen particles and
cause their redistribution
For example:
• Human sources
⎯ Hair cosmetics, dead human skin cells.
⎯ Fibres and lint from clothing, dust carried in on hair and clothes.
• MAIT
⎯ Chips and burrs from machined surfaces, solder and weld spatters.
⎯ Particles produced by wear or shedding, corrosion products, flakes
from coatings and air filters.
⎯ Particles released from anechoic walls during the test.
⎯ Redistribution of particles during pumping down and
repressurization of vacuum chambers, vibration test,
transportation…
• Other sources
⎯ Bacteria, fungi, viruses and secondary products
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⎯ Residues from adhesive masking tapes
⎯ Machine oils
⎯ Coolants
⎯ Lubricants
⎯ Solder fluxes
⎯ Cosmetics
⎯ Grease from human skin
⎯ Secondary products coming from micro‐organisms.
• Other contaminants
⎯ salt
⎯ acid
⎯ alkaline
⎯ corrosion products
⎯ oxidation products
⎯ finger prints
⎯ stains.
D.2.1.2. On launch
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Predictions of the molecular transfer during this period can be estimated: this
type of estimation can be made for co‐passengers when the outgassing
requirements are less stringent than those for the space system of interest.
D.2.1.3.1 Overview
Even with a good contamination and cleanliness control policy, contamination
during mission can not be completely avoided. Indeed, lessons learned from
space systems returned to Earth after quite a long exposure to space e.g. LDEF,
EURECA and solar arrays from the Hubble Space Telescope, indicated visible
contamination especially near venting holes and at locations where
photodeposition and photopolymerization occurred due to solar radiation, or
where atomic oxygen has converted the volatile contaminants into non‐volatile
contaminants.
Natural environments and induced environment are normally taken into
consideration.
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Radiation ionizes the outgassed molecules in space and so can influence
the amount of ionized particles.
Also, the ionized molecules are attracted by a negative charged space
system and thus contaminate it.
c. Thermal aspects (thermal cycling)
Solar radiation, rotating space systems and planetary shieldings cause
temperature cyclings and these temperature cyclings have effects on the
outgassing of materials and on the condensation and evaporation of
contaminants on surfaces whose temperatures vary.
d. Atomic oxygen (AO) (speed effects)
AO is the main constituent of the residual atmosphere in Earth orbit at
between 200 km and 700 km altitude. The density is a function of altitude
and of other parameters such as solar radiation. In most cases the effect of
thermal AO on deposited contaminants can be neglected. However, due
to the relative velocity between AO and the space system (approx 8 km/s)
the collisional energy in the ram direction is around 5 eV.
The items and surfaces in the ram direction of the space system can be
attacked by AO, whereas the items and surfaces in the wake direction are
hardly attacked.
The effect of AO can be described as an oxidation and some materials can
become resistant to AO, e.g. non‐volatile oxides can be formed on some
metals.
Organic materials can be oxidized to volatile products such as CO and
H2O. The presence of silica contaminants on space system surfaces can
be explained by the attack of condensed silicone species by AO and the
formation of SiOx.
e. Charged particles (electrons, ions)
The effect of charged particles on outgassing and on already condensed
contaminants is probably small, but no exact data are known at this
moment.
f. Micrometeoroids (debris)
Micrometeoroids have no direct effect on outgassing and on condensed
contaminants. Micrometeoroids can pierce some materials and can also
result in partly destruction of some materials, which causes release of a
large amount of new particles which escape into space or affect
neighbouring items. Impacts can also cause evaporation of the
micrometeoroid and of the impacted surface.
Redistribution of particles, which were already on space system surfaces
by micrometeoroid collisions, have been reported, but the effects are very
small.
g. Speed effects of space systems w.r.t. molecular speeds
The speed of a space system has no direct effect on the outgassing of
materials or on the deposition mechanisms of contaminants on surfaces.
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However, the return contamination flux via the ambient scatter is highly
affected by the local pressure around the space system. This local
pressure depends upon the actual space system speed with respect to the
speed of the natural species. Because of the speed effects, the ram
direction pressure can be orders of magnitude higher than the normal
pressure for that orbit and the ambient scatter is then also orders of
magnitude higher than the normal ambient scatter.
The same can be expected for the wake directions, i.e. orders of
magnitude lower pressures and thus orders of magnitude lower ambient
scatter than expected.
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impingement of micrometeoroids and debris is small compared to the
amount of particles released from the surface materials by the same
impingements.
For molecular contaminants that collected on surfaces during ground
activities, the same outgassing effect can be expected as from material
outgassing.
e. Secondary products
Secondary products are generated by various intermolecular interactions
and chemical or physical processes due to payload or experiment
operations or interactions of the natural and induced environment
constituents and the space
D.2.2.1. Overview
Most of the effects of contamination occur in space, especially when solar
radiation is involved.
D.2.2.2.1 Overview
Surfaces can become contaminated by particles during all on ground phases
(e.g. MAIT, pre‐launch, and transportation).
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D.2.2.3.2 Molecular contaminants transport
• Creeping
Liquid contaminants and also lubricants can contaminate adjacent items
by the liquid creeping over surfaces, and silicone fluids especially are
known to have a high creeping effect.
In order to reduce the creeping effect, anti‐creep barriers made of special
materials are generally applied.
• Direct flux
Contaminants in space move in straight lines from the space system into
deep space and can sometimes contaminate items located in the direct
view.
In order to mitigate this effect, design provision are generally a solution.
• Indirect flux
Contaminants from space systems can impinge on a surface and after
reflection (specular) or re‐evaporation (diffusive) these contaminants can
affect other items or areas.
• Collision with natural gases
Contaminants coming from the space system can collide with the natural
gases around the space system and after collision can return to the space
system. This phenomenon is known as ambient atmospheric scattering
and depends upon the density (and thus upon the altitude) of the natural
gas.
• Collision with other outgassed molecules
Molecules released from space systems (e.g. outgassing via venting
holes) can collide with other molecules from the same origin or from
other origins (e.g. plumes). After the collisions, some molecules can
return to the space system. This phenomenon is called self‐scattering and
the return flux strongly depends upon the intensities of the fluxes from
the contaminant sources.
• Ionization of gaseous contaminants and the re‐attraction by the negative
charged space system
Contaminants emitted from the space system can be ionized in space by
solar radiation (especially ultra‐violet radiation, electrons, protons and
ions) and these ions can be re‐attracted by a negative charged space
system. This phenomenon is well known, but has not yet been quantified.
One of the simple rules is that instruments that have deployable shutters
or ejectable covers can be deployed or ejected when the outgassing has
dropped to a certain level or after a pre‐determined time after the launch.
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• Light scattering by particle and molecular contaminants.
• Electrical discharge or arcing in high voltage equipment due to high
outgassing and other contamination.
• Noise on slip rings and electrical contacts.
• Results of certain experiments obscured by excessive molecular
contamination (e.g. mass spectrometers and ion counters).
• Degradation of optical elements (e.g. lenses, mirrors and windows) due
to molecular contamination, especially X‐ray and UV equipment and low
temperature IR detectors.
• Degradation of thermal control surfaces (absorptivity/emissivity ration,
α/ε) especially in the case of molecular contamination on optical solar
reflectors at low temperatures.
• Loss of efficiency in heat pipes.
• Effects on conductive and non‐conductive surfaces (leak paths in
electronics).
• Loss of efficiency in solar cell generators.
• Corrosion of electrical contacts due to the presence of halogenated solder
fluxes.
• Space charge and discharge effects related to contaminants.
• Thermal radiation from particles.
• Disorientation due to erroneous reaction of star trackers to luminous
particles.
• Multipaction in waveguides.
• Bad closing of a valve.
• Explosion of a cryotechnic motor (Oil + O2).
• HF for a motor.
• Disturbance of gas flux and combustion within thrusters.
• Disturbance and propagation within RF wave guides.
• For the space environment around the space system, the “column
density”, local gas pressures and gas composition can be limiting factors
for some experiments.
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Annex E (informative)
Cleanliness-oriented design
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limitations of certain hardware or because the products released
during the bakeout can have effects on other items).
10. Where sensitive items are expected, the design of the instruments
or space system should be such that purging is feasible in the
periods of assembly, integration, tests and launch preparations or
even up to launch.
11. Based upon these effects, the venting holes and other contaminant
sources should be located in the wake side of the space system.
c. On the other hand, the wake side of a space system can be used for
special experiments for which extremely low pressures in relatively low
Earth orbit are required.
d. Cleaning aptitude of materials and mechanical parts, e.g. in case
hardware cannot be cleaned after manufacturing temporary protection
devices are needed.
e. Measurement of contamination, e.g. adaptations for contamination
sensors.
f. Verification of the compatibility of the surface treatment with the
cleanliness level.
g. Ground support equipment, packaging, containerization, transportation
and storage.
h. Any other design provisions according to the specificity of the mission
(e.g. planetary missions).
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Annex F (informative)
Modelling guidelines
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Annex G (informative)
Airborne particulate cleanliness classes
equivalence
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Annex H (informative)
Particulate levels on surfaces
H.2.1 Overview
The obscuration factor (OF) is the ratio of the projected area of all particles to
the total surface area on which they rest.
This OF is in principle independent of the number‐size distribution of the
particles and even independent of the shape and colour of the particles. In
general the levels are expressed in parts per million (mm2/m2) and acceptable
values are roughly between 10 mm2/m2 and 10 000 mm2/m2.
The OF has the advantage that a number of performance loss parameters are
directly related to the particle coverage of the critical item.
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Annex I (informative)
Compatibility of various solvents with
listed materials
Table I‐1 shows examples of compatibility of various solvents with listed
materials.
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Annex J (informative)
evaporation residue of commercially
available solvents
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Annex K (informative)
Molecular contaminant content of some
wipe materials
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Annex L (informative)
Effects of humidity on materials and
components
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Annex M (informative)
Cleaning methods
M.1.1 Overview
The removal of particulate contamination can be performed with, but not
limited to, the methods described in M.1.2 to M.1.4
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M.2.1 Overview
The removal of molecular contamination can be performed with, but not
limited to, the methods described in M.2.2 to M.2.8.
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M.2.7 Bakeout
• Volatilizing under vacuum is especially successful for cleaning
assembled units, or when solvent cleaning is too delicate an operation.
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Bibliography
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