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1. The energy of hydrogen atom in its ground state is 13.6 eV. The energy of the level corresponding to
n 5 is :
(1) 0.54 eV (2) 5.40 eV
(3) 0.85 eV (4) 2.72 eV
2. The wavelength of a spectral line for an electronic transition is inversely proportional to :
(1) number of electrons undergoing transition
(2) the nuclear charge of the atom
(3) the velocity of an electron undergoing transition
(4) the difference in the energy involved in the transition
3. In a sample of H - atom electron make transition from 5th excited state upto ground state, producing all
possible types of photons, then number of lines in infrared region are
(1) 4 (2) 5
(3) 6 (4) 3
4. Total no. of lines in Lyman series of H spectrum will be (where n = no. of orbits)
(1) n (2) n 1
(3) n 2 (4) n n 1
5. No. of visible lines when an electron returns from 5th orbit upto ground state in H spectrum :
(1) 5 (2) 4
(3) 3 (4) 10
6. Suppose that a hypothetical atom gives a red, green, blue and violet line spectrum. Which jump
according to figure would give off the red spectral line.
(1) 3 1 (2) 2 1
(3) 4 1 (4) 3 2
7. Let v1 be the frequency of the series limit of the Lyman series, v 2 be the frequency of the first line of
the Lyman series, and v3 be the frequency of the series limit of the Balmer series :
(1) v1 v 2 v3 (2) v 2 v1 v3
(3) v3 1 / 2 v1 v3 (4 ) v1 v 2 v 3
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8. No. of visible lines when an electron returns from 5th orbit upto ground state in H spectrum:
(1) 5 (2) 4
(3) 3 (4) 10
9. If the shortest wave length of Lyman series of H atom is x, then the wave length of the first line of
Balmer series of H atom will be -
9x 36x
(1) (2)
5 5
5x 5x
(3) (4)
9 36
10. What is the wave number of the radiation of lowest frequency in the Lyman series of the spectrum of
Li 2 ion ?
4 27 R
(1) 27 R (2)
4
27 RC 4C
(3) (4) 27 R
4
11. The wavelength of a spectral line obtained by an electronic transition is inversely proportional to
(1) Number of transit electrons
(2) Nuclear charge of the atom
(3) Energy differene of the related energy levels
(4) Speed of the transit electron
12. The given diagram indicates the energy levels of a certain atom. When the system moves from 2E level
to E level, a photon of wavelength is emitted. The wavelength of the photon emitted during its
transition from 4E/3 level to E level is.
2E
4E/3
(1) / 3 (2) 3 / 4
(3) 4 / 3 (4) 3
13. What transition in the hydrogen spectrum would have the same wavelength as the Balmer transition
n 4 to n 2 of He spectrum ?
(1) n 4 to n 2 (2) n 4 to n 1
(3) n 2 to n 1 (4) n 3 to n 2
14. For the same electronic transition in the following atom or ion, the frequency of the emitted radiation will
be maximum for
(1) H - atom (2) D - atom
(3) He ion (4 ) Li 2 ion
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15. An electron jumps from the fourth orbit to the first in a H - atom. The number of photons liberated out
will be
(1) 1 (2) 2
(3) 3 (4) 6
16. Calculate the two longest wavelengths of the radiation emitted when hydrogen atoms make transitions
from higher states to n = 2 state.
17. What electron transition in the He spectrum would have the same wavelength as the first Lyamn
transition of hydrogen.
18. Calculate the frequency of light emitted for an electron transition from the sixth to second orbit of the
hydrogen atom. In what region of the spectrum does this light occur?
19. At what atomic number would a transition from n 2 to n 1 energy level result in emission of photon
of 3 108 m.
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