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Kinetics and Solution Class XII

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14 views3 pages

Kinetics and Solution Class XII

Uploaded by

untraceable2023censor
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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1)a) If the rate constant of a reaction is k = 3 × 10-4 s-1, then identify the order of the

reaction.

2)For a reaction R → P, half-life (t1/2) is observed to be independent of the initial


concentration of reactants. What is the order of reaction?

3) A reaction is of second order with respect to a reactant. How will the rate of reaction
be affected if the concentration of this reactant is
(i) doubled, (ii) reduced to half?

4) The thermal decomposition of HCO 2H is a first order reaction with a rate


constant of 2.4 × 10-3 s-1 at a certain temperature. Calculate how long will it take
for three-fourths of initial quantity of HCO 2 H to decompose. . (log 0.25 = -
0.6021)
5) Rate constant k for a first order reaction has been found to be 2.54 × 10 -
3
sec-1. Calculate its 3/4th life, (log 4 = 0.6020).
6) A first order gas phase reaction : A2B2(g) → 2A(g) + 2B(g) at the temperature
400°C has the rate constant k = 2.0 × 10 -4 sec-1. What percentage of A2B2 is
decomposed on heating for 900 seconds? (Antilog 0.0781 = 1.197)

7) reaction is of second order with respect to its reactant. How will its reaction
rate be affected if the concentration of the reactant is (i) doubled (ii) reduced to
half?
8) A first order reaction has a rate constant of 0.0051 min -1. If we begin with 0.10
M concentration of the reactant, what concentration of reactant will remain in
solution after 3 hours?
9) For a decomposition reaction the values of rate constant k at two different
temperatures are given below :
k1 = 2.15 × 10-8 L mol-1 s-1 at 650 K
k2 = 2.39 × 10-7 L mol-1 s-1 at 700 K
Calculate the value of activation energy for this reaction.
(R = 8.314 J K-1 mol-1)
10) The rate constant for a first order reaction is 60 s -1. How much time will it
take to reduce the initial concentration of the reactant to its l/10th value?
11) The rate constant for the first order decomposition of H 2O2 is given by the
following equation:
log k = 14.2 – 1.0×104TK
Calculate Ea for this reaction and rate constant k if its half-life period be 200
minutes.
(Given: R = 8.314 J K-1 mol-1)
12) If the half-life period of a first order reaction in A is 2 minutes, how long will it
take [A] to reach 25% of its initial concentration?
13) A first order reaction takes 20 minutes for 25% decomposition. Calculate the
time when 75% of the reaction will be completed.
(Given: log 2 = 0.3010, log 3 = 0.4771, log 4 = 0.6021)
14) For a first order reaction, show that time required for 99% completion is
twice the time required for completion of 90% reaction
15) (a) With the help of a labelled diagram explain the role of activated complex
in a reaction.
(b) A first order reaction is 15% completed in 20 minutes. How long will it take to
complete 60% of the reaction ?
16) (a) For a reaction A + B → P, the rate is given by Rate = k[A] [B]2
(i) How is the rate of reaction affected if the concentration of B is doubled?
(ii) What is the overall order of reaction if A is present in large excess?
(b) A first order reaction takes 30 minutes for 50% completion. Calculate the
time required for 90% completion of this reaction.
17) For the hydrolysis of methyl acetate in aqueous solution, the
following result were obtained.

(i) Show that it follows pseudo first order reaction, as’the concentration
of water remains constant.
(ii) Calculate the average rate of reaction between the time interval 30
to 60 seconds. (Given: log 2 = 0.301, log 3 = 0.4771, log 4 = 0.6021)
18

19

20. Differentiate between molality and molarity of a solution. What is the effect of
change in temperature of a solution on its molality and molarity?
21. Explain why aquatic species are more comfortable in cold water rather than
in warm water.

22. State Henry’s law and mention two of its important applications

23. 18 g of glucose, C6H12O6 (Molar mass – 180 g mol-1) is dissolved in 1 kg of


water in a sauce pan. At what temperature will this solution boil? (K b for water =
0.52 K kg mol-1, boiling point of pure water = 373.15 K)

24. Explain why on addition of 1 mol of glucose to 1 litre of water, the boiling
point of water increase

25. A solution of glycerol (C3H8O3; molar mass = 92 g mol-1) in water was


prepared by dissolving some glycerol in 500 g of water. This solution has a
boiling point of 100.42 °C. What mass of glycerol was dissolved to make this
solution? Kb for water = 0.512 K kg mol -1

26. A solution containing 30 g of non-volatile solute exactly in 90 g of water has a


vapour pressure of 2.8 kPa at 298 K. Further 18 g of water is added to this
solution. The new vapour pressure becomes 2.9 kPa at 298 K. Calculate
(i) the molecular mass of solute and
(ii) vapour pressure of water at 298 K

27. 45 g of ethylene glycol (C2H6O2) is mixed with 600 g of water. Calculate


(i) the freezing point depression and
(ii) the freezing point of the solution
(Given : Kf of water = 1.86 K kg mol-1

28. a) Differentiate between molarity and molality for a solution.


How does a change in temperature influence their values?
(b) Calculate the freezing point of an acqueous solution containing 10.50 g of
MgBr2 in 200 g of water. (Molar mass of MgBr 2 = 184 g) (Kf for water = 1.86 K kg
mol-1)

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