Safety data sheet in accordance with 2001/58/EC
DODICOR 2725 NF Page 1
Substance key: SXR005073 Revision Date: 11.02.2005
Version : 3 - 4 / EU Date of printing : 23.02.2005
1. Identification of the substance/preparation and company
Trade name
DODICOR 2725 NF
Use of the substance/preparation.
Industry sector : Mineral Oil
Type of use : Corrosion inhibitor for the petroleum industry
Identification of the company
Clariant GmbH
65926 Frankfurt am Main
Telephone no. : +49 69 305 18000
Information about the substance/preparation
Division Functional Chemicals
++49(0)69-305-2092/15315/32251
Emergency telephone number : +49 69 305 6418
2. Composition/information on ingredients
Chemical characterization
Mixture of an alkinol containing alkylammonium compound and a nonionic surfactant in glycol
Hazardous ingredients
Prop-2-yn-1-ol
Concentration : 1-5%
CAS number : 107-19-7
EINECS number : 203-471-2
Hazard symbols T N
R phrases 10 23/24/25 34 51/53
Naphthenic acid imidazoline benzylquat
Concentration : 15 %
CAS number : 73049-47-5
EINECS number : 277-250-4
Hazard symbols C
R phrases 34
Diethylene glycol
Concentration : 10 - 20 %
CAS number : 111-46-6
EINECS number : 203-872-2
Hazard symbols Xn
R phrases 22
Nonylphenol polyglycol ether
Concentration : 50 - 70 %
CAS number : 9016-45-9
R phrases 52/53
Safety data sheet in accordance with 2001/58/EC
DODICOR 2725 NF Page 2
Substance key: SXR005073 Revision Date: 11.02.2005
Version : 3 - 4 / EU Date of printing : 23.02.2005
3. Hazards identification
Causes burns.
Harmful by inhalation, in contact with skin and if swallowed.
Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
4. First aid measures
General information
Remove soiled or soaked clothing immediately
In case of accident or if you feel unwell, seek medical advice immediately.
After inhalation
When inhaled remove to fresh air and seek medical aid.
After contact with skin
In case of contact with skin wash off immediately with soap and water
After contact with eyes
In case of contact with eyes rinse thoroughly with water
After ingestion
When swallowed seek medical aid immediately and show the physician the packaging or the
label of the packaging.
5. Fire-fighting measures
Suitable extinguishing media
water spray jet
alcohol-resistant foam
carbon dioxide
dry powder
Special hazards from the substance itself, its combustion products or from its vapours
In case of fires, hazardous combustion gases are formed: Carbon monoxide (CO)
Nitrous gases (NOx)
Special protective equipment for firefighting
Use self-contained breathing apparatus
6. Accidental release measures
Personal precautions
Ensure adequate ventilation.
Use personal protective clothing.
Keep away sources of ignition.
Environmental precautions
Do not allow to enter drains or waterways
Methods for cleaning up/taking up
Take up mechanically. Dilute remainder with water and take up with absorbent material (eg
sawdust, sand, universal binder)
Safety data sheet in accordance with 2001/58/EC
DODICOR 2725 NF Page 3
Substance key: SXR005073 Revision Date: 11.02.2005
Version : 3 - 4 / EU Date of printing : 23.02.2005
7. Handling and storage
Advice on safe handling
Open and handle container with care.
Ensure adequate ventilation.
Advice on protection against fire and explosion
Keep away from sources of ignition - refrain from smoking.
Further information on storage conditions
Keep container tightly closed
8. Exposure controls/personal protection
General protective measures
Avoid contact with eyes and skin
Do not inhale vapours
Hygiene measures
Observe the usual precautions when handling chemicals.
Respiratory protection : Use respiratory protection in case of insufficient exhaust
ventilation or prolonged exposure
Full mask, filter A
Full mask to standard DIN EN 136
Filter class 2
The use of filter apparatus presupposes that the environment
atmosphere contains at least 17% oxygen by volume, and does
not exceed the maximum gas concentration, usually 0.5% by
volume. Relevant guidelines to be considered include EN
136/141/143/371/372 as well as other national regulations.
Observe applicable relevant national regulations,(e.g. TRGS
900 and BGR 190 in Germany).Take note of the
recommendedations regarding the duration for which
Respiratory Protective Equipment may be worn, according to
chapter 19 Abs. 5 GefStoffV in conjunction with the rules of
wearing such equipment.
Hand protection : For long-term exposure:
Butyl rubber gloves
Minimum breakthrough time / gloves : 480 min
Minimum thickness / gloves 0,7 mm
For short-term exposure (splash protection):
Nitrile rubber gloves.
Minimum breakthrough time / gloves : 30 min
Minimum thickness / gloves 0,4 mm
Safety data sheet in accordance with 2001/58/EC
DODICOR 2725 NF Page 4
Substance key: SXR005073 Revision Date: 11.02.2005
Version : 3 - 4 / EU Date of printing : 23.02.2005
These types of protective gloves are offered by various
manufacturers. Please note the manufacturers´ detailed
statements, especially about the minimum thickness and the
minimum breakthrough time. Consider also the particular
working conditions under which the gloves are being used.
Eye protection : Depending on the risk, wear sufficient eye protection (safety
glasses with side protection or goggles, and if necessary, face
shield.)
Body protection : protective clothing
9. Physical and chemical properties
Form : Liquid
Colour : brownish yellow
Odour : slight, original odour
Pourpoint : approx. 5 °C
Method : DIN/ISO 3016
Starts to boil : approx. 115 °C
Method : DIN 51751
Flash point : approx. 96 °C
Method : DIN 51758 (closed cup)
Ignition temperature : not determined
Oxidizing properties : Not applicable
Self-ignition temperature : Not applicable
Lower explosion limit : not determined
Upper explosion limit : Not applicable
Evaporation rate : Not applicable
Vapour pressure : approx. 10 mbar (20 °C)
Density : approx. 1,07 g/cm3 (20 °C)
Method : DIN 51757
Bulk density : Not applicable
Vapour density in relation to Not applicable
air :
Solubility in water : (20 °C)
soluble
Soluble in ... : fat
not determined
pH value : approx. 3,5 (20 °C, 10 g/l)
Octanol/water partition not determined
coefficient (log Pow) :
Safety data sheet in accordance with 2001/58/EC
DODICOR 2725 NF Page 5
Substance key: SXR005073 Revision Date: 11.02.2005
Version : 3 - 4 / EU Date of printing : 23.02.2005
Viscosity (dynamic) : approx. 380 mPa.s (20 °C)
Method : DIN 53015
Viscosity (kinematic) : not determined
Combustion number : Not applicable
10. Stability and reactivity
Thermal decomposition : not determined
Hazardous reactions
Uncleaned empty vessels may contain product gases which can form explosive mixtures with
air.
11. Toxicological information
Acute oral toxicity : LD50 > 2.000 mg/kg (rat)
Method : OECD 401
Acute inhalation toxicity : not determined
Acute dermal toxicity : not determined
Irritant effect on skin : not determined
Irritant effect on eyes : not determined
Sensitization : not determined
Mutagenicity : not determined
Remarks
The product was classified on the basis of the calculation procedure of the Dangerous
Preparations Directive (1999/45/EC).
12. Ecological information
Biodegradability : > 80 %
Method : OECD 302 B
Source : Analogy
Fish toxicity : LC50 10 - 100 mg/l (96 h, golden orfe)
Source : Analogy
Bacteria toxicity : EC50 100 - 1.000 mg/l
Method : OECD 209
Source : Analogy
Chemical oxygen demand 1.853 mg/g
(COD) :
Safety data sheet in accordance with 2001/58/EC
DODICOR 2725 NF Page 6
Substance key: SXR005073 Revision Date: 11.02.2005
Version : 3 - 4 / EU Date of printing : 23.02.2005
13. Disposal considerations
Product
In accordance with local authority regulations, take to special waste incineration plant
14. Transport information
ADR
Proper shipping name: Corrosive liquid, acidic, organic, n.o.s.
Class: 8
Packing group: II
UN no. UN 3265
Primary risk: 8
Hazard no. : 80
Remarks Shipment permitted
Hazard inducer(s): NAPHTHENIC ACID IMIDAZOLINE BENZYL QUAT
ADNR
Proper shipping name: Corrosive liquid, acidic, organic, n.o.s.
Class: 8
Packing group: II
UN no. UN 3265
Primary risk: 8
Remarks Shipment permitted
Hazard inducer(s): NAPHTHENIC ACID IMIDAZOLINE BENZYL QUAT
RID
Proper shipping name: Corrosive liquid, acidic, organic, n.o.s.
Class: 8
Packing group: II
UN no. UN 3265
Primary risk: 8
Hazard no. : 80
Remarks Shipment permitted
Hazard inducer(s): NAPHTHENIC ACID IMIDAZOLINE BENZYL QUAT
IATA
Proper shipping name: Corrosive liquid, acidic, organic, n.o.s.
Class: 8
Packing group: II
UN/ID number: UN 3265
Primary risk: 8
Remarks Shipment permitted
Hazard inducer(s): NAPHTHENIC ACID IMIDAZOLINE BENZYL QUAT
Safety data sheet in accordance with 2001/58/EC
DODICOR 2725 NF Page 7
Substance key: SXR005073 Revision Date: 11.02.2005
Version : 3 - 4 / EU Date of printing : 23.02.2005
IMDG
Proper shipping name: Corrosive liquid, acidic, organic, n.o.s.
Class: 8
Packing group: II
UN no. UN 3265
Primary risk: 8
Remarks Shipment permitted
Hazard inducer(s): NAPHTHENIC ACID IMIDAZOLINE BENZYL QUAT
EmS : F-A S-B
15. Regulatory information
Labelling in accordance with EC-Directives
hazard warning labelling compulsory
Classification according to the calculation procedure of the Dangerous Preparations Directive
(1999/45/EC).
Hazard symbols
C Corrosive
Hazardous component(s) to be indicated on label
Prop-2-yn-1-ol
Naphthenic acid imidazoline benzylquat
Diethylene glycol
Nonylphenol polyglycol ether
R phrases
34 Causes burns.
20/21/22 Harmful by inhalation, in contact with skin and if swallowed.
52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
S phrases
26 In case of contact with eyes, rinse immediately with plenty of water and seek
medical advice.
28.2 After contact with skin, wash immediately with water and soap.
36/37/39 Wear suitable protective clothing, gloves and eye/face protection.
45 In case of accident or if you feel unwell, seek medical advice immediately
(show the label where possible).
61 Avoid release to the environment. Refer to special instructions/Safety data
sheets.
National regulations
Other regulations
Observe the requirements of Directive 2003/53/EC of 18.6.2003 (26th Ammendment of
Directive 76/769/EEC, "Restrictions on marketing and use").
Safety data sheet in accordance with 2001/58/EC
DODICOR 2725 NF Page 8
Substance key: SXR005073 Revision Date: 11.02.2005
Version : 3 - 4 / EU Date of printing : 23.02.2005
16. Other information
Text of the R-phrases which are allocated to the ingredients/components mentioned
in section 2 of this Safety Data Sheet.
10 Flammable.
22 Harmful if swallowed.
23/24/25 Toxic by inhalation, in contact with skin and if swallowed.
34 Causes burns.
51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
The data are based on the current state of our knowledge, and are intended to describe the
product with regard to the requirements of safety. The data should not be taken to imply any
guarantee of a particular or general specification. It is the responsibility of the user of the
product to ensure to his satisfaction that the product is suitable for the intended purpose and
method of use. We do not accept responsibility for any harm caused by the use of this
information. In all cases, our general conditions of sale apply.
