SR MPC (CAT-B & C) DATE: 02-12-2024 TO 07-12-2024

CHEMISTRY
REVISON ASSIGNMENT
CHEMICAL BONDING
1. Which of the given statements is/are true?
A) H2 S is gas while H 2O is liquid.
B) Ethanol has higher boiling point than diethyl ether.
C) Both (a) and (b).
D) None of these.
2. o-Nitrophenol is
A) less volatile than p -nitrophenol B) equally volatile as p -nitrophenol
C) more volatile than p -nitrophenol D) none of these.
3. Dispersion force is present between
A) Polar + polar B) non polar + non polar
C) polar + non polar D) all
4. Lattice energy is inversely proportional to sum of radii of
A) anion B) cation C) ions D) Both (a) and (b)
5. The correct order regarding the solubility of alkaline earth metal halides in water is
A) BeCl2  MgCl2  CaCl2  SrCl2  BaCl2 B) MgCl2  BeCl2  BaCl2  SrCl2  CaCl2
C) BaCl2  MgCl2  CaCl2  BeCl2  SrCl2 D) BeCl2  MgCl2  CaCl2  SrCl2  BaCl2
6. The ionic radius of cation will be smaller and more efficient in polarizing
A) carbonate ion B) carbonate molecule C) hydrogen ion D) water
7. Which of the following is not isomorphous with others?
A) White vitriol  ZnSO4 .7H2O B) Epsum salt  MgSO4  7H2O
C) Green salt  FeSO4  7H2O D) Washing salt  Na 2CO3.10H2O
8. Solubility of KI is maximum in
A) CH3OH(Er  34) B) CH3  O  CH3 (Er  4.1)

C) C2 H5  OH(Er  27) D)
9. The degree of polarization depends on
A) Charge density of cations only
B) Charge density of anions only
C) Charge denisty of cations oand polarizability of the anion
D) all of these
10. Even though the crystal radii of both K  and Ag are almost same, the melting point
of AgCl is only 455 C , while that of KCl is 776 C . The best explanation is
A) AgCl has more ionic character than KCl due to greater polarizing power of
potassium ion
B) KCl has more ionic character than AgCl due to greater polarizing power of
 potassium ion
C) AgCl has more covalent character than KCl due to greater polarizing power of
silver ion
D) KCl has more covalent character than AgCl due to greater polarizing power of
silver ion.
11. The correct order of covalent nature of alkali metal chlorides is
A) LiCl < NaCl , KCl < RbCl < CsCl B) CsCl < NaCl < KCl < RbCl < LiCl
C) LiCl > NaCl > KCl > RbCl > CsCl D) LiCl = NaCl = KCl = RbCl < CsCl
12. Incorrect solubility order:
A) CH3OH  C2H5OH  C3H7OH B) CH3OH  CH3  O  CH3  C2H5  O  C2H5

C) D) O-nitrophenol > p-nitorphenol

13. Correct order of stability of metal
A) Sn4  Sn2 B) Pb2  Pb4 C) Pb*2  Sn*2 D) Pb4  Sn 4
14. In C3O2 , there are
A) 2C  C double bonds and 2C  O double bonds. B) 2C  C double bond and 3C  O
double bonds.
C) 1 C-C triple and 3C  0 double bonds D) 3 C-O double bonds.

15. The formal charge on sulphur in HSO 4 is
A) + 2 B) – 2 C) + 4 D) – 4
16. The Lewis structure of chloric acid contains single bonds, double bonds and lone
pairs of electrons are respectively
A) 3, 2, 5 B) 2, 0, 7 C) 2, 2, 7 D) 2, 3, 8
17. In which of the following species, all the three types of hybrid carbon atoms are
presents ?
A) CH2  C  CH2 B) CH3  CH  CH  CH 2
C) CH3  C  C  CH 2 D) CH3  CH  CH  CH 2
18. In which one of the following species, the central atom has the type of hybridization
which is not the same as that present in the other three ?
A) SbCl2 B) PCl5 C) SF4 D) I3
19. Dipole moment of cis and trans form of benzene-1, 4-diol is
A)  cis  0,  trans  0 B)  cis  0,  trans  0
C)  cis  0,  trans  0 D)  cis  0,  trans  0
20. The relative energies of molecular orbitals depend upon
A) The energies of atomic orbitals combining to form MOs
B) the extent of overlapping between the atomic orbitals
C) both (A) and (B)
D) none of these
INTEGER TYPE
21. Which of the following show conductivity
(1) AlF3 (molten) (2) AlCl3 (3) HCl  l  (4) Graphite
(5) Na(s) (6) H 2SO 4  aq  (7) NaNO3 (8) KNO3  aq 
(9) MgCl 2  aq  (10) CuSO4 .5H2O
22. How many electron are involved in bodning in Lewis structure of S2O32 ion ?
23. According to Sidgwick-Powell theory prediction, the bond angle of a molcule
containing 6 electron pairs in outer shell, will be
24. How many nodes are threre in the antibonding molecular orbital formed by two 2s
atomic orbitals ?
25. The bond order for carbon monoxide is
25. Carbon monoxide has 10 bonding and 4 anitbonding electrons. Therefore, bond
order = 3
26. What will be the bodn order of resultant species when hydrogen atom containing
one electron is combing with hdyrogen ion having no electron ?
27. Total number of electorn present in MOs of B2 molecule is
28. C2 molecule is diamagnetic species with bond order 2. Double bond is C2 molecule
consists of both the pi bonds because of the presence of electron in two pi MOs
29. During the change : O2 to O + e  , bond order changes from 2 to

30. Among KO2 , AlO2 , BaO 2 & N O 2 unpaired e  is present in [July 29, 2020]

A) N O 2 & BaO2 B) KO2 & AlO2 C) KO2 D) BaO2

31. Out of N2O , SO2 , I3 I3 H 2O NO2 N3 the linear species are [Sep 2, 2020].
A) N 2O, I 3 , N3 B) NO2 , I3 , H2O C) N2O, I3(  ) , N3 D) N3 I 3 NO2

32. If Px and Py participate in sp 2 hybridisation of S atom, d orbitals involved in  -

bonding in SO3 are
A) d xz , d yz B) d x 2  y2 , d 2z C) d x2  y2 ,d xy D) d z2 ,d xy

33. AX 3 type of molecules are non planar when there are ________ lone pairs on A
[2018]
A) 1 B) 2 C) 0 D) None.

34. In which of the following pairs, the hybridisation of central atom is same but
geometry is not same
A) SO3 ,CO32 B) SO32 ,NH3 C) PCl5 ,POCl3 D) XeF2 , ICl3

35. Correct sequence of decreasing number of  -bond in the structure of H2SO3 , H2SO4
and H2 S2O7 is
A) H2 S2O7  H2SO4  H2SO3 . B) H2SO3  H2SO4  H2 S2O7
C) H2 S2O7  H2SO3  H2SO4 D) H2SO4  H2 S2O7  H2SO3

36. Group of molecules having identical shape

A) SF4 , XeF4 ,CCl4 B) ClF3 , XeOF2 , XeF3 C) PCl5 , IF5 , XeO2F2 D) BF3 , PCl3 , XeO3

37. RbI BrCl contains

A) Rb3 , I , Br  ,Cl B) Rb Br  and ICl C) Rb2 Br  ICl D) Rb IBrCl
38. Select the Incorrect statement [2004 S]
A) O3 and O 2 both are diamagnetic
B) out of O2 , O2 , O3 . Least 0  0 bond length is in O2
C) out of O2 , O2 , O2 only O2 is paramagnetic
D) out of O2 ,O2 ,O2 maximum spin magnetic moment have O2

39. Out of the given species which do not exist

BF63 , BiCl, H2 S , HN3 ,SF6 , CsXeF5 , PbI2 , ClF7 , NF6 , Li2CO3 , KH3

40. Number of species/ Ions which have bond angle of 1200


CH3 , C H 4 , NH3 , CO32 , BCl3 , PCl5

41. Total number of different bond lengths observed in PCl2 F3 are ______

42.

Column I Column II

A) O2 p) B.O  1

B) He2 q) Paramagnetic

C) C22 r) Homonuclear atomic orbital

combine with each other

D) NO s) Outermost e  in
antibonding molecular
orbital

A) A  P, q, r, s B  q, r, s C  P, r D  P, q, s B) A  p, q, r , s B  p, q, r C  p, r , s D  p, q, r
C) A  q, r, s B  p, q, s C  p, q, r D  q, r , s D) A  p, q, r B  p, q, s C  p, r , s D  q, s

43. Molecule AB has bond length of 1.617Å and a dipole moment of 0.38 D. The
fractional charge on each atom (absolute magnitude) is ( e0  4.802 1010 )(Apr 11
,2015)
A) 0 B) 1.0 C) 0.5 D) 0.05

44. Nodal plane of all  bonds is in same plane in [ July 25 2021]

A) C6 H 6 B) CO2 C) H2C  C  CH2 D) N2

45. In ICl2 , ICl2 , ICl4 sum of bond pairs and lone pairs on each I atom respectively
A) 2,2 and 4 B) 2,3 and 2 C) 4,5 and 4 D) 4,5 and 6 .

46. In CuSO4 .5H2O total number of H 2O molecules which form coordinate bond with
metal ion
A) 2 B) 4 C) 5 D) 0
47. I 3 and I 3 have same
A) Geometry B) Number of lone pairs

C) bond angle D) None

48. The species in which number of lone pair on I and number of d -orbitals used in
hybridisation by Iodine is same

A) ICl2 B) ICl2 C) IF7 D) ICl4

49. Which of the following species is non planar.

A) NO3 B) NO34 C) N2O5 D) NO2

50. Select covalent solid

A) S8 B) I 2 C) Si D) KCl

KEY
1.C 2.C 3.D 4.D 5.D 6.A 7.D 8.A 9.C 10.C
11.C 12.D 13.D 14.A 15.A 16.C 17.C 18.A 19.B 20.C
21.7 22.12 23.90 24.1 25.3 26.0.5 27.2 28.4 29.2.5 30.C
31.A 32.C 33.A 34.D 35.A 36.B 37.D 38.C 39.6 40.4
41.3 42.A 43.D 44.A 45.B 46.B 47.D 48.D 49.B 50.C
 CHEMICAL BONDING_SOLUTIONS

2.

4. Lattice energy is inversely proportional to interatomic distance of anion and cation

5.

6. The ionic radius of cation will be smaller and more efficient in polarizing carbonate
ion.
8.

9. Polarizing power depends on the tenency of catio of polarize and the polarizability of
the anion
10.

11. The covalent nature decreases with increase in the size of cation since the
polarizing power decreases with increase in the size.
12. Solubility  Inter molecular H – bonding > Intramolecular H – bonding.
13.

14.

15.
16.

17.

18.

19.

20. The relative energies of moelcular orbtials depend on both A and B.

21.

22.

23. For a molecule with 6 electron pairs, the bond angle will be 900 and the shape is
octahedral.
24.

26.
27.

28.

29.

39. BF63 , BiCl,SI6 ,ClF7 , NF6 , KH3


40. C H3 , CO32 , BCl3 , PCl5

41.

0.38 1018
43. Fraction of charge  0.05
4.8 1010 1.617 108