(1001CJA101021240024) Test Pattern

CLASSROOM CONTACT PROGRAMME JEE (Main)

PART TEST
(Academic Session : 2024 - 2025)
01-12-2024

JEE(Main + Advanced) : ENTHUSIAST COURSE (SCORE-I)

ANSWER KEY PAPER-1 (OPTIONAL)
PART-1 : PHYSICS
Q. 1 2 3 4 5 6 7 8 9 10
A. C B A A A A A A D C
SECTION-I
Q. 11 12 13 14 15 16 17 18 19 20
A. C D C A A A C D A B
Q. 1 2 3 4 5
SECTION-II
A. 3 7 2 21 7

PART-2 : CHEMISTRY
Q. 1 2 3 4 5 6 7 8 9 10
A. C B B D C A A B D B
SECTION-I
Q. 11 12 13 14 15 16 17 18 19 20
A. C C A C D A C C D C
Q. 1 2 3 4 5
SECTION-II
A. 80 4 7 6 60

PART-3 : MATHEMATICS
Q. 1 2 3 4 5 6 7 8 9 10

A. D B A C B A B B A B
SECTION-I
Q. 11 12 13 14 15 16 17 18 19 20

A. C C A C A A B B C B
Q. 1 2 3 4 5
SECTION-II
A. 5 2 3 5 1

HINT – SHEET
PART-1 : PHYSICS 2

= 1 × 1.7 × 1011 × 1.6 × 10–19 × ( 1

× 10−5 ) × (1)2
SECTION-I 2 √17

1. Ans ( C ) = 8 × 10–20 J = 0.58V

Radius of circular path described by a charged
By using ⇒ W0 = E – Kmax
particle in a magnetic field is given by
√2mK = ( 12375 ) eV – 0.5 eV = 4.5 eV
r= ; 2475
qB

Where K = Kinetic energy of electron

q 2 B 2 r2 e eB2 r2
⇒K= =( )
2m m 2

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2. Ans ( B ) 7. Ans ( A ) z

Given, 3L
Thermal resistance of rod A is R1 =
4KA
my = 2mx 2L 5L
similarly, R2 = and R3 =
3KA KC A
⇒ Zy = 2Zx
R1 + R2 2
If resistance of rod C is R3 then =
R3 3
(∵(A) =(
A
) =2 ⇒ n = p for both x and y)
Z x Z y
8. Ans ( A )
Let Zx = Z and Zy = 2Z
13.6 × Z 2 × 5
Energy of first line balmer →
36
13.6 × 5 13.6 × 5 17
∴ × [(2Z)2 − Z 2 ] =
36 36 3
⇒ Z=1

3. Ans ( A )
Both A and R are true and R is the correct Ptotal = σ (4 π R2)T4
explanation of A.
Pcross-section = Psquare + Pcircle
5. Ans ( A )
1 2π
= { σ (4 π R2)T4} + (1 – cos θ )
6 4π
{ σ (4 π R2)T4}
1 1
=( ){ σ (4 π R )T }
2 4
+
6 10
T = 5 cos 37° + 20 cos 53° = 16 N Pcross−sec tion 4
∴ =
Ptotal 15
F /A
Y= ΔL
9. Ans ( D )
L
In process CA PV – 2 = constant
FL
⇒ ΔL = = 8 × 10 – 5 m
YA
⇒ TV – 3 = constant
6. Ans ( A )
3
VA
–2
VT = constant TA = TC × ( ) = 2400K
VC
nR(TA − TC )
⇒ PV
1
2 = constant WCA = = 700R
1 − (−2)
nRΔT nRΔT In process AB (Isobaric),
Q= +
γ−1 1−x
nR50 nR50 VB
= +
TB = TA × = 1200K
7 VA
5
−1 1 − 12
WAB = nR(TB – TA) = – 1200R
= 225R
Δ UBC = nCV(TC – TB) = – 2250R

QAB = nCP(TB – TA) = – 4200R

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11. Ans ( C ) 14. Ans ( A )
dN λ1 M1 1
= αt3 − λN Given, =5 =
dt λ2 M2 3

At t = t1, 'N' is minimum.

P1 λ 1
∴ = 2 = ⇒ P2 = 5P1
3 3 P2 λ1 5
αt1 αt1
⇒ Nt 1 = =
λ 3
′ dN ′ Also, P12 + P22+ 2P1P2cos53o = P2
At t = t2, is minimum,
dt
3
d2N
= 3αt2 − λ
dN ⇒ 26P12 + 10P12 = ( ) = P 2
dt2 dt 5

= 3 α t2 – λ ( α t3 – λ N) = 0 ⇒ 32P12 + P2 ⇒ P1 = P
√32
3
λαt2 − 3αt2 2
⇒ = Nt 2
λ2 5P
∴ P2 =
3α (t2 3 − t2 2 ) √32
⇒ = Nt 2 P12 P22
9 +
Kf 2M1 2M2
Nt t 3 = .
∴ 1 = 31 3 Ki P2
Nt 2 2M
t2 − t2
( P2
) ( 25P )
2
32 32
12. Ans ( D ) = +
2x( M4 ) 2×( 3M
4
)

Inelastic collision
( 2M )
P 2

1 M KE
Q= ×V 2 = 1 25 7
2 2 2 =4[ + ]=
32 3 (32) 6
KEmax = 2Qmax = 2 × 13.6 = 27.2 eV.
ΔK Kf 1
∴ = −1=
13. Ans ( C ) K Ki 6

K.E. = 2E0 – E0 = E0 (for 0 ≤ x ≤ 1) 15. Ans ( A )

Based on theory
h
⇒ λ1 =
√2mE0 16. Ans ( A )
K.E. = 2E0 (for x > 1)
= R[ 2 − 2 ] ⇒
1 1 1 1 1 1
= R[ − ]
λ n1 n2 λ 9 25
h λ
⇒ λ2 = ⇒ 1 = √2
√4mE0 λ2 225
⇒λ=
16R

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17. Ans ( C ) 18. Ans ( D )
¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯ ¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯
y = (AB) ⋅ (CD) = (A
'D1' and 'D4' in forward bias, ¯¯¯¯¯¯ ¯ + B)
¯ ⋅ (C ¯¯¯¯¯¯¯
¯ + D)
¯

'D2' and 'D3' in reverse bias, ¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯

¯ + B)
¯ + (C
¯ + D)
¯ = AB + CD
¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯¯
= (A

V – 10i – 0.7 – 10(i – 0.5) – 0.7 = 0

20. Ans ( B )
⇒ i = V + 3.6 dNx
= − (2λ) NX ⇒ NX = NOe – 2 λ t
20 dt
For zener diode, dNY
= +3 (2λ) NX − λNY
dt
Given P = 1W, VZ = 2V ℓn10
"NY" is max at t =
λ
VZ 2
⇒ RZ = = 4Ω, iZ = 0.5A
P ⇒ O = 6 λ NX – λ NYmax

∴ Voltage across "10 Ω ",

⇒ NYmax = 6 NX
10 (R + 4)
V1 = i [ ] ℓn10
(R + 14) ⇒ NYmax = 6 Me−2λ ( )
10 (R + 4) λ
V + 3.6
V1 = i = ( )[ ] 6M
20 (R + 14) ⇒ NYmax = = 0.06M
(R + 4) 100
=( )[ ]
V + 3.6
2 (R + 14) PART-1 : PHYSICS
As, Vmax = 17.4 V SECTION-II

21 1. Ans ( 3 )
( )
R+4
⇒ V1max =
2 R + 14 ϕ = 6 – 2 = 4eV

KEmax = 2 × 6 – 4 = 8eV at emitter

At collection
KE = 8 – 5 = 3eV
3. Ans ( 2 )
V = Aℓ
For safe operation, d∀ dA dℓ
= +
V A ℓ
V1 max − VZ
R=
iZ 0 = –2μ ε + ε.
R = [ 21 ( )] − 2
R+4
2 R+14 1
⇒μ=
0.5 2

⇒ R2 – 3R – 28 = 0

⇒ R = 7Ω.

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4. Ans ( 21 ) 2. Ans ( B )
z2 z2 Δ H = nCP Δ T
f = f0 ⇒ =4 ....... (1)
n3 n3 CP is highest for XeF4.
z2 z2
E = E0 ⇒ = 16 ........ (2) (Non-linear polyatomic gas)
n2 n2
3. Ans ( B )
(1) and (2) ⇒ n = 4 and z = 16
0
ΔHRe action = (3 × 380) – 3(150 + 250)
Now, L = mvr = nh = 1140 – 1200
2π
ΔL Δn h = – 60 KJ/mol
⇒ τ= =
Δt Δt 2π 0 0
Resonance energy = ΔHf(exp) − ΔHf(theo)
3 (2.1 × 10−34 )
= × 0
– 120 = ΔHf(exp) – ( – 60)
(15 × 10−9 ) 2
0
ΔHf(exp) = – 180 KJ/mol
= 2.1 × 10 – 26 N – m
5. Ans ( C )
5. Ans ( 7 ) Δ fHo = 0 for elements in their reference elemental
1 4
Max KE converted =
2 5
mx V 2 states and for H+(aq).
4 6. Ans ( A )
= × 2.5 = 2 MeV
5
8A + 5 − 2 q = n Δ Hfusion
BEy = = 7 MeV
A+1 103
= ×9
PART-2 : CHEMISTRY 18
= 500 KJ
SECTION-I

1. Ans ( C ) 7. Ans ( A )
2
Slope of OA = 1
= 11.2
5.6
4
Slope of OB = 1
= 11.2
2.8
Δ HAtom > Δ HDiss.
If slope of OA is equal to slope of OB than AB
a
⇒ <1
is isothermal reversible process. b

v2
8. Ans ( B )
w = – nRT ln v1 NCERT
v2 9. Ans ( D )
= – PV ln v1
At equilibrium Δ G = 0, Δ °G ≠ 0
= – 2 × 5.6 ln All the process which are spontaneous has
= 7.84 ltr-atm Δ G < 0 and non-spontaneous has Δ G > 0.

= 784 Joule 10. Ans ( B )

K K*, σ 2s2 , σ *2s2 , π 2px2 = π 2py2, σ 2pz2,
π *2py0 = π *2px0
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11. Ans ( C ) 17. Ans ( C )
Basicity of acid is number of replaceable H+ ions.
( μ net ≠ 0) 18. Ans ( C )
Factual
19. Ans ( D )
SO2 is sp2 hybridised.
NH3 and H2O are sp3 hybridised.
H2S do not hybridise.
PART-2 : CHEMISTRY
XeO4 (Tetrahedral)
SECTION-II
12. Ans ( C )
1. Ans ( 80 )
( Δ S)syst for reversible adiabatic process is zero.
Δ Hvap = Δ Hsub – Δ Hfus
as qrev = 0
qrev = 38 – 6
Δs = =0
T = 32 kJ/mole
13. Ans ( A )
Δ Hvap – Tb Δ Svap = Δ Gvap = 0
XeOF2
ΔSvap
Hybridisation sp3d ∴ Δ Svap =
Tb
3-bond pair + 1 lone pair =
Two possible structures :
= 80 JK – 1 mol – 1
2. Ans ( 4 )
Ans (4) : (1), (2), (3), (5) are correct.
3. Ans ( 7 )
14. Ans ( C ) PVm = constant
σ - molecular orbitals are symmetric whereas R
C m = CV −
π -molecular orbitals are unsymmetric about the m−1
1
inter-nuclear axis. Given P V 2 = K
15. Ans ( D ) 1
m=
2
Qsyst = q then Qsurr = –q 3
Cm = R − 1 R
(ΔG)syst < 0 for all process occurring spontaneously. 2 ( 2 − 1)

16. Ans ( A ) 3
Cm = R + 2R
2
HA + NaOH → NaA + H2O 7
Cm = R
Δ H = – 13.7 + 6.7 2

= – 7 Kcal Cm = cal mol – 1 K – 1

Energy release = 7 Kcal
Cm = 7 cal
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4. Ans ( 6 ) 3. Ans ( A )
cos θ 1 + cos θ 2 + cos θ 3 = 0 = sin θ 1 + sin θ 2 + sin θ 3
centroid and circum centre are origin.
5. Ans ( 60 ) Δ ABC is equilateral. ortho centre is.
Resonance energy = (E)RS1 − (E)RH Also origin.
= – 240 – ( – 300)
= 60 4. Ans ( C )
π θ θ
OA = r cot( − ) = 2r cot
PART-3 : MATHEMATICS 4 2 2
θ
SECTION-I Let, tan =t
2
1. Ans ( D )
20 20
f(x) = A0 + ∑ Ak x k
= ∑ Ak x k
k=1 k=0
6
∵ ∑ f ( α rx) = f(x) + f( α x) + f( α 2x) + f( α 3x)
r=0

+ f( α 4x) + f( α 5x) + f( α 6x)

20
=∑ (Ak xk + Ak (αx)k + Ak (α2 x)k +. . . . +Ak (α6 x)k )
k=0 1+t 2
20 ⇒ =
1−t t
=∑ {Ak xk (1 + αk + (α2 )k + (α3 )k +. . . . +(α6 )k )}
√
−3 ± 17
k=0
⇒t=
2
= A0x0 (7) + A7x7(7) + A14x14(7) =7
θ √17 − 3
∴ tan =
[A0 + A7x7 + A14x14] 2 2
⇒ a + b + c = 17 + 3 + 2 = 22
⇒n=7
5. Ans ( B )
2. Ans ( B )
|2a – 1| = 3[a] + 2{a} = [a] + 2a
⎡ 4r + 1 4r2 + r3 3r3 + r5 + r4 ⎤
⎢ ⎥
1
f(r) = ⎢ 2r3 + r5 + 2r4 ⎥
case(i) If a ⩾
⎢ 3r + 2 4r2 r3 ⎥ 2
⎢ ⎥
+
⎣ 4r + 7 3r3 + r5 + 7r4 ⎦
2a – 1 = [a] + 2a
10r2 + r3
[a] = – 1
; a ∈ [ – 1, 0) Which is not possible
1
case(ii) If a <
2
R2 → R2 – R, & R3 → R3 – R1 – 2a + 1 = [a] + 2a
4a – 1 = – [a]
1
Case-1 : 0 ≤ a <
2
4a = 1
1
a=
|f(r)| = 0 4
No further solution possible.
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6. Ans ( A ) 8. Ans ( B )
C3 → C3 + C2 – C1

Expand along C3
1 1
f(n) = − ,
(n + 1)(n + 2)2 (n + 2)(n + 3)2
∞
1 1 1 1
So ∑ f(n) = ( − )+( − )
2 2 2
n=1 2.3 3.4 3.4 4.52

+......+ ( )
1 1
2
− 2
(n + 1)(n + 2) (n + 2)(n + 3)
7
49
So, for n = 7 ∑ f(n) =
n=1
900
1
For n → ∞ ∑ f(n) =
18

sin α cos(2α) 9. Ans ( A )

= 4
√2 4 (A) log2 . log2 20 + (log25)2
5
θ = 180° – (90° – α + 45°)
= (2 – log25)(2 + log25) + (log25)2
2√2 sin α = 1 − 2sin2 α
= 4 – (log25)2 + (log25)2 = 4
⇒ θ = 45° + α
2x+3
(B) log6 =x
2sin2 α + 2√2 sin α − 1 = 0 3x − 2
x x x
−2√2 ± √8 + 8 −2√2 + 4 1 ⇒ 8.2 = 6 . (3 – 2)
sin α = = =− +1
4 4 √2
⇒ 8 = (3x)2 – 2.3x
sin α = ( )
−1 + √2
√2 x x
⇒ (3 – 4)(3 + 2) = 0
7. Ans ( B )
⇒ 3x = 4 ⇒ x = log34 = a
Shaded area is the region traced by P,
its area = ⇒ 9log3 4 = 16

Δ ABC – 3 Δ ADC (C) log36 4 + 6log6 4.log6 9 + log36 9

=
√3
a2 − 3 (
a a
× tan 150 )
= (log64 + log69)3 = 23 = 8
4 2 2
√3 3 (D) (2a + 1)2 + (3b – 1)2 + (c – 2)2 = 0
= a − a2 tan 150
2
4 4
1 1
⇒ a = − ,b =
a2 ( )
√3 √3 − 1 ,c = 2
= 2 3
2 √3 + 1
⇒ 4a + 3b + c = -2 + 1 + 2 = 1

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10. Ans ( B ) 12. Ans ( C )
z3 + ( – α z1)3 + (( α – 1)z2)3 = 3z( – α z1)(( α – 1)z2) Here ABAT = ABTAT = I
So C = A(ABAT)25 (ABTAT)10 AT = AAT
⇒ z – α z1 + ( α – 1)z2 = 0
1 −2 1 0 5 −2
αz1 + (1 − α)z2 =[ ][ ]=[ ]
z= 0 1 −2 1 −2 1
α + (1 − α)
z lies on line joining z1 and z2. ⇒ Trace of matrix C = 6

|z|min = perpendicular distance of origin from line 13. Ans ( A )

log2a . log2 2a – log22a
joining z1 and z2.
= log2c. log28c + log28c
11. Ans ( C )
⇒ (log2a – 1) log22a = log28c . (log2c + 1)

⇒ (log2a – 1) (log2a + 1) = (log2c +3) (log2c + 1)

⇒ log22 a – 1 = log22 c + 4log2c + 3

⇒ (log2a)2 = (log2c + 2)2

eq. of circle x2 + y2 - 2x + 4y - 20 = 0 log2a = log2c + 2 ⇒ a
=4
c
eq. of chord of central form point P(h,k) to the or log2a = – 2 – log2c
circle is. 1
⇒ log2ac = – 2 ⇒ ac =
4
1
T=0 ⇒ a, , c are in GP.
2
⇒ hx + ky - (h + x) + 2(k + y) – 20 = 0 14. Ans ( C )

⇒ (h – 1) x + (k + 2)y – h + 2k – 20 = 0 xy (x – 2y – 4) = 0

In Δ OAM,
π OM
cos =
3 OA
5
⇒ OM = Δ 4
2 r= =
|(h − 1) − 2(k + 2) − h + 2k − 20| 5 s 3 + √5
⇒ =
2
√(h − 1)2 + (k + 2)2 Δ 4
r1 = =
s−a 1 + √5
⇒ (h – 1)2 + (k + 2)2 = 100
4
r2 =
√5 − 1
⇒ Locus is (x – 1)2 + (y + 2)2 = 100
4
r3 =
Radius = 10 3 − √5
1 1 1 1 3 + √5
Sum = + r + r + =
r 1 2 r3 2

so, a = 3 & b = 2
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15. Ans ( A ) 17. Ans ( B )
2x1 + x2 2y1 + y2
( ⋅ ) |z + 1| = |z – 3i|
3 3

z=α+i
⎛ + y3 ⎞
2x1 +x2 2y1 +y2
+ x3
P =⎜ ⎟
3 3
, w = zz¯ − 2z + 2
⎝ 2 2 ⎠

2x1 + x2 + 3x3 2y1 + y2 + 3y3 w = α 2 + 1 – 2( α + i) + 2

=( , )
6 6
w = α 2 – 2 α + 3 – 2i
∴ P lies in side the Δ ABC Re(w) = α 2 – 2 α + 3
= ( α – 1)2 + 2
⇒ Area of Δ PBC < area of Δ ABC
at α = 1
16. Ans ( A )
Re(w) min = 2, so that
w = 2 – 2i
w = 2(1 – i)
wn = 2n (1 – i)n
so the minimum value of n is
−−
→ −−
→ −−
→ −−
→
Rotate P A to get P C and rotate BC to get BA n=4
18. Ans ( B )
Applying rotation formula at P and B we get
Δ 1 = 3abc – a3 – b3 – c3
p+4 2
2iω − ω
× = −1
p− ω2 2iω + 4 Δ 2 is formed by cofactors of elements of Δ 1

⇒p

2i − 8iω + 8ω2 2(i − 4iω + 4ω2 )

= = × iω = −2iω
4iω − ω2 + 4 (−4ω2 − 1 + 4iω)

p + 2iω 2
So, z = = 0 ⇒ |z| = 0
2

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19. Ans ( C ) PART-3 : MATHEMATICS
Equation of tangent at (6, – 8) to the circle SECTION-II

1. Ans ( 5 )
x2 + y2 = 100 is :
z = x + iy, z̄ = x – iy, (2 iy)2 = 12(x2 + y2) – 4
T=0
⇒ 12x2 + 16y2 = 4 ⇒ 3x2 + 4y2 = 1
⇒ 6x – 8y = 100 ........... (1)
x2 y2
⇒ + =1
1 1
equation of normal at (6, – 8) is 3 4

x=√ cos θ, y = √ sin θ

1 1
(y + 8) = − 4 (x − 6) 3 4
3
3√3 Re (z) + 8 Im(z) = 3cos θ + 4 sin θ
⇒ 4x + 3y = 0 ...... (2)
max = 5
Area of triangle
2. Ans ( 2 )
1 25
= × ×6
2 2 Point may lie on the same side of the line or
75
= sq units atleast one on the line so
2
4[a2 + 2b(a + b + c) + 4] > 0
a2 + (2b)a + 2b(b + c) + 4 > 0
D<0
4b2 – 4[2b2 + 2bc + 4] < 0
20. Ans ( B )
– b2 – 2bc - 4 < 0
1967 + 1686i sin θ
A=
7 − 3i cos θ b2 + 2bc + 4 > 0
281(7 + 6i sin θ) 7 + 3i cos θ
= ×
7 − 3i cos θ 7 + 3i cos θ D < 0; 4c2 – 16 < 0
281(49 − 18 sin θ cos θ + i(21 cos θ + 42 sin θ))
=
49 + 9cos2 θ c2 – 4 < 0
for positive integer –2 < c < 2

Im(A) = 0 Max value of c = 2

21cos θ + 42sin θ = 0 3. Ans ( 3 )

−1 −4 4
Hint : XXT = I
tan θ = , sin 2θ = ; cos2 θ =
2 5 5 Now, PQ = AXB BXTA
281(49 − 9 sin 2θ)
Re(A) = = 3A2
49 + 9cos2 θ
281 (49 − 9 × −45
)
= = 281 (+ve integer)
49 + 9 × 45

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4. Ans ( 5 ) 5. Ans ( 1 )
Let f(x) = x4 + x3 + ax2 + bx + c 2x4 + 1 – 2x3 – x2 = 1 – x2 – 2x3 (1 – x) = (1 – x)
& x2 + x + 1 = (x + ω)(x + ω2)
(1 + x) – 2x3 (1 – x)
∵ f(x) is divisible by x2 + x + 1
= (1 – x)(x + 1 – 2x3) = (1 – x)(x(1 – x2) + 1 – x3)
f(ω) = 0 ⇒ ω + 1 + aω2 + bω + c = 0 .....(1)
= (1 – x)(x(1 – x)(1 + x) + (1 – x)(1 + x + x2))
f(ω2) = 0 ⇒ ω2 + 1 + aω + bω2 + c = 0 ....(2)
eq. (1) – eq. (2) = (1 – x)((1 – x)(x(1 + x) + 1 + x + x2))

⇒ ω – ω 2 – a( ω – ω 2) + b( ω – ω 2) = 0 = (1 – x)2 ((x + 1)2 + x2 ) ≤ 0.

⇒ 1 – a + b = 0 ⇒ a – b = 1 .....(3) Equality occurs if and only if x = 1.
& eq. (1) + eq. (2)
⇒ ( ω + ω 2) + 2 + a( ω + ω 2) + b( ω + ω 2) + 2c = 0
⇒ – a – b + 2c + 1 = 0
⇒ 2c = a + b – 1 .....(4)
Now, 5a – b – 4c = 5a – b – 2a –2b + 2
= 3 (a –b) + 2 = 3 + 2 = 5

HS-12/12 1001CJA101021240024
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