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    Final-HW1

    Uploaded by

    Thái Vĩ

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd

    Final-HW1

    Uploaded by

    Thái Vĩ
    3 views2 pages

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    Copyright:

    © All Rights Reserved
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    3 views2 pages

    Final-HW1

    Uploaded by

    Thái Vĩ

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    of 2

    a b Unit

    0.01 0.0058 M

    Time, ml NaOH for back- Concentration of


    (a-x) (b-x) ln(a-x) ln(b-x)
    min titrating NaOH reacted

    1 13.83 0.00076 0.00924 0.00504 -4.68421 -5.2903

    3 14.60 0.00112 0.00888 0.00468 -4.72395 -5.3645

    5 15.40 0.00200 0.00800 0.00380 -4.82831 -5.5728

    10 16.60 0.00300 0.00700 0.00280 -4.96185 -5.8781

    20 17.95 0.00404 0.00596 0.00176 -5.12268 -6.3424

    35 19.02 0.00484 0.00516 0.00096 -5.26682 -6.9486

    55 19.68 0.00544 0.00456 0.00036 -5.39043 -7.9294

    75 19.85 0.00558 0.00442 0.00022 -5.42162 -8.4219


    ln[(a-x)/(b-x)]
    3.5

    3
    0.606135804
    2.5
    LN[(A-X)/(B-X)]

    0.640503447
    2 y = 0.3496x - 0.1547
    0.744440475 R² = 0.8793
    1.5

    0.916290732 1

    0.5
    1.219756672
    0
    1 3 5 10 20 35 55 75
    1.681758574
    TIME, MIN
    2.538973871

    3.000267429
    RSQ 0.87930

    From graph, a straight line is obtained when ln[(a-


    x)/(b-x)] is plotted vs time, indicating a second-
    order reaction. Hence, he rate constant is the
    slope of the graph, which is 0.3496 M^(-1)⋅s^(-1).

    Rate Constant (k) 0.3496 M^(-1)⋅s^(-1)

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