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    Coordination Compounds

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    Divyansh Bhandari

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    © All Rights Reserved
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    Coordination Compounds

    Uploaded by

    Divyansh Bhandari
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    3 views1 page

    Coordination Compounds

    Uploaded by

    Divyansh Bhandari

    Copyright:

    © All Rights Reserved
    Download as DOCX, PDF, TXT or read online from Scribd
    Download as docx, pdf, or txt
    of 1

    CO-ORDINATION COMPOUNDS

    PRACTICE QUESTIONS

    Q1. a) What type of isomerism is shown by complex [Co(NH3)6] [Cr(CN)6]?


    b) Why is the solution of [Ni(H2O)6]2+ is green while a solution of [Ni(CN)4]2- is colourlesss?
    c) Write the IUPAC name of the following complex: [Co(NH3)5(CO3)]Cl.
    Q2. a) What type of isomerism is shown by the complex [Co(en) 3]Cl3?
    b) Write the hybridization and magnetic character of [Co(C2O4)3]3-
    c) Write the IUPAC name of the following complex [Cr(NH3)3Cl3].
    Q3. a) What type of isomerism is shown by the complex [Co(NH3)5(SCN)]2+?
    b) Why is [NiCl4]2- paramagnetic while [Ni(CN)4]2- is dimagnetic?
    c) Why are low spin tetrahedral complexes rarely observed?
    Q4. a) Define Crystal Field Splitting energy. On the basis of crystal field theory write the electronic
    configuration for d4 ion ∆o < P.

    Q5. When a co-ordination compound CrCl3⋅6H2O is mixed with AgNO3, 2 moles of AgCl are precipitated
    b) Write the hybridization and magnetic character of [CoF6]3-.

    per mole of the compound. Write


    (i) Structural formula of the complex. (ii) IUPAC name of the complex.
    Q6. When a coordination compound CoCl3.6NH3 is mixed with AgNO3, 3moles ofAgCl are precipitated
    per mole of the compound. Write :
    (i) structural formula of the complex. (ii) IUPAC name of the complex.
    Q7. When a co-ordination compound COCl3.4NH3 is mixed with AgNO3. 1 mole of AgCl is precipitated
    per mole of the compound. Write:
    (i) Structural formula of the complex. (ii) IUPAC of the compound.
    Q8. a) Draw one of the geometrical isomers of the complex [Pt(en) 2Cl2]2+ which is optically active.
    b) Draw one of the geometrical isomers of the complex [Pt(en) 2Cl2]2+ which is optically inactive.
    Q9. a) Why are tetrahedral complexes high spin?
    b) Write the IUPAC name of the complex [Pt(en)2Cl2]2+. What type of isomerism is shown by this
    complex.
    Q10. a) Define Crystal Field Splitting energy. On the basis of crystal field theory write the electronic
    configuration for d4 ion ∆o > P.
    b) What type of isomerism is shown by [Co(NH3)5ONO]Cl2 and [Ag(NH3)2] [Ag(CN)2]?
    Q11. a) Out of CN- and CO which ligand forms more stable complex with metal and why?
    b) Out of NH3 and CO which ligand forms more stable complex with metal and why?
    c) Out of NH3 and ‘en’ which ligand forms more stable complex with metal and why?
    Q12. a) Draw the geometrical isomers of the complex [Co(en) 2Cl2]+.
    b) [NiCl4]2- is paramagnetic while [Ni(CO)4] is dimagnetic, though both are tetrahedral. Why?
    Q13. a)Predict the number of unpaired electrons in hexaaquamanganese(II)ion.
    b) Write the chemical formula and shape of hexaamminecobalt(III)sulphate.
    Q14. Write the isomerism exhibited by following:
    a) [Co(NH3)5SO4]Cl b) [Co(NH3)5NO2]2+ c) [Cr(NH3)4Cl2]. d) [Co(en)3]3+ e) [Co(NH3)5SO4]Br
    Q15. Draw the structures of optical isomers of each of the following complex:
    a) [Co(C2O4)3]3- b) [PtCl2(en)2]2+ c) [Cr(NH3)Cl2(en)] d) [Pt(NH3)2Cl2]
    Q16. [Fe(CN)6] and [Fe(H2O)6]2+ are of different colours in dilute solutions.
    4-

    Q17. Define
    a) Ambidentate Ligand b) Denticity of a Ligand c) Crystal field splitting in an octahedral field.

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