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18 views7 pages

Previous Exams

Healthcare workers

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sesaeedhaniyah.d
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Qu L Choose the correct answer from the following. [35 marks. 1.25 each] Perform each calculation to the correct number of significant figures. ((1.7 « 105) + (2.63 « 105)] + 7.33 a. 13.79 ©. 137 b. 13.7938 a. 13 ‘The average U.S. farm occupies 435 acres. How many square miles is this? (1 acre = 43560 f12, 1 mile = $280 ft) a. 0.67968 mi? cc. 0.70 mit b. 0.6797 mi? d. 0,680 mi? Which sample contains the greatest number of atoms? a 14gC ce. 102g Ag b. 49. ¢Cr 4. 202 gPb An isotope of an element contains 82 protons and 122 neutrons. What is the symbol for the isotope? a. 24 Pb gp ce. Zr 49 b. Pb ge d. 24 Zr go, Fructose is a common sugar found in fruit, Elemental analysis of fructose gives this mass percent composition: C 40.00%, II 6.72%, O 53.28%. The molar mass of fructose is 180.16 g/mol. Find the molecular formula of fructose. a. CH20 e sO b. CoHi206 d. CsH20 What is the formula for manganese (IV) oxide? a, MnO ¢. MnO2 b. MnO« d. MnO Name the compound P21, a, Phosphorus iodide ©. Phosphorus (II) iodide b. Phosphorus diiodide 4. Diphosphorus tetraiodide List the elements in the compound CF,Ch in order of decreasing mass % composition 10- i 12 13 14 1s- a, C>F>Cl ce. CI>C>F b. F>CI>C d. CI>F>C Ammonia, NH, can be synthesized by the reaction: 2 NO +5 Haig) > 2 NHxie) + 2 H20 (ey Starting with 86.3 g NO and 25.6 g Ho, find the theoretical yield of ammonia in grams. a. 49.0 gNHs ©. 49.0 gNHs b. 87.04 g NH3 d. 87.04 g NHs What are the correct coefficients (reading from left to right) when the chemical equation is balanced? _PChiy +__H20(y > _HsPOx(a9) +_HClag) a 1,3,1,3 « 1 At a. 3,6,1,9 ‘Name the compound HNO2aq), a, Hydrogen nitrogen dioxide ©. Nitric acid b. Hydrogen nitrate d, Nitrous acid Whaat is the pressure of 1.78 g of nitrogen gas (N2) confined to a volume of 0.118 L at 90°F? a 13.2atm ec. 1.10 atm b. 369 atm d. 26.3 atm Which gas sample has the greatest volume at STP? a, 10.0gNa . 10.0¢Ca b. 100gK d. Allhave the same volume A 255-mL gas sample contains argon and nitrogen at 65 °C. The total pressure of the sample is 760 mm Hg, and the partial pressure of argon is 231 mm Hg. What mass of nitrogen is present in the sample? a, 0.324 g nitrogen ¢. 0.0837 g nitrogen b. 0.167 g nitrogen d. 0.179 g nitrogen A sample of Xe takes 75 seconds to effuse out of a container. An unknown gas takes 37 seconds to effuse out of the identical container under identical conditions. What is the most likely identity of the unknown gas? 2 16- 1 18 19- 20- 2 Bn Kr = 2 ae ‘A gas mixture in a 1.55-L container at 298 K contains 10.0 g of Ne and 10.0 g of Ar. Calculate the partial pressure (in atm) of Ne and Ar in the container. a, Prie= 10.5 atm, Par= 5.29 atm €. Pwe=5.83 atm, Par = 2.95 atm b, PNe= 7.82 atm, Par= 3.95 atm d. Pyo= 5.88 atm, Par 5.88 atm Rank the gases Ar, Nz, CHs, and C2Hg in order of increasing density at STP. a, CH4< CoH Ls'tag) +2 F200 In the first 10.0 seconds of the reaction, the concentration of I" drops from 1.000 M to 0.868 M. (1) Calculate the average rate of this reaction in this time interval. (2) Predict the rate of change in the concentration of H* (that is, A[H*//Ad) during this time interval. a, (1) 4.40 x 103 Mis, (2) 8.80% 103 M/s, (1) 4.40 x 1073 M/s, (2) -8.80% 103 Mis b. (1) 4.40 x 10 Mis, (2) -8.80% 103 Mis d. (1) -8.80x 10° Mis, (2) 4.40 * 105 Mis The reaction A ->B has been experimentally determined to be second order. The initial rate is 0.0100 M/s at an initial concentration of A of 0.100 M. What is the initial rate at [A] = 0.500 M? a 0,00200 Mis cc. 0.0500 Mis b. 0.0100 Mis d. 0,250 Mis A decomposition reaction has a half-life that does not depend on the ini concentration of the reactant, What is the order of the reaction? a. zero order c. second order b. first order d, Order cannot be determined The decomposition of ozone is important to many atmospheric reactions. 3 22- 24 25 Ox) > 02g) +O Determine the value of the frequency factor and activation energy for the reaction, if the Linear equation In k vs. 1/T(K) is; Y= -L12* 108 x + 26.8 k= -2(4 +InA nk = — > nA 1 ki/mol, A= 4.36 10"? 93.1 kiimol, A= 4.36 = 10! a, E.= 93.1 Jimol, A= 4.36 « 10! ce. Ei 9! b. Ex= 93.1 ki/mol, A= 4.36 101! a Which statement is true regarding the function of a catalyst in a chemical reaction? A catalyst increases the rate of a reaction A catalyst provides an alternate mechanism for the reaction. A catalyst is not consumed by the reaction. Alll the above are true. ae se Consider the reaction and its equilibrium constant: N204ig) 9 2NO2y) Ke = 5.85 103 A reaction mixture contains [NO2] = 0.0255 M and [N20«] = 0.0331 M. Calculate Q, and determine the direction in which the reaction will proceed. a, 1,965%10°, shift to the reactant ¢, 1,965%107, shift to the reactant b. 1.965%102, shift to the product 4d, 1,965%107 , shift to the product Molecular iodine (I2) decomposes at high temperature to form I atoms according to the reaction: lag) > 21a) Ke= 0.011 at 1200 °C In an equilibrium mixture, the concentration of I2 is 0.10 M. What is the equilibrium concentration of I? a, 2.75 x104M. c. 234x10?M b. 0.166M 4. 0.0332 M The following reaction is endothermic: CaCO54y CAO + COr) How to increase the concentration of CO2? ‘a. Increase temperature b. Decrease temperature 26- 2 28. Q2 L ¢, Increase the amount of CaCO3 d. Decreases the amount of CaO ction between NO and Cl to form NOCI. 2NOw) + Che) > 2 NOCle) A reaction mixture at a certain temperature initially contains only [NO] = 0.50 M and [Cl] = 0.50 M. After the reaction comes to equilibrium, the concentration of NOCIis 0.20 M. Find the value of the equilibrium constant (K.) at this temperature. Consider the re: a. 133 e b’. 43 d. 0.32 jon of A to form B. 2A@ > 2Be Ke= 1,8 * 10° (at 298 K) A reaction mixture at 298 K initially contains [A] = 0.50 M. What is the concentration of B when the reaction reaches equilibrium? Consider the re: a, 9.0 10M ©. 2.12 x 103M bv. 3 «103M d. 4,5 105M The reaction X21) > 2 X,q) occurs in a closed reaction vessel at constant volume and temperature, Initially, the vessel contains only X2 at a pressure of 1.55 atm. After the reaction reaches equilibrium, the total pressure is 2.85 atm. What is the value of the equilibrium constant, Kp, for the reaction? a, 27 © 52 b. 10 d. 32 Solve the following questions with full calculation. —_[15 marks, 3.75 each] Consider the chemical reaction: C+ H20 i) > CO w+ Hr How many liters of hydrogen gas are formed from the complete reaction of 18.7 gC? Assume that the hydrogen gas is collected at a pressure of 1.0 atm and a temperature of 355K. Consider the following reaction: CHCl + Chay CCl) +HChe) The initial rate of the reaction is measured at several different concentrations of the reactants with the following results: From the data, determine: [CHC] (M) {Cla} (M)__ Initial Rate (M/s) (a) the rate law for the reaction 0010 oo10 0.0085 (b) the rate constant (4) for the reaction 0.020 oo10 0.0069 0.020 0.020 0.0098, 0.040 040 0027 The following reaction is monitored as a function of time: ADB+C A plot of In [A] versus time yields a straight line with slope -0,0045 s+ a, What is the value of the rate constant (&) for this reaction at this temperature? b. Write the rate law for the reaction. ¢. What is the half-tife? 4. If the initial concentration of A is 0.250 M, what is the concentration after 225 s? 4 Consider the chemical equation and equilibrium constant at 25 2 COF 2p) > CO) + CFeig) — K= 2.2 « 108 Calculate the equilibrium constant for the following reaction at 25 °C: 2. COng) +2 CF) > 4 COF 2) K'= ?

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