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    Barium Nitrate (Ba (NO3) 2)

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    divyanshontheweb
    Cjch

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    © All Rights Reserved
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    Barium Nitrate (Ba (NO3) 2)

    Uploaded by

    divyanshontheweb
    5 views2 pages
    Cjch

    Original Title

    Barium nitrate (Ba(NO3)2)

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    © © All Rights Reserved

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    Cjch

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    5 views2 pages

    Barium Nitrate (Ba (NO3) 2)

    Uploaded by

    divyanshontheweb
    Cjch

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    of 2

    Aim- To identify acidic and basic radicals in given inorganic salt.

    S.No Experiment Observation Inference


    Preliminary tests
    Physical examination
    a) Noted the colour of the salt White Cu2+, Fe2+, Fe3+ absent
    NH4+, S-2, CH3COO-
    b) Noted the smell of the salt No specific odour Absent.

    Identification of acid radical


    Dil sulphuric acid test
    Treated a pinch of the salt No gas evolved CO32- , S2-absent.
    With dil H2SO4 and warmed.
    Con sulphuric acid test
    Heated a pinch of the salt with Con A reddish brown gas NO3- present.
    sulphuric acid evolved which turned
    FeSO4 solution black.
    Copper chips test
    Heated a pinch of the salt with Intensified Reddish NO3-present.
    conc. sulphuric acid and a few brown gas evolved.
    copper chips.

    S.No Experiment Observation Inference


    Confi matory test for acid radical
    a) Ring test
    To 2-3 ml of the salt solution, A dark brown ring NO3- confirmed
    added freshly prepared FeSO4 formed at the junction
    solution. Now added conc H2SO4 of the two liquids
    along the sides of the test tube.

    Identification of basic radical


    NaOH test
    Heated a pinch of salt with No ammonia gas evolved NH4+ absent
    conc.NaOH solution
    Preparation of original salt solution
    Prepared original salt solution by dissolving a pinch of salt in 10 to15mL of distilled water or dil.H
    Cl or conc.HCl, cold or hot. Label it original solution (O.S).
    Group separation
    a) To a few drops of the original No brown ppt. formed Group zero absent
    solution added 1 mL of (NH4+absent)
    Nessler’s reagent and excess of
    NaOH solution
    b) To a few drops of the original
    solution added 2 mL of dil.HCl. No precipitate formed Group I absent
    (Pb2+absent)
    c) To a few drops of the original
    solution added 2 mL of dil. HCl No precipitate formed Group II absent
    and then passed H2S gas (Cu2+absent)

    d)To a few drops of the original No precipitate formed Group III absent
    solution added1 mL of NH4Cl (Fe3+, Al3+absent)
    and 2ml of NH4OH.
    e) To a few drops of the original No precipitate formed Group IV absent
    solution added1 mL of NH4Cl (Zn2+ absent)
    and
    2mL of NH4OH and then
    passedH2S gas.
    f) To a few drops of the original White precipitate Group V present (Ba2+,
    solution added 1mL of NH4Cl, formed Sr2+, Ca2+ present)
    2mL of NH4OH and 2mL of
    saturated solution of (NH4)2CO3
    Confirmatory test for basic radical.
    a) Potassium chromate test
    To a few drops of the original Yellow precipitate Ba2+confirmed
    solution added 2 to 3 drops of obtained
    potassium chromate solution.
    b) Flame test
    Prepared a paste of the salt with Persistent grassy green Ba2+confirmed.
    Conc.HCl and performed flame flame On prolonged
    test. heating.

    Result:
    The given simple salt is: Barium chloride (Ba(NO3)2)
    Acid radical: NO3-
    Basic radical: Ba2+

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