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14 views1 page

ASA Page 1

Uploaded by

lancematthewte
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© © All Rights Reserved
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Name Larcro Ie section Slfrtl tr-s

Experiment 15

Advance Study Assignment: The todination of Acetone

1. In a reaction involving the iodination of acetone, the following volumes were used to make up the reac-
tion mixture:

5 mL 4.0 M acetone + 10 mL 1.0 M HCI + l0 mL 0.0050 M 12 + 25 mLHrO

a. How many moles of acetone were in the reaction mixture? Recall that, for a component A, moles
A : Mo X V, where Ml is the molarity of A and V is the volume in liters of the solution of A that
. was used.

L' !,i',r
l, + 0IA x a oo5

x8*otrU
0 '0L moles acetone

b. What was the molarity of acetone in the reaction mixture? The volume of the mixture was 50 mL,
0.050 L, and the number of moles of acetone was found in Part (a). Again,

t, _ moles of A
"'e -V6fso-inllnllGE
N^,W'--^Xy, (l'+ M acetone

c. How could you double the molarity of the acetone in the reaction mixture, keeping the total volume
at 50 mL and keeping the same concentrations of H+ ion and 12 as in the original mixture?

mtttpl/ thu rurhcr ,* ralt-s \ autono 4 L


2. Using the reaction mixture in Problem l, a student found that it took 510 seconds for the color of the I, to
disappear. \

a. What was the rate of the reaction? Hint: First find the initial concentration of L in the reaction mix-
ture, [I2]0. Then use Equation 5.

rute :
-ryStd st Zx t55wr".
= ,ut"= 7'o * lo *r."
-5
o'Y5aot.^#
inilht urw slIu, tonl-x It- ^ #o T : o.ootM
l0ttoat
O.ootM olru
b. Given the rate from Part (a), and the initial boncentrations of acetone, H* ion, and in the reaction 12
mixture, write Equation 3 as it would apply to the mixture.
faV'- ).0 rus M/g

rate= : p'b6 2 O.Lt^


ry ", KLo.,"f Lo'zf 1'r'oor1o

c. What are the unknowns that remain in the equation in Part (b)?

a t c
( continued on following page )

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