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Introduction To Experimental Programme Assignment

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Introduction To Experimental Programme Assignment

Uploaded by

venkatesh.pranauv
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© © All Rights Reserved
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Download as DOCX, PDF, TXT or read online on Scribd
You are on page 1/ 6

IB

Chemistry

Introduction to Experimental Programme


Name: …………………………………… ( ) Class: ……………

A1 An ammeter has a zero-offset error. This fault will affect

A neither the precision nor the accuracy of the readings.


B only the precision of the readings.
C only the accuracy of the readings.
D both the precision and the accuracy of the readings.
( )

A2 The reading of a constant potential difference is made four times by a


student. The readings are 1.176 V, 1.178 V, 1.177 V, 1.176 V. The student
averages these readings but does not take into account the zero error on
the voltmeter.
Which option best describes the average measurement of the potential
difference?

A precise and accurate.


B precise but not accurate
C accurate but not precise.
D not accurate and not precise.
( )

A3 Both random and systematic errors are present in the measurement of a


particular quantity. What changes, if any, would repeated measurements of this
quantity have on the random and systematic errors?

random systematic
A reduced reduced
B reduced unchanged
C unchanged reduced
D unchanged unchanged

( )

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IB
Chemistry

A4 A burette reading is recorded as 33.60 ± 0.05 cm3.


Which of the following could be the actual value?

I 33.58 cm3
II 33.1 cm3
III 33.64 cm3

A II only
B I and III only
C III only
D I, II and III
( )

A5 A student measures a distance several times. The readings lie between 49.8 cm
and 50.2 cm. How should the measurement be recorded?

A 49.8 ± 0.2 cm.


B 49.8 ± 0.4 cm.
C 50.0 ± 0.2 cm.
D 50.0 ± 0.4 cm.
( )

A6 The volume V of a cylinder of height h and radius r is given by the expression


V = πr2h. In a particular experiment, r is to be determined from
measurements of V and h. The uncertainties in V and in h are: V ±7%, h ±
3%. What is the approximate uncertainty of r?

A 10%
B 5%
C 4%
D 2%
( )

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IB
Chemistry

A7 Significant Figures in Calculations


Perform the following calculations, reporting the answers to the correct
number of significant figures.

(a) (8.71 x 0.0301) / 0.056 =

(b) 0.71 + 81.8 =

(c) 8.937 - 8.930 =

(d) 934 x 0.00435 + 107 =

(e) (847.89 - 847.73) x 14673 =

(f) 0.00015 x 54.6 + 1.002 =

3
IB
Chemistry

A8 Propagating Uncertainties in Calculations - Perform the mathematical


operations and report the answer using the correct number of significant
figures. Include in your answer the uncertainties.

(a) What is the total mass of two pieces of zinc of mass 1.21 g and 0.56 g?
(The masses were determined by using a digital balance with 2 decimal
places.)

……………………………………………………………………………………………..

……………………………………………………………………………………………..

(b) What is the total mass of a solution prepared by adding 51.00 g of


water to 1.00 g of sugar? (The masses were determined by using a
digital balance with 2 decimal places.)

……………………………………………………………………………………………..

……………………………………………………………………………………………..

(c) Consider two burette readings:

Initial reading / 24.05 ± 0.05


cm3
Final reading / cm3 48.20 ± 0.05

What value should be reported for the volume delivered?

……………………………………………………………………………………………..

……………………………………………………………………………………………..

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IB
Chemistry

A9 Propanone reacts with bromine in acidic solution according to the following


equation.
H+(aq)
CH3COCH3(aq) + Br2(aq) BrCH2COCH3(aq) + HBr(aq)

A student investigated the kinetics of this reaction, and the data are shown below .

Initial concentration / mol dm−3


Experimen [CH3COCH3] [Br2] ± [H+] ± Time for colour Rate of
t ± 0.001 0.0001 0.0001 to fade / s ± 1 reaction / mol
dm−3 s−1
1 0.200 0.0100 0.0500 250 4.00 × 10−5
2 0.400 0.0100 0.0500 125 8.00 × 10−5
3 0.200 0.0200 0.0500 500 4.00 × 10−5
4 0.200 0.0100 0.1000 125 8.00 × 10−5
5 0.400 0.0050 0.0500 63 X

a. Initial [Br 2]
Given that the average rate of reaction = fade¿ ,
time for colour ¿
Calculate the rate of reaction for Experiment 5 and explain the precision of your
result.

………………………………………………………………………………………………………………..

………………………………………………………………………………………………………………..

b. Determine the percentage uncertainty in the calculated rate for Experiment 4.

………………………………………………………………………………………………………………..

………………………………………………………………………………………………………………..

………………………………………………………………………………………………………………..

A10. A certain mass of water was weighed out in a polystyrene cup and a certain mass of
potassium bromide was weighed out using a weighing bottle. The initial temperature
of the water was measured accurately. Potassium bromide was then added to the
water, until it has all dissolved and the minimum temperature reached was recorded.
All raw data is tabulated below.

Mass of polystyrene cup /g 5.00 ± 0.01


Mass of polystyrene cup + water /g 105.23 ± 0.01
Initial temperature of water /oC 21.1 ± 0.1
Minimum temperature of water /oC 19.0 ± 0.1
Mass of weighing bottle /g 0.50 ± 0.01
Mass of weighing bottle + potassium 6.61 ± 0.01
bromide /g

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Chemistry

a Determine the mass of water,m ,weighed out and calculate the percentage uncertainty.
.
………………………………………………………………………………………………………………..

………………………………………………………………………………………………………………..

b Determine the amount (number of moles),n , of potassium bromide used and calculate
. the percentage uncertainty.

………………………………………………………………………………………………………………..

………………………………………………………………………………………………………………..

………………………………………………………………………………………………………………..

c Determine the change in temperature, ∆ T , of the solution and calculate the


. percentage uncertainty.

………………………………………………………………………………………………………………..

………………………………………………………………………………………………………………..

………………………………………………………………………………………………………………..

d Hence, calculate the enthalpy change of solution, ΔHsoln..


. Leave your answers to the appropriate number of significant figures and calculate the
absolute uncertainty.

m× c × ∆ T
Given that the specific heat capacity of water, c = 4.18 J g-1 oC-1 and ΔHsoln =
n
………………………………………………………………………………………………………………..

………………………………………………………………………………………………………………..

………………………………………………………………………………………………………………..

………………………………………………………………………………………………………………..

- end of worksheet -

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