0ionic Equilibria Class 12th Practice Paper

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PAWAN WAGH ACADEMY

Practice paper 1
Topic – Ionic Equilibria
Marks- 50

Section A (1 Mark Each)

Q.1 A) Choose the correct option (9m)


1. Solubility of AgCl is least in
a) Pure water b) 0.1M AlCl3
c) 0.1M NaCl d) 0.1M BaCl2

2. The PH of 10-8 M of HCl is


a) Greater than 7 b) less than 7
c) 7 d) 8

3. Which of the following is a buffer solution


a) CH3COOH + CH3COONa in water
b) HCl + NH4Cl in water
c) CH3COOH + HCl in water
d) CH3COONa + NaCl in water

4. Aqueous solution of which of the following will be


basic
a) CuSO4 b) CH3COONa
c) FeCl3 d) NH4Cl

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5. For PH>7, the Hydronium ion concentration would
be
a) <10-7m b) 10-7m
c) >10-7 d) ≥10-7m

Q.1 B) Answer the following


6. Define Acidic Buffer solution?
7. Define Ionic product of water?
8. AlCl3 is a Lewis acid explain?
9. Define molar solubility?

Section B (2 Marks Each)

Q.1 A) Answer the following (14m)


1. Define degree of dissociation and give its
expression?
2. Give a brief account of Bronsted-lowery theory of
acids and bases?
3. Explain the Amphoteric nature of water?
4. Explain the hydrolysis of salt of strong acid and
weak base?
5. Give the relation between Ksp and S in (as eq
Al(OH)3? (where Ksp=solubility product, S=molar
Solubility)
6. Explain common ion effect with suitable
example?
7. Given the relation between pH and pka?

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8. The PH of a solution is 5.85 Calculate its H3O+ ion
concentration?
9. Acetic acid is 2% ionized in decimolar solution,
calculate the dissociation constant of acid?

Section C (3 Marks Each)

Q.1 A) Answer the following (15m)


1. Calculate (H3O+) in 0.3 mol/dm3 solution of acetic
acid?
2. Calculate the PH of buffer solution containing 0.09
mol NaF per litre and 0.02 mol HF per lire where
Ka=7.2x10-10 for HF
3. Explain the statement ‘salt of strong acid and
strong base does not undergo hydrolysis’.
4. The solubility product of AgBr is 8.9x10-13 calculate
its solubility in mol/dm3 and in g/dm3(molar mass
of AgBr= 187.8g/mol)
5. Explain Ostwald’s dilution law weak acid with
expression for dissociation constant?
6. Explain buffer action with the help of Sodium
acetate-acetic acid buffer?
7. Explain the relation between ionic product and
solubility product to predict, whether a precipitate
will form, when two solutions are mixed?

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Section D (4 Marks Each)

Q.1 A) Answer the following (12m)


1. Solubility of a sparingly soluble gets affected in
presence of a soluble salt having one common ion?
Explain.
2. If 40cm3 0.08m Ba(NO3)2 are mixed with 20cm3 of
0.04 M NaF, will BaF2 precipitate ? Ksp of BaF2 is
1.7x10-6 at 218K.
3. The PH of monoacidic weak Base is 9, Calculate its
percent dissociation in 0.06M solution.
4. a) Define Solubility equilibria?
b) Any two applications of buffer solution?
c) Give reason, the dissociation of H2S is
suppressed in the presence of HCl. Name the
phenomenon.

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