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Today
Monday, April 6, 2020 4:42 PM
Exam 2 - April 9th (Thursday)
• I will send out at midnight US Central Time • Have 24 hours to complete • It should take you less than 2 • Submit through Gradescope • Don't panic
Today • Basic semiconductor physics • Band gap energy • The PN Junction • Exam 2 Topics
Basic Semiconductor Physics
• PV devices use semiconductor materials to convert sunlight into electricity • Technology is similar to solid-state technologies used to make transistors, diodes, and all other devices that we use today. • Most PV generation devices are made out of pure crystalline silicon.
Fourth group of the periodic table
• Includes Germanium, which is also widely used in devices
Lecture 17 Completed Page 1
Band Gap Energy Monday, April 6, 2020 7:47 PM
Band Gap Energy
• At absolute zero temperature, silicon is a perfect electrical insulator. There are no electrons free to roam around as there are in metals • As temperature rises, some electrons are given enough energy to free themselves from their nuclei, making them available to flow as current. • The warmer they get, the more electrons are available to carry current, so conductivity increases. • Silicon's conductivity at normal temperature is very low => it is referred to as a semiconductor.
Fig 5.4
We can use an energy band diagram (Fig 5.4).
• Electrons have energies that must fit within certain allowable energy bands • At room temperature, only about 1 out of 1010 electrons in silicon exists in the conduction band • The gaps between the allowable energy bands are called forbidden bands. The most important one is the band between the last filled band and the conduction band. • The energy than an electron must acquire to jump across the forbidden band is called the band-gap energy. • The units for band-gap energy are usually eV (electron-volts), where one eV is the energy that an electron acquires when its voltage is increased by 1 V (1 eV = 1.6 x 10-19 J). • The band-gap energy for silicon is 1.12 eV ○ The energy required to free an electron from its own nucleus. ○ In the case of a PV, this energy comes from the sun: photons of electromagnetic energy
Lecture 17 Completed Page 2
Lecture 17 Completed Page 3 The P-N Junction Monday, April 6, 2020 5:54 PM