Battery Basics
Battery Basics
LEAD ACID BATTERY-The storage battery, or secondary cell, which can be recharged by reversing the
chemical reaction, was invented in 1859 by the French physicist Gaston Planté. Planté's cell was a lead-
acid battery
The type widely used today. The lead-acid battery, which consists of three or six cells connected in
series.
Its chief advantage is that it can deliver a strong current of electricity for starting an engine; however, it
runs down quickly. The electrolyte is a dilute solution of sulfuric acid, the negative electrode consists of
lead, and the positive electrode of lead dioxide.
In operation, the negative lead electrode dissociates into free electrons and positive lead ions. The
electrons travel through the external electric circuit, and the positive lead ions combine with the sulfate
ions in the electrolyte to form lead sulfate. When the electrons reenter the cell at the positive lead-
dioxide electrode, another chemical reaction occurs.
The lead dioxide combines with the hydrogen ions in the electrolyte and with the returning electrons to
form water, releasing lead ions in the electrolyte to form additional lead sulfate.
A lead-acid storage cell runs down as the sulfuric acid gradually is converted into water and the
electrodes are converted into lead sulfate. When the cell is being recharged, the chemical reactions
described above are reversed until the chemicals have been restored to their original condition. A
lead-acid battery has a useful life of about four years. It produces about 2 V per cell. Recently, lead
batteries with useful lives of 50 to 70 years have been developed for special applications
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Lead Acid batteries have changed little since the 1880's although improvements in materials and
manufacturing methods continue to bring improvements in energy density, life and reliability. All lead acid
batteries consist of flat lead plates immersed in a pool of electrolyte. Regular water addition is required for
most types of lead acid batteries although low-maintenance types come with excess electrolyte calculated to
compensate for water loss during a normal lifetime.
Battery Construction
Lead acid batteries used in the RV and Marine Industries usually consist of two 6-volt batteries in series, or a
single 12-volt battery. These batteries are constructed of several single cells connected in series each cell
produces approximately 2.1 volts. A six-volt battery has three single cells, which when fully charged produce
an output voltage of 6.3 volts. A twelve-volt battery has six single cells in series producing a fully charged
output voltage of 12.6 volts.
A battery cell consists of two lead plates a positive plate covered with a paste of lead dioxide and a negative
made of sponge lead, with an insulating material (separator) in between. The plates are enclosed in a plastic
battery case and then submersed in an electrolyte consisting of water and sulfuric acid (see figure # 1). Each
cell is capable of storing 2.1 volts.
Chemical Reaction for Discharging
When the battery is discharged, it acts as a galvanic cell and the following chemical
reaction occurs.
Negative:
Pb(s) + HSO4– + H2O(l) –> 2e– + PbSO4(s) + H3O+(aq) (oxidation )
Positive:
PbO2(s) + HSO4–(aq) + 3H3O+(aq) + 2e– –> PbSO4(s) + 5H2O(l) (reduction)
Lead Acid Battery Discharging
Lead sulfate is formed at both electrodes. Two electrons are also transferred in the
complete reaction. The lead-acid battery is packed in a thick rubber or plastic case to
prevent leakage of the corrosive sulphuric acid.
In order for lead acid cell to produce a voltage, it must first receive a (forming)
charge voltage of at least 2.1-volts/cell from a charger. Lead acid batteries do not
generate voltage on their own; they only store a charge from another source. This
is the reason lead acid batteries are called storage batteries, because they only
store a charge. The size of the battery plates and amount of electrolyte
determines the amount of charge lead acid batteries can store. The size of this
storage capacity is described as the amp hour (AH) rating of a battery. A typical
12-volt battery used in a RV or marine craft has a rating 125 AH, which means it
can supply 10 amps of current for 12.5 hours or 20-amps of current for a period of
6.25 hours. Lead acid batteries can be connected in parallel to increase the total
AH capacity.
In figure # 2 below, six single 2.1-volt cells have been connected in series to make
the typical 12-volt battery, which when fully charged will produce a total voltage
of 12.6-volts.
In figure # 3, above a fully charged battery is connected to a load (light bulb) and the chemical reaction
between sulfuric acid and the lead plates produces the electricity to light the bulb. This chemical reaction
also begins to coat both positive and negative plates with a substance called lead sulfate also known
as sulfation (shown as a yellow build-up on plates). This build-up of lead sulfate is normal during a
discharge cycle. As the battery continues to discharge, lead sulfate coats more and more of the plates and
battery voltage begins to decrease from fully charged state of 12.6-volts (figure # 4).
In figure # 5 the battery is now fully discharged, the plates are almost completely covered with lead sulfate
(sulfation) and voltage has dropped to 10.5-volts.
NOTE: Discharging a lead acid battery below 10.5 volts will severely damage it!
Lead sulfate (sulfation) now coats most of the battery plates. Lead sulfate is a soft material, which can
is reconverted back into lead and sulfuric acid, provided the discharged battery is immediately connected to
If a lead acid battery is not immediately recharged, the lead
a battery charger.
sulfate will begin to form hard crystals, which can not be reconverted by a
standard fixed voltage (13.6 volts) battery converter/charger.
NOTE: Always recharge your RV or Marine battery as soon as possible to prevent loss of
During the recharging process as electricity flows through the water portion of the electrolyte
and water, (H2O) is converted into its original elements, hydrogen and oxygen. These gasses are
very flammable and the reason your RV or Marine batteries must be vented outside. Gassing
causes water loss and therefore lead acid batteries need to have water added periodically.
Sealed lead acid batteries contain most of these gasses allowing them to recombine into the
electrolyte. If the battery is overcharged pressure from these gasses will cause relief caps to
open and vent, resulting in some water loss. Most sealed batteries have extra electrolyte added
during the manufacturing process to compensate for some water loss.
The battery shown in figure # 7 above has been fully recharged using a fixed charging voltage of
13.6-volts. Notice that some lead sulfate (sulfation) still remains on the plates. This build-up will
continue after each recharging cycle and gradually the battery will begin to loose capacity to store a full
charge and eventually must be replaced. Lead sulfate build up is reduced if battery is given an Equalizing
Charge once every 10 discharge cycles or at least once a month. An Equalizing Chargeincreases charging
voltage to 14.4 volts or higher for a short period. This higher voltage causes gassing that equalizes (re-
mixes) the electrolyte solution.
Since most RV and Marine craft owners seldom remember to perform this function, Progressive
Dynamics has developed the microprocessor controlled Charge Wizard. The Charge Wizard will
automatically provide an Equalizing Charge every 21 hours for a period of 15 minutes, when the
battery is fully charged and not in use. Our 2000 Series of Marine Battery Chargers have
the Charge Wizard feature built-in.
One disadvantage of recharging a lead acid battery at a fixed voltage of 13.6-volts is the
recharge time is very long. A typical 125-AH RV or Marine battery will take approximately 80
hours to recharge at 13.6 volts. Increasing the charge voltage to 14.4-volts will reduce battery
recharge time for a 125-AH battery to 3-4 hours. Once a battery reaches 90% of full charge,
thevoltage must be reduced from 14.4-volts to 13.6-volts to reduce gassing and water loss. The
optional Charge Wizardautomatically senses when a battery has a very low state of charge and
automatically selects its BOOST MODE of operation.BOOST MODE increases the voltage of a PD9100
Series converter/charger to 14.4 volts. When the battery reaches the 90% charge level, the Charge
Wizard automatically reduces the charge voltage down to 13.6 volts to complete the charge. Again, this is a
standard feature on our Marine Chargers.
Another disadvantage of recharging a lead acid battery at a fixed voltage of 13.6-volts is that
once it is fully charged, 13.6 volts will cause considerable gassing and water loss. To prevent
this from occurring the charging voltage must be reduced to 13.2-volts. The Charge Wizard will
automatically select its STORAGE MODE of operation (13.2-volts) once the battery reaches full
charge and remains unused for a period of 30 hours. This feature is standard on all of
Progressive Dynamics Marine Battery Chargers.
At a charging voltage of 13.2 volts, the converter/charger will maintain a full charge, reduce gassing and
water loss. However, this lower voltage does not provide enough gassing to prevent a battery condition
called Battery Stratification. Battery Stratification is caused by the fact that the electrolyte in the
battery is a mixture of water and acid and, like all mixtures, one component, the acid, is heavier than water.
Therefore, acid will begin to settle and concentrate at the bottom of the battery (see figure #8).
This higher concentration of acid at the bottom of the battery causes additional build-up of lead sulfate
(sulfation), which reduces battery storage capacity and battery life. In order to prevent Battery
Stratification, an Equalization Charge(increasing charging voltage to 14.4-volts) must be applied
periodically. The Charge Wizard automatically selects itsEQUALIZATION MODE (14.4 volts) every 21
hours for a period of 15 minutes. This Equalizing Charge feature is standard on our Marine chargers.
As you have learned, in order to properly charge and maintain a lead acid battery you must use an
intelligent charging system. Progressive Dynamics, Inteli-Power 9100 Series RV converters with a Charge
Wizard installed, or one of our Inteli-Power Marine Battery Chargers will provide the intelligent charging
system your battery needs for a long life, with low maintenance.
Warning - A brand new battery may have a low electrolyte level. Charge the battery first and
then add water if needed. Adding water to a battery before charging may result in overflow
of the electrolyte.
Undercharging - Generally caused by not allowing the charger to restore the battery to full charge
after use. Continuously operating a battery in a partial state of charge, or storing the battery in the
discharged state results in the formation of lead sulfate (sulfation) on the plates. Sulfation reduces
the performance of the battery and may cause premature battery failure.
Overcharging - Continuous-charging causes accelerated corrosion of the positive plates, excessive
water consumption and in some cases, damaging temperatures within the battery. Lead acid
batteries should be charged after each discharge of more the 50% of its rated capacity and during or
after prolonged storage of 30 days or more.
Under-watering - In lead acid batteries water is lost during the charging process. If the electrolyte
level drops below the tops of the plates, irreparable damage may occur. Check your battery water
level frequently.
Over-watering - Excessive watering of a battery results in additional dilution of the electrolyte,
resulting in reduced battery performance. Add water to your battery after it has been fully charged,
never when the battery is partially discharged.
Can I reduce the need to add water to my battery by lowering the charging voltage to 13 volts or
less?
Lowering the charging voltage will reduce the need to add water, but this will cause a condition known as
battery stratification. Battery stratification is caused when the sulfuric acid in the electrolyte mixture
separates from the water and begins to concentrate at the bottom of the battery.
This increased concentration of acid increases the formation of lead sulfate (sulfation). To prevent
stratification, your battery should receive a periodic equalizing charge (increasing the charging voltage to
14.4 volts or above).
Lead-acid batteries are physically large batteries that contain lead plates in a solution of acid to create
electricity. They are a common power source for many applications; mostly cars, boats, standby power
generators. Each year a state employee is injured during the operation and maintenance of these
batteries. Nationally, 2300 people are injured each year using lead acid batteries. Acid burns to the face
and eyes comprise about 50% of these injuries as these batteries can easily explode. The remaining
injuries were mostly due to lifting or dropping batteries as they are quite heavy.
Standard Precautions:
Always store or recharge batteries in a well ventilated area
away from sparks or open flames
Damaged lead acid batteries shall be kept in properly
labeled acid-resistant secondary containment structures.
Use only chargers that are designed for the battery being
charged.
Always keep lead acid battery vent caps securely in place.
Do not store acid in hot locations or in direct sunlight.
Pour concentrated acid SLOWLY into water; do not add
water into acid.
Use nonmetallic containers and funnels.
If acid gets into your eyes, flush immediately with water for
15 minutes, and then promptly seek medical attention.
If acid gets on your skin, rinse the affected area immediately
with large amounts of water. Seek medical attention if the
chemical burns appears to be a second degree or greater.
Never over charge a lead acid battery and only replenish
fluid with distilled water.
Emergency wash stations should be located near lead-acid
battery storage and charging areas.
Prevent open flames, sparks or electric arcs in charging
areas.
Lead-acid storage and charging areas should be posted with
"Flammable - No Smoking" signs.
Neutralize spilled or splashed sulfuric acid solution with a
baking soda solution, and rinse the spill area with clean
water.
Safety Precautions
When maintaining a lead-acid battery, it is important to take safety
precautions to avoid accidents and injuries. Here are some safety tips
to keep in mind:
Regular Inspection
As a responsible owner of a lead-acid battery, I make sure to inspect it
regularly to ensure that it is functioning optimally. Here are the three
sub-sections of my regular inspection routine:
Cleaning Procedures
Cleaning Battery Surface
Maintaining a clean battery surface is crucial for the longevity of your
lead-acid battery. Dirt and grime can cause the battery to discharge
across the grime on top of the battery casing. To clean the surface of
the battery, follow these steps:
Charging Methods
When it comes to charging a lead-acid battery, there are two main
methods: trickle charging and float charging. Each method has its own
benefits and drawbacks, so it’s important to understand which one is
best for your battery.
Trickle Charging
Trickle charging is a slow and steady charging method that is best for
batteries that are used infrequently or are in storage. This method
involves charging the battery at a low rate, typically around 1-2 amps,
until it reaches full capacity.
Float Charging
Float charging is a method that is best for batteries that are used
regularly and need to be charged quickly. This method involves
charging the battery at a higher rate, typically around 10-20 amps,
until it reaches full capacity.
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