Air Pollution
Air Pollution
Air Pollution
Air Pollution is the release of pollutants such as gases, particles, biological molecules, etc. into the air
that is harmful to human health and the environment.
Air pollution refers to any physical, chemical or biological change in the air. It is the contamination of
air by harmful gases, dust and smoke which affects plants, animals and humans drastically.
There is a certain percentage of gases present in the atmosphere. An increase or decrease in the
composition of these gases is harmful to survival. This imbalance in the gaseous composition has
resulted in an increase in earth’s temperature, which is known as global warming.
Air pollutant
Air pollutant is any harmful substance present in the air that can have negative effects on human
health, animals, plants, and the environment. These substances can be in the form of gases,
particles, or biological molecules. They can come from various sources, including industrial
emissions, vehicle exhaust, agricultural practices, and natural processes.
Nitrogen oxides (NOx): Gases formed from the burning of fossil fuels.
Sulfur oxides (SOx): Gases emitted from the burning of coal and oil.
Carbon monoxide (CO): A colorless, odorless gas produced from incomplete combustion.
Volatile organic compounds (VOCs): Organic chemicals that evaporate into the air.
Primary Pollutants
The pollutants that directly cause air pollution are known as primary pollutants. Sulphur-dioxide
emitted from factories is a primary pollutant.
Secondary Pollutants
The pollutants formed by the intermingling and reaction of primary pollutants are known as
secondary pollutants. Smog, formed by the intermingling of smoke and fog, is a secondary pollutant.
Causes of Air Pollution
The combustion of fossil fuels emits a large amount of sulphur dioxide. Carbon monoxide released by
incomplete combustion of fossil fuels also results in air pollution.
Automobiles
The gases emitted from vehicles such as jeeps, trucks, cars, buses, etc. pollute the environment.
These are the major sources of greenhouse gases and also result in diseases among individuals.
Agricultural Activities
Ammonia is one of the most hazardous gases emitted during agricultural activities. The insecticides,
pesticides and fertilisers emit harmful chemicals in the atmosphere and contaminate it.
Factories and industries are the main source of carbon monoxide, organic compounds, hydrocarbons
and chemicals. These are released into the air, degrading its quality.
Mining Activities
In the mining process, the minerals below the earth are extracted using large pieces of equipment.
The dust and chemicals released during the process not only pollute the air, but also deteriorate the
health of the workers and people living in the nearby areas.
Domestic Sources
The household cleaning products and paints contain toxic chemicals that are released in the air. The
smell from the newly painted walls is the smell of the chemicals present in the paints. It not only
pollutes the air but also affects breathing.
Diseases
Air pollution has resulted in several respiratory disorders and heart diseases among humans. The
cases of lung cancer have increased in the last few decades. Children living near polluted areas are
more prone to pneumonia and asthma. Many people die every year due to the direct or indirect
effects of air pollution.
Global Warming
Due to the emission of greenhouse gases, there is an imbalance in the gaseous composition of the
air. This has led to an increase in the temperature of the earth. This increase in earth’s temperature is
known as global warming. This has resulted in the melting of glaciers and an increase in sea levels.
Many areas are submerged underwater.
Acid Rain
The burning of fossil fuels releases harmful gases such as nitrogen oxides and sulphur oxides in the
air. The water droplets combine with these pollutants, become acidic and fall as acid rain which
damages human, animal and plant life.
Effect on Animals
The air pollutants suspend in the water bodies and affect aquatic life. Pollution also compels the
animals to leave their habitat and shift to a new place. This renders them stray and has also led to
the extinction of a large number of animal species.
1. Health Effects
Respiratory Issues: Air pollution can cause asthma, bronchitis, and other respiratory
problems due to inhaling fine particulate matter (PM2.5), nitrogen dioxide (NO₂), and sulfur
dioxide (SO₂).
Cancer: Prolonged exposure to air pollution, especially toxic compounds like benzene, can
increase the risk of lung and other cancers.
Impaired Immune System: Pollutants may weaken the immune system, making people more
susceptible to infections.
Impact on Vegetarians: As air pollution can contaminate soil and water, it may also affect the
quality of plant-based foods, potentially leading to the consumption of toxic substances (e.g.,
heavy metals, pesticides).
2. Effect on Vegetarians
Food Contamination: Polluted air can deposit harmful particles on crops, leading to the
presence of heavy metals, toxins, and other pollutants in vegetables, fruits, and grains.
Decreased Nutritional Value: Studies suggest that elevated levels of CO₂ can reduce the
nutrient content of crops, affecting the quality of plant-based diets.
Water Pollution: Airborne pollutants can deposit into water bodies, affecting water quality
and contaminating the irrigation systems used in agriculture.
3. Effect on Materials
Corrosion of Buildings: Air pollutants like sulfur dioxide (SO₂) and nitrogen oxides (NOₓ) can
cause acid rain, leading to the corrosion of buildings, metals, and monuments, especially
those made of limestone, marble, and concrete.
Degradation of Fabrics: Airborne chemicals can damage textiles, rubber, and plastics,
weakening them over time.
Discoloration: Particulate matter, including soot, can discolor buildings, vehicles, and other
outdoor surfaces, leading to a need for frequent cleaning and maintenance.
Climate Change: Greenhouse gases (CO₂, methane, etc.) contribute to global warming,
leading to extreme weather events, sea-level rise, and ecosystem changes.
Ozone Layer Depletion: Air pollutants like chlorofluorocarbons (CFCs) deplete the ozone
layer, increasing exposure to harmful ultraviolet (UV) radiation.
Smog Formation: Air pollution leads to the formation of ground-level ozone and smog, which
affects visibility and human health.
Air pollution's impacts are interconnected, with health, the environment, and materials all being
affected by atmospheric contaminants.
People should avoid using vehicles for shorter distances. Rather, they should prefer public modes of
transport to travel from one place to another. This not only prevents pollution, but also conserves
energy.
Energy Conservation
A large number of fossil fuels are burnt to generate electricity. Therefore, do not forget to switch off
the electrical appliances when not in use. Thus, you can save the environment at the individual level.
Use of energy-efficient devices such as CFLs also controls pollution to a greater level.
The use of solar, wind and geothermal energies reduce air pollution at a larger level. Various
countries, including India, have implemented the use of these resources as a step towards a cleaner
environment.
2. Since industrial emissions are one of the major causes of air pollution, the pollutants can be
controlled or treated at the source itself to reduce its effects. For example, if the reactions of
a certain raw material yield a pollutant, then the raw materials can be substituted with other
less polluting materials.
3. Fuel substitution is another way of controlling air pollution. In many parts of India, petrol and
diesel are being replaced by CNG – Compressed Natural Gas fueled vehicles. These are
mostly adopted by vehicles that aren’t fully operating with ideal emission engines.
4. Although there are many practices in India, which focus on repairing the quality of air, most
of them are either forgotten or not being enforced properly. There are still a lot of vehicles
on roads which haven’t been tested for vehicle emissions.
5. Another way of controlling air pollution caused by industries is to modify and maintain
existing pieces of equipment so that the emission of pollutants is minimised.
6. Sometimes controlling pollutants at the source is not possible. In that case, we can have
process control equipment to control the pollution.
7. A very effective way of controlling air pollution is by diluting the air pollutants.
8. The last and the best way of reducing the ill effects of air pollution is tree plantation. Plants
and trees reduce a large number of pollutants in the air. Ideally, planting trees in areas of
high pollution levels will be extremely effective.
o Chemical Reactions:
SO2+H2O→H2SO3SO_2 + H_2O \rightarrow H_2SO_3SO2+H2O→H2SO3
2H2SO3+O2→2H2SO42H_2SO_3 + O_2 \rightarrow 2H_2SO_42H2SO3+O2→2H2SO4
Effect:
o Acid Rain: Sulfuric acid contributes to acid rain, which damages forests, lakes, and
aquatic life. It also accelerates the corrosion of buildings and structures.
o Nitrogen oxides (NO and NO₂) are released from vehicle exhaust, power plants, and
industrial emissions. NO₂ can react with oxygen and water vapor to form nitric acid
(HNO₃).
o Chemical Reactions:
NO2+H2O→HNO3NO_2 + H_2O \rightarrow HNO_3NO2+H2O→HNO3
NO+O2→NO2NO + O_2 \rightarrow NO_2NO+O2→NO2
Effect:
o Acid Rain: Nitric acid contributes to acid rain, affecting soil quality and water bodies,
causing long-term harm to ecosystems.
o Ground-Level Ozone (O₃): Nitrogen oxides react with volatile organic compounds
(VOCs) in the presence of sunlight to form ground-level ozone, a major component
of smog. NO2+VOCs+sunlight→O3NO_2 + VOCs + sunlight \rightarrow O_3NO2
+VOCs+sunlight→O3
o Health Problems: Exposure to nitrogen oxides can lead to respiratory diseases, lung
infections, and reduced lung function.
o VOCs, emitted from vehicle exhaust, industrial processes, and household products,
react with nitrogen oxides in sunlight to form ozone (O₃) and photochemical smog.
o Chemical Reaction:
VOCs+NOx+sunlight→O3VOCs + NO_x + sunlight \rightarrow O_3VOCs+NOx
+sunlight→O3
Effect:
o Smog Formation: Smog reduces visibility, harms plant life, and causes respiratory
issues.
o Ozone (O₃) Formation: Ground-level ozone irritates the respiratory system and
exacerbates conditions like asthma.
o Particulate matter (PM2.5 and PM10) consists of solid particles or liquid droplets
suspended in the air. They can arise from vehicle emissions, industrial processes,
construction, and natural sources like wildfires. While not chemical reactions, these
particles can carry heavy metals and toxins and react with other pollutants in the
atmosphere.
Effect:
o Health Impact: Fine particulate matter (PM2.5) penetrates deep into the lungs,
causing heart disease, respiratory problems, and even premature death.
o Chemical Reaction:
CO+OH→CO2+HCO + OH \rightarrow CO_2 + HCO+OH→CO2+H
Effect:
6. Chlorofluorocarbons (CFCs)
o CFCs, once used in refrigeration and aerosol sprays, are highly stable in the lower
atmosphere. When they reach the stratosphere, ultraviolet (UV) light breaks them
down, releasing chlorine atoms, which then destroy ozone molecules (O₃).
o Chemical Reaction:
CCl2F2+UV→CClF2+ClCCl_2F_2 + UV \rightarrow CClF_2 + ClCCl2F2+UV→CClF2+Cl
Cl+O3→ClO+O2Cl + O_3 \rightarrow ClO + O_2Cl+O3→ClO+O2
Effect:
o Methane is a potent greenhouse gas released from livestock, landfills, and fossil fuel
production. It reacts with hydroxyl radicals (OH) to form water vapor and carbon
dioxide.
o Chemical Reaction:
CH4+OH→CH3+H2OCH_4 + OH \rightarrow CH_3 + H_2OCH4+OH→CH3+H2O
Effect:
Summary of Effects:
Environment: Acid rain harms forests, lakes, and soil. Smog reduces visibility and damages
crops.
Pollutants in the atmosphere trigger a range of harmful chemical reactions, leading to significant
environmental, health, and structural impacts.
Smoke
Definition: Smoke consists of visible airborne particulates and gases released during the
combustion of materials. It is produced when organic substances, like wood, coal, or oil, burn
incompletely.
o Gases: Carbon dioxide (CO₂), carbon monoxide (CO), volatile organic compounds
(VOCs), and nitrogen oxides (NOₓ).
o Toxins: Can include chemicals like benzene, formaldehyde, and heavy metals
depending on the source of combustion.
Sources:
o Human-made: Burning fossil fuels (in vehicles, factories), wildfires, cooking, tobacco,
and industrial processes.
Effects:
o Health: Smoke can irritate the eyes, nose, and throat, and cause respiratory
problems. Long-term exposure increases the risk of heart and lung diseases.
o Indoor Air Pollution: Smoke from cooking, heating, and tobacco can significantly
degrade indoor air quality.
Smog
Definition: Smog is a type of severe air pollution that results from the interaction of
pollutants (especially nitrogen oxides and VOCs) with sunlight, forming ground-level ozone.
The word "smog" is derived from "smoke" and "fog."
Types of Smog:
Forms when nitrogen oxides (NOₓ) and volatile organic compounds (VOCs)
from vehicle exhaust and industrial emissions react with sunlight.
Common in sunny, warm cities like Los Angeles, Mexico City, and New Delhi.
Consists of sulfur dioxide (SO₂) and particulate matter, often combined with
fog.
Composition:
Sources:
Effects:
o Health: Smog irritates the respiratory system, exacerbates asthma, bronchitis, and
other lung diseases, and can cause eye irritation. Long-term exposure increases the
risk of cardiovascular diseases and premature death.
Key Differences:
Effects on Respiratory issues, eye and throat Exacerbates lung diseases, cardiovascular
Health irritation issues
The depletion of the ozone layer is primarily caused by human-made chemicals, particularly
chlorofluorocarbons (CFCs), and other related substances, such as:
1. Chlorofluorocarbons (CFCs):
o CFC molecules, once released into the atmosphere, are stable and can rise into the
stratosphere, where they are broken down by UV light, releasing chlorine atoms.
2. Halons:
o Used in fire extinguishers, halons release bromine atoms, which are even more
destructive to ozone than chlorine.
3. Hydrochlorofluorocarbons (HCFCs):
o Less harmful than CFCs but still contribute to ozone depletion and are being phased
out under international agreements.
4. Methyl Bromide:
o Used as a pesticide, methyl bromide releases bromine, which also destroys ozone.
o Released from fertilizers and burning of fossil fuels, NOₓ can also contribute to ozone
depletion.
When CFCs and other ozone-depleting substances reach the stratosphere, they undergo
photodissociation, releasing chlorine (Cl) and bromine (Br) atoms. These atoms then participate in
catalytic reactions that break down ozone (O₃) into oxygen (O₂), as shown in the following simplified
reactions:
In these reactions, a single chlorine atom can destroy thousands of ozone molecules because it acts
as a catalyst and is not consumed in the reaction. Bromine, though less abundant, is even more
efficient than chlorine in breaking down ozone.
Effects of Ozone Layer Disturbance:
1. Increased UV Radiation:
o The thinning of the ozone layer allows more UV-B radiation to reach the Earth's
surface, leading to:
Eye Damage: UV radiation can cause cataracts and other eye disorders.
2. Impact on Ecosystems:
o Marine Life: Phytoplankton, the base of the marine food chain, is sensitive to UV-B
radiation. Disruption in phytoplankton populations affects marine ecosystems and
fisheries.
o Terrestrial Plants: UV radiation can damage the DNA of plants, affecting growth and
reducing agricultural productivity.
o Although ozone depletion itself doesn't directly cause global warming, the chemicals
responsible for ozone depletion (such as CFCs) are also potent greenhouse gases,
contributing to climate change.
4. Damage to Materials:
o This international treaty aimed to phase out the production and consumption of
CFCs, halons, and other ozone-depleting substances. It has been highly successful,
with CFC production dramatically reduced, and the ozone layer showing signs of slow
recovery.
2. Hydrofluorocarbons (HFCs):
o HFCs were introduced as replacements for CFCs and HCFCs because they do not
deplete the ozone layer. However, HFCs are potent greenhouse gases, leading to
efforts to phase them out under the Kigali Amendment (2016) to the Montreal
Protocol.
3. Ozone Hole:
o The most significant ozone depletion occurs over Antarctica, where the cold
stratospheric temperatures create conditions conducive to rapid ozone destruction,
forming the so-called ozone hole. The hole typically forms during the Southern
Hemisphere's spring (September to November).
o Recent studies suggest that the ozone hole is beginning to shrink due to global
efforts to reduce CFCs, though full recovery is expected to take until the middle of
the 21st century.
Conclusion:
Ozone layer disturbance primarily results from human activities that release ozone-depleting
substances like CFCs and halons. This thinning leads to increased UV radiation exposure, which has
severe consequences for human health, ecosystems, and materials. Thanks to international efforts
like the Montreal Protocol, the ozone layer is on a path to recovery, but vigilance is needed to ensure
long-term success.
Greenhouse effect
The greenhouse effect is the process by which certain gases in the Earth’s atmosphere trap heat
from the sun, keeping the planet warm enough to support life. It is a natural phenomenon essential
for maintaining the Earth's temperature but has been exacerbated by human activities, leading to
global warming and climate change.
o The sun emits shortwave radiation (visible light and ultraviolet radiation) that passes
through the Earth’s atmosphere and reaches the surface.
o The Earth’s surface absorbs this solar energy and warms up. In turn, it emits
longwave infrared radiation (heat) back toward the atmosphere.
o Certain gases in the atmosphere, called greenhouse gases (GHGs), absorb some of
this outgoing infrared radiation and re-emit it in all directions, including back toward
the Earth’s surface. This process traps heat and keeps the planet warm.
o The re-radiated heat causes the Earth's surface and lower atmosphere to warm,
maintaining a global average temperature of about 15°C (59°F), which is suitable for
life.
o Released through burning fossil fuels (coal, oil, natural gas), deforestation, and
certain industrial processes. CO₂ is the most significant GHG due to its large quantity.
2. Methane (CH₄):
o Emitted during the production and transport of coal, oil, and natural gas. It also
comes from livestock (cow digestion), rice paddies, and organic waste decomposition
in landfills. Methane is over 25 times more effective at trapping heat than CO₂ over a
100-year period.
o Emitted from agricultural and industrial activities, as well as burning fossil fuels and
biomass. Nitrous oxide is around 298 times more potent than CO₂.
o The most abundant greenhouse gas. Water vapor increases as the Earth's
atmosphere warms but doesn’t directly cause warming. Instead, it acts as a feedback
mechanism because warmer air holds more moisture, which further amplifies the
greenhouse effect.
The natural greenhouse effect is vital for life on Earth, but human activities have increased the
concentration of greenhouse gases, leading to the enhanced greenhouse effect, which is driving
global warming. Key contributing factors include:
Burning Fossil Fuels: Energy production, transportation, and industry emit large amounts of
CO₂ and other gases.
Deforestation: Cutting down forests reduces the number of trees that absorb CO₂ for
photosynthesis, leading to higher concentrations of CO₂ in the atmosphere.
Industrial Agriculture: Livestock, rice farming, and fertilizer use increase methane and
nitrous oxide emissions.
1. Global Warming:
o The Earth's average temperature is rising due to the increased trapping of heat by
greenhouse gases. This has led to a 1.2°C (2.2°F) rise in global temperatures since the
late 19th century.
2. Melting Ice Caps and Rising Sea Levels:
o Polar ice caps and glaciers are melting, contributing to sea-level rise, which
threatens low-lying areas and coastal cities. The rise in sea levels can lead to flooding
and loss of land.
4. Ocean Acidification:
o As CO₂ levels rise, the oceans absorb more CO₂, which dissolves in seawater and
forms carbonic acid, reducing the pH of the ocean. This negatively impacts marine
life, especially coral reefs and shellfish.
o Climate change alters habitats and can lead to the extinction of species that cannot
adapt to changing temperatures or migrate to cooler regions.
6. Agricultural Disruptions:
o Transition to Renewable Energy: Shifting from fossil fuels to solar, wind, and
hydropower reduces CO₂ emissions.
2. Carbon Sequestration:
o Techniques such as reforestation and carbon capture and storage (CCS) can help
absorb excess CO₂ from the atmosphere.
3. International Agreements:
o The Paris Agreement (2015) aims to limit global temperature rise to below 2°C, with
efforts to restrict it to 1.5°C, by reducing emissions and enhancing global cooperation
on climate change action.
4. Sustainable Agriculture:
The greenhouse effect is crucial for life, but the enhanced greenhouse effect caused by human
activity is leading to climate change and global warming. Addressing these challenges requires global
cooperation, technological advancements, and lifestyle changes to reduce greenhouse gas emissions
and protect the Earth’s future.