Chemical Bonding

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Chapter 3

Chemical Bonding
3.2 Ions & ionic
bonding
Ion

An ion is an atom or molecule with an electrical charge, due to the loss or gain of an
electron.
The overall charge of an atom is zero( neutral)& the charge of an electron is negative so:
The gain of an electron to a non-metal results in a negative-charged ion , known as
anion.
E.g. If chlorine atom gains 1 electron , a chloride ion with a -1 charge is produced.
Ion

The loss of an electron from a metal results in a positive-


charged ion , known as cation.
E.g. If a sodium atom loses 1 electron , a sodium ion with a
+1 charge is produced.
Ionic bond

Ionic bond forms between a


cation and an anion , this bond An electron is transferred ( lost)
is electrostatic attraction from the cation to the anion,
between oppositely charged which gains the electron.
ions.
Formation of ionic bonds
between group Ι & group Ⅶ

Group 1 elements(metals) have 1 outer shell electron.


Group 7 elements (non-metals)have 7 outer shell electrons.
So if group 1 atom loses one electron & the group 7 atom gains the
electron, the resulting ions will have full outer shell of electrons.
An ionic bond is formed between the oppositely charged ions.
A dot & cross diagram can be
used to show this/
A dot & cross diagram can
be used to show this/
 The 1 outer shell electron of sodium is transferred to the outer shell in chlorine.
• Since sodium lost 1 electron, a sodium ion with +1 charge is formed.
• Since chlorine gained 1 electron, a chloride ion with -1 charge is formed.
 Square brackets with the associated charge is used to show that an ion has been
made.
A dot & cross diagram can be
used to show this/
 Use dots to represent the electrons from one element & crosses to represent the
electrons from the other element.
 The ions are drawn next to each other to indicate an ionic bond in the ionic
compound.
E.g. Sodium chloride (NaCl)
A dot & cross diagram can
be used to show this/
E.g./ Magnesium chloride (MgCl2)
 Magnesium must lose two electrons to gain the most stable arrangement of noble gas.
 Each chlorine atom will gain 1 electron to gain also the most stable arrangement of noble gas (full outer shell).
 So, two electrons from magnesium are transferred to each chlorine atom.
This forms two chloride ions with -1 charge & Magnesium ion with +2 charge, with ionic bonding between them.
Physical properties of ionic
compounds.
Physical properties of ionic
compounds.
 Ionic compounds have high melting & boiling points as they
have very strong electrostatic attraction forces so, they need
more energy to overcome them.
 Ionic compounds conduct electricity when molten or in an
aqueous solutions as the ions are free to move to carry
charge.
 They are poor conductors of electricity when solids, as the
ions are fixed in position & can’t move from one place to
another.
Physical properties of ionic
compounds.
 An ionic compound has a giant lattice structure which means the cations & anions are
arranged alternatively.
 E.g. Sodium chloride shown in the 3D model shown below.
 The ionic lattice is held by strong electrostatic attraction
forces between anions & cations.
 Ionic compounds are crystalline solids at room temperature
because of this giant lattice.
 They are often soluble in water(not usually soluble in
organic solvents like (ethanol& methyl benzene) as water is
attracted to charged ions& therefore many ionic compounds
Dissolve.
Any Questions?
Now let’s practice
what we’ve learned!
Summary questions

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Summary questions

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Summary questions
Summary questions

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Summary questions

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Presented by/

Dr.Eman Yousuf Mohammed

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