SAFETY DATA SHEET

1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE

COMPANY/UNDERTAKING

Product identifier

Product Name: Valve Regulated Lead-Acid Battery

Other means of identification

Synonyms: None

Recommended use of the chemical and restrictions on use

Recommended Use: Lead-Acid (Non-Spillable) Battery

Uses advised against: No information available

Details of the supplier of the safety data sheet

Supplier Name: DIEN CHUAN JOINT STOCK COMPANY.

Supplier Address: N.o 5 Lane 30/1, Phan Dinh Giot Street, Group 2, La Khe Ward, Ha Dong District, Hanoi

Supplier Phone Number: Phone:0988 265 325

Supplier Email: [email protected]
Website: https://dienchuan.vn/

2. HAZARDS IDENTIFICATION
Classification
This chemical is not considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) This
product is an article which is a sealed battery and as such does not require an MSDS per the OSHA hazard
communication
Acute standard unless ruptured. The hazards indicated are for a ruptured battery.
toxicity - Oral Category 4
Acute toxicity - Inhalation (Gases) Category 4
Acute toxicity - Inhalation (Vapors) Category 4
Acute toxicity - Inhalation (Dusts/Mists) Category 4
Skin corrosion/irritation Category 1 Sub-category A
Serious eye damage/eye irritation Category 2
Carcinogenicity Category 1A
Reproductive toxicity Category 1A
Specific target organ toxicity (repeated exposure) Category 2

GHS Label elements, including precautionary statements

Emergency Overview

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Signal word Danger

Hazard Statements
Harmful if swallowed
Harmful if inhaled
Causes severe skin burns and eye damage
Causes serious eye irritation
May cause cancer
May damage fertility or the unborn child
May cause damage to organs through prolonged or repeated exposure

This product is an article which contains a chemical substance. Safety information is given for exposure to the article as
sold. Intended use of the product should not result in exposure to the chemical substance. This is a battery. In case of
rupture: the above hazards exist.

Appearance: Gray black cuboid battery Physical State: Solid Odor: Odorless

Precautionary Statements - Prevention

Obtain special instructions before use
Do not handle until all safety precautions have been read and understood
Use personal protective equipment as required
Wash face, hands and any exposed skin thoroughly after handling
Do not eat, drink or smoke when using this product
Use only outdoors or in a well-ventilated area
Do not breathe dust/fume/gas/mist/vapors/spray

Precautionary Statements - Response

Immediately call a POISON CENTER or doctor/physician
Specific treatment (see supplemental first aid instructions on this label)

Eyes
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue
rinsing, Immediately call a POISON CENTER or doctor/physician

Skin
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.
Wash contaminated clothing before reuse

Inhalation
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
Call a POISON CENTER or doctor/physician if you feel unwell.
Immediately call a POISON CENTER or doctor/physician

Ingestion
IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell
Rinse mouth
Do NOT induce vomiting

Precautionary Statements - Storage

Store locked up

Precautionary Statements - Disposal

Dispose of contents/container to an approved waste disposal plant

Hazards not otherwise classified (HNOC)

Not applicable

Unknown Toxicity
0.6% of the mixture consists of ingredient(s) of unknown toxicity

Other information
Very toxic to aquatic life with long lasting effects

Interactions with Other Chemicals

Use of alcoholic beverages may enhance toxic effects.

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 3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical characterization: Mixtures

※PBB spices or PBDE spices is not involved

Chemical CAS No Weight-% Trade Secret
Lead 7439-92-1 45 ~ 60% *
Lead dioxide 1309-60-0 15 ~ 25% *
Sulfuric acid (Electrolyte) 7664-93-9 15 ~ 20% *
Calcium (Lead calcium alloy) 7440-70-2 <0.06% *
Tin 7440-31-5 <0.6% *
Arsenic (Inorganic) 7440-38-2 <0.0006% *
Non-Hazardous Materials N/A 5 ~ 10% *
(The non-hazardous materials include ABS plastic, glass fiber, rubber, copper, expoxide-resin glue)
*The exact percentage (concentration) of composition has been withheld as a trade secret

4. FIRST AID MEASURES

First aid measures
General Advice First aid is upon rupture of sealed battery.

Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15
minutes. Keep eye wide open while rinsing. Do not rub affected area. Seek
immediate medical attention/advice. Remove contact lenses, if present and
easy to do. Continue rinsing.

Skin Contact Immediate medical attention is required. Wash off immediately with soap and
plenty of water while removing all contaminated clothes and shoes.

Inhalation Remove to fresh air. If symptoms persist, call a physician. If breathing has
stopped, give artificial respiration. Get medical attention immediately. If not
breathing, give artificial respiration. Avoid direct contact with skin. Use barrier
to give mouth-to-mouth resuscitation. If breathing is difficult, (trained
personnel should) give oxygen. Seek immediate medical attention/advice.
Delayed pulmonary edema may occur.

Ingestion Do NOT induce vomiting. Rinse mouth. Rinse mouth immediately and drink
plenty of water. Never give anything by mouth to an unconscious person. Call
a physician or poison control center immediately.

Self-protection of the first aider Ensure that medical personnel are aware of the material(s) involved, take
precautions to protect themselves and prevent spread of contamination. Avoid
contact with skin, eyes or clothing. Avoid direct contact with skin. Use barrier
to give mouth-to-mouth resuscitation. Use personal protective equipment as
required. Wear personal protective clothing (see section 8).

Most important symptoms and effects, both acute and delayed

Most Important Symptoms and Burning sensation. Lead poisoning is characterized by a metallic taste in the
Effects mouth, loss of appetite, indigestion, nausea, vomiting, constipation, sleep
disturbances and overall weakness. Severe exposures can lead to shock,
circulatory collapse and death.

Indication of any immediate medical attention and special treatment needed

Notes to Physician Treat symptomatically. Product is a corrosive material. Use of gastric lavage
or emesis is contraindicated. Possible perforation of stomach or esophagus
should be investigated. Do not give chemical antidotes. Asphyxia from glottal
edema may occur. Marked decrease in blood pressure may occur with moist
rales, frothy sputum and high pulse pressure.

5. FIRE-FIGHTING MEASURES

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Suitable Extinguishing Media
Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.

Unsuitable extinguishing media

CAUTION: Use of water spray when fighting fire may be inefficient.

Specific Hazards Arising from the Chemical

The product causes burns of eyes, skin and mucous membranes. Thermal decomposition can lead to release of irritating
gases and vapors.
Uniform Fire Code Corrosive: Acid-Liquid
Toxic: Liquid
Hazardous Combustion Products
Carbon oxides

Explosion Data
Sensitivity to Mechanical Impact No

Sensitivity to Static Discharge No

Protective equipment and precautions for firefighters

As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and
full protective gear.

6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures
Personal Precautions Attention! Corrosive material. Avoid contact with skin, eyes or clothing.
Ensure adequate ventilation. Use personal protective equipment as required.
Evacuate personnel to safe areas. Keep people away from and upwind of
spill/leak. Avoid generation of dust.

Other Information Refer to protective measures listed in Sections 7 and 8.

Environmental Precautions

Environmental Precautions Refer to protective measures listed in Sections 7 and 8. Prevent further
leakage or spillage if safe to do so. Should not be released into the
environment. Do not allow to enter into soil/subsoil. Prevent product from
entering drains.

Methods and material for containment and cleaning up

Methods for Containment Prevent further leakage or spillage if safe to do so.

Methods for cleaning up Pick up and transfer to properly labeled containers.

7. HANDLING AND STORAGE

Precautions for safe handling

Handling In case of rupture: Handle in accordance with good industrial hygiene and
safety practice. Avoid contact with skin, eyes or clothing. In case of
insufficient ventilation, wear suitable respiratory equipment. Use only with
adequate ventilation and in closed systems. Do not eat, drink or smoke when
using this product. Take off contaminated clothing and wash before reuse.

Conditions for safe storage, including any incompatibilities

Storage Keep containers tightly closed in a dry, cool and well-ventilated place. Protect
from moisture. Store locked up. Keep out of the reach of children. Store away
from other materials.

Incompatible Products Acids. Bases. Oxidizing agent.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

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Control parameters

Exposure Guidelines

Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH

Lead TWA: 0.05 mg/m3 TWA: 50 μg/m3 TWA: 50 μg/m3 IDLH: 100 mg/m3
7439-92-1 Pb TWA: 0.050 mg/m3
Action Level: 30 μg/m 3 Poison,
See 29 CFR 1910.1025 Action
Level: 30 μg/m3 Pb Poison, See
29 CFR 1910.1025

Lead dioxide TWA: 0.05 mg/m3 Pb TWA: 50 μg/m3 Pb Action Level: IDLH: 100 mg/m3 Pb
1309-60-0 30 μg/m3 Pb Poison, See 29 CFR TWA: 0.050 mg/m3 Pb
1910.1025

Sulfuric acid TWA: 0.2 mg/m3 thoracic fraction TWA: 1 mg/m3 IDLH: 15 mg/m3
7664-93-9 (vacated) TWA: 1 mg/m3 TWA: 1 mg/m3

ACGIH TLV: American Conference of Governmental Industrial Hygienists - Threshold Limit Value OSHA PEL: Occupational Safety and
Health Administration - Permissible Exposure Limits NIOSH IDLH Immediately Dangerous to Life or Health
Other Exposure Guidelines Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA,
965 F.2d 962 (11th Cir., 1992) See section 15 for national exposure control
parameters

Appropriate engineering controls

Engineering Measures Showers Eyewash

stations Ventilation
systems

Individual protection measures, such as personal protective equipment

Eye/Face Protection None required for consumer use. If splashes are likely to occur: Face
protection shield.

Skin and Body Protection Wear protective gloves and protective clothing. Long sleeved clothing.
Chemical resistant apron. Impervious gloves.

Respiratory Protection No protective equipment is needed under normal use conditions. If exposure
limits are exceeded or irritation is experienced, ventilation and evacuation
may be required.

Hygiene Measures Handle in accordance with good industrial hygiene and safety practice. Do not
eat, drink or smoke when using this product. Take off contaminated clothing
and wash before reuse. Avoid contact with skin, eyes or clothing. Wear
suitable gloves and eye/face protection. Contaminated work clothing should
not be allowed out of the workplace. Regular cleaning of equipment, work
area and clothing is recommended. Wash hands before breaks and
immediately after handling the product. For environmental protection, remove
and wash all contaminated protective equipment before re-use.

9. PHYSICAL AND CHEMICAL PROPERTIES

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Physical and Chemical Properties
Physical State Solid
Appearance Cuboid battery Odor Odorless
Color Gray black Odor Threshold No information available

Property Values Remarks Method

pH No data available None known
Melting / freezing point Lead
Boiling point / boiling range 327.4℃ Lead
Flash Point 1740℃ None known
Evaporation Rate No data available None known
Flammability (solid, gas) No data available None known
Flammability Limit in Air No data available
Upper flammability limit
Lower flammability limit No data available
Vapor pressure No data available Electrolyte
Vapor density <0.3mmHg @25℃ Electrolyte
Specific Gravity 3.4 Electrolyte
Water Solubility 1.170-1.40 Electrolyte
Solubility in other solvents 100% None known
Partition coefficient: n-octanol/water No data available None known
Autoignition temperature No data available None known
Decomposition temperature No data available None known
Kinematic viscosity No data available None known
Dynamic viscosity No data available None known
Explosive properties No data available
Oxidizing Properties No data available
No data available
Other Information
Softening Point
VOC Content (%) No data available
Particle Size No data available
Particle Size Distribution No data available

10. STABILITY AND REACTIVITY

Reactivity
No data available.

Chemical Stability
Stable under recommended storage conditions.

Possibility of Hazardous Reactions

None under normal processing.

Hazardous Polymerization
Hazardous polymerization does not occur.

Conditions to Avoid
Exposure to air or moisture over prolonged periods.
Avoid shorting circuit or sparks near battery. Avoid prolonged over-charging.
Use only approved charging methods. Do not charge in gas tight containers. Keep battery away from strong
oxidizers, sparks, open flames.

Incompatible Materials
Acids. Bases. Oxidizing agent.

Hazardous Decomposition Products

Carbon oxides.

11. TOXICOLOGICAL INFORMATION

Information on likely routes of exposure

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Product Information Product does not present an acute toxicity hazard based on known or
supplied information.
In case of rupture:

Inhalation Specific test data for the substance or mixture is not available. Corrosive by
inhalation. (based on components). Inhalation of corrosive fumes/gases may
cause coughing, choking, headache, dizziness and weakness for several
hours. Pulmonary edema may occur with tightness in the chest, shortness of
breath, bluish skin, decreased blood pressure and increased heart rate.
Inhaled corrosive substances can lead to a toxic edema of the lungs.
Pulmonary edema can be fatal. May cause irritation of respiratory tract.

Eye Contact Specific test data for the substance or mixture is not available. Causes burns
(based on components). Corrosive to the eyes and may cause severe
damage including blindness. Expected to be an irritant based on components.

Skin Contact Specific test data for the substance or mixture is not available. Corrosive
(based on components). Causes burns.

Ingestion Specific test data for the substance or mixture is not available. Causes burns
(based on components). Ingestion causes burns of the upper digestive and
respiratory tracts. May cause severe burning pain in the mouth and stomach
with vomiting and diarrhea of dark blood. Blood pressure may decrease.
Brownish or yellowish stains may be seen around the mouth. Swelling of the
throat may cause shortness of breath and choking. May cause lung damage if
swallowed. May be fatal if swallowed and enters airways. Ingestion may
cause irritation to mucous membranes. Ingestion may cause gastrointestinal
irritation, nausea, vomiting and diarrhea. May be harmful if swallowed.

Component Information

Chemical Name Oral LD50 Dermal LD50 Inhalation LC50

Sulfuric acid = 2140 mg/kg ( Rat ) - = 510 mg/m3 ( Rat ) 2 h
7664-93-9

Information on toxicological effects

Symptoms Erythema (skin redness). Burning. May cause blindness. Coughing and/or
wheezing. May cause redness and tearing of the eyes.

Delayed and immediate effects as well as chronic effects from short and long-term exposure
Sensitization No information available.

Mutagenic Effects No information available.

Carcinogenicity The table below indicates whether each agency has listed any ingredient as a
carcinogen.

Chemical Name ACGIH IARC NTP OSHA

Lead A3 Group 2A Reasonably Anticipated X
7439-92-1

Lead dioxide A3 Group 2A Reasonably Anticipated X

1309-60-0

Sulfuric acid A3 Group 1 Known X

7664-93-9

ACGIH (American Conference of Governmental Industrial Hygienists)

A2 - Suspected Human Carcinogen
A3 - Animal Carcinogen
IARC (International Agency for Research on Cancer)
Group 1 - Carcinogenic to Humans
Group 2A - Probably Carcinogenic to Humans
NTP (National Toxicology Program)
Known - Known Carcinogen
Reasonably Anticipated - Reasonably Anticipated to be a Human Carcinogen
OSHA (Occupational Safety and Health Administration of the US Department of Labor)
X – Present
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Reproductive Toxicity Product is or contains a chemical which is a known or suspected reproductive
hazard. Contains a known or suspected reproductive toxin.

Developmental Toxicity Contains ingredients that have suspected developmental hazards.

STOT - single exposure No information available.

STOT - repeated exposure Causes damage to organs through prolonged or repeated exposure. Based
on classification criteria from the 2012 OSHA Hazard Communication
Standard (29 CFR 1910.1200), this product has been determined to cause
systemic target organ toxicity from chronic or repeated exposure. (STOT RE).

Chronic Toxicity Chronic exposure to corrosive fumes/gases may cause erosion of the teeth
followed by jaw necrosis. Bronchial irritation with chronic cough and frequent
attacks of pneumonia are common. Gastrointestinal disturbances may also be
seen. Contains a known or suspected carcinogen. Contains a known or
suspected reproductive toxin. Possible risk of irreversible effects. Avoid
repeated exposure. Prolonged exposure may cause chronic effects. May
cause adverse effects on the bone marrow and blood-forming system. Lead
compounds may be absorbed by ingestion, by inhalation and through the
skin. Lead may damage kidney function, the blood forming system and the
reproductive system.

Target Organ Effects Respiratory system. Eyes. Skin. Gastrointestinal tract (GI). Reproductive
System. Blood. Central Nervous System (CNS). Gingival Tissue. Kidney.
Teeth. Cardiovascular system. Hematopoietic system. Immune system. May
damage the unborn child.

Aspiration Hazard No information available.

Numerical measures of toxicity Product Information

The following values are calculated based on chapter 3.1 of the GHS document

ATEmix (oral)
500.00 mg/kg
ATEmix (inhalation-gas)
5,625.00 ppm (4 hr)
ATEmix (inhalation-dust/mist)
1.10 mg/l
ATEmix (inhalation-vapor)
14.00 ATEmix

12. ECOLOGICAL INFORMATION

This product contains a chemical which is listed as a severe marine pollutant according to DOT

Ecotoxicity
Very toxic to aquatic life with long lasting effects.

Chemical Name Toxicity to Algae Toxicity to Fish Toxicity to Daphnia Magna (Water
Microorganisms Flea)
Lead 96h LC50: = 0.44 mg/L 48h EC50: = 600 μg/L
7439-92-1 (Cyprinus carpio) 96h
LC50:= 1.17 mg/L
(Oncorhynchus
mykiss) 96h LC50: = 1.32
mg/L (Oncorhynchus
mykiss)

Sulfuric acid 96h LC50: > 500 mg/L 24h EC50: = 29 mg/L
7664-93-9 (Brachydanio rerio)

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Persistence and Degradability
No information available.

Bioaccumulation
No information available.

Other adverse effects

No information available.

13. DISPOSAL CONSIDERATIONS

Waste treatment methods This material, as supplied, is a hazardous waste according to federal
Disposal Methods regulations (40 CFR 261).

Dispose of contents/containers in accordance with local regulations.

Contaminated Packaging
D002 D004 D008
US EPA Waste Number

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 14. TRANSPORT INFORMATION
Transportation Information
Proper shipping name:
“Batteries, Wet, Non-spillable, Electric storage, Not regulated”

15. OTHER INFORMATION

Disclaimer

The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date
of its publication. The information given is designed only as a guide for safe handling, use, processing, storage,
transportation, disposal and release; and is not to be considered a warranty or quality specification. The information relates
only to the specific material designated and may not be valid for such material used in combination with any other materials
or in any process, unless specified in the text.

End of Safety Data Sheet

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