SET-B

PUBLIC
S.S.HALIYAPUR SCHOOL
SULTANPUR
Class: 12 Subiect:Chemistry2024-25
PRE BOARD- FKAMINATION

General Instructions:

instructions carefully.
Read the following

paper with internal choice.

this question
1. There are 33 questions in

questions carrying 1 mark each.

2. SECTION A consists of 16 multiple-choice

questions carrying2
marks each.
5 very answer
SECTION B consists of short
3.
3marks each.
SECTION C consists of 7short answer questions carrying
4.
carrying 4 marks each.
questions
5. SECTION D consists of2 case-based

5 marks each.
3 iong answer questions carrying
6. SECTION E consists of

7. All questions are compulsory.

calculators is not allowed.
8. Use of log tables and
Section A
[1]

1 What is A in the following reaction?

CH,-CH=CH,

+HCI A

b)
a CH,-CHCH,
CH-CH,-CH,
CI

d) CH,-CH-CH,
c) CH,-CH-CH,-CI

and held together by hydrogen bonds between pairs of

each other
are wound about
acid chains
2
Two nucleic

this is called
bases,
b) Primary structure of DNA
of DNA
a) Secondarystructure
d) Primary structure of RNA
of RNA
c) Secondary structure
reacts with Phenyl
by KzCr07. The product obtained
An organic compound X is oxidized using acidified
3

The possible structure of X is:

does not answer the silver miror test.
hydrazine but

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 Page No: .
a) (CH3),CHOH b)(CH)>CH;0H

c) CH3CHO d)
CH,CH,OH
4. The reagent which does not react with both acetone and benzaldehvde.

a) Sodium hydrogensulphite b) Phenyl hydrazine

c) Fehling's solution d) Grignard reagent

[1]
5 As temperature increases, the reaction rate:

a) First decreases then increases

b) Increases

d) Stays the same

c) Decreases
[1]
column with appropriate entries of column

II.
6. Match the items of I

)
ColumnI Column II

(a) Kb Elevation in boiling point

|(b) Kf (ii) Van't Hoff factor

(c) i (i) Cryoscopic constant

()ATs (iv) Ebullioscopic constant

a) (a) -(), (b) -(1), ()-(ii), (d) - (iv) b) (a) - (ii), (b) - (),(c)- (iii), (d) - (iv)

c) (a) - (iii), (b) - (iv), (c) - (), (d) -(ii) d) (a) - (iv), (b) - (i),(c)- (),()- ()
7 Racemisation occurs in [1]

a) SN2 reaction b) Sy2 reaction as well as SN1 reaction

c) Neither SN1 nor S2 reactions d) SN1 reaction

8. The magnetic moment is associated with its spin angular momentum and orbital angular momentum. Spin only [1]
is
of Cr3t ion
magnetic moment value

B.M b) 3.87 B.M

a) 2.87

B.M d) 3.47 B.M

c) 3.57

role of a catalyst is to change

9. The
b) equilibrium constant
a) gibbs energy of reaction
d) activation energy of reaction
c) enthalpy of reaction
conversion? [1)
reagent for the following
10. Which is the most suitable

-CH=CH-CH, --OH
CH,-CH CH- CH, -- CH, =
CH3
b) Tollen's reagent
a) lz and NaOH solution

d) Benzoyl peroxide
c) Sn and NaOH solution

toms a carboxylic acid as the only organic product [1]

11. An organiccompound containing oxygen,upon oxidomon

its molecular mass higher by 14 units, The organne compound is

with

b) a primary
a) a ketone alcohol
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 c) an aldehyde
alcohol
d) a secondary

Propanamide on reaction with bromine in aqueous NaOH gives: I1]

a) Ethanamine
b) N-Methyl ethanamine

c) Propanamine d) Propanenitrile
Br H,O2
13. gives D(-)-erythrose. [1]
Assertion (A):D()-Ribose on consecutive treatment with H,0' Fez (S04)s
Brz HO2 method and D(-)-ribose and D(-)-erythrose differ only in
Reason (R): H,0
0 Fe2t
iS used in Ruffdegradation
one carbon atom.

A and R are true but R is not the

a) Both A and R are true and R is the correct b) Both

of
correct explanation

A.
explanation of A.

c) A is true but R is false. d) A is false but R is true.

[1|
14. Assertion(A): Carbonyl compounds do not show intemolecular hydrogen bonding

Reason (R):Boiling points of cabonyl compounds are lower than alkanes.

BothA and R R is not the

a) BothA and R are true and R is the correct b) are true but

A. correct explanation
of A.
explanation of

c) A is true but R is false. d) A is false but R is true.

[1]
15. Alkylhalides are insoluble in water

between the alkyl b) alkyl halides are non polar Compounds

a) the force of attraction

halide and water is weaker and cannot

overcome the force of attraction between

alkyl halide and alkyl halide as also that of

water and water molecules

is released when new attractions d) weak hydrogenbonds exist between water

c) high energy

up between the haloalkane and the molecules

are set

water molecule

bromide with sodium [1]

16. (A):Tert. butyl methyl ether is not prepared by the reaction of tert. butyl
Assertion

methoxide.

Reason (R):Sodium methoxide is a strong nucleophile.

not the
BothA and R are true and R is the correct b) Both A and R are true but R is
a)

explanation of
A.
of correct
explanation
A.
but R is true.
d) A is false
c) A is true but R is false.

Section
B [2
of compleves in biological system?
17.
Give some example showing importance (21

18. Write balanced equations to represent what happens when

1. Acidified KMnO4 solution reacts with iron (I)ons

ii. Pyrolusite is fused with KOHI in the presence

of air (21
19 Answer the following:
(a Give two examples of non-

(b) Define half life period

chemical
of a reaction.
process which obeys the first order
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20. the density some lake
If of water is 1.25 g mL did contains 92 of Nat ions ner ke of water, calculate the

molarity of Nat ions in the lake.

OR
Obtain a relationship between relative lowering of Vapour pressure and mole fraction of solute?

21. Give the IUPAC name of the following compound :

NO2
coOH
ON NO2
Section C
22. Ni - Cd cell, Is it primary or secondary cell? 3]
Write electrode reactions taking placein

[3
23.
A first order decomposition reaction takes 40 minutes for 30% decomposition, calculate t12 value for it.

24. [3
Write structures of the compounds whose IUPAC names are as follows:

i. 2, 3 - diethylphenol

ii.
1-Ethoxypropane

iii. 2-EthOxy-3-methylpentaine

OR
Why is the C-O-H bond angle in alcohols slightly less than the tetrahedral angle whereas the C-0-C bond angle in

ether is slightly greater?

25. Write the reactions involved in the following reactions: 3]

i. Clemmensen reduction

ii. Cannizzaro reaction

26. Depict the galvanic cell in which the reaction: 3]

Zn(s) +2Agt(aq) Zn²t (aq) +2Ag(s)
takes place. Further show:

i. Which of the electrodes is negatively charged?

The carries of current in the cell.

ii.
reaction at each electrode.
ii. Individual

be carried out?
27. How the following conversions can 3]
i. Ethanol to propanenitrile

Aniline to chlorobenzene
ii.
to3, 4-dimethylhexane
ii. 2-Chlorobutane

cell: (3
28. Calculate the emf of the following

Zn (s) Zn2 | (0-01 M) (0-001 M) Ag* |Ag

(s)
||
=-0-76 V
Given : E2 /Zn
and

Eg /Ag = +0-80 V
2 =0-3010, 3= log 0:4771, log 10 = 1]
[log
Section D
that follow: [4]
following text carefully and answer the questions
29. Read the
forp thir, protectiya pxide
oxygen
The transition metals when exposed to at iow

tmness,
dnd intermediate

metal
temperatures

oxides lie
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films of up to some thousands of Angstroms in Iransition

ionic and covalent compounds fomed by

binary of elements from the left or right side the periodic table. They
 range from metallic to semiconductingand deviate by both large and
electron bonding
small degrees from stoichiometry. Since d
levels are involved, the cations-exist in various valence states and hence give rise to a large
number of oxides. The crystal structures are often claseified by considering a cubic or hexagonal close-packed
lattice of one set of ions with the other set of ions fli he octahedral or tetrahedral interstices. The actual

Oxide structures, however, generally show departures from such regular arrays due in part to distortions caused

by packing of ions of different size and to ligand field offects. These distortions depend not only on the number

of d-electrons but also on the valence and the position of the transition metal in a period or group.

serjes of transition metal exhibits +1 oxidation state most frequently? (1)

1. Why does copper, which is in first

ii. The lowest oxide of transition metal is basic. Why? (1)

(2)
The variability in oxidation states of d-block different from that of the p-block elements. Explain.
11.

OR
Crystal structure of oxides of transition metals often show defects. Given reason. (2)

30. [41
Read the following text carefully and answer the questions that follow:

A raw mangoplaced in concentrated salt solution loses water via osmosis and shrivel into pickle. Wilted flowers

revive when placed in fresh water. A carrot that has become limp because of water loss into the atmospherecan

be placed into the water making it firm once again. Waterwill move into its cells through osmosis. When placed
in water containing less than 0.9% (mass/volume)salt, blood cells swell due to flow of water in them by

OSmosis.

People taking a lot of salt or salty food suffer from puffiness or edema. What is the reason behind this?
i.
ii. The preservation of meat by salting and of fruits by adding sugar protects against bacterial action. How?
to the
iii. Why the direction of osmosis gets reversed if a pressure larger than the osmotic pressure is applied

solution side? Write its one application.

OR
What care is generally taken during intravenous injections and why?

Section E

the following: [5]

31. Attempt any five of

Name the deficiency disease resulting from lack of vitamin A andE in the diet. [11
(a)
between: [11
Differentiate
(b)
and Glycosidic linkage
i. Peptide linkage

Nucleoside and Nucleotide

ii.
protein. [11
Give an example of fibrous
(c)
in our body? [1]
(d) Which vitamin B group can be stored
[11
reducing sugars?
feature characterising
What is the structural
(e) [1)
of vitamin
A?
good sources
What are any two
with anti-sterility?
is linked
(9) Which vitamin

(geometrical
and optical)

Draw all the isomers of:

32.

i. [CoCl,(en)2l*

ii. [Co(NH3)Cl(en)²12*

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 a. For the complex [Fe(H,0)6l", the

i.
write hybridization
Imagnetic character and spin of the complex. (A
number:Fe = 26).

ii. Draw one of the geometrical isomers of he complex [P(en),CH2*which is optically inactive.

b. i. Using crystal field theory, write the electronC configuration of iron ion in the following complex ion. Also

predict its magnetic behaviour:[Fe(H-0)6l"*

ii. Write the IUPAC name of the coordination comnplex: [CoCh(en)]NO3

33. Write short notes on the (5]
following:

i. Carbylamine reaction

ii. Diazotisation

iii. Hofmann's bromamide reaction

iv. Coupling reaction

v. Ammonolysis

OR
Give one chemical test to distinguish between the following pairs of compounds:

i. Methylamine and dimethylamine

ii. Secondary and tertiary amines

ii. Ethylamine and aniline

iv. Aniline and benzylamine

v. Aniline and N-methyl aniline

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