Chemistry

Questions from HBSE last papers

Chapter: 9
[2012 Set- A]
1. Define the following: (A) Co-ordination compounds (B) Ambidentate Ligands. 2.
2. Write IUPAC name of the following: (A) K3[Al(C2O4)3] (B) Hg[Co(SCN)4] (C) [Co(NH3)2(CO3)]Cl. 3.
3. [Fe(H2O)6]3+ is strongly paramagnetic while [Fe(CN)6]3- is weakly paramagnetic explain. 3.
[2012 Set- B]
1. Define the following: (A) Co-ordination number (B) Co-ordination sphere. 2.
2. Write IUPAC name of the following: (A) K2[Zn(OH)4] (B) [Co(NH3)4(H2O)Cl]Cl2 (C) [Ag(NH3)2][Ag(CN)2]. 3.
3. Explain [Co(NH3)]3+ is an inner orbital complex whereas [Ni(NH3)6]2+ is an outer orbital complex. 3.
[2012 Set- C]
1. Define: (A) Chelates (B) Ligands. 2.
2. Write IUPAC name of the following: (A) K3[Cr(C2O4)3] (B) [Ni(CO)4] (C) [Pt(NH3)2 Cl (NO2)]. 3.
3. Explain why [Ni Cl4]2- is paramagnetic while [Ni(CO)4] is diamagnetic. 3.
[2013 Set- A]
1. Explain linkage isomerism with the help of example. 2.
2. Write IUPAC name of the following: (A) K3[Al(C2O4)3] (B) [Cr(NH3)3(H2O)3]Cl3 (C) [Co(NH3)2(CO3)]Cl. 3.
3. Explain bonding in co-ordination compounds with the help of Werner’s postulates. 3.
[2013 Set- B]
1. Explain ionization isomerism with the help of example. 2.
2. Write IUPAC name of the following: (A) [Ag(NH3)2][Ag(CN)2] (B) Hg[Co(SCN)4] (C) [Ni(CO)4]. 3.
3. Explain bonding in co-ordination compounds with the help of Crystal Field theory. 3.
[2013 Set- C]
1. Explain co-ordination isomerism with the help of example. 2.
2. Write IUPAC name of the following: (A) [Co(en)3]2(SO4)3 (B) K3[Cr(C2O4)3] (C) [Pt(NH3)2 Cl (NO2)]. 3.
3. Explain bonding in co-ordination compounds with the help of Valence Bond theory. 3.
[2014 Set- A]
1. What is the co-ordination number of metal in [Co(en)2Cl2]Cl: (A) 4 (B) 5 (C) 6 (D) 3. 1.
2. Define the following: (A) Co-ordination isomerism (B) Linkage isomerism. 2.
3. Write IUPAC name of the following co- ordination compounds: (A) [Co(NH3)6]Cl3 (B) [Co(NH3)5 Cl]Cl2
(C) K3[Fe(C2O4)3] (D) K3[Fe(CN)6] (E) K2[PtCl4] 5.
4. Discuss the main features of Werner’s theory. 5.
[2014 Set- B]
1. Which of the following is hexadentate ligand? (A) diene (B) CN- (C) en (D) EDTA. 1.
2. Which of the following has Mg metal? (A) Chlorophyll (B) Hemoglobin (C) Vitamin B-12 (D) Starch. 1.
3. Write IUPAC name of the following: (A) [Ni(CO)4] (B) Na3[Co(NO2)6]. 2.
4. Calculate the oxidation no. of metal in compounds [Co(NH3)5Cl]2+. 2.
5. Define the term ligand and give one example of unidentate and tetradentate ligand. 3.
[2014 Set- C]
1. The Oxidation number of Cr in complex [Cr(H2O)4Cl2]+ is : (A) 1 (B) 3 (C) 5 (D) 6. 1.
2. K4[Fe(CN)6] is a: (A) Double salt (B) Complex compound (C) Simple salt (D) None of these. 1.
3. The colour of cuprous sulphate is: (A) Blue (B) Green (C) White (D) None of these. 1.
4. Write two differences between double salt and co-ordination compounds. 2.
5. Explain the following: (A) Co-ordination sphere (B) Chelate. 3.
[2015 Set- A]
1. In [Co(NH3)6]Cl3 complex secondary valency is: (A) 3 (B) 9 (C) 6 (D) 0. 1.
2. Write two differences between double salt and co-ordination compounds. 2.
3. Discuss the following: (A) Hydrate isomerism (B) Linkage isomerism. 5.
4. Explain inner orbital complex and outer orbital complex with one example of each. 5.
[2015 Set- B]
1. On adding AgNO3 solution in 1 mole of PdCl2.4NH3, two moles of AgCl are formed then secondary valency of Pd in the
complex will be: (A) 0 (B) 2 (C) 4 (D) 1. 1.
2. Draw structure of EDTA and also write number of donar atoms (denticity). 2.
3. What is meant by spectrochemical series? 2.
4. Write formulae of the following using IUPAC rules: (i) Potassium tetrachloridonickelate(II).
(ii) Diamminechloridonitrito-N-platinum(II) (iii) Tetracarbonylnickel(0). 3.
[2015 Set- C]
1. Oxidation number of Pt in [Pt(C2O4)Cl3]- is: (A) +1 (B) +2 (C) +4 (D) +3. 1.
2. Discuss briefly chelate and chelating agent. 2.
3. Discuss five importance and applications of co-ordinate compounds. 5.
4. Explain that [Co(NH3)6]3+ is a low spin complex while [CoF6]3- is a high spin complex. 5.
[2016 Set- A]
1. Oxidation number of Cu in [Cu(CN)4]3- is: (A) +2 (B) +1 (C) +4 (D) −3 1.
2. Define Homoleptic and Heteroleptic complexes. 2.
3. Explain the splitting of d-orbitals in an octahedral crystal field. 2.
4. Explain the relationship between stepwise stability constants and overall stability constant. 3.
[2016 Set- B]
1. How many ions are given by [Co(NH3)5Br]Cl2 complex in water? (A) 4 (B) 2 (C) 6 (D) 3 1.
2. Give IUPAC names of the following coordinate compounds: (A) [Co (H 2O)3 Br Cl NO2] (B) K3[Cr(C2O4)3] 2.
3. Define the following (i) Coordination number (ii) Coordination sphere 2.
4. Explain the splitting of d-orbitals in a tetrahedral crystal field. 3.
[2016 Set- C]
1. Which is present in Metal carbonyls? (A) M−C σ bond (B) M−C π bond (C) M−C σ and M−C π bond (D) None. 1.
2. Potassium ferricynide is: (A) K2[Fe(CN)6] (B) K[Fe(CN)6] (C) K4[Fe(CN)6] (D) K3[Fe(CN)6] 1.
3. Among [Fe(H2O)6]3+ and [Fe(C2O4)3] 3- complex which is more stable and why? 2.
4. Give IUPAC name, coordination number, oxidation state and magnetic moment of complex [Cr(NH3)5Cl]Cl2. 2.
5. How does crystal field theory explain the colour of complexes? 2.
[2017 Set- A]
1. Which complex exhibit geometrical isomerism? (A) [MnBr4]2+ (B) [Pt (NH3)3Cl]+ (C) [Pt Cl2(P(C2H5)3)2 ]
(D) [Fe(H2O)5NO]2+. 1.
2. Draw the diagram to show splitting of d-orbital in an octahedral crystal field. 2.
[2017 Set- B]
1. Define chelate with example. Write the importance of chelate. 3.
[2017 Set- C]
1. Copper sulphate dissolves in excess of KCN to give: (A) [Cu (CN)4]3− (B) [Cu (CN)4]2− (C) CuCN (D) [Cu (CN)2] 1.
2. What is optical isomerism? Explain with one example. 2.
[2017 Set- D]
1. Which metal carbonyl has the strongest C–O bond? (A) Mn(CO)6+ (B) Cr(CO)6 (C) V(CO)6 (D) Fe(CO)5 1.
2. Write IUPAC names of following: (i) [Co(NH3)6]Cl3 (ii) K3[Fe(C2O4)3] 2.
[2018 Set- A]
1. Write the IUPAC name of this compound. [Cr(NH3)3 Br Cl I] 1.
2. In the following chelating ligand is: (A) OH− (B) CN− (C) Cl− (D) NH2CH2CH2NH2 1.
3. What is the coordination number in the K3[Cr(C2O4)3] coordination compound: (A) 3 (B) 6 (C) 4 (D) 2 1.
[2018 Set- B]
1. Write IUPAC names of following coordinate compounds: (i) [Co(NH 3)5Br]SO4 (ii) K3[Fe(CN)6] (iii) K3[Cr(C2O4)3] 3.
[2018 Set- C]
1. Write IUPAC names of following coordinate compounds: (A) [Pt(H2O)2Br(NO2)] (B) [Ni(CO)4] (C) K3[Al(C2O4)3] 3.
[2018 Set- D]
1. Which one is coloured? (A) Cu2Cl2 (B) [Sc(H2O)6]3+ (C) [Zn(H2O)6]2+ (D) [Ti(H2O)6]3+ 1.
2. Which type of Isomerism present in [Co(NH3)4Cl2]NO2 and [Co(NH3)4Cl(NO2)]Cl.
(A) Ionic (B) Linkage (C) Optical (D) Geometrical 1.
3. In the following in which metal of complex ion has zero oxidation number?
(A) [Cr(H2O)6]3+ (B) [CuCl4]2- (C) [Fe(CO)5] (D) [Fe(CN)6]3- 1.
[Sample paper 2019]
1. How many ions are given by the complex [Co(NH3)5Br]SO4 in water? (A) 1 (B) 2 (C) 3 (D) Zero 1.
2. Explain diamagnetic behaviour of [Ni(CN)4]2– complex on the basis of valence bond theory. 3.
[2019 Set- A]
1. What is hybridization of Ni in [NiCl4]2−? (A) sp3d (B) dsp2 (C) sp3d2 (D) sp3 1.
2. Explain [Co(NH3)6] is an inner orbital complex whereas [Ni(NH3)6] is an outer orbital complex.
3+ 2+ 3.
[2019 Set- B]
1. Write IUPAC name of K4[Mn(CN)6]. 1.
2. (A) [Fe(CN)6]4− and [Fe(H2O)6]2+ are of different colours in dilute solution. Why? 2.
(B) Draw structures of optical isomers of [Co(NH3)Cl(en)2]2+. 1.
[2019 Set- C]
1. What is relation between [Co(NH3)5Cl]SO4 and [Co(NH3)5SO4]Cl?
(A) Linkage isomers (B) Coordination isomers (C) Ionisation isomers (D) Solvate isomers 1.
2. Explain the splitting of ‘d’ orbitals in octahedral crystal field. 3.
[2019 Set- D]
1. Give IUPAC name of [Co(NH3)4 Cl(NO2)]Cl. 1.
2. (A) The hexaquamanganese (II) ion contains five unpaired electrons, while the hexacynoion contains only one unpaired
electron. Explain using Crystal Field Theory. 2.
(B) What is meant by Chelate complex? 1.