Effect of The Paper Surface Properties o
Effect of The Paper Surface Properties o
Printing
investigated and presented the methods for mottling deter- as well as their range of the types of coatings, enabled the
mination on the print on various substrates (Anayath and analysis of the influence of their particular surface charac-
Baral 2016, Jurič et al. 2013), mainly for the application in teristic on the ink transfer and the properties of the print.
digital printing. Influence of the surface free energy of pa- Printing ink used in this research was standard cold-set
per on mottling has been investigated, as well (Gigac et al. sheetfed process black. The ink was produced by the Sun-
2014), but as a sole parameter of the paper surface. Fur- Chemical (USA), member of the DIC group, with the com-
thermore, effects of the paper properties on the print gloss mercial name SunLit Express Process Black.
and ink mileage have been well investigated for printing
techniques other than offset (Xu 2006). In offset printing,
ink mileage was recently investigated in terms of various Methods and devices
process and material parameters, without focusing on the
Smoothness (Bekk method)
influence of the paper in the ink transfer process (Thakur
and Crasta 2016). Automatization of the ink transfer was
For the purpose of determining the smoothness of the pa-
also recently analysed (Varepo et al. 2018). One can con-
per, ten samples were cut for each type of paper to dimen-
clude that present economical and qualitative parameters
sions of 50 x 50 mm. Smoothness of the paper samples was
encourage further research and detailed analysis of mate-
determined according to Bekk method. The smoothness
rials that are included in the printing process – paper and
test was carried out according to TAPPI standard T 479.
ink being the crucial ones.
Each sample was placed on the glass plate above which
The aim of this research was to evaluate the signifi-
the measuring head is located. Measuring head was then
cance of the surface properties of the paper – specifically,
lowered to the sample, pressing it with weight of 10 kg. Af-
the components of the surface free energy, smoothness
ter that, the vacuum pump adjusted the air tank to a tar-
and gloss – on the ink transfer, ink usage and offset print
get pressure of 50.7 kPa. Depending on the smoothness of
quality in terms of the optical density, ΔE, gloss and mot-
the test sample, the air remaining between the paper sur-
tling.
face and the glass plate is transferred to the tank until the
pressure drops to 48.0 kPa. The time it takes for the air vol-
ume of 10 ml to achieve pressure of 48.0 kPa presented the
Experimental smoothness value expressed in seconds. The higher the re-
sult, the smoother the surface is (Smithers Pira n.d.).
Selection and preparation of samples
For this experiment, 5 types of papers with different sur- Gloss
face properties were chosen: four coated papers (marked
with C1–C4) and one uncoated paper (marked with U). C1 Paper and print gloss were measured using a glossmeter
was gloss coated paper, C2 matte coated, C3 bulk coated that measures reflective glare. Light intensity was mea-
and C4 bulk low-coated (4 times lesser amount of coat- sured over a range of reflected angles. The intensity of
ing). The C1 and C2 are papers with grammage of 300 g/m2 the light depends on the material and the angle of illumi-
from the producer UPM with the commercial names Fi- nation. In the case of non-metals (coating, plastics), the
nesse gloss and Finesse silk, respectively. The C3 and C4 amount of reflected light increases with increased angle
are same paper sample SinarVANDA with the grammage of illumination. The remaining part of the light penetrates
of 305 g/m, C3 being felt side with the minimal coating into the material and is absorbed or diffused (van der Walle
amount of 20 g/m2 and C4 wire side with the minimal coat- et al. 1999). In this research, glossmeter Elcometer 407 was
ing amount of 6 g/m2 . The sample denoted as U is Sappi used for the measurements (Elcometer n.d.). Gloss was
Tauro uncoated paper with the grammage of 115 g/m2 . Pa- measured at the angle of 60°, ten times for each paper sam-
pers were cut to the dimensions required for different mea- ple, and five times for each print sample (50 measurements
suring methods used to analyse their properties, and to in total for each set of prints on one paper substrate). Since
conduct the laboratory printing. After that, samples were two types of paper used in this research were low-gloss pa-
conditioned at temperature of 21 ± 1 °C and 50–55 % rel- pers (C4, U) and did not qualify for the measurements ac-
ative humidity for 24 hours before the measurements and cording to TAPPI/ANSI T 480 om-15 method at 75° or 20°,
printing. Papers chosen for this research are widely used in universal gloss measurement at 60° was conducted. This
the offset printing, and their different surface properties, enabled the comparison between the gloss of all papers
and their corresponding prints in order to assess the rela- printing roller. Precut paper samples were placed on the
tionship between the paper gloss and the gloss of the print, rubber plate that sits on the belt-feed console and driven
and calculate the correlation coefficients. under the printing roller, producing a print. Before and af-
ter every print, roller had to be weighed for the gravimetric
measurements of ink transfer. After every print, printing
Surface free energy roller was washed from ink residue and dried to maintain
repeatability and consistency of the results. The printing
Surface free energy (SFE) and contact angles on paper sam- process was conducted by making three series of prints by
ples were analysed using the Data Physics OCA 30 go- varying amount of the printing ink put into the distribut-
niometer and four test liquids: water, diiodomethane, glyc- ing system of the printability tester. The amounts of the ink
erol and formamide. SFE of the test liquids and their con- used were 0.12 cm³ (S1), 0.15 cm³ (S2) and 0.18 cm³ (S3). For
tact angles on the paper were the parameters used to cal- each type of paper, 10 prints were produced. The printing
culate the SFE of the paper samples. Contact angles were ink was distributed for the 30 second and then inking of
measured by sessile drop method, ten times on each paper the printing roller was made in 30 cycles. Printing speed
at different positions on the sample. The shape of the drop was 1 m/s and printing pressure was set at 150 N/cm2 .
was a spherical cap and the volume of the drop was 1 µl
(Tomašegović et al. 2016). All measurements of the contact
angles were performed at the same moment after the drop Gravimetry of the ink transfer and ink mileage
had touched the paper surface – with a delay of 20 frames.
The measurements of the contact angle were performed by Gravimetry was calculated for the wet ink transfer to the
applying 10 droplets of each liquid on the paper surface. print. Before each print, the printing roller was weighed
SFE was calculated using the OWRK method (Owens on Mettler Toledo XS205 analytic scale, and then weighed
and Wendt 1969). After the contact angles were obtained immediately after the print. In this way, the exact amount
for each test liquid on the sample, the mean values for of the ink transferred to each paper could be measured.
each sample were calculated. Contact angles of probe liq- Quantity of ink applied (M) could be calculated since the
uids (water, diiodomethane, glycerol and formamide) en- area of each print was known. The quantity of ink applied
able the calculation of SFE and its polar and dispersive is calculated using Equation 2:
components (Equation 1):
G1 − G2
M= (2)
A
= √γsP √ + √γsD
(1 − cosθ) ⋅ γs γlP
(1)
√γ
2 D
l
γlD where G1 is the mass of the printing roller before printing,
G2 is the mass of the printing roller after printing and A is
where γs surface tension of the solid, γl surface tension of the printing roller area.
liquid, γD dispersive component of surface tension, γP po-
lar component of surface tension and θ contact angle.
Optical measurements of papers and prints
Printing process In order to make sure that printing on each paper was in
respect to ISO 12647-2:2013 standard, L*a*b* values were
Printing process was carried out by means of Prüfbau mul- calculated on each unprinted paper type. ΔEab was calcu-
tipurpose printability tester MZ II (Prüfbau 2016). For the lated from measurements of L*a*b* values on each print.
purpose of the printing process, all papers were cut by Furthermore, optical density was measured on prints, as
means of Heidelberg Polar cutter to 25 cm × 4.6 cm. Prüf- it is commonly used to detect instability of the ink trans-
bau multipurpose printability tester can simulate various fer in a print series. All optical measurements were carried
printing techniques, among them the offset printing. In out by means of X-rite eXact spectrophotometer. The ΔEab
this experiment, printing was carried out without a print- was calculated as a difference between print and target val-
ing plate, using only printing roller in waterless system. ues for colour on coated/uncoated substrates set by ISO
Ink was applied using an ink micro pipette into the dis- 12647-2:2013 standard (for coated papers the L*a*b* coor-
tribution system, the rubber-metal roller system with rota- dinates are 16, 0, 0 and for uncoated papers 32, 1, 0). In
tional and axial movement and spread for 30 seconds in addition, ΔEab was also used to detect visual differences
order to get even ink film which will be transferred to the between prints on different substrates. Gloss on the prints
free energy is calculated from the contact angle measure- The average value and associated standard deviation
ment with the low volume of liquid drop in millimetre di- of the ink weight transferred on the printing substrate (m),
mensions. In addition to the results presented in Table 1, i. e. ink film weight on the printing substrate is given in Ta-
L*a*b* coordinates of the paper samples were measured. ble 2. As it can be seen, increase of the printing ink amount
Although surface properties of the paper samples are dif- in the distribution system increases the ink transfer on the
ferent, all paper samples, except U which is outside the tol- substrates on all printing samples. By smallest ink quan-
erances in the b* value, are in the tolerances of the infor- tity (0.12 cm3 ) the coated papers accept smaller quantities
mative tables presented in ISO 12647-2:2013 meaning that of ink, and the ink transfer on the low coated paper (C4) is
they are all in the same paper substrate group (PS1), i. e. highest for all ink quantities.
must comply to the same colour reproduction target.
Table 2: Weight of the wet ink transferred on the printing substrate.
Sample S1 S2 S3
Figure 2: Change of the optical density of the ink film due to the
drying process.
Table 4: Print samples ΔEab [1].
Sample S1 S2 S3
The presented results indicate that by printing on less C1 3.69±0.96 4.01±0.60 6.89±0.68
coated or uncoated papers, the ink adsorption is higher C2 2.16±1.11 2.48±0.86 5.49±1.12
due to the paper structure, which will require printing with C3 2.07±0.60 2.85±1.20 5.49±0.55
C4 12.26±1.03 3.02±0.86 4.46±1.04
higher amounts of ink. This can cause difficulties in the
U 4.91±0.62 4.56±0.35 2.69±1.12
post printing production.
Figure 7: Smoothness of paper substrate and GLCM entropy on Figure 9: Paper substrates and imprints gloss value.
print.
Conclusions
ing roller is thinner. As the surface free energy of paper
is mainly dispersive (Table 1), it causes good adhesion of This research was conducted with the aim of performing
oil-based printing ink. On the other hand, when the ink the evaluation of the paper substrate influence on the ink
film on the printing roller is thicker, higher viscosity of the transfer in the offset printing process and consequently,
printing ink, the printing pressure and ink splitting mech- on the properties of the print. The experimental part was
anisms will have larger influence on the ink transfer than set to obtain the laboratory prints with colour differences
the substrate-ink interaction. within the tolerances set by the ISO 12647-2:2013 standard.
After the printing process, gloss value on the printed The paper substrates were chosen to have different sur-
papers increases compared to the values on the unprinted face finish and were characterized by determining surface
papers (Figure 9). The increase of gloss is higher for the free energy, and optically by measuring gloss and smooth-
Sample C1 C2 C3 C4 U
2
Ink mileage [g/m ] 0.7942±0.1146 0.7048±0.0712 0.9250±0.0363 1.1550±0.1022 1.0521±0.0649
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