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Test Name: 24IIT1-INTG-MN-07S

PHYSICS, CHEMISTRY AND MATHEMATICS


Class I IIT-JEE Achiever (Integrated) 2024-25 Max. Marks 300
Solution to Test – 07 (Main) Duration 3 Hours
Date 09-11-2024
PART - I: PHYSICS
Multiple choice questions with one correct alternative

1. A wire can sustain a weight of 100 kg before it breaks. The wire is cut into two equal parts, each part can
hold weight upto
(A) 100 kg (B) 40 kg (C) 200 kg (D) 50 kg
Ans (A)
Maximum force
Breaking stress =
Area of cross − sec tion
It doesnot depend on length.
2. Bulk modulus of water is 2  109 Nm −2 . The pressure required to increase the density of water by 0.1%
in Nm −2 is
(A) 2  109 (B) 2  108 (C) 2  106 (D) 2  104
Ans (C)
Stress Pr essure P PV BV
Bulk modulus, B = = = or B =  P=
vol. strain vol. strain V V V
V
Substituting B = 2  10 Nm ,
9 −2

Substituting B = 2  109 Nm−2


V 0.1
= 0.1 % =
V 100
3. Which of the following relation is true? Where Y → Young’s modulus of elasticity,  → Shear modulus
of elasticity and  → Poisson’s ratio.
(A) Y = 2 (1 − 2) (B) Y = 2 (1 + 2) (C) Y = 2 (1 − ) (D) Y = 2 (1 + )
Ans (D)
Y = 2 (1 + )

4. The load versus elongation graph for four wires of the same length and material is
shown in the figure. The thinnest wire is represented by the line
(A) OC
(B) OD
(C) OA
Elongation
(D) OB
Ans (C)
It is clear from the graph that, for same value of load (F), elongations l1, l2, l3, l4 are such that
l4 > l3 > l2 > l1
 OA will represent the thinnest wire.

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5. A steel ring of radius r and cross-sectional area A is fitted to a wooden disc of radius R (R > r). If
Young’s modulus is Y, the force with which the steel ring is expanded is
R R−r Y R−r Yr
(A) AY (B) AY   (C)   (D)
r  r  A  r  AR
Ans (B)
Forcefully expanding the steel ring so that it fits on to the wooden disc creates strain in it. Strain causes
steel to try and restore itself. This induces stress. Steel ‘tries to restore’.
F = YA  strain
l 2R − 2r R −r R−r
Strain = = =  F = YA  strain = YA  
l 2r r  r 

6. A load of 10 kN is supported from a pulley, which in turn is supported by a rope of


cross-sectional area 103 mm2 and modulus of elasticity 103 N mm−2 as shown in the
figure. Neglecting friction at the pulley, then downward deflection of the load (in mm)
is
(A) 3.75 (B) 4.25
(C) 2.75 (D) 4.00
Ans (A)
Let T be the tension in the rope. Then, 2T = 10 kN  T = 5000 N
T 5000 N
Longitudinal stress in the rope is  = = 3 = 5N mm −2
A 10 mm2
Stress 5
Extension in the rope =  L = 3  (600 + 900) = 7.5 mm
Y 10
7.5
 Downward deflection of the load = = 3.75 mm
2

7. A wire of length 1 m and radius 1 mm is subjected to a load. The extension is x. The wire is melted and
then drawn into a wire of square cross-section of side 2 mm. Its extension under the same load will be
2 x 2 x 2 x x
(A) (B) (C) (D)
8 16 2 2
Ans (B)
Volume of wire is V = L  r2 = 1  (10−3)2 =   10−6 m3
Area of square cross-section = (2  10−3)2 = 4  10−6 m2
Volume   10−6 
Length of new wire = = = m
area 4  10−6 4
FL F  1  F (
Initially extension is x = =  −6 
 =   10−6 ) x
AY Y  10  Y

FL F L 2
Finally extension is x = =  or x  = (   10−6 )  4 −6 = x
AY Y A 4  10 16

8. When the tension on wire is 4 units, its length is l1 and when the tension is 5 units, its length is l2. Its
natural length is
l +l
(A) 4l1 − 3l2 (B) 5l1 − 4l2 (C) 4l1 − 5l2 (D) 1 2
2
Ans (B)

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1I(I)2425PCMT07S(M)

Fl 4l 5l
Y=  Y= =  4l2 − 4l = 5l1 − 5l  l = 5l1 − 4l2
A l A ( l1 − l ) A ( l2 − l )

9. In the situation shown in the figure, the coefficient of kinetic friction between block of mass 1 kg and
vertical walls is k = 0.5. The block starts from rest and travels a distance of 1 m in 1 s. Find the contact
force exerted by each wall on the block. (Take, g = 10 ms−2)
(A) 8 N
(B) 20 N
(C) 4 5 N
(D) 10 5 N
Ans (C)
1
As, s = at 2 = 1 m  a = 2 m s −2
2
From free body diagram of the block, mg − 2kN = ma
or 10 − 2  0.5  N = 2
125
 N = 8 N  FC = N 2 + (k N)2 = 8 1 + 0.25 = 8 =4 5 N
100

10. Two blocks A and B each of mass 1 kg are on an inclined plane of inclination 37 The coefficient of
kinetic friction between blocks and the inclined plane is k = 0.5. At t = 0, block A is released from rest
but block B is projected up along inclined plane with speed 10 m s −1. The initial separation between
blocks is 6 m. Find the distance from initial position of A, where they will collide. (Given, g = 10 ms−2)
(A) 1 m
(B) 2 m
(C) 3 m
(D) 4 m
Ans (A)
From free body diagram of B, mgsin 37 + kmgcos 37 = maB
 aB = 10 m s−2 in downward direction along the plane.
From free body diagram of block A,
mgsin 37 − kmgcos 37 = maA
 aA = 2 m s−2 in downward direction along the plane.
1 1 1
 srel = u rel t + a rel t 2 or 6 = 10t −  8t 2  t = 1 s  s A = a A t 2
2 2 2
1
 sA =  2  12 = 1 m
2

11. Kinetic energy of a particle moving in a straight line varies with time t as K = 4t 2. The force acting on
the particle
(A) is constant (B) is increasing
(C) is decreasing (D) first increases and then decreases
Ans (A)
1 8
mv 2 = 4t 2  v= t
2 m

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1I(I)2425PCMT07S(M)

Comparing with v = at, a = constant


i.e., the force acting on the particle is constant.

12. A particle of mass 2 kg starts moving in a straight line with an initial velocity of 2 ms −1 at a constant
acceleration of 2 ms−2. Then, rate of change of kinetic energy
(A) is four times the velocity at any moment
(B) is two times the displacement at any moment
(C) is four times the rate of change of velocity at any moment
(D) 8 Js−1 is constant throughout
Ans (A)
1
K = mv2
2
dK dv  dv 
 = mv  =  m  v = (ma)v = 4v
dt dt  dt 
As m = 2 kg and a = 2 ms−2
th
3
13. A particle moves on a rough horizontal ground with some initial velocity say v0. If of its kinetic
4
energy is lost in friction in time t0. Then, coefficient of friction between the particle and the ground is
v v 3v 0 v
(A) 0 (B) 0 (C) (D) 0
2gt 0 4gt 0 4gt 0 gt 0
Ans (A)
th
3
energy is lost
4
th
1 v
i.e., kinetic energy is left. Hence, its velocity becomes 0 under a retardation of g in time t0.
4 2
v0 v0 v0
 = v0 − gt 0 or gt 0 = or  =
2 2 2gt 0

14. Two particles 1 and 2 are allowed to descend on two frictionless chords OP and OQ. The ratio of the
speeds of the particles 1 and 2 respectively when they reach on the circumference is
1 1
(A) (B)
4 2
1
(C) 1 (D)
2 2
Ans (B)
1
OP = OQ cos 60 = (2R)   = R
2
R
 h1 = OP cos60 = (R = Radius)
2
h2 = 2R
v1 2gh1 h1 1 1
= = = =
v2 2gh 2 h2 4 2

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1I(I)2425PCMT07S(M)

15. A body is displaced from (0, 0) to (1 m, 1 m) along the path x = y by a force F = ( x 2 ˆj + yiˆ ) N . The work
done by this force will be
4 5 3 7
(A) J (B) J (C) J (D) J
3 6 2 5
Ans (B)
(1, 1)

W= 
(0, 0)
F  ds

Here, ds = dxiˆ + dyjˆ + dzkˆ


(1, 1) (1, 1)

 W= 
(0, 0)
(x 2 dy + ydx) = 
(0, 0)
(y 2 dy + x  dx) (as x = y)

(1, 1)
 y3 x 2  5
 W= +  = J
3 2  (0, 0) 6

16. A uniform flexible chain of mass m and length 2l hangs in equilibrium over a smooth horizontal pin of
negligible diameter. One end of the chain is given a small vertical displacement so that the chain slips
over the pin. The speed of chain when it leaves the pin is
(A) 2gl (B) gl (C) 4gl (D) 3gl
Ans (B)
Decrease in potential energy = increase in kinetic energy
 l  mgl 1 mgl
 K = mg  l −  = or mv 2 =
 2 2 2 2
 v = gl

17. A body which is moving with negligible initial speed is moved along its direction of motion by a
k
machine exerting a force which varies as F = where k = constant and v is instantaneous speed. The
v
graph showing the ratio of displacement and velocity (s/v) variation with time t is

(A) (B) (C) (D)

Ans (A)
k = w F
k
mvdv = dx
v
v x
k
0 =
m 0
2
v dv dx

v3 k
= x  (i)
3 m
k
F=
v
dv k
=a =
dt mv

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1I(I)2425PCMT07S(M)

v t
k
 vdv =
0
m 0
dt

v2 k
= t  (ii)
2 m
From equation (ii) in (i), we get
v  2kt  k
 = x
3 m  m
x
t
v
18. A vertical spring of force constant 100 Nm−1 is attached with a hanging mass of 10 kg is at rest in
equilibrium. Now an external force is applied on the mass so that the spring is stretched by additional 2m
slowly. The work done by the force F is (g = 10 ms−2)
(A) 200 J
(B) 400 J
(C) 450 J
(D) 150 J
Ans (A)
From work-energy theorem, k = 0 = Wg + Wspring + WF
k
0 = mg(2) − [32 − 12 ] + WF  WF = 200J
2

19. System shown in figure is released from rest. Pulley and spring is massless and friction is absent
everywhere. The speed of 5 kg block when 2 kg block leaves contact with ground is (Take force constant
of spring k = 40 Nm−1 and g = 10 ms−2)
(A) 2 ms −1
(B) 2 2 ms−1
(C) 2 ms−1
(D) 4 2 ms−1
Ans (B)
Let x be the extension in the spring when 2 kg block leaves the contact with ground.
2g 2  10 1
Then, kx = 2g or x = = = m
k 40 2
Now, from conservation of mechanical energy
1 1
mgx = kx 2 + mv2 (m = 5 kg)
2 2
kx 2
or v = 2gx −
m
1 (40)
Substituting the values v = 2 10  − = 2 2 ms−1
2 45

20. Force acting on a particle is ( 2iˆ + 3jˆ ) N . Work done by this force is zero, when a particle is moved on
the line 3y + kx = 5. Here value of k is
(A) 2 (B) 4 (C) 6 (D) 8

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1I(I)2425PCMT07S(M)

Ans (A)
3y + kx = 5
3dy + kdx = 0
k
dy = − dx
3
ds = dxiˆ + dyjˆ
F  ds = W
2dx + 3dy = W
k
2dx − 3 dx = 0  k = 2
3

Numerical problems

21. A cylinder of mass m = 10 g is held at rest by prongs of a forceps. If s = 0.01 be


the coefficient of friction, find the minimum normal force (in newton) exerted by
the cylinder on one of the prongs. (Take, g = 10 ms−2)
Ans 5
The normal reaction of each prong is N.
Weight of the cylinder is balanced by the frictional force between the prongs and the cylinder
 mg = sN + sN = 2sN
mg 10  10−3 10
 N= = N=5N
2s 2  0.1

22. A graph between the restoring force (F) of a wire and the extension (x) produced in it, is shown in the
YA
figure. Then (in SI unit) is p , where p is _____
L

Ans 3
F / A FL
Y= =
x / L Ax
F YA
=
x L
YA = tan 60 =
 Slope =  3
L

23. A 4 kg block is on a smooth horizontal table. The block is connected to a


second block of mass 1 kg by a massless flexible taught cord that passes over
a frictionless pulley. The 1 kg block is 1 m above the floor. The two blocks
are released from rest. With what speed (in ms−1) does the 1 kg block hit the
ground?
Ans 2

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1I(I)2425PCMT07S(M)

Decrease in potential energy of 1 kg = increase in kinetic energy of both


1
 1 10  1 = (4 + 1)v 2  v = 2 ms−1
2

24. A force of F = 0.5 N is applied on lower block as shown in figure. The work done
by lower block on upper block for a displacement of 6m of the upper block with
respect to ground is (in J). Take, g = 10 ms−2
Ans 1
If they move with a common acceleration, then that common acceleration is
0.5 1 −2
a1 = = ms
1+ 2 6
Maximum acceleration to upper block which can be provided by friction is
mg
a2 = = g = 0.1 10 = 1 ms −2
m
Since, a2 > a1 they will move together with same acceleration.
1 1
f = m1a1 = (1)   = N
6 6
1
 Wf = f  s =   (6) = 1 J
6

25. An ideal massless spring S can be compressed 1 m by a force of 100 N in


equilibrium. The same spring is placed at the bottom of a frictionless plane
inclined at 30° to the horizontal. A 10 kg block M is released from rest at the
top of the incline and is brought to rest momentarily after compressing the
spring by 2 m. If g = 10 ms−2, the speed of mass just before it touches the
spring is  5 ms−1 . Then  is
Ans 2
F = kx
F 100
 k= = Nm−1 = 100 Nm −1
x 1
Now from energy conservation, between natural length of spring and its maximum compression state.
1 2 1 2
mv + mgh = kx max
2 2
kx 2max (100)(2)2  2
 v= − 2gh = − (2)(10)   = 20 ms−1
m 10  2

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1I(I)2425PCMT07S(M)

PART - II: CHEMISTRY


Multiple choice questions with one correct alternative

26. Column-I and Column-II contains four entries each. Entries of Column-I are to be matched with some
entries of Column-II. One or more than one entries of Column-I may have the matching with the same
entries of Column-II.
Column - I Column - II
(i) Formal charge on the O-atoms in (P) −1
the ion O N O

(ii) Formal charge O – atom marked (Q) Zero

(1) is

(iii) Order of covalent character (R) LiCl > NaCl > KCl > RbCl > CsCl
(iv) Order of ionic character (S) LiCl < NaCl < KCl < RbCl < CsCl
(A) (i) → (P); (ii) → (Q); (iii) → (S); (iv) → (R) (B) (i) → (R); (ii) → (S); (iii) → (P); (iv) → (Q)
(C) (i) → (Q); (ii) → (P); (iii) → (S); (iv) → (R) (D) (i) → (Q); (ii) → (P); (iii) → (R); (iv) → (S)
Ans (D)
F.C. = Total valence e − 's in free atom - Number of non-bonding
1 1
e − s − number of bonding e − s = 6 − 4 −  4 = 0
2 2
1( )
F.C. on O-atom = 6 − 6 − 2 = −1
2
The covalent character is greater when
(i) The cation is small
(ii) The anion is large
(iii) There is a high charge on the ions
27. In which of the following set, the value of bond order will be 2.5 for all the species?
(A) O+2 , NO, NO+2 , CN (B) CN, NO+2 , CN− ,F2
(C) O+2 , NO+2 , O+22 , CN− (D) O−22 , O−2 , O+2 , O2
Ans (A)
28. Which of the following ions does not involve p-d bonding?
(A) SO32− (B) PO34− (C) NO3− (D) XeOF4
Ans (C)
N does not have d orbitals
29. Indicate the correct statement
(A) A sigma bond has no free rotation around its axis
(B) p-orbitals always have only sideways overlap
(C) s-orbitals never form -bonds
(D) There can be more than one sigma bond between two atoms
Ans (C)

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1I(I)2425PCMT07S(M)

30. Given that bond enthalpy of C−H, O=O, C=O, O−H and C−C are x1, x2, x3, x4 and x5 kJ/mol respectively.
Then enthalpy of combustion of propane according to the equation.
C3H8(g) + 5O2(g) → 3CO2(g) + 4H2O(l)
(A) 8x1 + 5x2 − 6x3 − 8x4 + 2x5 (B) 6x1 + 5x2 − 3x3 – 4x4 + x5
(C) 8x1 − 5x2 + 6x3 + 8x4 − 2x5 (D) 6x1 + 5x2 + 6x3 – 8x4 + 2x5
Ans (A)
H =  bond enthalpy of reactants −  bond enthalpy of products
H = 2 × BE of C−C + 8 × BE of C−H + 5 × BE of O=O − [6 × bond enthalpy of C=O + 8 × bond
enthalpy of O−H]
H = 2x5 + 8x1 + 5x2 − 6x3 − 8x4
 H = 8x1 + 5x2 − 6x3 − 8x4 + 2x5

31.

True statement for the above compounds is


(A) (a) is phenol while (b) is alcohol (B) Both (a) and (b) are primary alcohol
(C) (a) is primary and (b) is secondary alcohol (D) (a) is secondary and (b) is primary alcohol
Ans (D)

32.

Steric inhibition of resonance takes place


(A) In A, B only (B) In A, B, C, E (C) C only (D) In A only
Ans (D)
33. Electron affinities of O, F, S and Cl are in the order
(A) O < S < Cl < F (B) O < S < F < Cl (C) S < O < Cl < F (D) S < O < F < Cl
Ans (B)
34. Which of the following C–H bonds participate in hyperconjugation?

(A) I and II (B) I and IV (C) I and III (D) III and IV
Ans (B)
35. In which of the following molecules  - electron density in ring is maximum

(A) (B) (C) (D)

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1I(I)2425PCMT07S(M)

Ans (B)
36. Which of the following compounds does not show Lassaigne test for nitrogen?
(A) Urea (B) Hydrazine (C) Phenyl hydrazine (D) Azo benzene
Ans (B)

37. Magnetic moment of X3+ ion of 3d series is 2 6 BM. What is the atomic number of X?
(A) 24 (B) 26 (C) 25 (D) 28
Ans (C)
Magnetic moment
n ( n + 2 ) = 2 6  n ( n + 2 ) = 24
n=4
 Mn3+ has 4 unpaired electrons
38. If radius of 2nd Bohr orbit of H–atom is 'X' then velocity of electron in 1st Bohr orbit of H–atom is
(m = mass of electron)
h 2h h 3h
(A) (B) (C) (D)
mX mX 2mX 2mX
Ans (B)
r2 = r1  ( 2 ) = X
2

nh
mv1r1 =
2
2h
v1 =
mX
1 3
39. x 2 + y2 → xy3 H r = −30 kJ
2 2
Entropies of x 2 , y 2 and xy 3 are 60, 40 and 50 J K−1 mol−1 respectively for the reaction. The temperature
kelvin at which the above reaction attains equilibrium is
(A) 750 (B) 650 (C) 550 (D) 880
Ans (A)
1 3  1 3 
S = Sxy3 −  Sx2 + Sy2  = 50 −   60 +  40  = −40 J K −1 mol−1
2 2  2 2 
G = H − TS
H
G = 0  T = = 750 K
S
40. Heat of neutralization of CsOH with all strong acid is 13.4 k calmol−1 . The heat released on
neutralization of CsOH with HF (weak acid) is 16.4 k calmol−1 . H− of ionization of HF is
(A) 3.0 kcal (B) −3.0 kcal (C) 6.0 kcal (D) 0.3 kcal
Ans (B)
(i) H + OH → H2O H1 = −13.4 kcal
(ii) OH + HF → H2O + F −
H 2 = −16.4 kcal
 −
(iii) HF → H + F H 3 = ?
H3 = H2 − H1 = −16.4 − ( −13.4) = −3.0 kcal

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1I(I)2425PCMT07S(M)

 5 
41. One mole of an ideal gas  Cvm = R  at 300 K and 5 atm is expanded adiabatically to a final pressure
 2 
of 2 atm against a constant pressure of 2 atm. Final temperature of the gas is
(A) 270 K (B) 273 K (C) 248.5 K (D) 200 K
Ans (C)
For adiabatic process, dQ = 0
 dU = w
nC v.m T = − Pext dV
nCv.m T = −Pext ( V2 − V1 )
 nRT2 nRT1 
nC v.m T = −Pext  −
 P2 P1 
T T 
C v.m ( T2 − T1 ) = −Pext R  2 − 1 
 P2 P1 
5  T 300 
R ( T2 − 300 ) = −2R  2 − 
2  2 5 
5T2 − 1500 = −2T2 + 240
7T2 = 1500 + 240 = 1740
1740
T2 = = 248.5 K
7
 3 
42. 1 mol of an ideal gas A ( Cvm = 3R ) and 2 mole of an ideal gas B  Cvm = R  are taken in a container
 2 
and expanded reversibly an adiabatically from 1 L to 4 L starting from initial temperature of 320 K. The
change in internal energy for the process is
(A) −960R (B) +960 R (C) −480 R (D) +860 R
Ans (A)
(1 3R ) +  2  3 R 
CV ( mixture ) =  2  = 2R
1+ 2
C 3
CP = 2R + R = 3R, P = = 1.5
CV 2
−1 1.5−1
T1  V2  320  4 
=  =   T2 = 160 K
T2  V1  T2  1 
nR 3 R
Work done = ( T2 − T1 ) = (  (160 − 320 ) = −960R
(  − 1) 1.5 − 1)
Since q = 0, W = U = −960 R

43. A solution of KCl has a density of 1.69 g mL−1 and is 67% by weight. Find the density of the solution if
it is diluted so that the percentage by weight of KCl in the diluted solution is 30%
(A) 1.224 g mL−1 (B) 2.08 g mL−1 (C) 1.69 g mL−1 (D) 0.756 g mL−1
Ans (A)
Let the volume of the KCl should be 100 mL,
Weight of KCl solution = 100  1.69 = 169 g

12
1I(I)2425PCMT07S(M)

100 g of solution contains = 67 g of KCl


67
169 g of solution =  169 = 113.23 g
100
Let x mL of H2O be added
New volume of solution = (100 + x) mL
New weight of solution = (169 + x) g
(Since x mL of H2O = x g of H2O, dH2O = 1 )
New percentage of the solution = 30%
Weight of solute
% by weight =  100
weight of solution
113.23
30 =  100
(169 + x )
x = 208.43 mL = 208.43 g
New weight of solution (169 + x )
New density = =
New volume of solution (100 + x )
 d = 1.224 g mL−1

44. Resonance energy of these compounds will be in the order as

(I)
(II) (III) N
N O H
H

(A) III > I > II (B) I > II > III (C) II > III > I (D) II > I > III
Ans (B)

45. The hybridization of orbitals of N atom in NO3− , NO2+ and NH +4 are respectively:
(A) sp, sp2, sp3 (B) sp2, sp, sp3 (C) sp, sp3, sp2 (D) sp2, sp3, sp
Ans (B)
1
The formula to find the hybridisation of central atom is Z = [Number of valence electrons on central
2
atom + Number of monovalent atom attached to it + negative charge if any – positive charge if any]
1
For NO3− Z = 5 + 0 + 1 − 0 = 3
2
O

N sp2
O O−
1
For NO+2 , Z = 5 + 0 + 0 − 1 = 2
2
+
O = N = O → sp
1
For NH+4 , Z = [5 + 4 + 0 − 1] = 4
2

13
1I(I)2425PCMT07S(M)

+
H

N → sp3
H H
H

Numerical problems

46. How many of the following are paramagnetic?


C2 , B2 , O22− , BN, Cl2+ and NO+
Ans 2
Only B2 and Cl+2 are paramagnetic

47. The maximum work done when pressure of n moles of H2 was reduced from 20 atm to 1 atm at constant
temperature of 273 K is found to be 8180 calories. What is the value of n? [log 2 = 0.3010]
Ans 5
P
W = −2.303nRTlog 1
P2
20
or −8180 = −2.303n  2  273log or n = 5
1
48. Total number of aromatic compounds

Ans 4
(a), (b), (c) and (f) are aromatic
49. Write the number of pairs in which size of first element or ion is higher as compared to II nd out of
following eight pairs.
(O, S), (He, Ne), (Kr, Ne), (Na, Na+), ( Cl, Cl− ) , ( I− , Cl− ) , (Li, Na), (Li+, Na+)
Ans 3

50. A gas undergoes change from state (A) to state (B). In this process, heat absorbed and work done by the
gas is 5 J and 8 J respectively. Now gas is brought back to 'A' by another process during which 3 J of
heat is evolved. Find 'W' of the reverse process B → A in J,
Ans 6
A→B
U = Q + W
U = 5 − 8 = −3 J
B→A

14
1I(I)2425PCMT07S(M)

U = 3J; Q = −3J
U = Q + W
3 = −3 + W
W = +6 J
 in the reverse process of 6 J of work is done on the system

PART - III: MATHEMATICS


Multiple choice questions with one correct alternative

51. Solution of equation sin 2 x cos x + 4sin x cos x − cos2 x sin x − 4sin x + 4cos x − 2 = 0 , for real valued x, is
1  1 
(A) n + tan −1 ( n  ) (B) n + ( n  ) (C) n − tan −1 ( n  ) (D) n  ( n  )
2 4 2 4
Ans (B)
sin x cos x ( sin x − cos x ) + 2 (1 − ( sin x − cos x ) ) − 4 (sin x − cos x ) − 2 = 0
2

 ( sin x − cos x ) ( sin x cos x − 2 ( sin x − cos x ) − 4 ) = 0


 (sin x − cos x )(sin x + 2)( cos x − 2) = 0

 tan x = 1  x = n + ; n 
4
52. In a triangle ABC, the angle B is greater than the angle A. If the values of angles A and B satisfy the
equation 3sin x − 4sin3 x − k = 0, 0  k  1 , then the values of C is
  2 5
(A) (B) (C) (D)
3 2 3 6
Ans (C)
We have 3sin x − 4sin3 x = k, 0  k  1, which can also be written as sin3x = k. It is given that A and B
are solution of this equation.
Therefore sin3A = k and sin3B = k (where 0 < k < 1)
 0 < 3A <  and 0 < 3B <  (since 0 < k < 1)
 3A = 3B (which is not possible)
 3A + 3B   3A − 3B 
sin3A = sin3B  2cos   sin  =0
 2   2 
 3A + 3B   2
 cos   = 0  3(A + B) =   A + B =  C =
 2  3 3
53. Total number of solutions of [sin x] + cos x = 0 for x  [0, 2] is
(where [.] denotes the greatest integer function)
(A) 1 (B) 2 (C) 4 (D) 0
Ans (D)
Given equation is sin x  = − cos x
Real solution exists iff − cos x is integer i.e, cos x is an integer
 3
So possible solutions for x  [0, 2] are x = 0, , , , 2
2 2
When x = 0, 2 RHS = −1 and LHS = 0, no solution
 3
x = or RHS = 0 and LHS = 1, no solution
2 2

15
1I(I)2425PCMT07S(M)

x= RHS = 1 and LHS = 0, no solution


So, we can conclude that equations has no real solution
54. The number of all possible 5-tuples ( a1 , a 2 , a 3 , a 4 , a 5 ) such that
a1 + a 2 sin x + a 3 cos x + a 4 sin 2x + a 5 cos 2x = 0 holds for all x is
(A) zero (B) 1 (C) 2 (D) infinite
Ans (B)
Since the equation
a1 + a 2 sin x + a 3 cos x + a 4 sin 2x + a 5 cos 2x = 0
Holds for all values of x
So putting x = 0 in equation (i), a1 + a 3 + a 5 = 0
On putting x = , a1 − a 3 + a 5 = 0 in equation
 a3 = 0 and a1 + a5 = 0 … (i)
 3
Putting x = and , we get
2 2
a1 + a 2 − a 5 = 0 and a1 − a 2 − a 5 = 0
 a 2 = 0 and a1 − a 5 = 0 … (ii)
From (i) and (ii) we get a1 = a 2 = a 3 = a 5 = 0
The given equation reduces to a4 sin2x = 0. This is true for all values of x, therefore a4 = 0. Hence
a1 = a 2 = a 3 = a 4 = a 5 = 0 . Thus the number of 5-tuples satisfying the equation is one

55. Complete set of values of x in (0, ) satisfying 1 + log2 (sin x ) + log2 (sin3x )  0 is
 2 3    2 
(A)  ,  (B)  , 
 3 4  3 3 
     3 5    2 
(C)  ,    ,  (D)  , 
6 4  4 6  2 3 
Ans (C)
1 + log2 (sin x ) + log2 (sin3x )  0
 sin x, sin 3x > 0
 log2 ( 2  sin x  sin3x )  0
 2sin x  sin 3x  1
For sin x > 0  x  (0, ); sin 3x > 0  3x  ( 0,  )  ( 2, 3 )
    2 
 x   0,    ,   … (i)
 3  3 
For 2 sin x  sin 3x  1
 2sin 2 x ( 3 − 4sin 2 x )  1  8sin 4 x − 6sin 2 x + 1  0
 ( 2sin 2 x − 1)( 4sin 2 x − 1)  0
 1  1   1  1
  sin x −  sin x +   sin x −  sin x +   0
 2  2  2  2
1 1
  sin x 
2 2
     3 5 
 x ,    ,  … (ii)
6 4  4 6 

16
1I(I)2425PCMT07S(M)

     3 5 
In view of (i) and (ii), x   ,    , 
6 4  4 6 
56. Without changing the direction of co-ordinates axes, origin is transferred to ( ,  ) so that the linear
terms in the equation x 2 + y2 + 2x − 4y + 6 = 0 are eliminated. The points ( ,  ) is
(A) ( −1, 2 ) (B) (1, − 2 ) (C) (1, 2) (D) ( −1, − 2)
Ans (A)
The given equation is x 2 + y2 + 2x − 4y + 6 = 0 … (i)
Putting x = x  + , y = y +  in (i), we get
x 2 + y2 + x ( 2 + 2 ) + y ( 2 − 4 ) + (  2 + 2 + 2 − 4 + 6 ) = 0
To eliminate linear terms, we should have
2 + 2 = 0 and 2 − 4 = 0
  = −1 and  = 2  ( , ) = ( −1, 2 )

57. Vertices of a triangle are (1, 2); ( 5 cos , 5 sin  ) and ( 5 sin , − 5 cos  ) . Then locus of its
orthocenter is
(A) ( x − y + 3) + ( x + y − 1) = 20 (B) ( x + y − 3) + ( x − y + 1) = 20
2 2 2 2

(C) ( x + y − 1) + ( x + y + 1) = 19 (D) ( x + y − 4 ) + ( x − y + 4 ) = 25
2 2 2 2

Ans (B)
Let A  (1, 2 ) , B  ( 5 cos , 5 sin  ) and C  ( 5 sin , − 5 cos  ) .
Distance of A, B, C from (0, 0) is 5 units
 circumcenter of ABC is origin (0, 0)
Let G (h, k) be the centroid of triangle
 3h = 1 + 5 ( cos  + sin  ) and 3k = 2 + 5 (sin  − cos )
If 'O' is orthocenter of triangle having co-ordinates (a, b), then OG : GC = 2 : 1
 a = 3h, b = 3k
a −1
 cos  + sin  = … (i)
5
b−2
And sin  − cos  =
5
 a + b − 3   a − b +1
2 2
a + b−3 a − b +1
sin  = , cos  =   +  =1
2 5 2 5  2 5   2 5 
 Required locus is ( x + y − 3) + ( x − y + 1) = 20
2 2

58. If the point ( cos , sin ) does not fall in the region of y = x − 1 in which the origin lies, then  belongs
to
  3    
(A)  ,  (B)  − ,  (C) (0, ) (D) None of (A), (B) & (C)
2 2   2 2
Ans (B)
The point ( cos , sin ) lies on a circle x 2 + y2 = 1
y = x −1  y =  x −1
 y =  ( x − 1) and y =  (1 − x ) for x  1 and x < 1 respectively

17
1I(I)2425PCMT07S(M)

 
From the figure,  can vary from − to
2 2
59. A line passing through the point (2, 2) encloses with axes an algebraic area  . The intercepts on the
axes made by the line are given by the roots of equation
(A) x 2 −  x +  = 0 (B) x 2 −  x + 2  = 0
(C) x 2 +  x + 2  = 0 (D) None of (A), (B) & (C)
Ans (B)
Let the line cut intercepts 'a' and 'b' respectively from the axes
1
 Area = ( ab ) =   ab = 2 … (i)
2
x y
Also equation of line is + = 1
a b
2 2
As (2, 2) lies on it, + = 1
a b
 2 (a + b) = ab … (ii)
 using (i) in (ii), we ger 2 ( a + b ) = 2 
2
a+ =   a2 − a  + 2  = 0
a
Hence intercepts on axes made by the line are given by the roots of x 2 −  x + 2  = 0

60. The orthocenter of the triangle formed by (0, 0), (8, 0), (4, 6) is
 8
(A)  4,  (B) (3, 4) (C) (4, 3) (D) ( −3, 4 )
 3
Ans (A)
Let ABC be the given triangle and the vertices be A (0, 0), B (8, 0) and C (4, 6)
( 6 − 0) 3
∵ Slope of BC = =−
( 4 − 8) 2
 2
 Equation of line through A and perpendicular to BC is y − 0 =   ( x − 0 )
 3
i.e., 2x − 3y = 0 … (1)
( 6 − 0) 3
and slope of CA = =
( 4 − 0) 2
 2
 Equation of line through B and perpendicular to CA is y − 0 =  −  ( x − 8)
 3
i.e., 2x + 3y = 16 … (2)
 8
Solving (1) and (2), the orthocenter is  4,  which is given in (A)
 3

61. The equation of the line bisecting the obtuse angle between y − x = 2 and 3y + x = 5 is
y−x−2 3y + x − 5 y+x−2 3y + x − 5
(A) = (B) =
2 2 2 2
−y + x + 2 3y − x − 5
(C) = (D) None of (A), (B) & (C)
2 2
Ans (A)

18
1I(I)2425PCMT07S(M)

y−x−2  3y + x − 5 
Bisectors of given lines are =  
2  2 
 − ( 2 + 1) x + ( 2 − 3 ) y = 2 2 − 5 … (1)
And (1 − 2 ) x + ( 2 + 3 ) y = 2 2 + 5 … (2)
2 +1
Slope of line y − x = 2 is ( m1 = 1) and slope of first bisector = m2
2− 3
m 2 − m1 3 +1
Now tan  = =  1 . Therefore  > 45
1 + m1m 2 1 + 2 2 − 3
y−x−2 3y + x − 5
So, the bisector of obtuse angle is =
2 2
62. A system of lines is given as y = m i x + ci , where m i can take any value out of 0, 1, − 1 and when m i is
positive, then c i can be 1 or −1 ; when m i equal 0, c i can be 0 or 1 and when m i equals to −1, ci can
take 0 or 2. Then the area enclosed by all these straight lines is
(A)
3
( 2 − 1) sq unit (B) 3 sq unit (C)
3
sq unit (D) None of (A), (B) & (C)
2 2 2
Ans (C)
Lines are y = 1, y = 0
y = −x, y = −x + 2
y = x + 1, y = x − 1
Area of OABCDE
3 3
= area of OBGF =  1 = sq unit
2 2
63. If a, b, c are positive real numbers in GP then a + b, 2b, b + c are in
(A) AP (B) GP (C) HP (D) None of (A), (B) & (C)
Ans (C)
a, b, c in GP  b2 = ac
T1 = a + b = a ( a + c ) and T3 = b + c = c ( a + c )
Now HM of T1 and T3 is
2T1T3 2 a c ( a + c )
2

= = 2 ac
T1 + T3 ( a + c)
2

But T2 = 2b = 2 ac
 T1 , T2 , T3 are in H.P.
64. If the sum of the first 2n terms of the A.P. 2, 5, 8, is equal to the sum of the first n terms of the A.P.
57, 59, 61, , then n equals
(A) 10 (B) 12 (C) 11 (D) 13
Ans (C)
According to given condition, S2n = Sn , where S 2 n and S'n denotes the sum of first 2n-terms and
AP 2, 5, 8… and 57, 59, 61… respectively

2n
 2  2 + ( 2n − 1)  3 = n 2  57 + ( n − 1)  2
2 2

19
1I(I)2425PCMT07S(M)

1
 ( 4 + 6n − 3) = (114 + 2n − 2 )
2
 6n + 1 = 57 + n − 1  5n = 55  n = 11

65. Sum to n terms of the series 13 + 3  23 + 33 + 3  43 + 53 + is (n is even)


n ( n 2 + 1) ( 2n + 1) n ( n 3 + 4n 2 + 10n + 8)
(A) (B)
3 8
(
n n +13 ) 2
(
n 2n + 6n + 5)
2
(C) (D)
8 4
Ans (D)
We have Sn = 13 + 3  23 + 33 + 3  43 + 53 +
Let n = 2m
Then S2m = (13 + 33 + 53 + to m terms ) + 3 ( 23 + 43 + 63 + to m terms )
= 1 + 2 + 3 + 4 + + ( 2m − 1) + ( 2m ) 
3 3 3 3 3 3

−23 + 43 + + ( 2m )  + 323 + 43 + 63 + + ( 2m ) 
3 3

 2m ( 2m + 1) 
2

=  + 8  21 + 2 + 3 + + m 
3 3 3 3

 2
m2 ( m + 1)
2

= m2 ( 2m + 1) + 16 
2

4
n ( 2n + 6n + 5)
2 2
n
= [Put m = ]
4 2
66. The first, second and middle terms of an AP are a, b, c respectively. Their sum is
2(c − a ) 2c ( c − a ) 2c ( b − a ) 2b ( c − a )
(A) (B) +c (C) (D)
b−a b−a c−a b−a
Ans (B)
We have first term = a, second term = b
 d = common difference = b − a
It is given that the middle term is c.
This means that there are an odd number of terms in the AP.
Let there be (2n + 1) terms in the AP.
Then ( n + 1) term is the middle term.
th

 middle term = c  a + nd = c
c−a
 a + n (b − a ) = c  n =
b−a
2n + 1
 Sum =  2a + ( 2n + 1 − 1) d 
2
1   c − a    c − a ( 
= 2   + 1  2a + 2   b − a )
2   b − a    b−a  
1  2(c − a )  2c ( c − a )
=  + 12c = +c
2 b−a  b−a

20
1I(I)2425PCMT07S(M)

2
 1  1
67. The sum to n terms of the series 1 + 2 1 +  + 3 1 +  + is given by
 n  n
2
 1
(A) n 2
(B) n (n + 1) (C) n 1 +  (D) None of (A), (B) & (C)
 n
Ans (A)
1
Let S be the sum of n terms of the given series and x = 1 + .
n
Then, S = 1 + 2x + 3x 2 + 4x 3 + + nx n −1
 xS = x + 2x 2 + 3x3 + + ( n − 1) x n −1 + nx n
 S − xS = 1 +  x + x 2 + + x n −1  − nx n
1 − xn
 S (1 − x ) = − nx n
1− x
 1   1 n   1
n

 S  −  = −n 1 − 1 +   − n 1 + 
 n   n   n
1   1 n  1 n 
  S = n 1 − 1 +  + 1 +   = n
n   n  n 
S=n 2

68. If the roots of equation x 2 + bx + ac = 0 are ,  and roots of the equation x 2 + ax + bc = 0 are , 
then the value of , ,  are respectively
(A) a, b, c (B) b, c, a (C) c, a, b (D) None of (A), (B) & (C)
Ans (C)
From the given two equation
 +  = −b … (1)
 = ac … (2)
 +  = −a … (3)
 = bc … (4)
(1) − ( 3)   −  = a − b … (5)
( 2)  a
 =
( 4)  b
a
= … (6)
b
Putting the value of  in (5)
a (a − b)
− =a−b   = (a − b)
b b
  = b ,   = a and  = c

69. The number of ordered pairs (a, b) for which a ( x + 1) + b ( x 2 − 3x − 2 ) + x + 1 = 0, x  R is an identity


2

in x is
(A) 0 (B) 1 (C) 2 (D) infinite
Ans (A)
The equation is
( a + b ) x 2 + ( 2a − 3b + 1) x + ( a − 2b + 1) = 0

21
1I(I)2425PCMT07S(M)

Above is identity in x if a + b = 0; 2a − 3b + 1 = 0 and a − 2b +1 = 0


1 1
Solving first and second, we get a = − and b =
5 5
But these values do not satisfy third.
Hence, equation cannot be an identity for any value of a and b

70. If ,  are the roots of x 2 + px + q = 0 , and also of x 2n + pn x n + qn = 0 and is a root of

x n + 1 + ( x + 1) = 0,  n  n , then n must be
n

(A) any integer (B) an even integer (C) an odd integer (D) None of (A), (B) & (C)
Ans (B)
,  are the roots of
x 2 + px + q = 0   +  = −p and  = q … (1)
Again, ,  are also roots of x 2n + pn x n + qn = 0
 2n + pn n + qn = 0 and 2n + pnn + qn = 0
 ( 2n − 2n ) + pn ( n − n ) = 0
 n + n = −pn … (2)

is a root of ( x n + 1) + ( x + 1) = 0
n
Now

 n   
n

  n + 1 +  + 1  = 0
   
 (  n + n ) + (  +  ) = 0  − p n + ( − p ) = 0 , which holds only if n is an even integer
n n

Numerical problems
1
71. Find the value of p2 + q 2 if the solutions of the equation ( sin x ) + 2 4 cos x = 0 is given by
 p 
 2n + q 
 
Ans 5
1
sin x + 2 4 cos x = 0
1
 sin x = −2 4 cos x  sin x = 2  cos 2 x
 − 2 cos2 x + sin x = 0  − 2 (1 − sin 2 x ) + sin x = 0
 2 sin 2 x − 2 + sin x = 0
 2 sin 2 x + 2sin x − sin x − 2 = 0
 ( sin x + 2 )( 2 sin x − 1) = 0
1
 sin x = − 2 or sin x =
2
sin x = − 2 is not possible
1
sin x =
2

22
1I(I)2425PCMT07S(M)

3
x = 2n +
4
 p 
Comparing with  2n +   p = 3, q = 4  p + q = 5
2 2

 q 
72. Consider two points A  (1, 2 ) and B  ( 3, − 1) . Let M be a point on the straight line L : x + y = 0 . If M
be a point on the line L = 0 such that AM − BM is maximum, then find the distance of M from
N  (1, 1)
Ans 10
Given A (1, 2), B ( 3, − 1) and M lies on L: x + y = 0
Now, equation of AB is L2 : 3x + 2y = 7
AM − BM will be maximum = AB, when M is the point of intersection L and L2
 M ( 7, − 7 )
Hence distance between M ( 7, − 7 ) and N (1, 1) is MN = 62 + 82 = 10

73. Triangle ABC lies in the cartesian plane and has an area of 70 sq. units. The co-ordinates of B and C are
(12, 19) and (23, 20) respectively and the co-ordinates of A are (p, q). The line containing the median to
the side BC has slope −5 . Find the largest possible value of (p + q).
Ans 47
Given B (12, 19) and C (23, 20)
 BC = 112 + 12 = 122 and equation of BC is L1 : x − 11y + 197 = 0
Area of ABC = 70 sq units
2  70
 Altitude through A is h = units.
122
Equation of median through A (p, q) is y −
39
2  
= ( −5) x −
35
2
p + 55p − 1177 + 197 140
 5x + y − 107 = 0  A ( p, 107 − 5p ) will be at distance h as =
122 122
 56p − 980 = 140  p = 20,15
 (20, 7) or (15, 32) which gives p + q = 27 or 47
The larger value is 47
74. Find the number of terms common to the two APs 3, 7, 11, 407 and 2, 9, 16, , 709 .
Ans 14
Let the number of terms in two APs be 'm' and 'n' respectively
Then, 407 = 3 + ( m − 1)  4 and 709 = 2 + ( n − 1)  7
 m = 102 and n = 102
 each AP consists of 102 terms
Let the pth term of 1st AP be equal to qth term of 2nd AP
Then, 3 + ( p − 1)  4 = 2 + ( q − 1)  7
p +1 q
 4 ( p + 1) = 7q  = = k (say)
7 4
 p = 7k − 1 and q = 4k since, p ≤ 102 and q ≤ 102

23
1I(I)2425PCMT07S(M)

 7k − 1  102 and 4k ≤ 102


5 1
 k  14 and k  25
7 2
 k ≤ 14 corresponding to each value of k, we get a pair of identical terms
Hence, there are 14 identical terms in two Aps.
75. If rth term of a series is ( 2r + 1) 2− r , then sum of its infinite terms is
Ans 5
Here Tr = ( 2r + 1) 2−r
1 5 7 
Series is: 3 + + 2 + 
2 2 2 
Obviously, the series in the bracket is arithmetic-geometrical series.
a dr
Therefore, by the formula S = +
1 − r (1 − r )2
 1 
2  
1 3
We have, S =  +  2 2  = 5
2 1 − 1  1 
 2 1 − 2  

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