Colligative Properties
Colligative Properties
between the total number of solute particles (in the solution) to the total number of
solvent particles. Colligative properties are not dependent on the chemical nature of
the solution’s components. Thus, colligative properties can be linked to several
quantities that express the concentration of a solution, such as molarity, normality,
and molality. The four colligative properties that can be exhibited by a solution are
given below:
The word “colligative” has been adapted or taken from the Latin word “colligatus”
which means “bound together”. In the context of defining a solution, colligative
properties help us understand how the properties of the solution are linked to the
concentration of solute in the solution.
What Are Colligative Properties?
A dilute solution containing non-volatile solute exhibits some properties which
depend only on the number of solute particles present and not on the type of solute
present. These properties are called colligative properties, and they are mostly seen
in dilute solutions.
We can further consider colligative properties as those properties that are obtained
by the dissolution of a non-volatile solute in a volatile solvent. Generally, the solvent
properties are changed by the solute, where its particles remove some of the solvent
molecules in the liquid phase. This also results in the reduction of the concentration
of the solvent.
Besides, when we talk about the given solute-solvent mass ratio, colligative
properties are said to be inversely proportional to the solute molar mass.
Similarly, if we add alcohol to water, the solution’s freezing point goes down below
the normal temperature, and that is observed for either pure water or alcohol.
Different Types of Colligative Properties of Solution
There are different types of colligative properties of a solution, which include vapour
pressure lowering, boiling point elevation, freezing point depression and osmotic
pressure.
If P0 is the vapour pressure of pure solvent and Ps is the vapour pressure of the
solution, the difference Po – Ps is termed as the lowering in vapour pressure. The
ratio, Po – Ps / Po, is known as the relative lowering of vapour pressure.
Raoult, in 1886, established a relation between relative lowering in vapour pressure
and mole fraction. The relationship is known as Raoult’s law. It states that the relative
lowering in vapour pressure of a dilute solution is equal to the mole fraction of the
solute present in the solution.
Po – Ps / Po = n / n + N
The boiling point of a liquid is the temperature at which the vapour pressure is equal
to atmospheric pressure. We know that with the addition of a non-volatile liquid to a
pure solvent, the vapour pressure of a solution decrease. Therefore, to make vapour
pressure equal to atmospheric pressure, we have to increase the temperature of the
solution. The difference in the boiling point of the solution and the boiling point of the
pure solvent is termed elevation in boiling point.
If T0b is the boiling point of the pure solvent and Tb is the boiling point of the solution,
then elevation in boiling point is given as
∆Tb =T0b-Tb
Experimental results show that there is a relation between elevation in boiling point
and molality ‘m’ of the solute present in the solution.
∆Tb ∝ m
∆Tb = kb m
Where,
∆Tb = 1000 x kb x m2 / M2 x m1
Where,
m2 = mass of solvent in g
M1 = mass of solvent in kg
The freezing point of a substance may be defined as the temperature at which the
vapour pressure of the substance in its liquid phase is equal to its vapour pressure in
the solid phase. According to Raoult’s law, when a non-volatile solid is added to the
solvent, its vapour pressure decreases, and now it would become equal to that of a
solid solvent at a lower temperature. The difference between the freezing point of the
pure solvent and its solution is called depression in freezing point.
If T0f is the freezing point of the pure solvent and Tf is the freezing point when a non-
volatile solute is dissolved in it, then depression in the freezing point is given as
Just like elevation in boiling point, depression in freezing point is also directly related
to molality ‘m’.
∆Tf = 1000 x kf x m2 / M2 x m1
Where,
m2 = mass of solvent in g
M1 = mass of solvent in kg
The flow of solvent molecules through the semipermeable membrane can be stopped
if some extra pressure is applied from the solution side. This pressure that prevents
the flow of solvent is called the osmotic pressure of the solution.
If m2 is the weight of solute and M2 molar mass of solute, then n2= m2/M2
ℼ = W2 RT / M2V
Thus, by knowing the values of ℼ,w2, T and V, we can calculate the molar mass of
the solute.
Different Solutions
Isotonic solution: Two solutions having the same osmotic pressure at a given
temperature are known as isotonic solutions. When such solutions are separated by a
semi-permeable membrane, then there is no osmosis.
Hypotonic solution: A hypotonic solution has a lower osmotic pressure than that of the
surrounding, i.e., the concentration of solute particles is less than that of the
surrounding. If the hypotonic solution is separated by a semipermeable membrane,
then water moves out of the hypotonic solution.
Hypertonic solution: A hypertonic solution has a higher osmotic pressure than that of
the surrounding, i.e., the concentration of solute particles is more than that of the
surrounding. If the hypertonic solution is separated by a semipermeable membrane,
then water moves inside the hypertonic solution.
To determine the molar mass, the osmotic pressure method has an advantage over
other methods as pressure measurement is around room temperature. It is
particularly useful for the determination of the molar mass of biomolecules as they
are unstable at higher temperatures.
Solution:
∆Tb = 0.8
⇒ T0b-Tb = 0.8
=100.80 0C
2. A solution of CaCl2 was prepared by dissolving 0.0169 g in 1 kg of distilled
water (molar mass of Ca2+= 41g mol– and Cl= 35.5gmol–). The molal depression
constant of water is 2kg mol–. The depression in the freezing point of the
solution is:
Solution:
Kf = 2 kg mol–
Given,
∆Tf = i x 1000X Kf x m2 / M2 x m1
= 9× 10-4
3. Hexane and heptane were mixed to form an ideal solution. At 100 0C, the
vapour pressure of two liquids (Hexane and heptane) are 190 kPa and 45 kPa,
respectively. What will be the vapour pressure of the solution obtained by
mixing 25 g of hexane and 35 g of heptane?
Solution :
𝜒1 = n1 / n1 + n2
𝜒1 = 0.45
𝜒2 = 1 – 0.45
𝜒2 = 0.55
P = P01𝜒1 +P02𝜒2
= 1900.45 + 450.55
= 110 kPa
4. Which of the following effects is observed on adding non-volatile solute to a
solvent?
Solution: Option d
In a pure solvent, the entire surface is occupied by the molecules of the solvent. If a
non-volatile solute is added to the solvent, the surface now has both solute and
solvent molecules; thereby fraction of the surface covered by solvent molecules gets
reduced. Since the vapour pressure of the solution is solely due to the solvent alone,
at the same temperature, the vapour pressure of the solution is found to be lower
than that of the pure solvent.
Solution:
M2 = W2 RT / ℼ V
= 50381 g mol–