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DSE2

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0% found this document useful (0 votes)
34 views4 pages

DSE2

Uploaded by

Ritesh Meher
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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+3(5th Sem)- Chem (H)

DSE II (NC)

2021
Time: 3 hours
FullMarks 60
The figures in the right-hand margin indicate marks.

Answer all questions.

1. Fill in the blanks 1x8 8


(a) Prevention of waste or by product is the
principle of .

(b) Supercritical CO, is used as in


Green Chemistry.
(c) The example of addition reaction-atom
economy is. .rearrangement.
(d) In green chemistry ehtyl ammonium nitrate is
Used as. solvent.

(e) Complete the reaction in green systhesis


O

OCHOCH +KOH 2 , ?
C

of
use of catalytic reagent and designing
RQ-18/1 (Turn over)
reaction is
solid phase
( n green synthesis,
I
reaction.
known as
is taken as
(g) In Strecker synthesis,
reaction.
alternative in green
example of
(h) Saponification is an
reaction in green synthesis.

within 2-3 sentences


2. Answer any eight questions
1x8 12
each
limitations of the goal of Green
(a) Explain the
Chemistry
What do meant by atom Economy ?
(b)
solvents" with suitable
(c) Explain "green
examples.
(d) Write note on immobilized solvent.

(e) Discuss safer route to cyclohexanol.


() Explain bio-ethanol in Green Chemistry.

(g) Write briefly about inherent safer design


greener.
(h) How can adipic acid is prepared by Green
Synthesis ?
Explain the hydrolysis of methyl benzoate to
benzoic acid by micro assisted reaction.
) Write the green synthesis of poly lactic acid
from corm.
RQ-18/1 (2)
Contd.
3. Explain, brief, any eightquestions within 75 words
each 2x8 16
(a) Goais of Green Chemistry
(b) Safer solvents and auxiliaries.
(c) Blocking and Protection groups.
(d) Designing of biodegradable products.
(e) Green synthesis of Urethane.
( Microwave assisted reaction and oxidation
of toluene.
reaction and
(g) Ultrasound assisted
esterification.
(h) Synthesis of azo pigment.
) Bio-diesel.

) Combinatorial green chemistry.


4. Answer all questions with 500 words:
6x4 24

(a) Define green chemistry ? Explain what is the


need of green chemistry?
OR

Discuss the principles of green chemistry


with special reference to designing green
synthesis process.
(b) What do you meant by energy efficient
process for synthesis ? Discuss briefly the

RQ-18/1 (3) (Turn over)


DIOdegredable product for chemically sefer
substances
OR

Explain the development of green analytical


the
techniques to prevent and control
generation of hazardous substances.
(c)Write the green synthesis any three ofthe
following
() Catechol
(i) Hofmann elimination
(ii) Diels-Alder reaction

(iv) Paracetamol
() Bimmons-Smith reaction
the
Write short notes on any three of
(d)
following
() Marine antifoulant

(ii) Fully recycle carpet"


(ii) Biogas
in green
(iv) Oxidizing and reducing agent
chemistry
C
() Surfactants for CO

RQ-18/1 (2,100) (4 )+3(5th Sem)-Chem (H)


DSE-I (NC)

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