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CHEMISTRY
IUPAC NOMENCLATURE
 Exercise - 01
1. The correct structure of 2,6-dimethyl-dec-4-ene 7. The IUPAC name of the compound having the
is [NEET 2021] formula CH ≡ C − CH = CH2 is [AIPMT 2009]
(1) 3-butene-1-yne
(1) (2)
(2) 1-butyn-3-ene
(3) but-1-yne-3-ene
(3) (4) (4) 1-butene-3-yne

8. The state of hybridisation of C2, C3, C5 and C6 of

2. How many (i) sp2 hybridised carbon atoms and the hydrocarbon, [AIPMT 2009]
(ii)  bonds are present in the following
compound? [NEET 2020]

(1) 7, 5 (2) 8, 6
(3) 7, 6 (4) 8, 5 is in the following sequence
(1) 𝑠𝑝, 𝑠𝑝3, 𝑠𝑝2 and 𝑠𝑝3
3. The number of sigma (𝜎) and pi (𝜋) bonds in (2) 𝑠𝑝3, 𝑠𝑝2, 𝑠𝑝2 and 𝑠𝑝
pent-2-en-4-yne is [NEET 2019] (3) 𝑠𝑝, 𝑠𝑝2, 𝑠𝑝2 and 𝑠𝑝3
(1) 8𝜎-bonds and 5𝜋-bonds (4) 𝑠𝑝, 𝑠𝑝2, 𝑠𝑝3 and 𝑠𝑝2
(2) 11𝜎-bonds and 2𝜋-bonds
(3) 13𝜎-bonds and no 𝜋-bonds
(4) 10𝜎-bonds and 3𝜋-bonds 9. In the hydrocarbon [AIPMT 2008]

4. Which of the following molecules represents the

the state of hybridisation of carbons 1,3 and 5 are
order of hybridization 𝑠𝑝2, 𝑠𝑝2, 𝑠𝑝, 𝑠𝑝 from left
to right atoms? [NEET 2018] in the following sequence
(1) CH2 = CH − CH = CH2 (1) 𝑠𝑝2, 𝑠𝑝, 𝑠𝑝3 (2) 𝑠𝑝, 𝑠𝑝3, 𝑠𝑝2
(2) CH2 = CH − C ≡ CH 2
(3) 𝑠𝑝, 𝑠𝑝 , 𝑠𝑝 3
(4) 𝑠𝑝3, 𝑠𝑝2, 𝑠𝑝
(3) CH ≡ C − C ≡ CH
(4) CH3 − CH = CH − CH3 10. The correct order regarding the electronegativity
of hybrid orbitals of carbon is [AIPMT 2006]
5. The structure of isobutyl group in an organic
compound is [NEET 2013] (1) 𝑠𝑝 > 𝑠𝑝2 < 𝑠𝑝3
(2) 𝑠𝑝 > 𝑠𝑝2 > 𝑠𝑝3
(1) (3) 𝑠𝑝 < 𝑠𝑝2 > 𝑠𝑝3
(4) 𝑠𝑝 < 𝑠𝑝2 < 𝑠𝑝3
(2)

(3) 11. Names of some compounds are given. Which one

is not correct in IUPAC system? [AIPMT 2005]
(1)
(4)

(2)
6. The correct IUPAC name of the compound
(3)
is [AIPMT 2011]

(1) 3-ethyl-4-ethenylheptane
(2) 3-ethyl-4-propylhex-5-ene (4)
(3) 3-(1-ethyl propyl) hex-1-ene
(4) 4-ethyl-3-propylhex-1-ene

[1]
12. Name of the compound given below 17. Which nomenclature is not according to IUPAC
[AIPMT 2003] system? [AIPMT 2012]
(1)

(2)
(1) 2, 3-diethylheptane
(2) 5-ethyl-6-methyloctane
(3) 4-ethyl-3-methyloctane (3)
(4) 3-methyl-4-ethyloctane

13. IUPAC name of the following is [AIPMT 2002] (4)

CH2 = CH − CH2 − CH2 − C ≡ CH
(1) 1, 5-hexenyne
(2) 1-hexene-5-yne
18. IUPAC name of the compound [AIPMT 1998]
(3) 1-hexyne-5-ene
(4) 1, 5-hexynene is

14. The IUPAC name of [AIPMT 1996] (1) trans-3-iodo-4-chloro-3-pentene

(2) cis-2-chloro-3-iodo-2-pentene
(3) trans-2-chloro-3-iodo-2-pentene
(4) cis-3-iodo-4-chloro-3-pentene
(1) 1,3-isopropyl-3-methyl propane
(2) 2,3,6-trimethyl heptane 19. Which of the following possesses a sp-carbon in
(3) 2,5,6-trimethyl heptane its structure? [AIPMT 1989]
(4) 2,6,3-trimethyl heptane (1) CH2 = CCl − CH = CH2
(2) CCl2 = CCl2
15. For the compound which of the following IUPAC (3) CH2 = C = CH2
'names is correct? [AIPMT 1994] (4) CH2 = CH − CH = CH2

20. The IUPAC name of [AIPMT 1992]

(1) 2-methyl-3-ethyl pentane

(2) 3-ethyl-2-methyl pentane
(3) 2-ethyl-3-methyl pentane (1) 4-hydroxy-1-methyl pentanal
(4) 3-methyl-2-ethyl pentane (3) 4-hydroxy-2-methyl pent-2-en-1-al
(3) 2-hydroxy-4-methyl pent-3-en-5-al
16. 2-methyl-2-butene will be represented as (4) 2-hydroxy-3-methyl pent-2-en-5-al
[AIPMT 1992]
21. The IUPAC name of the compound
[AIPMT 1992]
(1)
(2)

(3)
(1) 3-keto-2-methylhex-4-enal
(2) 5-formylhex-2-en-3-one
(4) (3) 5-methyl-4-oxohex-2-en-5-al
(4) 3-keto-2-methylhex-5-enal

[2]
22. The IUPAC name of is [NEET 2017] 24. The correct IUPAC name of the following
compound [NEET 2022]

(1) 3,4-dimethylpentanoyl chloride

(1) 6-bromo-4-methyl-2-chlorohexan-4-ol
(2) 1-chloro-1-oxo-2, 3-dimethylpentane
(2) 1-bromo-5-chloro-4-methylhexan-3-ol
(3) 2-ethyl-3-methylbutanoyl chloride
(3) 6-bromo-2-chloro-4-methylhexan-4-ol
(4) 2,3-dimethyl pentanoyl chloride
(4) 1-bromo-4-methyl-5-chlorohexan-3-ol
23. The incorrect IUPAC name is [AIPMT 2006]
25. The number of σ bonds, π bonds and lone pair of
(1)
electrons in pyridine, respectively are:
[NEET 2023]
(1) 12, 2, 1 (2) 11, 2, 0
(2) (3) 12, 3, 0 (4) 11, 3, 1

26. The given compound is an example of

__________. [NEET 2023]
(3)

(4)

(1) vinylic halide (2) benzylic halide

(3) aryl halide (4) allylic halide

Exercise - 02
1. Which one is not correct for a homologous series- 5. IUPAC name for given structure is
(1) All members have same general formula COOH
(2) All members have same chemical properties
COOH
(3) All members have same physical properties
(1) 2-Ethyl-2-carboxypentanoic acid
(4) All members have same functional group (2) 2-Carboxy-2-ethylpentanoic acid
(3) 2-Ethyl-2-propylpropanedioic acid
2. How many carbon atoms are present in third (4) 2-Propyl-2-ethylpropanedioic acid
homologue of Dimethyl ether? 6. The correct IUPAC name of the compound
(1) 1 (2) 2
(3) 3 (4) 4

3. Which of the following is not a heterocyclic is :-

(1) 4-Ethyl-3-propylhex-1-ene
compound? (2) 3-Ethyl-4-ethenylheptane
(1) Thiophene (2) Furan (3) 3-Ethyl-4-propylhex-5-ene
(3) Toluene (4) Pyridine (4) 3-(1-ethylpropyl) hex-1-ene

4. The correct triad of molecular formula, bond line 7. The structure of the compound whose IUPAC
name is 3-Ethyl-2-hydroxy-4-methylhex -3-en-5-
notation and IUPAC name is :-
ynoic acid is :-
OH
(1) C2H4O, O 1, 2-Epoxyethane
COOH COOH
(1) (2)
(2) C3H4O, O Cyclopropenone
OH
OH
(3) C4H6, 1,3-Butadiene OH
(4) C4H8, Cyclobutene (3) COOH (4) COOH

[3]
8. Which of the following compound has wrong 12. The common and IUPAC names for the group,
IUPAC name? (CH3)2CHCH2–respectively are
(1) CH3CH2CH2COOCH2CH3→ (1) Isobutyl and 2-methylpropyl
(2) Isobutyl and 1-methylpropyl
Ethylbutanoate
(3) tert-Butyl and 1,1-dimethylethyl
(2) CH3— CH — CH2 — CHO→3-Methylbutanal (4) sec-Butyl and 2-methylpropyl
CH3
13. Which alkane would have only the primary and
(3) CH3— CH — CH — CH3→2-Methyl-3-butanol tertiary carbon?
OH CH3 (1) Pentane
O (2) 2-Methylbutane
(3) 2,2-Dimethylpropane
(4) CH3— CH — C — CH2 — CH3→2-Methyl-3- (4) 2,3-Dimethylbutane
CH3 14. The IUPAC name of the compound is :
pentanone O

O
Cl
9. The IUPAC name of is :-
O
O
(1) Cyclobutanedioic anhydride
(1) 3,4-Dimethylpentanoyl chloride
(2) Butanedicarboxylic anhydride
(2) 1-Chloro-1-oxo-2,3-dimethylpentane (3) Cyclobutanedicarboxylic anhydride
(3) 2-Ehtyl-3-mehtylbutanoyl chloride (4) Butanedioic anhydride
(4) 2,3-Dimethylpentanoyl chloride
15. The correct IUPAC name of compound is :
10. Match the column-I and column-II O
Column-I Column-I Cl
(a) CH 3— CH 2 — CH — NH 2 (p) Isobutyl
amine O
CH3 (1) 1-Chloropentane-1, 4-dione
(2) 4-Chlorocarbonylbutan-2-one
(b) CH3— CH — CH2 — NH2 (q) tert. butyl (3) 4-Oxopentanoyl chloride
amine (4) 3-Oxobutanecarbonyl chloride
CH3
(c) CH3–CH2–CH2–CH2–NH2 (r) sec. butyl 16. The correct IUPAC name of the compound is :
amine
(d) CH3 (s) n Butyl
amine OH OH
CH3 — C — NH 2 (1) 4-Ethyl-3-methylnonane-2, 8-diol
(2) 6-Ethyl-7-methylnonane -2, 8-diol
CH3
(3) 5-Ethyl-1, 6, 7-methylnonane -1, 7-diol
Correct option is (4) 4-Ethyl-2-methylnonane -2, 7-diol
(1) (a→p), (b→r), (c→q), (d→s)
17. The correct IUPAC name of the compound is :
(2) (a→p), (b→r), (c→s), (d→q) OH
(3) (a→r), (b→p), (c→s), (d→q)
(4) (a→r), (b→q), (c→s), (d→p)

11. Correct Common name of O

(1) 3-(1-Methylethenyl)-4-hydroxypentan-2-
CH3— C — O — C — CH2 — CH3 is
one
O O (2) 3-(1-Hydroxyethyl)-4-methylpent-4-en-2-
(1) Propionic acetic anhydride one
(2) Acetic propionic acid (3) 3-(1-hydroxymethyl)-4-methylenepentan-2-
(3) Valeric anhydride one
(4) 3-(1-Oxoethyl) -4-methylpent-4-en-2-ol.
(4) Acetic propionic anhydride

[4]
18. Ethoxyethene is written as follows, 20. In which of the following cyclic chain is the main
chain ?
H2C = CH –O – CH2 – CH3.
The structure of 2-Chloro-1-ethoxyethene (1) (2)
(incorrect name) with correct numbering will be
(3) (4)
1 2
(1) H2C = CH – O – CH2 – CH2 – Cl
1 2 21. In which of the following side chain (acyclic
(2) CH2 = CH – O – CH – CH3 chain) is the main chain.
Cl
2 1
(3) H2C = C – O – CH2 – CH2 – Cl (1) (2)

Cl
1 2 (3) (4)
(4) Cl – CH = CH – O – CH2 – CH3

19. The correct IUPAC name of the following C2 H5 – O

compound is : 22. The IUPAC name of C = O is
CH3 – CH
H NO2
CH3
F – C – C – Et (1) Ethoxymethanone
(2) Ethyl-2-methylpropanoate
I Br (3) Ethoxypropanone
(1) 1-Bromo-1-ethyl-2-fluoro-2-iodo-1- (4) 2-Methylethoxypropanone

nitroethane. 23. The IUPAC name of the following compound is:

CHO
(2) 3-Bromo-4-fluoro-4-iodo-3-nitrobutane.
(3) 2-Bromo-1-fluoro-1-iodo-2-nitrobutane.
(4) 3-Fluoro-1-iodo-2-bromo-2-ethyl-2- Br OH
(1) 5-Bromo-3-hydroxybenzenecarbaldehyde
nitroethane. (2) 3-Bromo-5-formylphenol
(3) 3-Bromo-5-hydroxybenzencarbaldehyde
(4) 1-Bromo-3-formyl-5-hydroxybenzene
Exercise - 03
2. Which of the following compound is unsaturated
1.
hydrocarbon?
I II III

Incorrect statement for the above structure: (1)

(1) I, II & III have CnH2n – 2 general formula. (2) CH3–CN

(2) I, II & III have same empirical formula.

(3) I, II are identical and homologous of (3)

compound III.
(4) All of these
(4) I, II & III have same molecular formula.

[5]
3. The correct IUPAC name of the following 7. IUPAC name of given compound is:
compound is:

(1) 3- Carbonitrile-3-methylbutanal
(2) 2-Methyl-4-oxobutanecyanide
(3) 3-Cyanobutanal
(1) 1-Bromo-1-ethyl-2-fluoro-2-iodo-1- (4) 2-Methyl-4-oxobutanenitrile
nitroethane.
(2) 3-Bromo-4-fluoro-4-iodo-3-nitrobutane. 8. Total number of heteroatoms present in the
(3) 2-Bromo-1-fluoro-1-iodo-2-nitrobutane. following compound is/are :
(4) 1-Fluoro-1-iodo-2-bromo-2-ethyl-2-ethane CH3
nitroethane.
N
4. Which of the following is a correct priority order
of functional groups? N
(1) 2 (2) 3
(1) (3) 1 (4) 4

9. How many carbons are in simplest alkyne having

(2) two side chains?
(1) 5 (2) 6
(3) 7 (4) 8
(3)
10. IUPAC name of neopentyl group is:
(4) (1) 2,2-dimethylbutyl
(2) 2,2-dimethylpropyl
(3) 1,1-dimethylbutyl
5. The correct IUPAC name of the given compound
(4) 1,2-dimethylpropyl
is:
11. The third member of the family of alkenynes has
the molecular formula –
(1) 3-Chloro-1-fluoro-1-iodo-4-methoxybut-1- (1) C6H6 (2) C5H6
en-3-yne (3) C6H8 (4) C4H4
(2) 4-Methoxy-2-chloro-1-fluoro-1-
iodobutenyne 12. The Cl–C–Cl bond angle in 1,1,2,2–tetrachloro
(3) 3-Chloro-4-fluoro-4-iodo-1- ethene and tetrachloromethane respectively are:-
methoxybutenyne (1) 120° and 109.5° (2) 90° and 109.5°
(4) 2-Chloro-1-fluoro-1-iodo-4- (3) 109.5° and 90° (4) 109.5° and 120°
methoxybutenyne
13. Which of the following is correctly matched:
6. The IUPAC name of the compound is: (1) Acrylonitrile CH2 = CHCN
(2) Allyl chloride CH2 = CH – CH2Cl
(3) s-Butyl group CH3 –CH–C2H5

(4) All the above

14. The IUPAC name for isobutyl chloride is:-

(1) 4-bromo toluene (1) 2–Methyl–2–chlorobutane
(2) 1-bromo-4-methyl benzene (2) 2–Chloro–2–methylbutane
(3) 1-bromo toluene (3) 1–Chloro–2–methylpropane
(4) 2–Methyl–3–chloropropane
(4) Both (1) and (2)

[6]
 OH 21. The IUPAC name of
15. The IUPAC name of is: CH2 – CHO
OH OHC – CH2 – CH2 – CH – CH2 – CHO is :
(1) But-2-ene-2,3-diol (1) 4,4-Di-formylmethyl-butanal
(2) Pent-2-ene-2,3-diol
(2) 2-Formylmethyl-butane-1,4-dicarbaldehyde
(3) 2-Methylbut-2-ene-2,3-diol
(4) Pent-3-ene-3,4-diol (3 Hexane-3-acetal-1,6-dial

16. The IUPAC name of the given compound is - (4) 3-formylmethylhexane-1,6-dial

CH–CH3
22. The IUPAC name of :-
HCC–CC–C–CH2–CH3 O
(1) 5-Ethyl-5-heptene-1,3-diyne C–O–CH2CH3 is:
(1) Ethylcyclohexanoate
(2) 3-Ethyl-2-heptene-4,6-diyne
(2) Cyclohexylpropanoate
(3) 5-Ethenyl-1,3-heptadiyne
(4) 3-Ethenyl-4,6-heptadiyne (3) Ethoxycyclohexylketone
(4) Ethylcyclohexanecarboxylate

Cl F
17. The IUPAC name of the compound F is: 23. The IUPAC name of H2N OCH3 is :-
Br F
(1) 1–methoxy–4–aminobenzene
(1) Haloethane
(2) 1,1,1-Trifluoro-2-bromo-2-chloroethane (2) Amino phenyl methyl ether
(3) 2-Bromo-2-chloro-1,1,1-trifluoroethane (3) 4–methoxyaniline
(4) 1-Bromo-1-chloro-2,2,2-trifloroethane (4) 4-Aminoanisole

O 24. Examine the following structures :

O
CH3 CH3
18. The IUPAC name of is
O H (A) CH3–C–OH (B) CH3–C–NH2
(1) Acetic anhydride CH3 CH3
(2) Formylethanoate
(3) Butane–2,4–dione Which of the following statement is correct:
(4) Ethanoic methanoic anhydride (1) A is tertiary alcohol while B is tertiary amine
(2) A is primary alcohol while B is primary amine
19. The correct IUPAC name of given compound is - (3) A is tertiary alcohol while B is primary amine
CH3–C==C–CH3 (4) A is primary alcohol while B is tertiary amine
H5C2 C2H5
25. IUPAC name of the compound is -
(1) 1,2-Diethylbutane
(2) 2-Ethyl-3-methylpentane CH3
(3) 3,4-Dimethyl-3-hexene CH3 – C – COOC2H5
(4) 2,3-Dimethyl-2-hexene
NO2
20. The IUPAC name of the given compound is -
(1) Ethyl-2-methyl-2-(m-
O OH
nitrophenyl)propanoate
HO–C–CH2–C – CH2–C–OH (2) Ethyl-2-methyl-2-(o-
COOH O nitrophenyl)propanoate
(1) 3-Carboxy-3-hydroxybutanedioic acid (3) Ethyl-2-methyl-2-(3-
(2) 2-Hydroxypropane-1,2,3-tricarboxylic acid nitrophenyl)propanoate
(3) 3-Hydroxybutanedioic acid (4) Ethyl-2-methyl-2-(3-nitrophenyl)propanoic
(4) 2-Bis(carboxymethyl)-2-hydroxyethanoic acid acid

[7]
26. IUPAC name of the following compound is : 31. The IUPAC name of the given compound is -
O CHO CONH2

CH3–CH CH – C – CH2Br CH3 – CH – CH –– CH – CH – COOH

O Br COCl
C (1) 2-Bromo-4-carbamoyl-5-chloroformyl-3-
H3C CH3 formylhexanoic acid
(1) 1-Bromo-3,5-epoxy-4,4-dimethyl-2- (2) 5-Bromo-3-carbamoyl-2-chloroformyl-4-
formylhexanoic acid
hexanone
(3) 4-Formyl-2-chloroformyl-5-carbamoyl-5-
(2) 1-Bromo-3,3-dimethyl-2-oxo-2-hexanone bromohexanoic acid
(3) 1-Bromo-3,3-dimethylacetone (4) 2-Chloroformyl-3-carbamoyl-4-formyl-5-
bromohexanoic acid
(4) 1-Bromo-4,4-dimethyl-5-oxo-hexanone
32. Write the correct IUPAC name of the following
bond line formula:
27. The structure of 2-butenyl radical is
(1) CH3–CH=C–CH3 CHO

(2) CH3–CH=CH–CH2– (1) 4-Methyl-3-(1-methylpropyl)pent-3-enal

(3) CH3–CH2–C=CH2 (2) 3-Isopropenyl-4-methylhexanal
(3) 3,5-Di-methylhex-4-en-al
(4) CH2=CH–CH–CH3 (4) None of the above
33. Which of the following pairs of trivial names and
28. The IUPAC name of the given compound is: IUPAC names are incorrectly matched-
(1) Isohexane 2-Methylhexane
O
(2) Isooctane 2,2,4-
(CH3)2CH(CH2)2–C–N(CH3)2 Trimethylpent
(1) N,N,4-Trimethylpentanamide ane
(2) Dimethylamino-4-methylpentanone (3) Isobutyraldehyd 2-Methylpropanal
(3) N,N-Dimethylamino-4-methylpentanamide e
(4) 2-Methyl-5-oxodimethylpentanamine (4) Isobutylene 2-Methylpropene

OH
29. The IUPAC name of the given compound is -
CH3 O
34. The IUPAC name of is -
CH – O – C – CH3
O H
(1) 1-Phenyl-1-acetyloxyethane (1) 2-Formyl-3-hydroxy-4-methylenepentane
(2) 1-Acetoxyethylbenzene (2) 4-Formyl-2-methyl-1-penten-3-ol
(3) [1-Phenylethyl]ethanoate (3) 3-Hydroxy-2-methyl-4-methylenepentanal
(4) 3-Hydroxy-2,4-dimethyl-4-pentenal
(4) 1-[Methylbenzyl]acetate
35. The IUPAC name of the given compound is –
COOH O
30. The IUPAC name of is - Me
COOH
(1) 6-Carboxy-2,3-dimethyl-4-heptenoic acid Me
(2) 2,3,6-Trimethyl-1-heptene-1,7-dioic acid
(1) 2,4–Dimethylcyclohexa–2,4–dienone
(3) 2,5,6-Trimethyl-3-heptenedioic acid (2) 2,4–Dimethylcyclohexa–2,5–dienone
(4) 6-Carboxy-2,5-dimethyl-3-heptenoic acid (3) 2,5–Dimethylcyclohexa–2,4–dienone
(4) 2,5–Dimethylcyclohexa–2,5–dienone

[8]
36. The IUPAC name of the following structure is - 42. In which of the following compounds, the
Principle Carbon (PC) Chain has been correctly
numbered :-
7 6 5 4 3 2 1
(1) CH3–CH2–CH––CH–CH2–CH2–CH3
(1) 4-Ethyl-5-ethenyl-2,7-dimethyloctane C2H5 CH3
(2) 4-Ethyl-6-methyl-3-(2-methylpropyl)hept-1-ene 1 2 3
(3) 3-(1-Ethyl-3-methyl butyl)-5-methyl hex-1-ene (2) CH3–CH2–C=CH–CH3
4 5
(4) None of the above CH2– CH3
5 4 3 2 1
O (3) CH3–CH2–CH–CCH
OH
OH CH2– CH2–CH3
37. The IUPAC name of is-
CH3
O
(1) 4-Carboxy-5-methylheptanoicacid (4) CH3–C–CH=CH–CHO
(2) 1,3-Dicarboxy-4-methylhexane 5 4 3 2 1
CH3
(3) 4-(1-Methylpropyl)pentanedioicacid
(4) 2-Propylpentanedioicacid 43. The IUPAC name of [(CH3)3C]4C is -
(1) Tetra-t-butylmethane
CH2OH (2) 3,3-Bis-(1,1-dimethylethyl)-2,2,4,4
38. The IUPAC name for is tetramethylpentane
OH
(3) Tetrakis(1,1-dimethylethyl)methane
(1) Orthohydroxymethylphenol (4) Tetraneobutylmethane
(2) 2-Hydroxybenzylalcohol
44. The IUPAC name of CH3 is -
(3) Salicylalcohol
(4) 2-Hydroxymethylphenol (1) 3-Cyclobutylcyclopropane
(2) 1-Cyclopropyl-3-methylcyclobutane
(3) 1,3-Cyclopropylmethylcyclobutane
39. The IUPAC name of N is - (4) 2-Methylbicyclo[4,3,0]heptane
(1) N-Ethyl-N,2-dimethyl-4-hexanamine
(2) N,4-Diethyl-N,2-dimethyl-4-butanamine 45. The derived name of isovaleric acid is :–
(1) Ethylmethylacetic acid
(3) N-Ethyl-N,5-dimethyl-3-hexanamine
(2) Isopropylacetic acid
(4) 3-Ethylmethylamino-5-methylhexane
(3) Trimethylacetic acid
(4) All of the above
40. Give IUPAC name of the following :
CH2CHO 46. The IUPAC name of the following structure is -
Br COOH

(1) 2-(2-Bromophenyl)ethanal Cl
(2) 3-Bromophenylethanal (1) 3-Chloro-2-(1-propenyl)-2,4-hexadienoic acid
(3) 2-Bromobenzeneethanal (2) 4-Chloro-5-(1-propenyl)2,4-hexadienoic acid
(4) Bromobenzenecarbaldehyde (3) 3-Chloro-2,3-di(1-propenyl)propanoic acid
(4) 4-Carboxy-5-chloroocta-2,4,6-octatriene
41. Which is not the first member of given
homologous series – 47. The IUPAC name of the given compound is:
(1) Alkadiene CH2=C=CH2 CH2–CN
(2) Alkenyne HCC–CH=CH2
(3) Ethyl ester CH3–CH2–O–C–CH3
CH–CN

O CH2–CN
O (1) 1,2,3-Tricyanopropane
(2) Propane-1,1,1-tricarbylamine
(4) Ketone CH3–C–CH3 (3) Propane-1,2,3-tricarbonitrile
(4) 3-Cyanopentanedicyanide

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 56. The IUPAC name of the given compound is :-
48. The IUPAC name of HO is:-
O
(1) 2-Acetyl-2-buten-1-ol
(2) 3-[Hydroxymethyl]-3-penten-2-one
(3) 3-Ethylidene-4-hydroxy-2-butanone
(1) 3–Methyl–2–cyclohexenone
(4) 3-Acetyl-2-buten-4-ol
(2) 2–Methyl–3–cyclohexenone
49. How many  &  bonds are present in CH3COOH: (3) 1–Oxo–3–methylcyclohexene
(1) 1, 7 (2) 5, 2 (4) 2–Oxo–6–methylcyclohexene
(3) 7, 1 (4) 3, 2
57. The IUPAC name of the compound having
50. Number of bond angles of 109º28’ and 120º in structure C2H5 – C –– CH – CH3 is :-
the structure CH2 = CH – CH3 respectively are :
(1) 6, 6 (2) 6, 7 CH2 CH3
(3) 8, 6 (4) 6, 3 (1) 3-Methyl-2-ethyl-1-butene

51. The geometry of the given compound is : (2) 2-Ethyl-3-methyl-1-butene

CH2 = CH – CH = CH2 (3) 3-Methyl-3-methyl-1-butene
(1) Tetrahedral (2) Linear (4) Ethylisopropylethene
(3) Planar (4) Pyramidal
58. Which of the following compound is wrongly
52. Which of the following is the triad of a
homologous series :- named according to IUPAC system :-
(1) (CH3)2NH, CH3NHCH2CH3, (1) CH3CH2CH2CHCOOH ;
H5C2NHC2H5 Cl
(2) C2H5OH, (CH3)2CHOH, (CH3)3COH 2-Chloropentanoicacid
(3) CH2=CH2, CH3–CH=CH2,
(2) CH3C  CCHCOOH
C2H5–CH=CH2
(4) All the above CH3
2-Methylhex-3-enoicacid
53. The IUPAC name of following polyfunctional
(3) CH3CH2CH=CHCOCH3
compound is:-
Hex-3-en-2-one
O
(4) CH3–CHCH2CH2CHO
OHC– –COOH
CH3
(1) 2,4-Dioxocyclohexanoic acid 4-Methylpentanal
(2) 2,4-Dioxocycloheptanoic acid
(3) 4-Formyl-2-oxocyclohexane-1-carboxylic acid
(4) 2,4-Dioxo cyclohexane-1-carboxylic acid 59. The IUPAC name of is :-
54. The IUPAC name of Cl – C – OC2H5 is :- (1) 4-Ethyl-3-methylhexane
֪ O (2) 3-Ethyl-4-methylhexane
(1) Ethoxyformylchloride (3) 3-Methyl-4-ethylhexane
(2) Ethoxymethanoylchloride (4) All of the above
(3) Ethylchloromethanoate
(4) Ethoxycarbonylchloride 60. The common name of given ester is :-
CH3 CH3
55. The IUPAC name of given compound is :-
O CH3 – CH – C – O – C – CH3
CH3 – CH – C – CH – OCH2CH3 O CH3
OCH3 CH3 (1) Neobutylisobutyrate
(1) 2-Ethoxy-4-methoxypentan-3-one (2) t-Butyl-n-butyrate
(2) 2-Methoxy-4-ethoxypentan-3-one
(3) t-Butylisobutyrate
(3) 2-Ethoxy-4-methoxypentan-2-one
(4) 2-Ethoxy-3-methoxypentan-3-one (4) Isobutylisobutyrate

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61. An unsaturated compound have :- 67. The name for the structure
(1) Carbon - carbon double bond CH2—CH2
(2) Carbon - carbon triple bond H2C CH—C—Cl :
CH2—CH2
(3) Carbon - carbon double or triple bond
(4) Carbon - carbon single bond O

62. What is not true about homologous series :- (1) Cyclohexanoylchloride

(1) All the members have similar chemical (2) Cyclohexanecarbonylchloride
properties
(3) 1-Chlorocyclohexanal
(2) They have identical physical properties
(4) Chlorocyclohexylmethanol
(3) They can be represented by same general
formula
(4) Adjacent members differ in molecular mass 68. Which IUPAC name is correct?
by 14 (1) Methylbutane
(2) Ethylbutanoicacid
63. No. of hetero atoms (other than C) present in the
following heterocyclic compound is- (3) Ethylpentanone
N O (4) All of these

O NH 69. Which is incorrect IUPAC name?

O (1) Dimethylbutane
(1) 3 (2) 2 (2) Trimethylamine
(3) 1 (4) zero
(3) 2-Cyanobutane
(4) All of the above
64. Considering the state of hybridization of carbon
atoms, find out the molecule among the following
70. Correct IUPAC name for a compound is:
in which all Carbon atoms are linear?
(1) CH3 – CH2 – CH2 – CH3 (1) 2-Chloro-4-bromopentane
(2) CH3 – CH = CH – CH3 (2) 2-Bromo-4-chloropentane
(3) CH3 – C  C – CH3 (3) 4-Bromo-2-chloropentane
(4) CH2 = CH – CH2 – C  CH (4) 1-Bromo-3-chloro-1,3-dimethylpropane
65. The compound having only primary hydrogen
atom is :- 71. Statement I : CH2=CH–CH=CH2 is a planar
(1) Isobutylene compound.
(2) 2,3-Dimethyl-1-butene Statement II : It has 9 bonds and 2 bonds.
(3) Cyclohexane
(1) Statement I and Statement II both are
(4) Propene
correct
66. Correct IUPAC name of the given compound is: (2) Statement I is incorrect but Statement II is
correct

O (3) Statement I is correct but Statement II is

incorrect
(1) Oxirane
(2) Ethylene oxide (4) Statement I and Statement II both are
(3) Epoxyethane incorrect
(4) All of these

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72. Statement I: The IUPAC name of 74. Statement I: The IUPAC name of
CH3–CH=CH–CC–H is pent-3-en-1-yne CH3 – CH – C – CH – CH3
but not pent-2-en-4-yne. H3C – O O OCH2CH3
Statement II: Lowest locant rule for multiple is 2-ethoxy-4-methoxypentan-3-one.
bond is preferred. Statement II : Larger substituents are assigned
(1) Statement I and Statement II both are lower locants.
correct (1) Statement I and Statement II both are
(2) Statement I is incorrect but Statement II is
correct
correct
(2) Statement I is incorrect but Statement II is
(3) Statement I is correct but Statement II is
correct
incorrect
(3) Statement I is correct but Statement II is
(4) Statement I and Statement II both are
incorrect
incorrect
(4) Statement I and Statement II both are
incorrect
73. Statement I: The IUPAC name for
CH3–CH2–CH–CH2––CH–CH2–CH3
75. Statement I : CHO is called
CH – CH3 Cl
CH3 cyclohexanecarbaldehyde.
Statement II : It contains six carbon atoms in the
is 5-chloro-3-ethyl-2-methylheptane but not
ring and CHO as a substituent.
3-chloro-5-isopropylheptane.
(1) Statement I and Statement II both are
Statement II: The parent carbon chain should
correct
contain more number of substituents.
(2) Statement I is incorrect but Statement II is
(1) Statement I and Statement II both are
correct
correct
(3) Statement I is correct but Statement II is
(2) Statement I is incorrect but Statement II is
incorrect
correct
(4) Statement I and Statement II both are
(3) Statement I is correct but Statement II is
incorrect incorrect
(4) Statement I and Statement II both are
incorrect

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 Answer Key
Exercise - 01
1. (1) 8. (1) 15. (2) 22. (4)
2. (3) 9. (2) 16. (2) 23. (1)
3. (4) 10. (2) 17. (1) 24. (2)
4. (2) 11. (4) 18. (3) 25. (4)
5. (1) 12. (3) 19. (3) 26. (4)
6. (4) 13. (2) 20. (3)
7. (4) 14. (2) 21. (1)

Exercise - 02
1. (3) 7. (3) 13. (4) 19. (3)
2. (4) 8. (3) 14. (4) 20. (2)
3. (3) 9. (4) 15. (3) 21. (3)
4. (3) 10. (3) 16. (1) 22. (2)
5. (3) 11. (4) 17. (2) 23. (3)
6. (1) 12. (1) 18. (4)

Exercise - 03
1. (3) 20. (2) 39. (3) 58. (2)
2. (3) 21. (4) 40. (1) 59. (2)
3. (3) 22. (4) 41. (3) 60. (3)
4. (2) 23. (3) 42. (4) 61. (3)
5. (4) 24. (3) 43. (2) 62. (2)
6. (4) 25. (3) 44. (2) 63. (1)
7. (4) 26. (1) 45. (2) 64. (3)
8. (1) 27. (2) 46. (1) 65. (1)
9. (2) 28. (1) 47. (3) 66. (3)
10. (2) 29. (3) 48. (2) 67. (2)
11. (3) 30. (3) 49. (3) 68. (4)
12. (1) 31. (2) 50. (1) 69. (4)
13. (4) 32. (1) 51. (3) 70. (2)
14. (3) 33. (1) 52. (4) 71. (1)
15. (2) 34. (4) 53. (3) 72. (1)
16. (1) 35. (4) 54. (3) 73. (1)
17. (3) 36. (2) 55. (1) 74. (3)
18. (4) 37. (4) 56. (1) 75. (3)
19. (3) 38. (4) 57. (2)

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