11-05-2024

4602CJA101021240001 JM

PART-1 : PHYSICS

SECTION-I

1) A charge Q is uniformly distributed over a long rod AB of length L as shown in the figure. The
electric field at the point O lying at a distance L from the end A is:

(A)

(B)

(C)

(D)

2) At a distance r from a point located at origin in space, the electric potential varies as V = 10r.
Find the electric field at .

(A)

(B)

(C)

(D)
None of these

3) Eight dipoles of charges of magnitude e are placed inside a cube. The total electric flux coming
out of the cube will be :

(A)

(B)

(C)

(D)
Zero

4) If earth suddenly stop rotating, then the weight of an object of mass m at equator will :
[ω is angular speed of earth and R is its radius]

(A)
Decrease by mω2R
(B)
Increase by mω2R
(C)
Decrease by mωR2
(D)
Increase by mωR2

5) Calculate the electric field at origin due to infinite number of charges as shown in figures below

(A)

(B)

(C)

(D)

6) The distance of the centres of moon and earth is D. The mass of earth is 81 times the mass of the
moon. At what distance from the centre of the earth, the gravitational force on a particle will be
zero.

(A)

(B)

(C)

(D)

7) A point dipole is kept at the origin. The potential and electric field due to this dipole on
the y-axis at a distance d are, respectively: (Take V = 0 at infinity)

(A)
(B)

(C)

(D)

8) Consider two solid spheres of radii R1 = 1m, R2 = 2m and masses M1 and M2, respectively. The
gravitational field due to sphere (1) and (2) are shown. The value of M1/M2 is:

(A)
2/3
(B)
1/3
(C)
1/2
(D)
1/6

9) Two point charges Q1 and Q2 exert a force F on each other when kept at certain distance apart. If
the charge
on each particle is halved and the distance between the two particles is doubled, then the new force
between the two particles would be

(A)

(B)

(C)
(D)

10) Two satellites A and B having masses in the ratio 4:3 are revolving in circular orbits of radii 3r
and 4 r respectively around the earth. The ratio of total mechanical energy of A to B is :

(A)
9 : 16
(B)
16 : 9
(C)
1:1
(D)
4:3

11) Two equal negative charges –q are fixed at the point (0, a) and (0, –a) on the y-axis. A charge +Q
is released from rest at the point (2a, 0) on the x-axis. The charge Q will :

(A)Execute simple harmonic motion about the origin.

(B)At origin velocity of particle is maximum
(C)Move to infinity
(D)Execute simple harmonic motion

12) Three charges Q, q and q are placed at the vertices of an equilateral triangle of side L as shown
in the figure. If the net electrostatic potential energy of the system is zero, the Q is equal to:

(A)
–0.5 q
(B)
–q
(C)
q
(D)
Zero

13) Assume that an electric field exist in space. If potential at origin is taken to be zero.
Find the potential at point (2, 3)

(A)
16 V
(B)
-16 V
(C)
-54 V
(D)
70 V

14) A charged ball hangs from a silk thread, which makes an angle θ with a large charged
conducting sheet. The surface charge density σ of the sheet is proportional to......

(A)tan θ
(B)sin θ
(C)cos θ
(D)cot θ

15) Shown in the figure is a shell made of a conductor. It has inner radius a and outer radius b, and
carries charge Q. A dipole as shown is placed at its center. Choose the correct statement.

(A)
Electric field outside the shell is the same as that of a point charge at the centre of the shell.
(B)
Surface charge density on the inner surface of the shell is zero everywhere.
(C)

Surface charge density on the inner surface is uniform and equal to .

(D)
Surface charge density on the outer surface depends on

16) A non-conducting solid sphere of radius R is charged uniformly. Electric field at a distance

from centre is 90 N/C. Then electric field at a distance outside from the surface will be

(A)80 N/c
(B)90 N/c
(C)135 N/c
(D)60 N/c

17) The escape velocity for a planet is Ve. A tunnel is dug along a diameter of the planet and a small
body is dropped into it at the surface. When the body reaches the centre of the planet, its speed will
be-

(A)
Ve
(B)

(C)
(D)
Zero

18) Figure shows a planet in an elliptical orbit around the sun S. Where is the kinetic energy of the

planet maximum?

(A)
P1
(B)
P2
(C)
P3
(D)
P4

19) A point charge Q is located just above the centre of the flat face of hemisphere as shown in
figure. The electric flux through the flat face and curved face of hemisphere are respectively

(A)

(B)

(C)

(D)

20) A line charge of uniform linear charge density passes through the centre of a imaginary
sphere of radius R as shown in figure. Then the electric flux through the sphere is
(A)

(B)

(C)

(D)
Zero

SECTION-II

1) A prism shaped imaginary structure is given. A point charge is kept as given in figure. Calculate

electric flux passing through the prism is value of n is _______ .

2) A particle of mass m0 is projected vertically upward from surface of earth with a speed of

. The maximum height of the particle from the earth surface is . [Mass of the earth Me
and R is radius of earth]. What is the value of k ?

3) Figure shows three concentric thin spherical shells A, B and C of radii a, b, c respectively. The
shells A and C are given charges 12µC and –12µC respectively and the shell B is earthed. Find the
charges appearing on the outer surfaces of B. (answer in µC)

4) In the figure electric field lines of three charges are shown. If q1 = + 8µC and q3 = –12µC what is

value of charge q2. (in µC)

5) A long cylindrical volume contains a uniformly distributed charge of density ρ Cm–3. The electric

field inside the cylindrical volume at a distance m from its axis is ______ Vm–1

6) 1000 drops of same size are charged to a potential of 1 V each. If they coalesce to form a single
drop, its potential (in volt) would be

7) The escape velocity of a body from earth's surface is ve. The escape velocity of the same body from

a height equal to 7 R from earth's surface is , find a :-

8) Two identical charged spheres are suspended by strings of equal lengths. The strings make an
angle of 30° with each other. When suspended in a liquid of density 1 g cm–3, the angle remains the
same. If density of the material of the sphere is 4/3 g cm–3, the dielectric constant of the liquid is:-

9) Two spheres of radius R & 2R having charge Q & 2Q respectively are placed far away from each

other. How much charge will flow when key 'k' is pressed ?

10) Three point charges of magnitude and are located at the vertices A,B and C
of a right angle triangle whose sides are and CA = 3cm and point A is the
right angle corner. Charge at point A experiences ______ N of electrostatic force due to the other two
charges.

PART-2 : CHEMISTRY

SECTION-I

1) For a reaction, the value of rate constant at 300 K is The value of Arrhenius factor
A at infinitely high temperature is

(A)

(B)

(C)

(D)

2) For a first order reaction P(g) → 3Q(g) + R(g), the total pressure after infinite time is P∞ and the
total pressure after time t is Pt then the rate constant of reaction is :

(A)

(B)

(C)

(D)
3) The rate of reaction at 273 K is R0. The rate of reaction at 313 K will be (Assuming temperature
coefficient equal to 2) :-

(A)
16 R0
(B)
64 R0
(C)
R0/32
(D)
R0/16

4) The rate of disintegration of a certain radioactive sample at any instant is 8100 dpm. Fifty
minutes later, the rate becomes 2700 dpm. The half life of the radioactive sample will be (Take log2
= 0.3, log3 = 0.5, log5 = 0.7)

(A)
30 minutes
(B)
61 minutes
(C)
47.8 minutes
(D)
33.3 minutes

5) For the reaction , the rate law is, rate = k[H2][Br2]1/2. Which of the
following statement is true about this reaction

(A)
The reaction is of second order
(B)
Molecularity of the reaction is 3/2
(C)
The unit of k is
(D)
Order of the reaction is 1.5

6) For ANY reaction progress of reaction is as follows:

A+B→C+D If for the given raction x = 30 kJ/mole , y = 10kJ/mole

at 300 K.
If pre-exponential factor for backward and forward reaction is the same then, the value of
equilibrium constant is approximately:

(A)
e2
(B)
e-4
(C)
e4
(D)
e-2

7) The R/ S configurations of these compounds are respectively

(i)

(ii)

(iii)

(A)
R, R, R
(B)
R, S, R
(C)
R, S, S
(D)
S, S, S

8) Which of the following is not D sugar:

(A)

(B)

(C)
(D)

9)
Structures T and U are

(A)
Identical
(B)
Enantiomers
(C)
Diastereomers
(D)
Homomers

10) 3-Methyl-1-Pentene has one chiral carbon. If a pure enantiomer of 3-Methyl-1-Pentene is treated
with HBr, the correct statement regarding the major product is

(A)
A pure enantiomer is formed
(B)
Racemic mixture is formed
(C)
Optically inactive product is formed
(D)
Meso product is formed

11)

Column-II
Column - I
Number of
(Compound)
isomers

(A) (P) 2

(B) (Q) 3
 (C) (R) 4

(D) (S) 6

(A)
(A) → (Q); (B) → (R); (C) → (P); (D) → (P)
(B)
(A) → (R); (B) → (P); (C) → (Q); (D) → (P)
(C)
(A) → (R); (B) → (Q); (C) → (P); (D) → (P)
(D)
(A) → (R); (B) → (Q); (C) → (Q); (D) → (P)

12) Match the following column :

Column-I Column-II

(P) (1) Structural

(Q) (2) Identical

(R) (3) Enantiomers

(S) (4) Diastereomers

(A)
P→1;Q→3;R→2;S→3
(B)
P→3;Q→2;R→4;S→1
(C)
P→3;Q→4;R→1;S→1
(D)
P→4;Q→2;R→1;S→3

13) Which of the following molecule are chiral :

(1) (2)

(3) (4)

(A)
1, 2, 3
(B)
1, 2, 4
(C)
2, 3, 4
(D)
1, 3, 4

14) Given below are two statements:

Statement – I: High concentration of strong nucleophilic reagent with secondary alkyl halides
which do not have bulky substituents will follow SN2 mechanism.
Statement – II: A secondary alkyl halide when treated with a large excess of ethanol follows SN1
mechanism. In the the light of the above statements, choose the most appropriate from the questions
given below :

(A)
Statement I is true but Statement II is false.
(B)
Statement I is false but Statement II is true.
(C)
Both statement I and Statement II are false.
(D)
Both statement I and Statement II are true.

15) The major product obtained in the following reaction, is

H – C ≡ C – CH2OH

(A)
CH3CH2 – C ≡ C – CH2OH
(B)
H – C ≡ C – CH2OCH2CH3
(C)
CH3CH2 – C ≡ C – CH2NH2
(D)
H – C ≡ C – CH2NH – CH2CH3

16) Arrange the given alkylhalides in the increasing reactivity towards Nucleophilic substitution
reactions.

(A)
I > II > IV > III
(B)
I > III > II > IV
(C)
II > III > I > IV
(D)
IV > I > III > II

17) Product is :

(A)

(B)

(C)

(D)

18) Rate of SN1 reaction is :

(A)P > Q > R > S

(B)Q > R > S > P
(C)P > R > Q > S
(D)R > S > Q > P

19) Arrange the following compounds in order of decreasing rate of hydrolysis for SN1 reaction :

(I)

(II)

(III)

(IV)

(A)
II > III > IV > I
(B)
IV > III > II > I
(C)
III > IV > II > I
(D)
I > II > III > I

20) Consider the following reactions :

(a)

(b)

(c)

(d)
Which of these reaction(s) will not produce Saytzeff product ?

(A)
(c) only
(B)
(a), (c) and (d)
(C)
(d) only
(D)
(b) and (d)

SECTION-II

1) The time for half life period of a certain reaction A → Product is 1 hour. When the initial
concentration of the reaction ‘A’ is 2.0 mol L–1, how much time (in hour) does it take for its
concentration to come for 0.50 to 0.25 mol L–1 if it is a zero order reaction :

2) In the above first order reaction the initial concentration of N2O5 is

2.40 x 10 mol L at 318 K. The concentration of N2O5 after 1 hour was 1.60 x 10-2 mol L-1. The rate
-2 -1

constant of the reaction at 318 K is ______x 10-3 min-1. (Nearest integer).

[Given : log 3 = 0.477, log 5 = 0.699]

3) The activation energy of a non-catalysed reaction at 37oC is 200 kcal/mol and the activation
energy of the same reaction when catalysed decreases to only 60.0 kcal/mol. the ratio of rate
constants of the two reactions (with catalyst : without catalyst). is 10x. Find the value of x:

4) The half life period for catalytic decomposition of AB3 at 50 mm Hg is 4 hrs and at 100 mm Hg it is
2 hrs. Find the order of reaction.

5) Total number of following carbocation which will undergo rearragement ?

(a) (b) (c)

(d) (e) (f) (g)

(h) (i) (j)

6) In the given reaction :

Total number of alkenes (including stereo isomers formed will be

7) Among the following the number of electrophiles are :

(i) (ii)
(iii) (iv)
(v) (vi)
(vii) (viii) H+
(ix) AlCl3 (x) CH3OH

(xi) (xii) BH3

8)
Number of α-Hydrogen atoms in Hydrocarbon formed as major product.

9) How many of the statement(s) are correct

(i) The nucleophile makes a back side attack in SN2 reaction and expels the leaving group from front
side.
(ii) CH3O — CH = CH2 adds to HBr according to Anti-Markownikoff ’s rule.
(iii) The basicity of halides decreases in the order F– > Cl– > Br– > I–, but the nucleophillicity is
reverse of it. (in polar protic solvents)
(iv) The rate of SN1 reaction is independent of the polarity of the solvent.
(v) Sigma complex or arenium ion is resonance stablised

10) How many of the following having POS (Plane of symmetry) and COS (center of symmetry) (both)

PART-3 : MATHEMATICS

SECTION-I

1) If and , then is equal to

(A)

(B)

(C)

(D)
25

2) If , the value of

is

(A)
0
(B)
1
(C)
2
(D)
3

3) Which of the following function is identical to

(A)

(B)

(C)

(D)

4) Let be a function defined by then

(A)
f is both one-one & onto
(B)
f is one-one but not onto
(C)
f is onto but not one-one
(D)
f is neither one-one nor onto

5) ,
The number of solutions of the equation f(x) + g(x) = 0, is-

(A)
0
(B)
1
(C)
2
(D)
3

6) f(x) = x2 – 2ax + a(a + 1),

If one of the solutions of the equation f(x) = f–1(x) is 5049 then the other may be :-

(A)
5051
(B)
5048
(C)
5052
(D)
5053

7) Let and satisfy

. Suppose
satisfies and fog(x) = gof(x),
the g =

(A)
{(1, 3), (2, 1), (3, 2), (4, 4)}
(B)
{(1, 3), (2, 4), (3, 1), (4, 2)}
(C)
{(1, 3), (2, 2), (3, 4), (4, 3)}
(D)
{(1, 3), (2, 4), (3, 2), (1, 4)}

0
8) If 2ƒ(x2) + 3ƒ = x2 – 1 ∀x ∈ R then ƒ(x2) is

(A)

(B)

(C)

(D)
9) If is given by , then equals

(A)

(B)

(C)

(D)

10) If x ∈ [–1, 0), then cos–1 (2x2 – 1) – 2 sin–1 x is equal to

(A)

(B)
π
(C)

(D)
–2π

11) The domain of where [.] represents greatest integer

function, is

(A)
R
(B)
R – [–1, 0]
(C)
R – [0, 1]
(D)
R – [–1, 0)

12) If f and g are two real valued function defined by and then is
equal to

(A)

(B)

(C)

(D)
None of these

13) Let g(x) = f(x) – 1, if f(x) + f(1 – x) = 2 then g(x) is symmetrical about

(A)
The origin
(B)

The line
(C)
The point (1, 0)
(D)

The point

14) Suppose f is a function satisfying f (x + y) = f (x) + f (y)

for all and

If then m is equal to ___________.

(A)
15
(B)
5
(C)
10
(D)
20

15) A is set having 6 distinct elements. The number of distinct functions from A to A which are not
bijections is

(A)
6! - 6
(B)
66 - 6
(C)
66 - 6!
(D)
6!

16) Which of the following is periodic with fundamental period π ?

(A)

where [.] denotes greatest integer function

(B)
(C)
where {.} denotes fractional part function
(D)

17) If the mapping maps [–1, 1] onto [0, 2] then

is equal to

(A)

(B)

(C)

(D)

18) The value of is

(A)

(B)

(C)

(D)

19) Let . Then is equal to :

(A)
(B)

(C)

(D)
tan–1(3)
20) The value of is

(A)

(B)

(C)

(D)

SECTION-II

1) Let . Then the value of

is given by

2) If a + α = 1, b + β = 2 and af(x) + αf = bx + , x ≠ 0, then the value of expression

is _______.

3) Number of integers in domain of (where [x] denotes

greatest integer ≤ x)

4) Let [k] denotes the greatest integer less than or equal to k.

If number of positive integral solutions of the equation is n,

then find the value of .

5) If ,

then is equal to
6) If , then value of 'a' which satisfies

7) Let ‘ f ‘ be a function such that f (3) = 1 and

f (3 x) = x + f (3 x – 3) for all ‘ x ‘.
Then find the value of f (300).

8) If sin–1 x + sin–1 y = , then is equal to :-

9) Let is such that

3 3
f (x) – 3xf(x) + x + 1 = 0 and f(x) is an invertible
function, then number of solution(s) of the
equation f (f(x)) = f–1(x) is

10)
f (x) is an odd function then find the value of
 ANSWER KEYS

PART-1 : PHYSICS

SECTION-I

Q. 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20
A. A B D B B D A D D B B A B A A A B D B B

SECTION-II

Q. 21 22 23 24 25 26 27 28 29 30
A. 4.00 5.00 8.00 6.00 1.00 100.00 2.00 4.00 0.00 17.00

PART-2 : CHEMISTRY

SECTION-I

Q. 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50
A. D A A A D C A B C C C A A D A C D B A A

SECTION-II

Q. 51 52 53 54 55 56 57 58 59 60
A. 0.25 7.00 98.00 2.00 6.00 5.00 7.00 3.00 3.00 6.00

PART-3 : MATHEMATICS

SECTION-I

Q. 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80
A. B A A D C B B D A B D B D C C B D B C D

SECTION-II

Q. 81 82 83 84 85 86 87 88 89 90
A. 2.00 2.00 3.00 4.00 1.00 3.00 5050.00 2.00 1.00 1.00
 SOLUTIONS

PART-1 : PHYSICS

1)

3) As net charge inside cube is zero.

4)

mg’ = mg – mω2r

5)

8)

10)

Given that ,

Now TE = mv2+

but
12) Potential energy of the system

13)

= = -16 volt

14)

⇒
⇒

15)
Total charge of dipole = 0, so charge induced on outside surface = 0.
But due to non uniform electric field of dipole, the charge induced on inner surface is non zero and
non uniform.
So, for any abserver outside the shell, the resultant electric field is due to Q uniformly distributed on
outer surface only and it is equal to.

17)

18)
 19)

Place another identical hemisphere on given one, so that flat faces of two coincide The total flux

linked with cross-section of bottom half (lower hemisphere) is as charge enclosed by given

hemisphere is zero. So flux linked with flat face of hemisphere is

20)

21)

No. of prism in base = =8

No. of prism on the base = 8

Flux through the given prism =

22)

by energy conservation

24) Number of electric field lines are drawn in proportion to charge magnitudes

25)
 27)

29)

Potential of both spheres are same so no charge will flow.

30)
=8N

PART-2 : CHEMISTRY

31)

32)

P → 3Q + R
t=0 P0
t=t P0 3x x
t=∞ – 3P0 P0
P∞ = 4P0

0
P =
Pt = P0 – x + 3x + x
Pt = P0 + 3x

x=

x=

x=

33)

rnew = rinitial × μ(ΔT/10)

= R0 × (2)40/10
= 16 R0

35)

Rate law,

Order of reaction
Molecularity of reaction = 2
The unit of

36)

41)

44)

Statement – I: Rate of SN2 ∝ [R–X][Nu–]

SN2 reaction is favoured by high concentration of nucleophile (Nu–) & less crowding in the
substrate molecule.
Statement – II: Solvolysis follows SN1 path.
Both are correct Statements.

45)
 49) Alkyl halide which has more -hydrogens readily undergo a chemical reaction (According
to hyper conjugation, stable carbocation formed)

51)

t1/2 = (for zero order reaction)

t = 0.25 hr

54) (2) where n is the order of reaction

or
∴n=2

55)

(b), (d), (e), (f), (g), (j)

59)

(i) The nucleophile makes a rear attack in SN2 reaction and expels the leaving group from front
side.
(iii) The basicity of halides decreases in the order F– > Cl– > Br– > I–, but the nucleophillicity is
reverse of it. (in polar protic solvents)
(v) Sigma complex or arenium ion is resonance stabilised.
The above statements are correct.
CH3O–CH = CH2 adds to HBr according to Markownikoff's rule,
(iv) The rate of SN2 reaction is faster in polar aprotic solvent.

60)

Compound which have POS + COS both are → a, b, c, e, f , h

PART-3 : MATHEMATICS

61)

and
 63)

65)

66)

f(x) = f–1(x) = x
x2 – 2ax + a2 + a = x
(x – a)2 + a – x = 0
(x – a) (x – a – 1) = 0
x = a or x = a + 1
If a = 5049 then a + 1 = 5050
and if a + 1 = 5049 then a = 5048.

68)
2f(x2) + = x2 – 1 ....(i)

replace x by

....(ii)
solving (i) and (ii)

70)

71)

74)
 78)

= cot(tan–1(24) – tan–1(1))

= cot tan–1
= =

81)

Thus f (x) + f (1 – x)

Now

82)

...(1)

replace x by

...(2)
(1) + (2)

84)

Case-I : and
⇒ 0 ≤ x < 9 and 0 ≤ x < 11 ⇒ common value of x is {1, 2, 3, ......8}

Case-II : and
⇒ 9 ≤ x < 18 and 11 ≤ x < 22 ⇒ x ∈ {11, 12, ......., 17}

Case-III : and
⇒ 18 ≤ x < 27 and 22 ≤ x < 33 ⇒ x ∈ {22, 23, ......., 26}

Case-IV : and
⇒ 27 ≤ x < 36 and 33 ≤ x < 44 ⇒ x ∈ {33, 34, 35}
Case-V : and ⇒ x = 44
∴ Total positive integer x = 8 + 7 + 5 + 3 + 1 = 24
∴ Answer =

85)

sin–1 sin +

b = 10

86)

f–1(2a – 4) = ⇒

2 = 2a – 4
a=3

88)

sin–1 x + sin–1 y = ⇒ sin–1 x = – sin–1 y

⇒ sin–1 x = sin–1 ⇒ x2 + y2 = 1

⇒ =

= =2