Safety Data Sheet

SHINEX

Safety Data Sheet dated 4/12/2014, version 1

In compliance with Regulation (EC) 453/2010
1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
1.1. Product identifier
Mixture identification:
Trade name: SHINEX
Product type: Water based cleaner
1.2. Relevant identified uses of the substance or mixture and uses advised against
Recommended use:
Washing and cleaning products (including solvent based products)
Uses advised against:
Not available
1.3. Details of the supplier of the safety data sheet
Supplier:
AirChem Consumables. Sharjah Airport International Zone (SAIF Zone, A2-099), Sharjah, UAE.
P.O. BOX 8994.
TEL: +971 6 552 8946 FAX: +971 6 552 8947, Email: [email protected]
Competent person responsible for the safety data sheet:
[email protected]
1.4. Emergency telephone number
AirChem Consumables, TEL: +971 6 552 8946 FAX: +971 6 552 8947, Email: [email protected]
SECTION 2: Hazards identification
2.1. Classification of the substance or mixture
Directive criteria, 67/548/CE, 99/45/EC and following amendments thereof:
Properties / Symbols:
Xi Irritant
R Phrases:
R36 Irritating to eyes.

Adverse physicochemical, human health and environmental effects:

No other hazards
2.2. Label elements
Directive criteria, 67/548/CE, 99/45/EC and following amendments thereof:

Symbols:
Xi Irritant
R Phrases:
R36 Irritating to eyes.
S Phrases:
S24/25 Avoid contact with skin and eyes.
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical
advice.

Special provisions according to Annex XVII of REACH and subsequent amendments:

None
2.3. Other hazards
vPvB Substances: None - PBT Substances: None
Other Hazards:
No other hazards
SECTION 3: Composition/information on ingredients
3.1. Substances
Not applicable
3.2. Mixtures
Hazardous components within the meaning of EEC directive 67/548 and CLP regulation and related
classification:

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1 - 5% Alcohol (C11-13) polyethoxylated

REACH N°: Polymer, CAS: 68439-54-3, EC: 931-985-3
Xn,Xi; R22-41
3.1/4/Oral Acute Tox. 4 H302

3.3/1 Eye Dam. 1 H318

1 - 5% Alkyl betaine
REACH N°: 01-2119529251-48, CAS: 66455-29-6, EC: 211-669-5
C; R34
3.2/1B Skin Corr. 1B H314

3.3/1 Eye Dam. 1 H318

4.1/C3 Aquatic Chronic 3 H412

1 - 5% Dipropylen glycol ether

REACH N°: 01-2119450011-60-XXXX, CAS: 34590-94-8, EC: 252-104-2
substance with a Community workplace exposure limit

1 - 5% Sodium metasilicate
REACH N°: 01-2119449811-37-XXXX, Index number: 014-010-00-8, CAS: 10213-79-3, EC:
229-912-9
Xi,C; R34-37
3.2/1B Skin Corr. 1B H314

3.8/3 STOT SE 3 H335

2.16/1 Met. Corr. 1 H290

1 - 5% Glycerol
CAS: 56-81-5, EC: 200-289-5

0.1-0.5% Quaternary ammonium compounds, benzyl-alkyldimethyl, chlorides

CAS: 68424-85-1, EC: 270-325-2
Xn,C,N; R50-21/22-34
3.1/4/Dermal Acute Tox. 4 H312

3.1/4/Oral Acute Tox. 4 H302

3.2/1B Skin Corr. 1B H314

4.1/A1 Aquatic Acute 1 H400

0.1-0.5% 2,2'-iminodiethanol
REACH N°: 01-2119488930-28-XXX, Index number: 603-071-00-1, CAS: 111-42-2, EC: 203-868-0
Xn,Xi; R22-38-41-48/22
3.9/2 STOT RE 2 H373

3.2/2 Skin Irrit. 2 H315

3.3/1 Eye Dam. 1 H318

3.1/4/Oral Acute Tox. 4 H302

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0.1-0.5% 1,1’-oxybis(benzene)
REACH N°: 05-2114478530-48-0000, CAS: 101-84-8, EC: 202-981-2
Xi,N; R36/37/38-50/53
3.3/2 Eye Irrit. 2 H319

3.8/3 STOT SE 3 H335

3.2/2 Skin Irrit. 2 H315

4.1/A1 Aquatic Acute 1 H400

4.1/C1 Aquatic Chronic 1 H410

Declaration of ingredients according to Detergent Regulation 648/2004:

amphoteric surfactants, non-ionic surfactants, cationic <5%
surfactants
The product also contains: Perfumes

For the complete text of the hazard and risk phrases refer to paragraph 16
SECTION 4: First aid measures
4.1. Description of first aid measures
In case of skin contact:
Immediately take off all contaminated clothing.
Areas of the body that have - or are only even suspected of having - come into contact with the
product must be rinsed immediately with plenty of running water and possibly with soap.
Wash thoroughly the body (shower or bath).
Remove contaminated clothing immediately and dispose off safely.
After contact with skin, wash immediately with soap and plenty of water.
In case of eyes contact:
After contact with the eyes, rinse with water with the eyelids open for a sufficient length of time, then
consult an opthalmologist immediately.
Protect uninjured eye.
In case of Ingestion:
Do NOT induce vomiting.
Give nothing to eat or drink.
In case of Inhalation:
Remove casualty to fresh air and keep warm and at rest.
If breathing is irregular or stopped, administer artificial respiration.
In case of inhalation, consult a doctor immediately and show him packing or label.
4.2. Most important symptoms and effects, both acute and delayed
None
4.3. Indication of any immediate medical attention and special treatment needed
In case of accident or unwellness, seek medical advice immediately (show directions for use or safety data
sheet if possible).
Treatment:
None
SECTION 5: Firefighting measures
5.1. Extinguishing media
Suitable extinguishing media:
Water.
Carbon dioxide (CO2).
Extinguishing media which must not be used for safety reasons:
None in particular.
5.2. Special hazards arising from the substance or mixture
Do not inhale explosion and combustion gases.
Burning produces heavy smoke.
5.3. Advice for firefighters
Use suitable breathing apparatus .

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Collect contaminated fire extinguishing water separately. This must not be discharged into drains.
Move undamaged containers from immediate hazard area if it can be done safely.
SECTION 6: Accidental release measures
6.1. Personal precautions, protective equipment and emergency procedures
Wear personal protection equipment.
Remove persons to safety.
See protective measures under point 7 and 8.
6.2. Environmental precautions
Do not allow to enter into soil/subsoil. Do not allow to enter into surface water or drains.
Retain contaminated washing water and dispose it.
In case of gas escape or of entry into waterways, soil or drains, inform the responsible authorities.
Suitable material for taking up: absorbing material, organic, sand
6.3. Methods and material for containment and cleaning up
Wash with plenty of water.
6.4. Reference to other sections
See also section 8 and 13
SECTION 7: Handling and storage
7.1. Precautions for safe handling
Avoid contact with skin and eyes, inhalation of vapours and mists.
Don't use empty container before they have been cleaned.
Before making transfer operations, assure that there aren't any incompatible material residuals in the
containers.
Contamined clothing should be changed before entering eating areas.
Do not eat or drink while working.
See also section 8 for recommended protective equipment.
7.2. Conditions for safe storage, including any incompatibilities
Keep away from food, drink and feed.
Incompatible materials:
None in particular.
Instructions as regards storage premises:
Adequately ventilated premises.
7.3. Specific end use(s)
For more information see Technical date bulletin
None in particular
SECTION 8: Exposure controls/personal protection
8.1. Control parameters
Contained substances
Dipropylen glycol ether - CAS: 34590-94-8
ACGIH - LTE mg/m3(8h): 606 - LTE ppm: 100 - STE mg/m3(15min): 909 - STE ppm: 150 -
Behaviour: Binding - Notes: Skin - Critical effects: Eye and respiratory irritation , central nervous
system .
OEL - LTE mg/m3: 308 - LTE ppm: 50 - Behaviour: Binding - Notes: Skin
OSHA - LTE ppm: 150 - Behaviour: Binding
Sodium metasilicate - CAS: 10213-79-3
OEL - LTE mg/m3: 10 - Behaviour: Binding - Notes: Respirable fraction
OEL - LTE mg/m3: 3 - Behaviour: Binding - Notes: Inhalable fraction
OEL - STE mg/m3: 2 - Behaviour: Indicative - Notes: analogy with NaOH
Glycerol - CAS: 56-81-5
ACGIH - LTE mg/m3: 10 - Behaviour: Binding - Critical effects: mists , respiratory irritation
2,2'-iminodiethanol - CAS: 111-42-2
ACGIH - LTE mg/m3(8h): 1 - Behaviour: Binding - Notes: Cute, A3 - Critical effects: inhalable
particles , vapors and aerosols . Liver , kidneys .
OEL - LTE mg/m3(8h): 2 - LTE ppm: 0.46 - Behaviour: Binding
1,1’-oxybis(benzene) - CAS: 101-84-8
ACGIH - LTE mg/m3(8h): 7 - LTE ppm: 1 - STE mg/m3(15min): 14 - STE ppm: 2 - Behaviour:
Binding - Critical effects: eye and respiratory irritation , nausea

DNEL Exposure Limit Values

Alkyl betaine - CAS: 66455-29-6

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Worker Professional: 60.42 mg/kg - Consumer: 36.25 - U.M.: mg/kg - Exposure: Human Dermal -
Frequency: Long Term, systemic effects
Worker Professional: 63.6 mg/kg - Exposure: Human Inhalation - Frequency: Long Term, systemic
effects
Consumer: 3.63 - U.M.: mg/m3 - Exposure: Human Oral - Frequency: Long Term, systemic effects
Sodium metasilicate - CAS: 10213-79-3
Worker Professional: 6.22 mg/m3 - Consumer: 1.55 - U.M.: mg/m3 - Exposure: Human Inhalation -
Frequency: Long Term, systemic effects
Worker Professional: 1.49 mg/kg - Consumer: 0.74 - U.M.: mg/kg - Exposure: Human Dermal -
Frequency: Long Term, systemic effects
Consumer: 0.74 - U.M.: mg/kg - Exposure: Human Oral - Frequency: Long Term, systemic effects
Quaternary ammonium compounds, benzyl-alkyldimethyl, chlorides - CAS: 68424-85-1
Consumer: 3.4 - U.M.: mg/kg - Exposure: Human Oral - Frequency: Long Term, systemic effects
Worker Professional: 3.96 mg/m3 - Consumer: 1.64 - U.M.: mg/m3 - Exposure: Human Inhalation -
Frequency: Long Term, systemic effects
Worker Professional: 5.7 mg/kg - Consumer: 3.4 - U.M.: mg/kg - Exposure: Human Dermal -
Frequency: Long Term, systemic effects
2,2'-iminodiethanol - CAS: 111-42-2
Worker Professional: 0.13 mg/kg - Consumer: 0.07 - U.M.: mg/kg - Exposure: Human Dermal -
Frequency: Long Term, systemic effects
Worker Professional: 1 mg/m3 - Consumer: 0.25 - U.M.: mg/m3 - Exposure: Human Inhalation -
Frequency: Long Term, local effects
Consumer: 0.06 - U.M.: mg/kg - Exposure: Human Oral - Frequency: Long Term, systemic effects
1,1’-oxybis(benzene) - CAS: 101-84-8
Worker Professional: 58.3 mg/kg - Exposure: Human Dermal - Frequency: Long Term, systemic
effects
Worker Professional: 245.8 mg/m3 - Exposure: Human Inhalation - Frequency: Long Term, systemic
effects
Worker Professional: 0.15 mg/cm2 - Exposure: Human Dermal - Frequency: Long Term, local
effects
Worker Professional: 9.68 mg/m3 - Exposure: Human Inhalation - Frequency: Long Term, local
effects

PNEC Exposure Limit Values

Alkyl betaine - CAS: 66455-29-6
Target: Fresh Water - Value: 0.0135 mg/l
Target: Marine water - Value: 0.00135 mg/l
Target: Sewerage treatment plants - Value: 2.7 mg/l
Target: Freshwater sediments - Value: 0.028 mg/kg
Target: Marine water sediments - Value: 0.0028 mg/kg
Target: Soil - Value: 0.002 mg/kg
Sodium metasilicate - CAS: 10213-79-3
Target: Fresh Water - Value: 7.5 mg/l
Target: Marine water - Value: 1 mg/l
Target: Occasional issue - Value: 7.5 mg/l
Target: Sewerage treatment plants - Value: 1000 mg/l
Quaternary ammonium compounds, benzyl-alkyldimethyl, chlorides - CAS: 68424-85-1
Target: Marine water - Value: 0.00096 mg/l
Target: Fresh Water - Value: 0.0009 mg/l
Target: Occasional issue - Value: 0.00016 mg/l
Target: Marine water sediments - Value: 13.09 mg/kg
Target: Freshwater sediments - Value: 12.27 mg/kg
Target: Soil - Value: 7 mg/kg
Target: Sewerage treatment plants - Value: 0.4 mg/l
2,2'-iminodiethanol - CAS: 111-42-2
Target: Fresh Water - Value: 0.0022 mg/l
Target: Marine water - Value: 0.00022 mg/l
Target: Freshwater sediments - Value: 0.019 mg/kg
Target: Marine water sediments - Value: 0.0019 mg/kg
Target: Soil - Value: 0.00108 mg/kg

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Target: Sewerage treatment plants - Value: 100 mg/l

Target: Occasional issue - Value: 0.022 mg/l
8.2. Exposure controls
Eye protection:
Use close fitting safety goggles, don't use eye lens.
Protection for skin:
No special precaution must be adopted for normal use.
Protection for hands:
Not needed for normal use.
Respiratory protection:
Not needed for normal use.
Thermal Hazards:
None
Environmental exposure controls:
None
SECTION 9: Physical and chemical properties
9.1. Information on basic physical and chemical properties
Appearance and colour: Clear green liquid
Odour: Marsiglia
Odour threshold: n.av. mg/m3
pH: < 12.5
Melting point / freezing point: initial 0 °C
Initial boiling point and boiling range: initial 100 °C
Solid/gas flammability: na
Upper/lower flammability or explosive limits: na % v/v
Vapour density (air=1): >1
Flash point: none °C
Evaporation rate: na
Vapour pressure: 3.2 kPa
Relative density: 1.07 g/ml
Solubility in water: complete
Solubility in oil: na
Partition coefficient (n-octanol/water): n.av.
Auto-ignition temperature: na °C
Decomposition temperature: n.av. °C
Viscosity: n.av. mPa.s
Explosive properties: none
Oxidizing properties: not Oxidant
9.2. Other information
Miscibility: complete in water
Fat Solubility: na
Conductivity: n.av.
Substance Groups relevant properties: na
SECTION 10: Stability and reactivity
10.1. Reactivity
Stable under normal conditions
10.2. Chemical stability
Stable under normal conditions
10.3. Possibility of hazardous reactions
10.4. Conditions to avoid
Stable under normal conditions.
10.5. Incompatible materials
None in particular.
10.6. Hazardous decomposition products
None.
SECTION 11: Toxicological information
11.1. Information on toxicological effects
Toxicological information of the main substances found in the mixture:
Alcohol (C11-13) polyethoxylated - CAS: 68439-54-3

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a) acute toxicity:
LD50 Oral Rat > 300-2000 mg/kg
LD50 Skin Rat > 2000 mg/kg
c) serious eye damage/irritation:
Eye Irritant Rabbit Positive serious injury
Alkyl betaine - CAS: 66455-29-6
a) acute toxicity:
LD50 Oral Rat = 3202 mg/kg
LD50 Skin Rat > 2000 mg/kg
b) skin corrosion/irritation:
Eye Corrosive EYES Rabbit Positive
Skin Corrosive Skin Rabbit Positive
Dipropylen glycol ether - CAS: 34590-94-8
a) acute toxicity:
LD50 Oral Rat = 5135 mg/kg
LD50 Skin Rabbit = 9500 mg/kg
LC50 Inhalation Rat = 55 mg/l 4 hours
LC50 Inhalation Rat > 275 Ppm 7 hours
Sodium metasilicate - CAS: 10213-79-3
a) acute toxicity:
LD50 Oral Rat > 1152 mg/kg
LD50 Oral Rat -1 1349 mg/kg
LC50 Inhalation Rat > 2.06 g/m3 4 hours
LD50 Skin Rat > 5000 mg/kg bw
b) skin corrosion/irritation:
Skin Corrosive Skin Rat Positive OECD 404
c) serious eye damage/irritation:
Eye Irritant EYES Rabbit Positive OECD 405
Glycerol - CAS: 56-81-5
a) acute toxicity:
LD50 Oral Rat = 12.6 g/kg
LD50 Oral Mouse = 26.0 g/kg
Quaternary ammonium compounds, benzyl-alkyldimethyl, chlorides - CAS: 68424-85-1
a) acute toxicity:
LD50 Oral Rat = 397.5 mg/kg
LD50 Oral Mouse = 919 mg/kg
LD50 Skin Rat > 800 mg/kg
LD50 Skin Rabbit = 3412 mg/kg
b) skin corrosion/irritation:
Eye Irritant EYES Rabbit Positive
Skin Corrosive Skin Rat Positive
2,2'-iminodiethanol - CAS: 111-42-2
a) acute toxicity:
LD50 Oral Rat > 680 mg/kg
LD50 Oral Rat -1 1100 mg/kg
LD50 Oral Rat = 1600 mg/kg
LD50 Skin Rabbit = 13 g/kg Portale Reach
LCLo Inhalation Rat = 0.2 mg/l 8 hours
1,1’-oxybis(benzene) - CAS: 101-84-8
a) acute toxicity:
LD50 Oral Rat > 5000 mg/kg
LD50 Oral Mouse = 2830 mg/kg
LD50 Skin Rabbit > 7940 mg/kg

If not differently specified, the information required in Regulation 453/2010/EC listed below must be considered
as N.AV.:
a) acute toxicity;
b) skin corrosion/irritation;
c) serious eye damage/irritation;
d) respiratory or skin sensitisation;

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e) germ cell mutagenicity;

f) carcinogenicity;
g) reproductive toxicity;
h) STOT-single exposure;
i) STOT-repeated exposure;
j) aspiration hazard.
SECTION 12: Ecological information
12.1. Toxicity
Based on the information available it is not expected that this product may cause any adverse
environmental effect when use instructions and disposal recommendations are followed.
Adopt good working practices, so that the product is not released into the environment.
List of substances hazardous to the environment and eco-toxicological information available:

Alkyl betaine - CAS: 66455-29-6

a) Aquatic acute toxicity:
LC50 Fish = 4.44 mg/l 96
Dipropylen glycol ether - CAS: 34590-94-8
a) Aquatic acute toxicity:
LC50 Fish > 10000 mg/l 96
LC50 Fish > 1000 mg/l 96 Poecilia reticulata
EC50 Daphnia = 1919 mg/l 48 Daphnia magna
EC50 Algae > 969 mg/l 72 Selenastrum capricornutum
Sodium metasilicate - CAS: 10213-79-3
a) Aquatic acute toxicity:
LC50 Fish = 210 mg/l 96 Brachydanio rerio
LC50 Fish = 2320 mg/l 96 Gambusia affinis
EC50 Daphnia = 1700 mg/l 48 Daphnia magna
EC50 Algae = 207 mg/l 72 Scenedesmus subspicatus
Glycerol - CAS: 56-81-5
a) Aquatic acute toxicity:
LC50 Fish > 5.000 mg/l 96
EC50 Daphnia > 10.000 mg/l 24
EC50 Bacteria > 10.000 mg/l 16
Quaternary ammonium compounds, benzyl-alkyldimethyl, chlorides - CAS: 68424-85-1
a) Aquatic acute toxicity:
LC50 Fish = 0.515 mg/l 96
EC50 Daphnia = 0.016 mg/l 48 Daphnia magna
EC50 Algae = 0.06 mg/l 96 Selenastrum capricornum
b) Aquatic chronic toxicity:
NOEC Algae = 0.009 mg/l
2,2'-iminodiethanol - CAS: 111-42-2
a) Aquatic acute toxicity:
EC50 Daphnia = 55 mg/l 48 Daphnia magna
LC50 Fish = 1460 mg/l 96 Pimephales promelas
EC50 Algae = 2.2 mg/l 96 Pseudokirchneriella subcapitata
b) Aquatic chronic toxicity:
NOEC Daphnia = 0.78 mg/l 504 Daphnia magna
1,1’-oxybis(benzene) - CAS: 101-84-8
a) Aquatic acute toxicity:
LC50 Fish = 36 mg/l 96
EC50 Daphnia = 1.7 mg/l 48
EC50 Algae = 2.5 mg/l 96
12.2. Persistence and degradability
Alkyl betaine - CAS: 66455-29-6
Biodegradability: Readily biodegradable - Test: CO2 production - Duration: 28 days - %: 63 - Notes:
Not applicable
Dipropylen glycol ether - CAS: 34590-94-8
Biodegradability: Readily biodegradable - Test: Not applicable - Duration: Not applicable - %: Not
applicable - Notes: Not applicable

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Quaternary ammonium compounds, benzyl-alkyldimethyl, chlorides - CAS: 68424-85-1

Biodegradability: Readily biodegradable - Test: Not applicable - Duration: Not applicable - %: Not
applicable - Notes: Not applicable
2,2'-iminodiethanol - CAS: 111-42-2
Biodegradability: Readily biodegradable - Test: Not applicable - Duration: Not applicable - %: Not
applicable - Notes: Not applicable
1,1’-oxybis(benzene) - CAS: 101-84-8
Biodegradability: Readily biodegradable - Test: Not applicable - Duration: Not applicable - %: Not
applicable - Notes: Not applicable
Regulation (EC) No. 648/2004 on Detergents and amendments:
Surfactant(s) contained in this preparation comply with biodegradability criteria as defined in (EC)
regulations on detergents.
12.3. Bioaccumulative potential
Alkyl betaine - CAS: 66455-29-6
Bioaccumulation: Not bioaccumulative - Test: Not applicable Not applicable - Duration: Not
applicable - Notes: Not applicable
Sodium metasilicate - CAS: 10213-79-3
Bioaccumulation: Not bioaccumulative - Test: Not applicable Not applicable - Duration: Not
applicable - Notes: Not applicable
Quaternary ammonium compounds, benzyl-alkyldimethyl, chlorides - CAS: 68424-85-1
Bioaccumulation: Not applicableTest: BCF - Bioconcentrantion factor 0.5 - Duration: Not applicable -
Notes: Not applicable
Bioaccumulation: Not applicableTest: Kow - Partition coefficient 0.5 - Duration: Not applicable -
Notes: Not applicable
2,2'-iminodiethanol - CAS: 111-42-2
Bioaccumulation: Not bioaccumulative - Test: Not applicable Not applicable - Duration: Not
applicable - Notes: Not applicable
1,1’-oxybis(benzene) - CAS: 101-84-8
Bioaccumulation: Not applicableTest: BCF - Bioconcentrantion factor 195 - Duration: 96 hours -
Notes: Rainbow trout
Bioaccumulation: Not applicableTest: Kow - Partition coefficient 4.21 - Duration: Not applicable -
Notes: Not applicable
12.4. Mobility in soil
Dipropylen glycol ether - CAS: 34590-94-8
Mobility in soil: Mobile - Test: Not applicable Not applicable - Duration: Not applicable - Notes: Not
applicable
2,2'-iminodiethanol - CAS: 111-42-2
Mobility in soil: Mobile - Test: Not applicable Not applicable - Duration: Not applicable - Notes: Not
applicable
1,1’-oxybis(benzene) - CAS: 101-84-8
Mobility in soil: Not mobile - Test: Not applicable 890 - Duration: Not applicable - Notes: Not
applicable
Mobility in soil: Not mobile - Test: Not applicable 4600 - Duration: Not applicable - Notes: Not
applicable
12.5. Results of PBT and vPvB assessment
vPvB Substances: None - PBT Substances: None
12.6. Other adverse effects
None
SECTION 13: Disposal considerations
13.1. Waste treatment methods
Product and its residue:
Do not dispose in the canals of wastewater, waterways and soil.
The codes indicating the type of waste are considered based on the recommendations and
scheduled use of this product. Different codes may be assigned bused on the end user's use and
the characteristics of the disposal.
Waste code CER/EWC (2000/532/CE), attributable to the product as:
07 06 01* aqueous solution of washing and mother liquors
H4 Irritant

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Any remaining product should be disposed of with the material.

Containers/contaminated packaging
Containers, even completely empty, must not be disposed in the environment. The packigings which
can not be cleaned should be disposed of as the material.
Recover, if possible. Send to authorised disposal plants or for incineration under controlled conditions. In so
doing, comply with the local and national regulations currently in force.
SECTION 14: Transport information

14.1. UN number
Not classified as dangerous in the meaning of transport regulations.
14.2. UN proper shipping name
Not classified in accordance with ADR / RID / ADNR / IMDG / ICAO / IATA
14.3. Transport hazard class(es)
Not applicable
14.4. Packing group
Not applicable
14.5. Environmental hazards
ADR-Enviromental Pollutant: No
IMDG-Marine pollutant: No
14.6. Special precautions for user
Not applicable
14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code
No
SECTION 15: Regulatory information
15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

Dir. 67/548/EEC (Classification, packaging and labelling of dangerous substances)

Dir. 99/45/EC (Classification, packaging and labelling of dangerous preparations)
Dir. 98/24/EC (Risks related to chemical agents at work)
Dir. 2000/39/EC (Occupational exposure limit values)
Dir. 2006/8/EC
Regulation (EC) n. 1907/2006 (REACH)
Regulation (EC) n. 1272/2008 (CLP)
Regulation (EC) n. 790/2009 (ATP 1 CLP) and (EU) n. 758/2013
Regulation (EU) n. 453/2010 (Annex I)
Regulation (EU) n. 286/2011 (ATP 2 CLP)
Regulation (EU) n. 618/2012 (ATP 3 CLP)
Restrictions related to the product or the substances contained according to Annex XVII Regulation (EC)
1907/2006 (REACH) and subsequent modifications:
None
Where applicable, refer to the following regulatory provisions :
Regulation (EC) nr 648/2004 and CE N. 907/2006 (Detergents).
Directive 2003/105/EC ('Activities linked to risks of serious accidents') and subsequent amendments.
Regulation (EC) n° 648/2004 (detergents).

1999/13/EC (VOC directive)

Volatile Organic compounds - VOCs = 2.09 %
Volatile CMR substances = 0.00 %
Halogenated VOCs which are assigned the risk phrase R40 = 0.00 %
Organic Carbon - C = 0.01

15.2. Chemical safety assessment

Not available
SECTION 16: Other information
Full text of phrases referred to in Section 3:
R21/22 Harmful in contact with skin and if swallowed.
R22 Harmful if swallowed.
R34 Causes burns.

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R36/37/38 Irritating to eyes, respiratory system and skin.

R37 Irritating to respiratory system.
R38 Irritating to skin.
R41 Risk of serious damage to eyes.
R48/22 Harmful: danger of serious damage to health by prolonged exposure if swallowed.
R50 Very toxic to aquatic organisms.
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

H302 Harmful if swallowed.

H318 Causes serious eye damage.
H314 Causes severe skin burns and eye damage.
H412 Harmful to aquatic life with long lasting effects.
H335 May cause respiratory irritation.
H290 May be corrosive to metals.
H312 Harmful in contact with skin.
H400 Very toxic to aquatic life.
H373 May cause damage to organs through prolonged or repeated exposure.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H410 Very toxic to aquatic life with long lasting effects.
This document was prepared by a competent person who has received appropriate training.
This MSDS cancels and replaces any preceding release.
Where applicable, refer to the following regulatory provisions :
Council Directive 67/548/EEC (Classification, packaging and labelling of dangerous substances) and
subsequent amendments; Regulation (EC) n°1272/2008; Regulation (EC) N. 790/2009 (annex VI),
Regulation (EC) n. 1907/2006 (REACH).
Commmission Directive 1999/45/EC (Classification, packaging and labelling of dangerous preparation)
and subsequent amendments; Commmission Directive n. 2006/8/CE.
Regulation (EC) nr 648/2004 and CE N. 907/2006 (Detergents).
Directive 2003/105/EC ('Activities linked to risks of serious accidents') and subsequent amendments.
Directive 2013/10/EU (aerosols) amending Directive 75/324/EEC on the approximation of the laws of the
Member States relating to aerosol dispensers in order to adapt its labelling provisions to Regulation (EC)
n° 1272/2008 on classification, labelling and packaging of substances and mixtures and subsequent
amendments.
Regulation (EC) No 1223/2009 on cosmetic products and subsequent amendments.
Regulation (EU) No 126/2013 amending Annex XVII to Regulation (EC) No 1907/2006 on the Registration,
Evaluation, Authorisation and Restriction of Chemicals (REACH) and subsequent amendments.
Regulation (EC) N. 304/2003 and subsequent amendments. Regulation (EU) No 528/2012 concerning
the making available on the market and use of biocidal products and subsequent amendments.
Directives 91/156/CEE, 91/689/CEE, 94/62/CE (Disposal of waste ) and subsequent amendments.
The European Agreement concerning the International Carriage of Dangerous Goods by Road (ADR),
current edition.
regulations IATA/ICAO = Dangerous Goods Regulations by air, current edition.
RID = Regulations concerning the International Carriage of Dangerous Goods by Rail, current edition.
IMDG Code = International Maritime Dangerous Goods Code produced by the International Maritime
Organization (IMO), current edition.
Directive 91/271/EEC and 91/676/CEE (protection of waters) and subsequent amendments.

Main bibliographic sources:

ESIS: European chemical Substances Information System and Environmental hazard classification.
Occupational exposure limit values (Commission Directives 2000/39/EC and 2006/15/CE)
ACGIH - TLV's for 2010
NIOSH - Registry of toxic effects of chemical substances (1983)
Material Safety Data Sheets of chemicals, REACH database
Material Safety Data Sheet and Technical Data of raw material as by Supplier
The ISS National Inventory of Chemical Substances (INSC)
Abbreviations and acronyms:
TLV-TWA = Threshold Limit Value- time-weighed average, 8-hour workday, 40-hour workweek;
TLV-STEL-15 min = Threshold Limit Values - Short Term Exposure Limit; TLV-C = Ceiling exposure limit;
Notes: IBE= Biological Exposure Indices; SEN= sensitizer; Skin= Can be absorbed through the skin.

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Safety Data Sheet
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Carcinogenicity categories: A1 / A2 = confirmed / suspected human carcinogen; A3 = Animal carcinogen;

A4 / A5 = Not Classificable/not suspected as a human carcinogen. ACGIH = American Conference on
Governmental Industrial Hygienists. OEL =Occupational Exposure Limit. VLPE = Occupational Exposure
Limit Values. LTE =long term exposure, STE=short term exposure.
n.av.= Not Available, n.a. = not applicable; LD50=lethal dose (solids and liquids), LC50=lethal
concentration (gases) that will kill 50% of the test animals; ADR= European Agreement concerning the
International Carriage of Dangerous Goods by Road. Regulations IATA/ICAO = Dangerous Goods
Regulations by air, current edition.
RID = Regulations concerning the International Carriage of Dangerous Goods by Rail, current edition.
IMDG Code = International Maritime Dangerous Goods Code produced by the International Maritime
Organization (IMO), current edition.
PBT = Persistent, Bioaccumulative and Toxic substances. ; vPvB = very Persistent and very
Bioaccumulative substances; CMR = Carcinogenic, mutagenic or reproduction toxic substances.
The information contained herein is based on our state of knowledge at the above-specified date. It refers solely
to the product indicated and constitutes no guarantee of particular quality.
It is the duty of the user to ensure that this information is appropriate and complete with respect to the specific
use intended.

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