IIMMIPPORRTTAINNITT QQ.

MY POUNDS

ÉTAESILIELEMMENTS V
1 Potassium Dichromatekzczof

ÉÉÉÉÉÉI omits one ie chromite one

Feo 8203

step fused with Narcos in

The chromite one is

presence of oxygen
when it gives yellow coloured
solution of sodium chromate
4 Fe 2204 8NazCO3 702 8092804 216203 8 Coz

step 2
acidified to Form
Chro mate solution is then

dichromate solution
orange coloured
2 Nat t H2O
2Naz 804 t 244 Nazca207
Dichromate
orange

stem
then treated with ka when it
Nazca Oz is
crystals of Kz 8207
generates orange
Naz6207 2 KU kzCrzOz t 2Nall
orange
crystals
 STRUCTIRES

i It
Cr
Eal t

Ho
Tetrahedral
Dichromate
chromate
ion Not ion
Warning : DON'T SHARE THESE
NOTES WITH NON-EWC

PROPERTIES are
Dichromate ions
i chromate and
the
interconvertible depending upon
pH of solution

CPH 7
a
InAcidicsoln
2604 2Mt 8205 t H2O

yellow orange
 b
InBasicsolnm pH 7

2207 204 26805 t H2O

yellow
orange

ii Kzerzoy is a very good oxidising

agent in acidic medium and is reduced
to Cost Reduction HR

2204 14 Htt 65 263 71120

It oxidises iodide I to iodine Iz
to
sulphide sulphur stannous to stannic
acid and Ferrous to Ferric ion
65 312 t be

35h't 3sn4t be
oxidation
Half Reactions
3425 6 Htt 3s t be
6 Felt 6 Fest t be

Note Add OHR and RHR For

proper equations
8205 t 14kt 61 2683 748 312
2205 14Mt 35h 26834 71120 t 35h4

0205 t 14 Ht 342s 203 7420 6 Htt 35

8205 t 14 Htt 6Feat 2183 71120 t 6 Fest

Yggishanitary standard in
volumetric Analysis
used as an oxidant for preparation of
many azo compounds
used in Leather
Industry
A Sodium Dichromate has greater
in water and it
solubility is extensively
used as an
oxidising agent in
organic
chemistry

POTASSIUM
Phat 4mn04

A p
ÉÉANaANATeÉfm
From its one pyrolusite i.e Mnoz
obtained
Mno is fused with KOH when it
stepf
solution of
gives green coloured
potassium manganate
2mn02 4K OH 02 242mn04 t 2420
Potassium manganal
careen
 Éganate ion undergoes disproportionation
in acidic medium to form purple coloured
ion
permanganate
3mn04 4117 2mn04 t Mn Oz t 2420
permanganate
purple

oxidative
III Fusion Mno
name
Followed by
elect olytic
of
oxidation of Mn I
Fused with KOH
oxidised with

any
dinakh Mnof
ion
Manganate

mnoi
E.fi t ifmnoate
Man
ÉÉYYonÉÉuidised by peroxo
di sulphate to permanganate
10504 16 Ht
2mn't t 55205 81120 2mn Of t
 Secure
i
9
Mn Mn
Int

11 O
O

Tetrahedral
Mnog Mnog
Tetrahedral purple
Potassium permanganate forms dark purple (almost black) crystals which are isostructural with those of
KClO4. The salt is not very soluble in water (6.4 g/100 g of water at 293 K), but when heated it decomposes at
513 K.

The manganate and permanganate ions are tetrahedral; the green manganate is paramagnetic with
one unpaired electron but the permanganate is diamagnetic.
The π-bonding takes place by overlap of p orbitals of oxygen with d orbitals of manganese.

PEPERTIEI
i On
heating 12mn04 decomposes
24mn04 KzMnO4 t Mn Oz t Oz
of
Ii It has 2 physical properties
considerable interest
its intense colour
its weak temperature dependent
paramagnetism
Ciii KMnog acts as
good oxidising agent
in acidic neutral as well as alkaline
medium
A
Acindicedium
Mnof 81st 5e Mn t 4h20

Iodide is oxidised to Iodine

102 2mn04 8 Ht 2mn't t 8420 t 522

Fe't ion is oxidised to Fest ion

t 8Mt Matt 4420 5173

5 Fe't t Mn of
yellow
green
oxalate ion is oxidised to coz

56205 2 Mn OF t IGHT 2mn t 8h20 t 10602

Nitrite ion is oxidised to nitrate ion

6Mt 2mn t 5 NOT 31120
5 NOI t 2mn05
Alkaline Medium
B Neutral or Faintly
Iodide is oxidised to iodate

2mn05 H2O I 2mn02 t 20h IOS

Thio sulphate is oxidised to sulphate

8mn02 t 6504 204
8mn05 35205 420
 Manganous salt is oxidised to Mno

2mn05 3mn24 5mn02 t 4Mt

2420
Mohr salt or
O In KMnog titration with
Hce can be
oxalic acid neither A No not

used to make the medium acidic Why

sold two is itself a good oxidising agent

hence will onidise Feat to Fest
can
Ha can't be used because KMnog

easily oxidise a to da

UsesofkMnot
used in Analytical chemistry
used as a Fav oxidant in preparative
organic chemistry silk
of wool cotton
used in Bleaching
and other textile fibers
oils
used For decolourisation of
Q KMnog can act as an
oxidising
acidic alkaline and neutral
agent in
medium In which medium is the
oxidising
power man

E Glines
IT MAFORTAINITTNATEERIT
QESTEINE