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    Chem P3 Set 1

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    Chem P3 Set 1

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    CHEM P3 SET 1

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    Chem P3 Set 1

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    of 9

    Name……………………………………………………………….. Class ….

    …………………

    Index Number ……………………..……… Adm Number………………………

    233/3
    CHEMISTRY
    PAPER 3
    PRE- MOCK – MARCH 2022
    1
    TIME: 2 HOURS
    4

    SET 1

    1 The Examiner 1 SET 1


    1. You are provided with:
    - 4.5g of solid P in a boiling tube
    - Solution Q, 0.2M sodium hydroxide
    - Phenophthalein indicator.
    You are required to determine:
    i) The solubility of solid P at different temperatures

    ii) The value of n in the formula (HX)n 2H2O of solid P.

    PROCEDURE I
    i) a) Fill the burette with distilled water. Using the burette, add 4.0cm3 of distilled water to
    solid P. in a boiling tube. Heat the mixture in a water bath while stirring with a
    thermometer to about 700C until all the solid dissolves.
    b) Allow the solution to cool while stirring with the thermometer and note the temperature
    at which crystals of solid P start to appear. Record this temperature in table 1.
    c) Using the burette, add 2.0cm3 of distilled water to the contents of the boiling tube. Heat
    the mixture while stirring with the thermometer until all the solid dissolves while in the
    water bath.
    d) Allow the mixture to cool while stirring and note the temperature at which crystals of
    solid P start to appear.
    e) Repeat the procedure (c) and (d) four more times, heating the solution in a water bath
    and record the temperature in the table. Retain the contents of the boiling tube for use in
    procedure II.

    2 The Examiner 2 SET 1


    ii) Complete the table by calculating the solubility of solid P at the different temperatures. (the
    solubility of a substance is the mass of that substance that dissolves in 100cm3(100g) of
    water at a particular temperature. (6 mks)

    Table I
    Volume of water in Temperature at which Solubility of solid P
    the boiling tube (cm3) crystals of solid P first appear (g/100g) of water
    (0C)
    4
    6
    8
    10
    12

    3 The Examiner 3 SET 1


    i) On the grid provided plot a graph of the solubility of solid P against temperature.
    (3mks)

    4 The Examiner 4 SET 1


    ii) Using your graph determine the temperature at which 100g of solid P would dissolve in
    100cm3 of water. (1mk)

    iii) Determine the solubility of solid P at 550C (1mk)

    iv) Other than temperatures give two other factors which affect solubility. (2mks)

    PROCEDURE II
    1. Transfer the contents of the boiling tube into a 250ml volumetric flask. Rinse the boiling
    tube and the thermometer with distilled water and add to the volumetric flask. Add more
    distilled water to make up to the mark. Label this solution P.
    Fill the burette with solution P. using a pipette and pipette filler place 25.0cm3 of solution
    Q into a conical flask. Titrate solution Q with solution P. Using phenolphthaline indicator.

    Table II
    I II III
    Final burette reading cm3
    Initial burette reading cm3
    Volume of solution P used cm3
    (4mks)
    Calculate the;
    i) Average volume of solution P used in the experiment. (1mk)

    5 The Examiner 5 SET 1


    ii) Number of moles of sodium hydroxide used in solution Q. (2mks)

    iii) Number of moles of solution P reacted with the sodium hydroxide given that the relative
    formula mass of P, (HX)n  2H2O is 126. (3mks)

    iv) The number of moles of sodium hydroxide required to react with one mole of P. Hence find the
    value of n in the formula (HX) n  2H2O (3mks)

    6 The Examiner 6 SET 1


    2 a) You are provided with solid M carry out the tests below and record your observations and
    inferences.

    Place a spatula of solid M in a boiling tube, add 10 cm3 of distilled water and shake well until all
    the solid dissolves.

    Observations Inference

    1
    1mk mk

    i) To about 1 cm3 of the solution add 2 M sodium hydroxide drop wise until in excess.
    Observations Inference

    1
    1mk mk

    ii) Place 1cm 3 of the solution in a test tube and add 2 to 3 drops of 2 M sulphuric (VI)
    acid.
    Observations Inference

    1
    1mk mk

    iii) To about 1 cm3 of the solution add 4-5 drops of lead (II) nitrate solution.
    Observations Inference

    7 The Examiner 7 SET 1


    1
    1mk mk

    b) You are provided with solid N. Carry out the test in (a) and (b)and fill the table below.

    i) Place one third of N in a metallic spatula and burn in a non- luminous flame.

    Observations Inference

    1
    1mk mk

    ii) Dissolve all of the remaining N in about 10 cm3 distilled water in a boiling tube.

    a) Place 2cm3 of solution in a test tube and add 2 drops of acidified potassium
    manganate (VII)

    Observations Inference

    1
    1mk mk

    b) To 2 cm3 of the solution, add all the solid sodium hydrogen carbonate.

    Observations Inference

    8 The Examiner 8 SET 1


    1
    1mk mk

    9 The Examiner 9 SET 1

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