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PMT

Cambridge IGCSE™

CHEMISTRY 0620/21
Paper 2 Multiple Choice (Extended) May/June 2022
45 minutes

You must answer on the multiple choice answer sheet.


*9070200185*

You will need: Multiple choice answer sheet


Soft clean eraser
Soft pencil (type B or HB is recommended)

INSTRUCTIONS
 There are forty questions on this paper. Answer all questions.
 For each question there are four possible answers A, B, C and D. Choose the one you consider correct
and record your choice in soft pencil on the multiple choice answer sheet.
 Follow the instructions on the multiple choice answer sheet.
 Write in soft pencil.
 Write your name, centre number and candidate number on the multiple choice answer sheet in the
spaces provided unless this has been done for you.
 Do not use correction fluid.
 Do not write on any bar codes.
 You may use a calculator.

INFORMATION
 The total mark for this paper is 40.
 Each correct answer will score one mark.
 Any rough working should be done on this question paper.
 The Periodic Table is printed in the question paper.

This document has 16 pages. Any blank pages are indicated.

IB22 06_0620_21/RP
© UCLES 2022 [Turn over
PMT

1 Which two gases will diffuse at the same rate, at the same temperature?

A carbon monoxide and carbon dioxide


B carbon monoxide and nitrogen
C chlorine and fluorine
D nitrogen and oxygen

2 A student measures the time taken for 2.0 g of magnesium to dissolve in 50 cm3 of dilute
sulfuric acid.

Which apparatus is essential to complete the experiment?

1 stop-clock
2 measuring cylinder
3 thermometer
4 balance

A 1, 2 and 4 B 1 and 2 only C 1 and 4 only D 2, 3 and 4

3 The numbers of protons and neutrons and the electronic structures of four particles, W, X, Y and
Z, are shown.

number of number of electronic


protons neutrons structure

W 8 8 2,8
X 8 10 2,6
Y 8 8 2,6
Z 10 8 2,8

Which particles have the same chemical properties?

A W and Y B W and Z C X and Y D X and Z

4 Which substance should be pure for the intended use?

A a drug for curing disease


B limestone for iron extraction
C petroleum for fractional distillation
D water for washing a car

© UCLES 2022 0620/21/M/J/22


PMT

5 Metals and ionic compounds have similarities and differences in their structure and properties.

Which row about metals and ionic compounds is correct?

similarity difference

A both contain positive ions only ionic compounds contain anions


B both contain positive ions ionic compounds conduct using a ‘sea of electrons’
C both are malleable only ionic compounds contain anions
D both are malleable ionic compounds conduct using a ‘sea of electrons’

6 Which diagram represents the outer-shell electron arrangement in a nitrogen molecule?

A B C D

N N N N N N N N

7 The equation for the reaction between barium chloride and dilute sulfuric acid is shown.

BaCl 2 + H2SO4  BaSO4 + 2HCl

Which row shows the state symbols for this equation?

BaCl 2 H2SO4 BaSO4 2HCl

A (aq) (aq) (s) (aq)


B (aq) (l) (s) (aq)
C (l) (aq) (s) (l)
D (aq) (l) (aq) (l)

8 The relative atomic mass, Ar, of an element is determined by comparing the mass of one atom of
the element with the mass of one atom of element Q.

What is Q?

A carbon
B chlorine
C hydrogen
D oxygen

© UCLES 2022 0620/21/M/J/22 [Turn over


PMT

9 The equation for the reaction between aqueous lead(II) nitrate and aqueous sodium chloride is
shown.

Pb(NO3)2(aq) + 2NaCl (aq)  PbCl 2(s) + 2NaNO3(aq)

If 100 cm3 of aqueous lead(II) nitrate of concentration 0.1 mol / dm3 is reacted with an excess of
aqueous sodium chloride, which mass of lead(II) chloride is obtained?

A 1.16 g B 2.42 g C 2.78 g D 3.31 g

10 The diagram shows the electrolysis of concentrated hydrochloric acid and concentrated aqueous
sodium chloride using carbon electrodes.

+ – + –
electrode 1 electrode 2 electrode 3 electrode 4

concentrated concentrated aqueous


hydrochloric acid sodium chloride

At which electrodes is hydrogen produced?

A electrode 1 only
B electrodes 1 and 3
C electrode 2 only
D electrodes 2 and 4

11 Aqueous copper(II) sulfate is electrolysed using copper electrodes.

What is the ionic half-equation for the reaction at the cathode?

A Cu  Cu2+ + 2e–

B Cu2+ + 2e–  Cu

C 2H+ + 2e–  H2

D 2O2–  O2 + 4e–

© UCLES 2022 0620/21/M/J/22


PMT

12 Which row identifies a chemical change and a physical change?

chemical change physical change

A boiling ethanol burning ethanol


B burning ethanol evaporating ethanol
C dissolving ethanol in water burning ethanol
D evaporating ethanol dissolving ethanol in water

13 The equation for the reaction between gaseous hydrogen and gaseous iodine to form gaseous
hydrogen iodide is shown.

H2(g) + I2(g)  2HI(g)

The reaction is exothermic.

Which statement explains why the reaction is exothermic?

A Energy is released when H–H and I–I bonds are broken.


B The bond energies of the reactants are larger than the bond energies of the products.
C The products are at a higher energy level than the reactants.

D More energy is released when two HI bonds are formed than is used when the H–H and I–I
bonds are broken.

14 Acidified aqueous silver nitrate is added to a test-tube containing aqueous chloride ions.

The test-tube is then left in direct sunlight.

Which row describes the observations and explains what happens to the reaction mixture?

observation on adding observation after


explanation
aqueous silver nitrate leaving in sunlight

A yellow precipitate precipitate dissolves silver chloride forms


B yellow precipitate precipitate turns grey silver ions are reduced
C white precipitate precipitate dissolves silver chloride forms
D white precipitate precipitate turns grey silver ions are reduced

© UCLES 2022 0620/21/M/J/22 [Turn over


PMT

15 Water is added to anhydrous copper(II) sulfate.

What happens during the reaction?

A The copper(II) sulfate turns blue and the solution formed gets colder.

B The copper(II) sulfate turns blue and the solution formed gets hotter.

C The copper(II) sulfate turns white and the solution formed gets colder.

D The copper(II) sulfate turns white and the solution formed gets hotter.

16 Aqueous iron(III) chloride, FeCl 3, reacts with aqueous potassium iodide, KI.

vFeCl 3 + wKI  xFeCl 2 + yKCl + I2

Which statements are correct?

1 In the balanced equation, v, w, x and y have the same value.


2 Potassium iodide is an oxidising agent.
3 A dark brown solution is produced in the reaction.

A 1 and 2 B 1 and 3 C 2 only D 2 and 3

17 Which statement about acids is correct?

A A strong acid has a higher pH than a weak acid of the same concentration.
B A strong acid is a proton acceptor.
C A weak acid is a proton donor.
D A weak acid is fully ionised in aqueous solution.

© UCLES 2022 0620/21/M/J/22


PMT

18 The oxides of two elements, X and Y, are separately dissolved in water and the pH of each
solution tested.

oxide tested pH of solution

X 1
Y 13

Which information about X and Y is correct?

oxide is oxide is
metal non-metal
acidic basic

A X Y X Y
B X Y Y X
C Y X X Y
D Y X Y X

19 An acid is neutralised by adding an excess of an insoluble solid base.

A soluble salt is formed.

How is the pure salt obtained from the reaction mixture?

A crystallisation  evaporation  filtration

B evaporation  crystallisation  filtration

C filtration  crystallisation  evaporation

D filtration  evaporation  crystallisation

20 The electronic structure of element Z is 2,8,1.

Which statements about Z are correct?

1 It is a metal.
2 It has two outer-shell electrons.
3 It is in Period 3.

A 1, 2 and 3 B 1 and 2 only C 1 and 3 only D 2 only

© UCLES 2022 0620/21/M/J/22 [Turn over


PMT

21 Elements in Group IV of the Periodic Table are shown.

carbon
silicon
germanium
tin
lead

What does not occur in Group IV as it is descended?

A The proton number of the elements increases.


B The elements become more metallic.
C The elements have more electrons in their outer shell.
D The elements have more electron shells.

22 Element M forms both M+ and M2+ ions.

In which part of the Periodic Table is M placed?

A Group I
B Group II
C Group III
D transition elements

23 In the extraction of aluminium by electrolysis, cryolite is added to the bauxite ore.

Which row describes the role of cryolite and gives the ionic half-equation at the cathode?

role of cryolite ionic half-equation at the cathode

A catalyst Al 3+ + 3e–  Al
B catalyst Al 3+ + 3e–  3Al
C lowers melting point of electrolyte Al 3+ + 3e–  Al
D lowers melting point of electrolyte Al 3+ + 3e–  3Al

© UCLES 2022 0620/21/M/J/22


PMT

24 Mild steel is galvanised to prevent corrosion of the iron.

Which statements about galvanising are correct?

1 Galvanising prevents corrosion because the zinc forms an alloy.


2 If the coating is damaged, water and oxygen do not corrode the iron.
3 Zinc is a sacrificial metal and corrodes in preference to iron.

A 1 and 2 B 1 and 3 C 2 only D 2 and 3

25 Which diagram represents the arrangement of the outer-shell electrons of a noble gas?

A B C D

26 Which statements about the general properties of metals are correct?

1 They are good conductors of heat and electricity.


2 They have low melting points.
3 They react with dilute acids to form a salt and water.
4 They react with oxygen to form basic oxides.

A 1 and 2 B 1 and 4 C 2 and 3 D 3 and 4

27 Reactions of three metals and their oxides are shown.

add dilute heat


metal hydrochloric acid metal oxide
to metal with carbon

1   key
2    = reacts
3    = does not react

What is the order of reactivity of these metals, from most reactive to least reactive?

A 123 B 132 C 213 D 231

© UCLES 2022 0620/21/M/J/22 [Turn over


PMT

10

28 Three metal compounds, J, K and L, are heated using a Bunsen burner.

The results are shown.

J colourless gas produced, which relights a glowing splint


K colourless gas produced, which turns limewater milky
L no reaction

Which row identifies J, K and L?

J K L

A magnesium carbonate potassium carbonate potassium nitrate


B magnesium carbonate potassium nitrate potassium carbonate
C potassium nitrate magnesium carbonate potassium carbonate
D potassium nitrate potassium carbonate magnesium carbonate

29 The diagram shows the uses and treatment processes of muddy river water.

process 1 process 2
muddy river water clear river water disinfected water

use 1 use 2

Which row identifies uses 1 and 2 and processes 1 and 2?

use 1 use 2 process 1 process 2

A drinking watering crops chlorination filtration


B drinking watering crops filtration chlorination
C watering crops drinking chlorination filtration
D watering crops drinking filtration chlorination

© UCLES 2022 0620/21/M/J/22


PMT

11

30 The equation for the manufacture of ammonia in the Haber process is shown.

3H2(g) + N2(g) 2NH3(g)

The forward reaction is exothermic.

Which row describes the effect of the stated change on the reaction rate and the yield of
ammonia?

change effect on reaction rate effect on yield of ammonia

A decrease pressure increases decreases


B decrease temperature decreases increases
C increase pressure increases decreases
D increase temperature increases increases

31 Fertilisers are used to provide three of the elements needed for plant growth.

Which two compounds would give a fertiliser containing all three of these elements?

A Ca(NO3)2 and (NH4)2SO4


B Ca(NO3)2 and (NH4)3PO4
C KNO3 and (NH4)2SO4
D KNO3 and (NH4)3PO4

32 The flow chart shows part of the process for the manufacture of sulfuric acid and its electrolysis.

electrolysis

gas 2

concentrated dilute
gas 3
sulfuric acid sulfuric acid

gas 1

What are gases 1, 2 and 3?

gas 1 gas 2 gas 3

A sulfur dioxide hydrogen sulfur trioxide


B sulfur dioxide oxygen sulfur trioxide
C sulfur trioxide hydrogen sulfur dioxide
D sulfur trioxide oxygen sulfur dioxide

© UCLES 2022 0620/21/M/J/22 [Turn over


PMT

12

33 Which statements about sulfur dioxide are correct?

1 Sulfur dioxide decolourises acidified potassium manganate(VII).

2 Sulfur dioxide forms when acids react with carbonates.

3 Sulfur dioxide is used as a bleach.

4 Sulfur dioxide is used to treat acidic soil.

A 1 and 3 B 1 and 4 C 2 and 3 D 2 and 4

34 What are the products when limestone (calcium carbonate) is heated strongly?

A calcium hydroxide and carbon dioxide


B calcium hydroxide and carbon monoxide
C calcium oxide and carbon dioxide
D calcium oxide and carbon monoxide

35 The structure of ester W is shown.

H O

H C C H

H O C H

Which row gives the names of ester W and the carboxylic acid and alcohol from which it is made?

name of ester W carboxylic acid alcohol

A ethyl methanoate ethanoic acid methanol


B ethyl methanoate methanoic acid ethanol
C methyl ethanoate ethanoic acid methanol
D methyl ethanoate methanoic acid ethanol

36 Ethanol is made industrially by the fermentation of glucose or by the catalytic addition of steam to
ethene.

Which statement describes an advantage of fermentation compared to catalytic addition?

A Ethanol is the only product of fermentation.


B Fermentation uses a batch process but catalytic addition is continuous.
C Fermentation uses a higher temperature than catalytic addition.
D Fermentation uses a renewable resource.

© UCLES 2022 0620/21/M/J/22


PMT

13

37 Some properties of colourless liquid L are listed.

● It boils at 65 C.
● When added to water, two layers form which do not mix.
● It does not react with sodium carbonate.
● It has no effect on bromine water.

What is L?

A ethanol
B hexane
C hexene
D ethanoic acid

38 A molecule of compound P contains two carbon atoms and four hydrogen atoms.

Which row represents P?

name of reacts with


Mr
compound aqueous bromine

A ethane 30 
B ethene 16 
C ethene 28 
D ethene 28 

39 The reaction of ethanol with acidified potassium manganate(VII) is shown.

KMnO4
CH3CH2OH CH3COOH
H+

Which type of reaction is taking place?

A addition
B condensation
C hydrolysis
D oxidation

© UCLES 2022 0620/21/M/J/22 [Turn over


PMT

14

40 Which polymer is a synthetic polyamide?

A nylon
B poly(ethene)
C protein
D Terylene

© UCLES 2022 0620/21/M/J/22


PMT

15

BLANK PAGE

Permission to reproduce items where third-party owned material protected by copyright is included has been sought and cleared where possible. Every
reasonable effort has been made by the publisher (UCLES) to trace copyright holders, but if any items requiring clearance have unwittingly been included, the
publisher will be pleased to make amends at the earliest possible opportunity.

To avoid the issue of disclosure of answer-related information to candidates, all copyright acknowledgements are reproduced online in the Cambridge
Assessment International Education Copyright Acknowledgements Booklet. This is produced for each series of examinations and is freely available to download
at www.cambridgeinternational.org after the live examination series.

Cambridge Assessment International Education is part of Cambridge Assessment. Cambridge Assessment is the brand name of the University of Cambridge
Local Examinations Syndicate (UCLES), which is a department of the University of Cambridge.

© UCLES 2022 0620/21/M/J/22


The Periodic Table of Elements
Group
I II III IV V VI VII VIII

© UCLES 2022
1 2

H He
hydrogen helium
Key 1 4
3 4 atomic number 5 6 7 8 9 10

Li Be atomic symbol B C N O F Ne
lithium beryllium name boron carbon nitrogen oxygen fluorine neon
7 9 relative atomic mass 11 12 14 16 19 20
11 12 13 14 15 16 17 18
Na Mg Al Si P S Cl Ar
sodium magnesium aluminium silicon phosphorus sulfur chlorine argon
23 24 27 28 31 32 35.5 40
19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36
K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr
potassium calcium scandium titanium vanadium chromium manganese iron cobalt nickel copper zinc gallium germanium arsenic selenium bromine krypton
39 40 45 48 51 52 55 56 59 59 64 65 70 73 75 79 80 84
37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54

Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe
rubidium strontium yttrium zirconium niobium molybdenum technetium ruthenium rhodium palladium silver cadmium indium tin antimony tellurium iodine xenon
85 88 89 91 93 96 – 101 103 106 108 112 115 119 122 128 127 131
16

55 56 57–71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86
lanthanoids
Cs Ba Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn

0620/21/M/J/22
caesium barium hafnium tantalum tungsten rhenium osmium iridium platinum gold mercury thallium lead bismuth polonium astatine radon
133 137 178 181 184 186 190 192 195 197 201 204 207 209 – – –
87 88 89–103 104 105 106 107 108 109 110 111 112 114 116
actinoids
Fr Ra Rf Db Sg Bh Hs Mt Ds Rg Cn Fl Lv
francium radium rutherfordium dubnium seaborgium bohrium hassium meitnerium darmstadtium roentgenium copernicium flerovium livermorium
– – – – – – – – – – – – –

57 58 59 60 61 62 63 64 65 66 67 68 69 70 71
lanthanoids La Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu
lanthanum cerium praseodymium neodymium promethium samarium europium gadolinium terbium dysprosium holmium erbium thulium ytterbium lutetium
139 140 141 144 – 150 152 157 159 163 165 167 169 173 175
89 90 91 92 93 94 95 96 97 98 99 100 101 102 103
actinoids Ac Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No Lr
actinium thorium protactinium uranium neptunium plutonium americium curium berkelium californium einsteinium fermium mendelevium nobelium lawrencium
– 232 231 238 – – – – – – – – – – –

The volume of one mole of any gas is 24 dm3 at room temperature and pressure (r.t.p.).
PMT
PMT

Cambridge IGCSE™

CHEMISTRY 0620/22
Paper 2 Multiple Choice (Extended) May/June 2022
45 minutes

You must answer on the multiple choice answer sheet.


*2772444271*

You will need: Multiple choice answer sheet


Soft clean eraser
Soft pencil (type B or HB is recommended)

INSTRUCTIONS
 There are forty questions on this paper. Answer all questions.
 For each question there are four possible answers A, B, C and D. Choose the one you consider correct
and record your choice in soft pencil on the multiple choice answer sheet.
 Follow the instructions on the multiple choice answer sheet.
 Write in soft pencil.
 Write your name, centre number and candidate number on the multiple choice answer sheet in the
spaces provided unless this has been done for you.
 Do not use correction fluid.
 Do not write on any bar codes.
 You may use a calculator.

INFORMATION
 The total mark for this paper is 40.
 Each correct answer will score one mark.
 Any rough working should be done on this question paper.
 The Periodic Table is printed in the question paper.

This document has 16 pages.

IB22 06_0620_22/2RP
© UCLES 2022 [Turn over
PMT

1 Which two gases will diffuse at the same rate, at the same temperature?

A carbon monoxide and carbon dioxide


B carbon monoxide and nitrogen
C chlorine and fluorine
D nitrogen and oxygen

2 A student measures the time taken for 2.0 g of magnesium to dissolve in 50 cm3 of dilute
sulfuric acid.

Which apparatus is essential to complete the experiment?

1 stop-clock
2 measuring cylinder
3 thermometer
4 balance

A 1, 2 and 4 B 1 and 2 only C 1 and 4 only D 2, 3 and 4

3 A chromatogram of a single substance T is shown.

solvent front

3
1 4
2
baseline

Which measurements are used to find the Rf value of T?

A 1 and 2 B 1 and 4 C 2 and 3 D 3 and 4

4 X and Y are two different elements.

X and Y have the same number of nucleons.

Which statement about X and Y is correct?

A They have the same physical properties.


B Their atoms have the same number of electrons.
C They are in different groups of the Periodic Table.
D They have different relative masses.

© UCLES 2022 0620/22/M/J/22


PMT

5 The diagrams show the structures of three macromolecules P, Q and R.

P Q R

What are P, Q and R?

P Q R

A diamond silicon(IV) oxide graphite


B graphite diamond silicon(IV) oxide
C silicon(IV) oxide diamond graphite
D silicon(IV) oxide graphite diamond

6 Which dot-and-cross diagram shows the arrangement of outer shell electrons in a molecule of
hydrogen chloride?

A B C D

H Cl H Cl H Cl H Cl

7 The equation for the reaction between barium chloride and dilute sulfuric acid is shown.

BaCl 2 + H2SO4  BaSO4 + 2HCl

Which row shows the state symbols for this equation?

BaCl 2 H2SO4 BaSO4 2HCl

A (aq) (aq) (s) (aq)


B (aq) (l) (s) (aq)
C (l) (aq) (s) (l)
D (aq) (l) (aq) (l)

© UCLES 2022 0620/22/M/J/22 [Turn over


PMT

8 Methane and steam react in the presence of a catalyst.

CH4(g) + H2O(g)  CO(g) + 3H2(g)

0.5 mol of methane reacts completely with 0.5 mol of steam.

What is the volume of carbon monoxide and hydrogen produced, measured at room temperature
and pressure?

volume volume
of CO / dm3 of H2 / dm3

A 0.5 1.5
B 1.0 3.0
C 12.0 12.0
D 12.0 36.0

9 A compound of element X has the formula X2O and a relative formula mass of 144.

What is element X?

A copper, Cu
B gadolinium, Gd
C sulfur, S
D tellurium, Te

© UCLES 2022 0620/22/M/J/22


PMT

10 The diagram shows the electrolysis of concentrated hydrochloric acid and concentrated aqueous
sodium chloride using carbon electrodes.

+ – + –
electrode 1 electrode 2 electrode 3 electrode 4

concentrated concentrated aqueous


hydrochloric acid sodium chloride

At which electrodes is hydrogen produced?

A electrode 1 only
B electrodes 1 and 3
C electrode 2 only
D electrodes 2 and 4

11 The diagram shows the electrolysis of aqueous copper(II) sulfate using inert electrodes.

Which arrow shows the movement of electrons in the circuit?

power
supply
A B

anode cathode

© UCLES 2022 0620/22/M/J/22 [Turn over


PMT

12 Which row identifies a chemical change and a physical change?

chemical change physical change

A boiling ethanol burning ethanol


B burning ethanol evaporating ethanol
C dissolving ethanol in water burning ethanol
D evaporating ethanol dissolving ethanol in water

13 Which statements explain why increasing the concentration of a reactant increases the rate of
reaction?

1 It increases the collision rate of particles.


2 It lowers the activation energy.
3 A greater proportion of the colliding molecules have the required activation energy.
4 There are more particles per unit volume.

A 1 and 3 B 1 and 4 C 2 and 3 D 2 and 4

14 When the colourless gas N2O4 is heated, it forms the brown gas NO2.

When the reaction mixture is cooled, the brown colour fades and turns back to colourless.

Which type of reaction is described by these observations?

A decomposition
B displacement
C reduction
D reversible

15 Water is added to anhydrous copper(II) sulfate.

What happens during the reaction?

A The copper(II) sulfate turns blue and the solution formed gets colder.

B The copper(II) sulfate turns blue and the solution formed gets hotter.

C The copper(II) sulfate turns white and the solution formed gets colder.

D The copper(II) sulfate turns white and the solution formed gets hotter.

© UCLES 2022 0620/22/M/J/22


PMT

16 Which arrow on the energy level diagram shows the overall energy change for an endothermic
reaction?

C
products
energy A
D
reactants B

progress of reaction

17 When a hydrogen–oxygen fuel cell is in operation, a different reaction happens at each electrode.

at the hydrogen electrode H2  2H+ + 2e–

at the oxygen electrode O2 + 2H2O + 4e–  4OH–

The electrons that are lost at the hydrogen electrode travel through the external circuit to the
oxygen electrode, where they are gained by the oxygen and water.

A hydrogen–oxygen fuel cell is operated for a period of time and four moles of oxygen molecules
are consumed.

Which mass of hydrogen is consumed?

A 2.0 g B 4.0 g C 8.0 g D 16.0 g

18 The oxides of two elements, X and Y, are separately dissolved in water and the pH of each
solution tested.

oxide tested pH of solution

X 1
Y 13

Which information about X and Y is correct?

oxide is oxide is
metal non-metal
acidic basic

A X Y X Y
B X Y Y X
C Y X X Y
D Y X Y X

© UCLES 2022 0620/22/M/J/22 [Turn over


PMT

19 An acid is neutralised by adding an excess of an insoluble solid base.

A soluble salt is formed.

How is the pure salt obtained from the reaction mixture?

A crystallisation  evaporation  filtration

B evaporation  crystallisation  filtration

C filtration  crystallisation  evaporation

D filtration  evaporation  crystallisation

20 Substance J takes part in a redox reaction.

In the reaction, J gains electrons.

Which statement is correct?

A J is the oxidising agent and it is oxidised in the reaction.


B J is the oxidising agent and it is reduced in the reaction.
C J is the reducing agent and it is oxidised in the reaction.
D J is the reducing agent and it is reduced in the reaction.

21 Elements in Group IV of the Periodic Table are shown.

carbon
silicon
germanium
tin
lead

What does not occur in Group IV as it is descended?

A The proton number of the elements increases.


B The elements become more metallic.
C The elements have more electrons in their outer shell.
D The elements have more electron shells.

© UCLES 2022 0620/22/M/J/22


PMT

22 Which statement about acids is correct?

A Acids are proton acceptors.


B Acids transfer electrons to bases in aqueous solution.
C Hydrochloric acid reacts with ammonium hydroxide to produce ammonia.
D Ethanoic acid partially ionises in aqueous solution.

23 Which elements have both a high melting point and variable oxidation states?

A alkali metals
B transition elements
C halogens
D noble gases

24 Lithium, sodium and potassium are elements in Group I of the Periodic Table.

Chlorine, bromine and iodine are elements in Group VII of the Periodic Table.

Which row identifies the least dense of these elements in each group?

Group I Group VII

A lithium chlorine
B lithium iodine
C potassium chlorine
D potassium iodine

© UCLES 2022 0620/22/M/J/22 [Turn over


PMT

10

25 The reactions of metals P, Q, R and S are shown.

reaction reaction with reduction of the


metal
with water hydrochloric acid metal oxide with carbon

P no reaction no reaction reduced


Q slow vigorous no reaction
R vigorous vigorous no reaction
S very slow vigorous reduced

What is the order of reactivity of the metals?

least most
reactive reactive

A P S Q R
B P Q S R
C R S Q P
D R Q S P

26 The number of protons and the number of neutrons in the atoms of elements X, Y and Z are
shown.

number of number of
protons neutrons

X 6 6
Y 7 6
Z 8 10

Which statement about the elements is correct?

A X and Y are isotopes of the same element.


B Z forms an ion with a +2 charge.
C X and Z react together to form an ionic compound.
D X, Y and Z are non-metals.

© UCLES 2022 0620/22/M/J/22


PMT

11

27 Which diagram represents the arrangement of atoms in an alloy?

A B C D

28 Three metal compounds, J, K and L, are heated using a Bunsen burner.

The results are shown.

J colourless gas produced, which relights a glowing splint


K colourless gas produced, which turns limewater milky
L no reaction

Which row identifies J, K and L?

J K L

A magnesium carbonate potassium carbonate potassium nitrate


B magnesium carbonate potassium nitrate potassium carbonate
C potassium nitrate magnesium carbonate potassium carbonate
D potassium nitrate potassium carbonate magnesium carbonate

29 Processes involved in the extraction of zinc are listed.

1 Heat zinc oxide with carbon.


2 Condense zinc vapour.
3 Vaporise the zinc.
4 Roast zinc ore in air.

In which order are the processes carried out?

A 1234

B 4312

C 4132

D 1432

© UCLES 2022 0620/22/M/J/22 [Turn over


PMT

12

30 Which process uses sacrificial protection to prevent steel from rusting?

A galvanising
B oiling
C copper plating
D painting

31 Fertilisers are used to provide three of the elements needed for plant growth.

Which two compounds would give a fertiliser containing all three of these elements?

A Ca(NO3)2 and (NH4)2SO4


B Ca(NO3)2 and (NH4)3PO4
C KNO3 and (NH4)2SO4
D KNO3 and (NH4)3PO4

32 Which processes produce carbon dioxide?

1 respiration
2 photosynthesis
3 fermentation
4 combustion of hydrogen

A 1 and 3 B 1 and 4 C 2 and 3 D 2 and 4

33 Which reaction in the Contact process requires the use of a catalyst?

A S + O2  SO2

B 2SO2 + O2  2SO3

C SO3 + H2SO4  H2S2O7

D H2S2O7 + H2O  2H2SO4

34 What are the products when limestone (calcium carbonate) is heated strongly?

A calcium hydroxide and carbon dioxide


B calcium hydroxide and carbon monoxide
C calcium oxide and carbon dioxide
D calcium oxide and carbon monoxide

© UCLES 2022 0620/22/M/J/22


PMT

13

35 The structure of ester W is shown.

H O

H C C H

H O C H

Which row gives the names of ester W and the carboxylic acid and alcohol from which it is made?

name of ester W carboxylic acid alcohol

A ethyl methanoate ethanoic acid methanol


B ethyl methanoate methanoic acid ethanol
C methyl ethanoate ethanoic acid methanol
D methyl ethanoate methanoic acid ethanol

36 Ethene reacts with substance X to form ethanol.

What is X?

A ethanoic acid
B glucose
C hydrogen
D steam

37 Alkenes can be produced by cracking large hydrocarbon molecules to form smaller hydrocarbon
molecules.

Which equations represent possible reactions when tetradecane, C14H30, is cracked?

1 C14H30  C2H6 + C3H6 + C4H8 + C5H10

2 C14H30  H2 + C2H4 + C3H6 + C4H8 + C5H10

3 C14H30  C2H6 + 4C3H6

4 C14H30  C2H6 + C3H8 + C9H18

A 1 only B 1 and 4 C 1, 2 and 3 D 3 and 4

© UCLES 2022 0620/22/M/J/22 [Turn over


PMT

14

38 The structures of some hydrocarbons are shown.

1 2 3 4
H H H
H H H H H H H
H C C H H C H
H C C C H H C C C C H
H H H
H
H H H H H H H
H C C H H C C C H

H H H H H

Which statement about the hydrocarbons is correct?

A 1 and 2 have a different general formula.


B 1 and 4 are in different homologous series.
C 2 and 3 are structural isomers.
D 3 and 4 have the same empirical formula.

39 Ethane reacts with chlorine in the presence of ultraviolet light.

Which substances are produced in the reaction?

1 2 3 4
H H H H

H H H C C Cl H C C H H Cl

H H Cl Cl

A 1, 2 and 3 B 1 and 3 only C 2, 3 and 4 D 2 and 4 only

© UCLES 2022 0620/22/M/J/22


PMT

15

40 Which polymer structure has the same linkages as Terylene?

A B

CH3 CH3 CH3 CH3 O

C C O C C C

C H n H H n
O OH

C D

H CH3 CH3 O CH3 CH3

N C C C C C O

H H n H H n

Permission to reproduce items where third-party owned material protected by copyright is included has been sought and cleared where possible. Every
reasonable effort has been made by the publisher (UCLES) to trace copyright holders, but if any items requiring clearance have unwittingly been included, the
publisher will be pleased to make amends at the earliest possible opportunity.

To avoid the issue of disclosure of answer-related information to candidates, all copyright acknowledgements are reproduced online in the Cambridge
Assessment International Education Copyright Acknowledgements Booklet. This is produced for each series of examinations and is freely available to download
at www.cambridgeinternational.org after the live examination series.

Cambridge Assessment International Education is part of Cambridge Assessment. Cambridge Assessment is the brand name of the University of Cambridge
Local Examinations Syndicate (UCLES), which is a department of the University of Cambridge.

© UCLES 2022 0620/22/M/J/22


The Periodic Table of Elements
Group
I II III IV V VI VII VIII

© UCLES 2022
1 2

H He
hydrogen helium
Key 1 4
3 4 atomic number 5 6 7 8 9 10

Li Be atomic symbol B C N O F Ne
lithium beryllium name boron carbon nitrogen oxygen fluorine neon
7 9 relative atomic mass 11 12 14 16 19 20
11 12 13 14 15 16 17 18
Na Mg Al Si P S Cl Ar
sodium magnesium aluminium silicon phosphorus sulfur chlorine argon
23 24 27 28 31 32 35.5 40
19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36
K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr
potassium calcium scandium titanium vanadium chromium manganese iron cobalt nickel copper zinc gallium germanium arsenic selenium bromine krypton
39 40 45 48 51 52 55 56 59 59 64 65 70 73 75 79 80 84
37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54

Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe
rubidium strontium yttrium zirconium niobium molybdenum technetium ruthenium rhodium palladium silver cadmium indium tin antimony tellurium iodine xenon
85 88 89 91 93 96 – 101 103 106 108 112 115 119 122 128 127 131
16

55 56 57–71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86
lanthanoids
Cs Ba Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn

0620/22/M/J/22
caesium barium hafnium tantalum tungsten rhenium osmium iridium platinum gold mercury thallium lead bismuth polonium astatine radon
133 137 178 181 184 186 190 192 195 197 201 204 207 209 – – –
87 88 89–103 104 105 106 107 108 109 110 111 112 114 116
actinoids
Fr Ra Rf Db Sg Bh Hs Mt Ds Rg Cn Fl Lv
francium radium rutherfordium dubnium seaborgium bohrium hassium meitnerium darmstadtium roentgenium copernicium flerovium livermorium
– – – – – – – – – – – – –

57 58 59 60 61 62 63 64 65 66 67 68 69 70 71
lanthanoids La Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu
lanthanum cerium praseodymium neodymium promethium samarium europium gadolinium terbium dysprosium holmium erbium thulium ytterbium lutetium
139 140 141 144 – 150 152 157 159 163 165 167 169 173 175
89 90 91 92 93 94 95 96 97 98 99 100 101 102 103
actinoids Ac Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No Lr
actinium thorium protactinium uranium neptunium plutonium americium curium berkelium californium einsteinium fermium mendelevium nobelium lawrencium
– 232 231 238 – – – – – – – – – – –

The volume of one mole of any gas is 24 dm3 at room temperature and pressure (r.t.p.).
PMT
PMT

Cambridge IGCSE™

CHEMISTRY 0620/23
Paper 2 Multiple Choice (Extended) May/June 2022
45 minutes

You must answer on the multiple choice answer sheet.


*3981974951*

You will need: Multiple choice answer sheet


Soft clean eraser
Soft pencil (type B or HB is recommended)

INSTRUCTIONS
 There are forty questions on this paper. Answer all questions.
 For each question there are four possible answers A, B, C and D. Choose the one you consider correct
and record your choice in soft pencil on the multiple choice answer sheet.
 Follow the instructions on the multiple choice answer sheet.
 Write in soft pencil.
 Write your name, centre number and candidate number on the multiple choice answer sheet in the
spaces provided unless this has been done for you.
 Do not use correction fluid.
 Do not write on any bar codes.
 You may use a calculator.

INFORMATION
 The total mark for this paper is 40.
 Each correct answer will score one mark.
 Any rough working should be done on this question paper.
 The Periodic Table is printed in the question paper.

This document has 16 pages. Any blank pages are indicated.

IB22 06_0620_23/RP
© UCLES 2022 [Turn over
PMT

1 Which two gases will diffuse at the same rate, at the same temperature?

A carbon monoxide and carbon dioxide


B carbon monoxide and nitrogen
C chlorine and fluorine
D nitrogen and oxygen

2 A student measures the time taken for 2.0 g of magnesium to dissolve in 50 cm3 of dilute
sulfuric acid.

Which apparatus is essential to complete the experiment?

1 stop-clock
2 measuring cylinder
3 thermometer
4 balance

A 1, 2 and 4 B 1 and 2 only C 1 and 4 only D 2, 3 and 4

3 Which statement describes the properties of both diamond and silicon(IV) oxide?

A They are brittle, with a low melting point, and are insoluble in water.
B They are hard, with a high melting point, and are electrical insulators.
C They are malleable, with a high melting point, and are electrical conductors.
D They are soft, with a low melting point, and are electrical insulators.

© UCLES 2022 0620/23/M/J/22


PMT

4 Paper chromatography is used to separate four different coloured inks, W, X, Y and Z, and an
unknown ink T.

The chromatogram is shown.

solvent front

baseline
W X Y Z T

Which inks are present in ink T?

A W and X B W and Y C X and Z D Y and Z

5 Particle P has an atomic number of 18, a mass number of 40 and no overall charge.

Particle Q has an atomic number of 19, a mass number of 40 and a single positive charge.

Which statement is correct?

A They are isotopes of the same element.


B They are both ions.
C Q has more neutrons than P.
D They have the same number of electrons in their outer shell.

6 Which statement about the properties of metals is correct?

A Metals are malleable because the layers of positive ions can slide over each other.
B Metals conduct electricity when solid because the positive ions move freely through the
metal.
C Metals conduct electricity because there is a strong force of attraction between the positive
ions and the delocalised electrons.
D Metals have a high melting point because the positive ions attract each other strongly.

© UCLES 2022 0620/23/M/J/22 [Turn over


PMT

7 The equation for the reaction between barium chloride and dilute sulfuric acid is shown.

BaCl 2 + H2SO4  BaSO4 + 2HCl

Which row shows the state symbols for this equation?

BaCl 2 H2SO4 BaSO4 2HCl

A (aq) (aq) (s) (aq)


B (aq) (l) (s) (aq)
C (l) (aq) (s) (l)
D (aq) (l) (aq) (l)

8 A 0.5 g sample of calcium carbonate is reacted with excess dilute hydrochloric acid.

CaCO3(s) + 2HCl (aq)  CaCl 2(aq) + H2O(l) + CO2(g)

Which volume of CO2 is produced at r.t.p.?

A 0.12 dm3 B 0.18 dm3 C 0.24 dm3 D 12 dm3

9 Aluminium is manufactured from aluminium oxide by electrolysis.

Which row shows the ionic half-equations at each electrode and describes the role of cryolite in
the process?

reaction at anode reaction at cathode role of cryolite

A 2O2–  O2 + 4e– Al 3+ + 3e–  3Al catalyst


B Al 3+ + 3e–  Al 2O2–  O2 + 4e– solvent for aluminium oxide
C 2O2–  O2 + 4e– Al 3+ + 3e–  Al solvent for aluminium oxide
D Al 3+ + 3e–  3Al 2O2–  O2 + 4e– catalyst

© UCLES 2022 0620/23/M/J/22


PMT

10 The diagram shows the electrolysis of concentrated hydrochloric acid and concentrated aqueous
sodium chloride using carbon electrodes.

+ – + –
electrode 1 electrode 2 electrode 3 electrode 4

concentrated concentrated aqueous


hydrochloric acid sodium chloride

At which electrodes is hydrogen produced?

A electrode 1 only
B electrodes 1 and 3
C electrode 2 only
D electrodes 2 and 4

11 Which statement about fuels is correct?

A Coal and ethanol are examples of non-renewable energy sources.


B Hydrogen and oxygen can be reacted to produce an electric current.
C Large amounts of energy are taken in by a fuel when it burns.
D Radioactive isotopes are burned to produce heat.

12 Which row identifies a chemical change and a physical change?

chemical change physical change

A boiling ethanol burning ethanol


B burning ethanol evaporating ethanol
C dissolving ethanol in water burning ethanol
D evaporating ethanol dissolving ethanol in water

© UCLES 2022 0620/23/M/J/22 [Turn over


PMT

13 Metal M reacts with steam and produces gas G.

Which row identifies gas G and the type of reaction when metal M reacts with steam?

gas G type of reaction

A hydrogen redox
B hydrogen neutralisation
C oxygen redox
D oxygen neutralisation

14 Which statement explains why increasing the concentration of a reactant increases the rate of the
reaction?

A A greater proportion of the particles have the activation energy so there are more successful
collisions.
B Particles have more energy so there are more frequent collisions.
C There are more particles in the same volume so there are more frequent collisions.
D The particles move more quickly so there are more frequent collisions.

15 Water is added to anhydrous copper(II) sulfate.

What happens during the reaction?

A The copper(II) sulfate turns blue and the solution formed gets colder.

B The copper(II) sulfate turns blue and the solution formed gets hotter.

C The copper(II) sulfate turns white and the solution formed gets colder.

D The copper(II) sulfate turns white and the solution formed gets hotter.

16 Which statement explains why lime is added to soil?

A to decrease the pH of acidic soil


B to decrease the pH of alkaline soil
C to increase the pH of acidic soil
D to increase the pH of alkaline soil

© UCLES 2022 0620/23/M/J/22


PMT

17 Sulfur dioxide is bubbled through water containing litmus.

sulfur dioxide

water and litmus

Which row describes and explains what happens to the litmus?

observation explanation

A it turns blue sulfur dioxide is a basic oxide


B it turns blue sulfur dioxide is an acidic oxide
C it turns red sulfur dioxide is an acidic oxide
D it turns red sulfur dioxide is a basic oxide

18 The oxides of two elements, X and Y, are separately dissolved in water and the pH of each
solution tested.

oxide tested pH of solution

X 1
Y 13

Which information about X and Y is correct?

oxide is oxide is
metal non-metal
acidic basic

A X Y X Y
B X Y Y X
C Y X X Y
D Y X Y X

© UCLES 2022 0620/23/M/J/22 [Turn over


PMT

19 An acid is neutralised by adding an excess of an insoluble solid base.

A soluble salt is formed.

How is the pure salt obtained from the reaction mixture?

A crystallisation  evaporation  filtration

B evaporation  crystallisation  filtration

C filtration  crystallisation  evaporation

D filtration  evaporation  crystallisation

20 Which ion forms a precipitate that dissolves in excess with both aqueous ammonia and with
aqueous sodium hydroxide?

A calcium ion, Ca2+

B copper(II) ion, Cu2+

C iron(III) ion, Fe3+

D zinc ion, Zn2+

21 Elements in Group IV of the Periodic Table are shown.

carbon
silicon
germanium
tin
lead

What does not occur in Group IV as it is descended?

A The proton number of the elements increases.


B The elements become more metallic.
C The elements have more electrons in their outer shell.
D The elements have more electron shells.

© UCLES 2022 0620/23/M/J/22


PMT

22 W, X, Y and Z are elements in Period 3 of the Periodic Table.

The numbers of outer-shell electrons in an atom of each element are shown.

number of
element
outer-shell electrons

W 1
X 2
Y 7
Z 8

Which elements are non-metals?

A W, X and Y B W and X only C Y and Z D Z only

23 Selenium is an element in Group VI.

Group VI elements follow similar trends to Group VII elements.

Which statement about selenium is correct?

A It has a higher density than sulfur.


B It has a lower melting point than sulfur.
C It has six electron shells.
D It is a monoatomic element.

24 Which row describes the properties of a typical transition element?

melting used as
density
point catalyst

A high high yes


B high low no
C low high yes
D low low no

© UCLES 2022 0620/23/M/J/22 [Turn over


PMT

10

25 Which row describes an atom of a noble gas?

number of number of number of


protons neutrons electrons

A 2 2 0
B 2 2 2
C 8 8 8
D 8 8 10

26 Some properties of four elements, P, Q, R and S, are shown.

Solid P reacts with dilute hydrochloric acid to give hydrogen.


Solid Q does not conduct electricity.
Solid R is used to make saucepans because it is a good conductor of heat.
Solid S reacts with oxygen to form a compound where atoms of S share electrons with
atoms of oxygen.

Which elements are metals?

A P and R B P and S C Q and R D Q and S

27 Which substance is used to reduce zinc oxide in the manufacture of zinc?

A carbon
B carbon dioxide
C hydrogen
D sulfur dioxide

© UCLES 2022 0620/23/M/J/22


PMT

11

28 Three metal compounds, J, K and L, are heated using a Bunsen burner.

The results are shown.

J colourless gas produced, which relights a glowing splint


K colourless gas produced, which turns limewater milky
L no reaction

Which row identifies J, K and L?

J K L

A magnesium carbonate potassium carbonate potassium nitrate


B magnesium carbonate potassium nitrate potassium carbonate
C potassium nitrate magnesium carbonate potassium carbonate
D potassium nitrate potassium carbonate magnesium carbonate

29 Nitrogen oxide, NO, is formed in the engine of petrol-powered cars.

One constituent of petrol is octane, C8H18.

Nitrogen oxide is removed from exhaust fumes by catalytic converters.

Which row identifies the reactants that produce nitrogen oxide and a reaction that removes it in a
catalytic converter?

reactants that produce NO reaction that removes NO

A octane + one gas found in air 2NO + 2CO  N2 + 2CO2


B octane + one gas found in air NO + CO2  NO2 + CO
C two gases found in air 2NO + 2CO  N2 + 2CO2
D two gases found in air NO + CO2  NO2 + CO

30 A magnesium block is attached to iron to prevent it from rusting.

Which statement about this method of rust prevention is correct?

A Magnesium corrodes instead of iron because it is more reactive.


B Magnesium prevents oxygen from reaching the iron.
C The iron does not rust because it has a greater tendency to form ions than magnesium.
D This method of rust prevention is called galvanising.

© UCLES 2022 0620/23/M/J/22 [Turn over


PMT

12

31 Fertilisers are used to provide three of the elements needed for plant growth.

Which two compounds would give a fertiliser containing all three of these elements?

A Ca(NO3)2 and (NH4)2SO4


B Ca(NO3)2 and (NH4)3PO4
C KNO3 and (NH4)2SO4
D KNO3 and (NH4)3PO4

32 Which processes increase the amount of carbon dioxide in the air?

1 combustion of hydrogen
2 combustion of methane
3 photosynthesis by plants
4 thermal decomposition of limestone

A 1 and 3 B 1 and 4 C 2 and 3 D 2 and 4

33 In the Contact process, sulfur dioxide is converted into sulfur trioxide.

2SO2(g) + O2(g) 2SO3(g)

What is the effect of lowering the pressure on the rate of formation and percentage yield of
sulfur trioxide at equilibrium?

rate of percentage
formation yield

A decreases decreases
B decreases increases
C increases decreases
D increases increases

34 What are the products when limestone (calcium carbonate) is heated strongly?

A calcium hydroxide and carbon dioxide


B calcium hydroxide and carbon monoxide
C calcium oxide and carbon dioxide
D calcium oxide and carbon monoxide

© UCLES 2022 0620/23/M/J/22


PMT

13

35 The structure of ester W is shown.

H O

H C C H

H O C H

Which row gives the names of ester W and the carboxylic acid and alcohol from which it is made?

name of ester W carboxylic acid alcohol

A ethyl methanoate ethanoic acid methanol


B ethyl methanoate methanoic acid ethanol
C methyl ethanoate ethanoic acid methanol
D methyl ethanoate methanoic acid ethanol

36 The equation for the reaction between butane, C4H10, and chlorine is shown.

C4H10 + Cl 2  C4H9Cl + HCl

Which type of reaction does butane undergo when it reacts with chlorine?

A addition
B reduction
C acid–base
D substitution

37 Butene has three structural isomers which are alkenes.

Which statements about these isomers are correct?

1 They have the same molecular formula.


2 They have different numbers of bonds in the molecule.
3 They have a C=C bond in the structure.

A 1 and 2 B 1 and 3 C 2 only D 3 only

© UCLES 2022 0620/23/M/J/22 [Turn over


PMT

14

38 The hydrocarbon C12H26 is cracked to give X and Y, as shown.

C12H26  X + Y

Which statement is correct?

A If X is C6H12 then Y will react with aqueous bromine.


B If X is C10H22 then Y can be used to make a polymer.
C If X is a hydrogen molecule then Y is an alkane.
D X and Y could be structural isomers.

39 An ester, C4H8O2, is made by reacting 0.06 mol of ethanol, C2H6O, and 0.05 mol of ethanoic acid,
C2H4O2.

C2H6O + C2H4O2  C4H8O2 + H2O

0.0375 mol of the ester was made.

What is the percentage yield and the Mr of the ester?

percentage
Mr
yield / %

A 62.5 48
B 75.0 48
C 62.5 88
D 75.0 88

40 Which type of compound is made when a protein is hydrolysed?

A alkene
B amino acid
C carboxylic acid
D sugar

© UCLES 2022 0620/23/M/J/22


PMT

15

BLANK PAGE

Permission to reproduce items where third-party owned material protected by copyright is included has been sought and cleared where possible. Every
reasonable effort has been made by the publisher (UCLES) to trace copyright holders, but if any items requiring clearance have unwittingly been included, the
publisher will be pleased to make amends at the earliest possible opportunity.

To avoid the issue of disclosure of answer-related information to candidates, all copyright acknowledgements are reproduced online in the Cambridge
Assessment International Education Copyright Acknowledgements Booklet. This is produced for each series of examinations and is freely available to download
at www.cambridgeinternational.org after the live examination series.

Cambridge Assessment International Education is part of Cambridge Assessment. Cambridge Assessment is the brand name of the University of Cambridge
Local Examinations Syndicate (UCLES), which is a department of the University of Cambridge.

© UCLES 2022 0620/23/M/J/22


The Periodic Table of Elements
Group
I II III IV V VI VII VIII

© UCLES 2022
1 2

H He
hydrogen helium
Key 1 4
3 4 atomic number 5 6 7 8 9 10

Li Be atomic symbol B C N O F Ne
lithium beryllium name boron carbon nitrogen oxygen fluorine neon
7 9 relative atomic mass 11 12 14 16 19 20
11 12 13 14 15 16 17 18
Na Mg Al Si P S Cl Ar
sodium magnesium aluminium silicon phosphorus sulfur chlorine argon
23 24 27 28 31 32 35.5 40
19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36
K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr
potassium calcium scandium titanium vanadium chromium manganese iron cobalt nickel copper zinc gallium germanium arsenic selenium bromine krypton
39 40 45 48 51 52 55 56 59 59 64 65 70 73 75 79 80 84
37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54

Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe
rubidium strontium yttrium zirconium niobium molybdenum technetium ruthenium rhodium palladium silver cadmium indium tin antimony tellurium iodine xenon
85 88 89 91 93 96 – 101 103 106 108 112 115 119 122 128 127 131
16

55 56 57–71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86
lanthanoids
Cs Ba Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn

0620/23/M/J/22
caesium barium hafnium tantalum tungsten rhenium osmium iridium platinum gold mercury thallium lead bismuth polonium astatine radon
133 137 178 181 184 186 190 192 195 197 201 204 207 209 – – –
87 88 89–103 104 105 106 107 108 109 110 111 112 114 116
actinoids
Fr Ra Rf Db Sg Bh Hs Mt Ds Rg Cn Fl Lv
francium radium rutherfordium dubnium seaborgium bohrium hassium meitnerium darmstadtium roentgenium copernicium flerovium livermorium
– – – – – – – – – – – – –

57 58 59 60 61 62 63 64 65 66 67 68 69 70 71
lanthanoids La Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu
lanthanum cerium praseodymium neodymium promethium samarium europium gadolinium terbium dysprosium holmium erbium thulium ytterbium lutetium
139 140 141 144 – 150 152 157 159 163 165 167 169 173 175
89 90 91 92 93 94 95 96 97 98 99 100 101 102 103
actinoids Ac Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No Lr
actinium thorium protactinium uranium neptunium plutonium americium curium berkelium californium einsteinium fermium mendelevium nobelium lawrencium
– 232 231 238 – – – – – – – – – – –

The volume of one mole of any gas is 24 dm3 at room temperature and pressure (r.t.p.).
PMT
PMT

Cambridge IGCSE™

CHEMISTRY 0620/22
Paper 2 Multiple Choice (Extended) February/March 2022
45 minutes

You must answer on the multiple choice answer sheet.


*3837715510*

You will need: Multiple choice answer sheet


Soft clean eraser
Soft pencil (type B or HB is recommended)

INSTRUCTIONS
 There are forty questions on this paper. Answer all questions.
 For each question there are four possible answers A, B, C and D. Choose the one you consider correct
and record your choice in soft pencil on the multiple choice answer sheet.
 Follow the instructions on the multiple choice answer sheet.
 Write in soft pencil.
 Write your name, centre number and candidate number on the multiple choice answer sheet in the
spaces provided unless this has been done for you.
 Do not use correction fluid.
 Do not write on any bar codes.
 You may use a calculator.

INFORMATION
 The total mark for this paper is 40.
 Each correct answer will score one mark.
 Any rough working should be done on this question paper.
 The Periodic Table is printed in the question paper.

This document has 16 pages. Any blank pages are indicated.

IB22 03_0620_22/RP
© UCLES 2022 [Turn over
PMT

1 Which gas has the fastest rate of diffusion?

A H2 B CH4 C CO2 D SO2

2 In which state does 1 dm3 of methane contain the most particles?

A gas at 100 C
B gas at room temperature
C liquid
D solid

3 Which statement explains why isotopes of the same element have the same chemical properties?

A They have the same electronic structure.


B They have the same relative mass.
C They have the same nucleon number.
D They have the same proton number.

4 The electronic structures of atoms P and Q are shown.

P Q

P and Q form an ionic compound.

What is the formula of the compound?

A PQ B P2Q C P2Q3 D PQ2

5 Fermentation of sugar produces a mixture of ethanol solution and solid yeast.

How is the solid yeast removed from the mixture?

A crystallisation
B distillation
C filtration
D fractional distillation

© UCLES 2022 0620/22/F/M/22


PMT

6 Which row explains why copper is a good conductor of electricity at room temperature?

copper ions electrons


move freely move freely

A no no
B no yes
C yes no
D yes yes

7 Which pair of statements about diamond and graphite is correct?

diamond graphite

A Diamond and graphite are both pure carbon. They are both macromolecules.
B Diamond and graphite can both be used as electrodes. Graphite is also used as a lubricant.
C Diamond has covalent bonds. Graphite has ionic bonds.
D Diamond is hard with a high melting point. Graphite is soft with a low melting point.

8 Sodium nitride contains the nitride ion, N3–.

Sodium nitride is unstable and decomposes into its elements.

What is the equation for the decomposition of sodium nitride?

A 2NaN3  2Na + 3N2

B 2Na3N  6Na + N2

C 2NaN3  Na2 + 3N2

D 2Na3N  6Na + 2N

9 Compound X contains carbon, hydrogen and oxygen only.

By mass, it contains 26.7% carbon and 2.2% hydrogen.

What is the empirical formula of X?

A CHO B C2HO C CH2O D CHO2

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10 Caesium fluoride is an ionic compound.

Which statements about caesium fluoride are correct?

1 It conducts electricity when solid.


2 It has a high melting point.
3 It is soluble in water.
4 It is highly volatile.

A 1 and 2 B 1 and 4 C 2 and 3 D 3 and 4

11 Which diagram shows the direction of movement of ions and electrons during the electrolysis of
molten sodium chloride?

A B
power power
supply supply

cathode anode cathode anode


e– e–

Na+ e Na+ e–

Cl – Cl –

C D
power power
supply supply

anode cathode anode cathode


– –
e e

Na+ e Na+ e–

Cl – Cl –

© UCLES 2022 0620/22/F/M/22


PMT

12 Calcium carbonate, CaCO3, reacts with dilute hydrochloric acid to produce carbon dioxide.

The equation for the reaction is shown. The relative formula mass of calcium carbonate is 100.

CaCO3 + 2HCl  CaCl 2 + H2O + CO2

10 g of calcium carbonate is reacted with an excess of dilute hydrochloric acid.

Which mass of carbon dioxide is produced?

A 2.2 g B 2.8 g C 4.4 g D 44 g

13 Molten sodium chloride and concentrated aqueous sodium chloride are electrolysed using
platinum electrodes.

What are the products at the negative electrode (cathode) in each electrolysis?

molten concentrated aqueous


sodium chloride sodium chloride

A hydrogen hydrogen
B hydrogen sodium
C sodium hydrogen
D sodium sodium

14 An object is electroplated with silver using an aqueous silver salt as the electrolyte.

Which row is correct?

the object to be the other electrode


electroplated is the is made from

A anode carbon
B anode silver
C cathode carbon
D cathode silver

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15 Which row describes the changes that occur in an endothermic reaction?

energy change temperature


A energy given out to decreases
the surroundings
B energy given out to increases
the surroundings
C energy taken in from decreases
the surroundings
D energy taken in from increases
the surroundings

16 Which statement about fuels is correct?

A Heat energy is only produced by burning fuels.


B Hydrogen is used as a fuel although it is difficult to store.
C Methane is a good fuel because it produces only water when burned.
D Uranium is burned in air to produce energy.

17 Which statement about endothermic and exothermic reactions is correct?

A In an endothermic reaction, less energy is absorbed in bond breaking than is released in


bond forming.
B In an endothermic reaction, the activation energy is always higher than in an exothermic
reaction.
C In an exothermic reaction, more energy is absorbed in bond breaking than is released in
bond forming.
D In an exothermic reaction, the reactants are higher on an energy level diagram than the
products.

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PMT

18 The reaction used to manufacture ammonia from nitrogen and hydrogen is reversible.

An equilibrium is established between ammonia, nitrogen and hydrogen.

Which statement describes the equilibrium?

A Both the forward reaction and the backward reaction have the same rate.
B The rate of the backward reaction is greater than the rate of the forward reaction.
C The rate of the forward reaction is greater than the rate of the backward reaction.
D The forward and backward reactions have both stopped.

19 How does increasing the concentration affect the reacting particles in a chemical reaction?

increases the proportion


increases the
of particles with the
collision rate
activation energy

A  
B  
C  
D  

20 Methyl orange is added to dilute hydrochloric acid and to aqueous sodium hydroxide.

What is the colour of the methyl orange in each solution?

colour in dilute colour in aqueous


hydrochloric acid sodium hydroxide

A orange red
B red yellow
C red orange
D yellow red

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21 Zinc oxide is an amphoteric oxide.

Which types of substances will react with zinc oxide?

A acids and bases


B acids only
C bases only
D neither acids nor bases

22 Information about some silver compounds is shown.

compound formula solubility in water

silver carbonate Ag2CO3 insoluble


silver chloride AgCl insoluble
silver nitrate AgNO3 soluble
silver oxide Ag2O insoluble

Which equation shows a reaction which cannot be used to make a silver salt?

A AgNO3(aq) + HCl (aq)  AgCl (s) + HNO3(aq)

B Ag2O(s) + 2HNO3(aq)  2AgNO3(aq) + H2O(l)

C Ag2CO3(s) + 2HNO3(aq)  2AgNO3(aq) + H2O(l) + CO2(g)

D 2Ag(s) + 2HCl (aq)  2AgCl (s) + H2(g)

23 Aqueous ethanoic acid is a weak acid.

Aqueous sodium hydroxide is a strong base.

Aqueous ethanoic acid is neutralised by aqueous sodium hydroxide.

Which statements are correct?

1 Aqueous ethanoic acid accepts protons from hydroxide ions.


2 The aqueous ethanoic acid used is fully dissociated into ions.
3 The aqueous sodium hydroxide used is fully dissociated into ions.
4 The reaction produces a salt and water.

A 1 and 2 B 1 and 3 C 2 and 4 D 3 and 4

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PMT

24 Three properties of element X are listed.

● It contains atoms with a full outer shell of electrons.


● It is monoatomic.
● It is unreactive.

In which part of the Periodic Table is the element placed?

A Group I
B Group VII
C Group VIII
D transition elements

25 Which word equation represents a reaction that occurs?

A sodium oxide + carbon  sodium + carbon dioxide

B sodium oxide + iron  sodium + iron(II) oxide

C iron(II) oxide + copper  iron + copper(II) oxide

D iron(III) oxide + carbon  iron + carbon dioxide

26 Which statement about the extraction of aluminium is correct?

A Aluminium is formed at the cathode during the electrolysis of aluminium oxide.


B Hematite is mainly aluminium oxide.
C Molten cryolite is used to raise the melting point of the aluminium oxide.
D Oxygen gains electrons at the anode during the electrolysis of aluminium oxide.

27 Metal M is mixed with copper to produce brass.

What is M?

A chromium
B nickel
C vanadium
D zinc

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10

28 The table gives some properties of an element.

melting point in C 3422


appearance of the element grey
appearance of the chloride of the element dark blue
density in g / cm3 19.2
electrical conductivity when solid good

Which other property does this element have?

A acts as a catalyst
B brittle
C forms an acidic oxide
D highly reactive with water

29 Ammonia is produced using the Haber process.

Which row shows the source of the raw materials and the reaction conditions?

source of source of temperature pressure


nitrogen hydrogen / C / atm

A air hydrocarbons 200 200


B hydrocarbons air 450 2
C air hydrocarbons 450 200
D air hydrocarbons 450 2

30 How many species are acting as bases in this reversible reaction?

HNO3 + H2O H3O+ + NO3–

A 3 B 2 C 1 D 0

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11

31 The equation for a reaction occurring in the Contact process is shown.

2SO2 + O2  2SO3

What is the catalyst used in this reaction?

A iron

B phosphoric(V) acid
C sulfuric acid

D vanadium(V) oxide

32 Which information about carbon dioxide and methane is correct?

carbon dioxide methane

A formed when vegetation decomposes   key


B greenhouse gas    = correct
C present in unpolluted air    = not correct
D produced during respiration  

33 The structure of an ester is shown.

H O

H C C H H H

H O C C C H

H H H

What are the names of the carboxylic acid and the alcohol that react together to form this ester?

carboxylic acid alcohol

A ethanoic acid ethanol


B ethanoic acid propan-1-ol
C propanoic acid ethanol
D propanoic acid propan-1-ol

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12

34 Which statements about lime are correct?

1 Lime is made by heating calcium carbonate (limestone).


2 Lime is used to desulfurise flue gases.
3 Lime is used to treat alkaline soil.
4 The chemical name for lime is calcium oxide.

A 1 and 3 B 1, 2 and 4 C 1 and 4 only D 2, 3 and 4

35 Which structure is correctly named?

A B C D

H H H H H H H H

H C C C O H H C C H H C C O H C C C H

H H O H H H H H H H
ethanoic acid ethene ethanol propane

36 The structure of part of a polymer is shown.

Cl H Cl H Cl

C C C C C

H CH3 H CH3 H

Which monomers can be used to make this polymer?

1 2 3 4

Cl CH3 Cl H CH3 H Cl CH3

C C C C C C C C

H H H CH3 Cl H H Cl

A 1 and 2 B 1 and 4 C 2 and 3 D 3 and 4

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13

37 Carboxylic acids are made by the oxidation of alcohols.

Which carboxylic acid is produced from CH3CH2OH?

A butanoic acid
B ethanoic acid
C methanoic acid
D propanoic acid

38 Propene, C3H6, reacts with bromine, Br2, in an addition reaction.

Which structure represents the product of this reaction?

A B C D
H H H H Br H H H H H H H

H C C C H H C C C H H C C C H Br C C C Br

Br H H H Br H Br Br H H H H

39 Which statements about ethanol are correct?

1 Ethanol is used as a solvent.


2 Ethanol can be made directly from ethane.
3 Ethanol is a covalent compound.

A 1 only B 1 and 2 C 1 and 3 D 2 and 3

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14

40 Which diagram represents the structure of nylon?

O O

A C O O C

O O

B C N C

O O

C C N N C

H H

O O

D C O N C

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15

BLANK PAGE

Permission to reproduce items where third-party owned material protected by copyright is included has been sought and cleared where possible. Every
reasonable effort has been made by the publisher (UCLES) to trace copyright holders, but if any items requiring clearance have unwittingly been included, the
publisher will be pleased to make amends at the earliest possible opportunity.

To avoid the issue of disclosure of answer-related information to candidates, all copyright acknowledgements are reproduced online in the Cambridge
Assessment International Education Copyright Acknowledgements Booklet. This is produced for each series of examinations and is freely available to download
at www.cambridgeinternational.org after the live examination series.

Cambridge Assessment International Education is part of Cambridge Assessment. Cambridge Assessment is the brand name of the University of Cambridge
Local Examinations Syndicate (UCLES), which is a department of the University of Cambridge.

© UCLES 2022 0620/22/F/M/22


The Periodic Table of Elements
Group
I II III IV V VI VII VIII

© UCLES 2022
1 2

H He
hydrogen helium
Key 1 4
3 4 atomic number 5 6 7 8 9 10

Li Be atomic symbol B C N O F Ne
lithium beryllium name boron carbon nitrogen oxygen fluorine neon
7 9 relative atomic mass 11 12 14 16 19 20
11 12 13 14 15 16 17 18
Na Mg Al Si P S Cl Ar
sodium magnesium aluminium silicon phosphorus sulfur chlorine argon
23 24 27 28 31 32 35.5 40
19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36
K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr
potassium calcium scandium titanium vanadium chromium manganese iron cobalt nickel copper zinc gallium germanium arsenic selenium bromine krypton
39 40 45 48 51 52 55 56 59 59 64 65 70 73 75 79 80 84
37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54

Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe
rubidium strontium yttrium zirconium niobium molybdenum technetium ruthenium rhodium palladium silver cadmium indium tin antimony tellurium iodine xenon
85 88 89 91 93 96 – 101 103 106 108 112 115 119 122 128 127 131
16

55 56 57–71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86
lanthanoids
Cs Ba Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn

0620/22/F/M/22
caesium barium hafnium tantalum tungsten rhenium osmium iridium platinum gold mercury thallium lead bismuth polonium astatine radon
133 137 178 181 184 186 190 192 195 197 201 204 207 209 – – –
87 88 89–103 104 105 106 107 108 109 110 111 112 114 116
actinoids
Fr Ra Rf Db Sg Bh Hs Mt Ds Rg Cn Fl Lv
francium radium rutherfordium dubnium seaborgium bohrium hassium meitnerium darmstadtium roentgenium copernicium flerovium livermorium
– – – – – – – – – – – – –

57 58 59 60 61 62 63 64 65 66 67 68 69 70 71
lanthanoids La Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu
lanthanum cerium praseodymium neodymium promethium samarium europium gadolinium terbium dysprosium holmium erbium thulium ytterbium lutetium
139 140 141 144 – 150 152 157 159 163 165 167 169 173 175
89 90 91 92 93 94 95 96 97 98 99 100 101 102 103
actinoids Ac Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No Lr
actinium thorium protactinium uranium neptunium plutonium americium curium berkelium californium einsteinium fermium mendelevium nobelium lawrencium
– 232 231 238 – – – – – – – – – – –

The volume of one mole of any gas is 24 dm3 at room temperature and pressure (r.t.p.).
PMT
PMT

Cambridge IGCSE™

CHEMISTRY 0620/22
Paper 2 Multiple Choice (Extended) February/March 2023
45 minutes

You must answer on the multiple choice answer sheet.


*5975357987*

You will need: Multiple choice answer sheet


Soft clean eraser
Soft pencil (type B or HB is recommended)

INSTRUCTIONS
 There are forty questions on this paper. Answer all questions.
 For each question there are four possible answers A, B, C and D. Choose the one you consider correct
and record your choice in soft pencil on the multiple choice answer sheet.
 Follow the instructions on the multiple choice answer sheet.
 Write in soft pencil.
 Write your name, centre number and candidate number on the multiple choice answer sheet in the
spaces provided unless this has been done for you.
 Do not use correction fluid.
 Do not write on any bar codes.
 You may use a calculator.

INFORMATION
 The total mark for this paper is 40.
 Each correct answer will score one mark.
 Any rough working should be done on this question paper.
 The Periodic Table is printed in the question paper.

This document has 16 pages. Any blank pages are indicated.

IB23 03_0620_22/2RP
© UCLES 2023 [Turn over
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1 Substance M is a solid at 30 C.

The substance is heated to 80 C and its temperature measured as it cools down to room
temperature.

The cooling curve is shown.

80 P
temperature / qC
60
R
40 Q
20 S T
0
0
time

Between which times is substance M freezing?

A P to Q B Q to R C R to S D S to T

2 Which gas has the fastest rate of diffusion?

A Ar B C2H6 C HCl D H2S

3 There are two stable isotopes of bromine.

The mass number of isotope 1 is 79.

The mass number of isotope 2 is 81.

Which statement is correct?

A The isotopes have the same number of neutrons.


B The isotopes have different chemical properties.
C The isotopes have different numbers of protons.
D The isotopes have the same number of outer electrons.

4 Which statement about ions and ionic bonds is correct?

A Bromine atoms form negatively charged bromide ions.


B Ionic bonds form between elements in Group VII of the Periodic Table.
C Positive ions are formed when atoms lose protons.
D Potassium iodide contains negatively charged potassium ions.

© UCLES 2023 0620/22/F/M/23


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5 Part of the Periodic Table is shown.

F G

Which type of chemical bonding is present in the oxide of F and in the oxide of G?

oxide of F oxide of G

A covalent covalent
B covalent ionic
C ionic covalent
D ionic ionic

6 Elements X and Y react to form a compound.

Element X loses two electrons and element Y gains one electron.

What is the charge on the ions of elements X and Y and what is the formula of the compound?

formula of
charge on X charge on Y
compound

A 2+ – X2Y
B 2+ – XY2
C 2– + X2Y
D 2– + XY2

7 Which statement about graphite explains why it is used as an electrode?

A It contains ions.
B It has a giant covalent structure.
C It is a metal.
D It has mobile electrons.

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8 Methane, CH4, burns in air to form carbon dioxide and water.

What is the balanced equation for this reaction?

A CH4(g) + O2(g)  CO2(g) + 2H2O(g)

B CH4(g) + 2O2(g)  CO2(g) + 2H2O(g)

C CH4(g) + 2O2(g)  CO2(g) + H2O(g)

D CH4(g) + 3O2(g)  CO2(g) + 2H2O(g)

9 The equation for the thermal decomposition of sodium hydrogencarbonate is shown.

2NaHCO3  Na2CO3 + H2O + CO2

The Mr of sodium hydrogencarbonate, NaHCO3, is 84.

The Mr of sodium carbonate, Na2CO3, is 106.

In an experiment, 2.1 g of sodium hydrogencarbonate is heated but not all of it decomposes. All of
the carbon dioxide is collected and measured at room temperature and pressure. The total
volume of carbon dioxide produced is 0.21 dm3.

The volume of 1 mole of a gas at room temperature and pressure is 24 dm3.

Which statement is correct?

A The mass of sodium carbonate produced is 0.93 g.


B The mass of sodium carbonate produced is 1.33 g.
C The percentage yield of carbon dioxide is 10%.
D The percentage yield of carbon dioxide is 35%.

10 An electrolysis experiment is done using carbon electrodes.

Hydrogen and oxygen are formed at the electrodes.

What is the electrolyte?

A aqueous copper(II) sulfate

B concentrated hydrochloric acid


C dilute aqueous sodium chloride
D molten potassium oxide

© UCLES 2023 0620/22/F/M/23


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11 Concentrated aqueous copper(II) sulfate is electrolysed using copper electrodes.

Which ionic half-equation describes the reaction taking place at the cathode?

A 2H+ + 2e–  H2

B 4OH–  O2 + 2H2O + 4e–

C Cu  Cu2+ + 2e–

D Cu2+ + 2e–  Cu

12 When powdered sodium carbonate and aqueous ethanoic acid are mixed, the temperature of the
mixture falls.

Which statement about this reaction is correct?

A The reaction is endothermic and ∆H is negative.


B The reaction is endothermic and ∆H is positive.

C The reaction is exothermic and H is negative.


D The reaction is exothermic and ∆H is positive.

13 Magnesium powder reacts with an excess of dilute hydrochloric acid to produce hydrogen gas.

Which statements about this reaction are correct?

1 The smaller the particles of magnesium powder, the more slowly the hydrogen is
produced.
2 The higher the temperature, the faster the magnesium powder disappears.
3 The lower the concentration of dilute hydrochloric acid, the faster the rate of
reaction.
4 The faster the magnesium powder disappears, the faster the rate of reaction.

A 1 and 2 B 2 and 3 C 2 and 4 D 3 and 4

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14 The reaction between two aqueous compounds, X and Y, is slow and exothermic.

The graph shows how the rate of this reaction changes with time.

rate

0
0
time

A student suggests that the rate of reaction decreases with time because:

1 the activation energy decreases


2 the speed of the molecules of X and Y decreases
3 the concentration of both X and Y decreases with time.

Which suggestions are correct?

A 1 and 2 B 1 and 3 C 2 only D 3 only

15 Hydrogen reacts with iodine to form hydrogen iodide.

H2(g) + I2(g)  2HI(g)

Which statements explain why the reaction is faster when the pressure is increased, at constant
temperature?

1 At higher pressure, the molecules are moving faster.


2 At higher pressure, more of the molecules have the required activation energy.
3 At higher pressure, the molecules are closer together.
4 At higher pressure, the molecules collide more frequently.

A 1 and 2 B 1 and 3 C 2 and 4 D 3 and 4

© UCLES 2023 0620/22/F/M/23


PMT

16 Ammonium sulfate is used as a fertiliser.

It is made from ammonia and sulfuric acid.

The ......1...... is made by the ......2...... process in which ......3...... is used as a catalyst.

Which words complete gaps 1, 2 and 3?

1 2 3

A ammonia Contact iron


B ammonia Haber vanadium(V) oxide
C sulfuric acid Contact vanadium(V) oxide
D sulfuric acid Haber iron

17 The reversible reaction shown takes place in a closed system at constant temperature.

P(g) + Q(g) + R(g) S(g) + T(g)

When the reaction has reached equilibrium, more T is added.

After the addition of T, which other substances increase in concentration?

A P, Q, R and S
B P and Q only
C P, Q and R only
D S only

18 In which equation is the underlined substance acting as a reducing agent?

A 3CO + Fe2O3  2Fe + 3CO2

B CO2 + C  2CO

C CuO + H2  Cu + H2O

D CaO + H2O  Ca(OH)2

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19 An aqueous solution reacts with a solid. The products are an alkaline gas, a salt and water.

What are the aqueous solution and the solid?

aqueous solution solid

A sodium hydroxide magnesium carbonate


B hydrochloric acid magnesium carbonate
C hydrochloric acid ammonium chloride
D sodium hydroxide ammonium chloride

20 Butanoic acid partially dissociates in aqueous solution.

Which row about butanoic acid is correct?

effect on
pH
thymolphthalein

A 3 turns blue
B 5 turns colourless
C 8 turns blue
D 10 turns colourless

21 Copper(II) sulfate is prepared by adding excess copper(II) carbonate to sulfuric acid.

Why is an excess of copper(II) carbonate added?

A to ensure all the copper(II) carbonate has reacted


B to ensure all the sulfuric acid has reacted
C to increase the rate of reaction

D to increase the amount of copper(II) sulfate produced

22 Part of the Periodic Table is shown.

Which element has two electrons in its outer shell and three electron shells?

A B
C D

© UCLES 2023 0620/22/F/M/23


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23 Elements in Group I and Group II show the same trends in their reactions with water and in their
density.

Which row shows how the properties of barium compare with calcium?

reaction
density
with water

A faster higher
B faster lower
C slower higher
D slower lower

24 Which pair of compounds shows a transition element in two different oxidation states?

A Cr2O3 and Cr2(SO4)3


B Cu2O and CuCO3
C ZnS and ZnSO4
D NiO and Ni(NO3)2

25 Which description of brass is correct?

A a compound of copper and zinc


B a compound of copper and tin
C a mixture of copper and zinc
D a mixture of copper and tin

26 What is the symbol of the metal used in the manufacture of aircraft because of its low density?

A Al B Cu C Fe D Zn

27 Which substances react to form hydrogen gas?

1 calcium and water


2 silver and dilute hydrochloric acid
3 magnesium and steam
4 zinc and dilute hydrochloric acid

A 1, 3 and 4 B 1 and 3 only C 2 and 4 D 4 only

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10

28 Coke (carbon) and limestone are two raw materials used in the extraction of iron from hematite.

Which type of reaction occurs when each substance is heated during the process?

coke limestone

A redox redox
B redox thermal decomposition
C thermal decomposition redox
D thermal decomposition thermal decomposition

29 Some combustion reactions produce pollutant gases.

Which reactions produce a pollutant gas that is not present in clean air?

1 2CH4 + 3O2  2CO + 4H2O

2 2H2 + O2  2H2O

3 C + O2  CO2

4 N2 + O2  2NO

A 1 and 3 B 1 and 4 C 2 and 3 D 3 and 4

30 One mole of alkane Y produces 72 dm3 of carbon dioxide when burned in excess oxygen,
measured at room temperature and pressure.

What is Y?

A butane
B ethane
C methane
D propane

© UCLES 2023 0620/22/F/M/23


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11

31 The structure of organic compound X is shown.

H O H

H C C O C H

H H

What is X?

A ethyl ethanoate
B ethyl methanoate
C methyl ethanoate
D methyl methanoate

32 What is the structural formula of the compound formed in the addition reaction of propene with
bromine?

A CH3CHBrCH2Br
B CH2BrCH2CH2Br
C CHBr2CH2CH3
D CH3CBr2CH3

33 Ethanol is produced industrially by fermentation and also by a catalysed addition reaction


involving steam.

Which row describes one advantage of each process?

catalysed addition reaction


fermentation
involving steam

A the reactant used is renewable it is a continuous process


B the reactant used is renewable it requires little energy
C it is a very rapid reaction it is a continuous process
D it is a very rapid reaction it requires little energy

34 Carboxylic acids react with alcohols when warmed with an acid catalyst.

Which type of substance is formed in this reaction?

A an alkene
B an ester
C a salt
D a polymer

© UCLES 2023 0620/22/F/M/23 [Turn over


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12

35 Nylon is formed by condensation polymerisation.

Which structure represents nylon?

O O O O

A C N C N C N C N

H H H H

O O O O

B C N N C C N N C

H H H H

O O O O

C C C N N C C N N

H H H H

O O O O

D C C O N N O C C O N

H H H

36 Which structure represents the repeat unit of the addition polymer formed from but-1-ene?

A B C D
H C 2H 5 CH3 CH3 H H CH3 H H H H

C C C C C C C C C C C

H H H H H H H H H H H

37 2.00 g of powdered calcium carbonate is added to 50.0 cm3 of hydrochloric acid.

Which apparatus is used to measure these quantities of calcium carbonate and


hydrochloric acid?

calcium carbonate hydrochloric acid

A balance burette
B balance thermometer
C pipette burette
D pipette thermometer

© UCLES 2023 0620/22/F/M/23


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13

38 The diagram shows a chromatogram obtained from the colours of three different sweets, X, Y
and Z.

red red

yellow yellow yellow


red red

sweet X sweet Y sweet Z

How many different red dyes are present in the sweets?

A 1 B 2 C 3 D 4

39 A mixture contains sand and an aqueous solution of sodium chloride.

Which processes are used to obtain a sample of solid sand and a sample of solid
sodium chloride from the mixture?

A crystallisation followed by filtration


B evaporation followed by filtration
C filtration followed by crystallisation
D simple distillation followed by crystallisation

40 A student tests an unknown compound M.

The compound:

● produces a lilac flame using a flame test


● produces a gas which turns limewater cloudy when dilute hydrochloric acid is added.

What is M?

A sodium sulfate
B sodium carbonate
C potassium sulfate
D potassium carbonate

© UCLES 2023 0620/22/F/M/23


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14

BLANK PAGE

© UCLES 2023 0620/22/F/M/23


PMT

15

BLANK PAGE

Permission to reproduce items where third-party owned material protected by copyright is included has been sought and cleared where possible. Every
reasonable effort has been made by the publisher (UCLES) to trace copyright holders, but if any items requiring clearance have unwittingly been included, the
publisher will be pleased to make amends at the earliest possible opportunity.

To avoid the issue of disclosure of answer-related information to candidates, all copyright acknowledgements are reproduced online in the Cambridge
Assessment International Education Copyright Acknowledgements Booklet. This is produced for each series of examinations and is freely available to download
at www.cambridgeinternational.org after the live examination series.

Cambridge Assessment International Education is part of Cambridge Assessment. Cambridge Assessment is the brand name of the University of Cambridge
Local Examinations Syndicate (UCLES), which is a department of the University of Cambridge.

© UCLES 2023 0620/22/F/M/23


The Periodic Table of Elements
Group

© UCLES 2023
I II III IV V VI VII VIII
1 2

H He
hydrogen helium
Key 1 4
3 4 atomic number 5 6 7 8 9 10

Li Be atomic symbol B C N O F Ne
lithium beryllium name boron carbon nitrogen oxygen fluorine neon
7 9 relative atomic mass 11 12 14 16 19 20
11 12 13 14 15 16 17 18
Na Mg Al Si P S Cl Ar
sodium magnesium aluminium silicon phosphorus sulfur chlorine argon
23 24 27 28 31 32 35.5 40
19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36
K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr
potassium calcium scandium titanium vanadium chromium manganese iron cobalt nickel copper zinc gallium germanium arsenic selenium bromine krypton
39 40 45 48 51 52 55 56 59 59 64 65 70 73 75 79 80 84
37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54

Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe
rubidium strontium yttrium zirconium niobium molybdenum technetium ruthenium rhodium palladium silver cadmium indium tin antimony tellurium iodine xenon
16

85 88 89 91 93 96 – 101 103 106 108 112 115 119 122 128 127 131
55 56 57–71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86

0620/22/F/M/23
lanthanoids
Cs Ba Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn
caesium barium hafnium tantalum tungsten rhenium osmium iridium platinum gold mercury thallium lead bismuth polonium astatine radon
133 137 178 181 184 186 190 192 195 197 201 204 207 209 – – –
87 88 89–103 104 105 106 107 108 109 110 111 112 113 114 115 116 117 118
actinoids
Fr Ra Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
francium radium rutherfordium dubnium seaborgium bohrium hassium meitnerium darmstadtium roentgenium copernicium nihonium flerovium moscovium livermorium tennessine oganesson
– – – – – – – – – – – – – – – – –

57 58 59 60 61 62 63 64 65 66 67 68 69 70 71
lanthanoids La Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu
lanthanum cerium praseodymium neodymium promethium samarium europium gadolinium terbium dysprosium holmium erbium thulium ytterbium lutetium
139 140 141 144 – 150 152 157 159 163 165 167 169 173 175
89 90 91 92 93 94 95 96 97 98 99 100 101 102 103
actinoids Ac Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No Lr
actinium thorium protactinium uranium neptunium plutonium americium curium berkelium californium einsteinium fermium mendelevium nobelium lawrencium
– 232 231 238 – – – – – – – – – – –

The volume of one mole of any gas is 24 dm3 at room temperature and pressure (r.t.p.).
PMT
PMT

Cambridge IGCSE™

CHEMISTRY 0620/21
Paper 2 Multiple Choice (Extended) October/November 2022
45 minutes

You must answer on the multiple choice answer sheet.


*6240325308*

You will need: Multiple choice answer sheet


Soft clean eraser
Soft pencil (type B or HB is recommended)

INSTRUCTIONS
 There are forty questions on this paper. Answer all questions.
 For each question there are four possible answers A, B, C and D. Choose the one you consider correct
and record your choice in soft pencil on the multiple choice answer sheet.
 Follow the instructions on the multiple choice answer sheet.
 Write in soft pencil.
 Write your name, centre number and candidate number on the multiple choice answer sheet in the
spaces provided unless this has been done for you.
 Do not use correction fluid.
 Do not write on any bar codes.
 You may use a calculator.

INFORMATION
 The total mark for this paper is 40.
 Each correct answer will score one mark.
 Any rough working should be done on this question paper.
 The Periodic Table is printed in the question paper.

This document has 16 pages. Any blank pages are indicated.

IB22 11_0620_21/3RP
© UCLES 2022 [Turn over
PMT

1 The diagram shows the changes of state between a solid, a liquid and a gas.

1 2
solid liquid gas
3 4

In which changes of state is energy being given out?

A 1 and 2 B 1 and 4 C 2 and 3 D 3 and 4

2 A coloured dye is separated by chromatography.

One component of the dye moves a distance of 13 cm and has an Rf value of 0.86.

Which distance did the solvent front move?

A 6.6 cm B 11.9 cm C 15.1 cm D 21.6 cm

3 A mixture contains salt, sand and sulfur.

Salt dissolves in water but not in xylene.

Sulfur dissolves in xylene but not in water.

Sand does not dissolve in water or xylene.

What is the order of the processes used to separate the salt, the sand and the sulfur from the
mixture?

A add water  filter  add xylene to the filtrate  filter

B add water  filter  add xylene to the residue  filter

C add xylene  filter  add water to the filtrate  filter

D add xylene  filter  add xylene to the residue  filter

4 Which statements about isotopes of the same element are correct?

1 They are atoms which have the same chemical properties because they have the
same number of electrons in their outer shell.
2 They are atoms which have the same number of electrons and neutrons but
different numbers of protons.
3 They are atoms which have the same number of electrons and protons but different
numbers of neutrons.

A 1 and 2 B 1 and 3 C 2 only D 3 only

© UCLES 2022 0620/21/O/N/22


PMT

5 Which type of structure and bonding is present in an element that is malleable and conducts
electricity?

A covalent molecular
B ionic lattice
C covalent macromolecular
D metallic lattice

6 Which statements about potassium bromide are correct?

1 It has a high melting point.


2 It dissolves in water.
3 It conducts electricity when solid.

A 1 and 2 B 1 and 3 C 2 and 3 D 3 only

7 Which substance has a similar structure to silicon(IV) oxide?

A carbon dioxide
B diamond
C graphite
D sodium oxide

8 Caffeine is a stimulant found in coffee.

O CH3

H 3C C N
N C
C H
C C
N
O N

CH3

caffeine

Which formula represents caffeine?

A C7H10N4O2 B C8H10N3O2 C C8H10N4O2 D C8H11N4O2

© UCLES 2022 0620/21/O/N/22 [Turn over


PMT

9 4.55 g of zinc is reacted with 50 cm3 of 2.25 mol / dm3 dilute hydrochloric acid.

The equation for the reaction is shown.

Zn + 2HCl  ZnCl 2 + H2

Which volume of hydrogen gas, at room temperature and pressure, is produced in the reaction?

A 1.35 dm3 B 1.67 dm3 C 2.70 dm3 D 3.34 dm3

10 In the electrolysis diagram, oxidation is occurring at electrode 1 and reduction at electrode 2.

battery

electrode 1 electrode 2

electrolyte

Which row shows the directions of movement of the electrons in the external circuit and of the
positive ions in the electrolyte?

direction of movement of direction of movement of


electrons in external circuit positive ions in electrolyte

A 12 12
B 12 21
C 21 12
D 21 21

11 When an acid is added to an alkali, the temperature of the reaction mixture rises.

Which words describe this reaction?

A decomposition and endothermic


B decomposition and exothermic
C neutralisation and endothermic
D neutralisation and exothermic

© UCLES 2022 0620/21/O/N/22


PMT

12 Some properties of four fuels are shown.

Which fuel is a gas at room temperature and makes two products when it burns in a plentiful
supply of air?

melting point boiling point


fuel formula
/ C / C

A hydrogen H2 –259 –253


B methane CH4 –182 –164
C octane C8H18 –57 126
D wax C31H64 60 400

13 Ethene can undergo complete combustion, as shown.

H H

C C + 3O O 2O C O + 2H O H

H H

Some bond energies are given in the table.

bond energy
bond
in kJ / mol

C=C 612
C–H 412
O–H 463
O=O 496

The energy change of the reaction is –1408 kJ / mol.

What is the bond energy of the C=O bond in CO2?

A 454 kJ / mol B 673 kJ / mol C 826 kJ / mol D 1619 kJ / mol

© UCLES 2022 0620/21/O/N/22 [Turn over


PMT

14 A student adds excess zinc to dilute hydrochloric acid at 25 C.

The hydrogen gas produced is collected and measured at room temperature and pressure.

The results are plotted and labelled as curve X on the graph.

The experiment is repeated at 50 C with all other conditions remaining the same.

Which graph shows the results at 50 C?

volume of X
hydrogen gas C

0
0 time

15 Dinitrogen tetroxide, N2O4, is converted into nitrogen dioxide, NO2, in a reversible reaction.

N2O4(g) 2NO2(g)

The forward reaction is endothermic.

Which conditions give the highest equilibrium yield of nitrogen dioxide?

pressure
temperature
/ atmospheres

A 2 high
B 2 low
C 50 high
D 50 low

© UCLES 2022 0620/21/O/N/22


PMT

16 When magnesium is heated with zinc oxide a reaction occurs.

The equation is shown.

Mg + ZnO  MgO + Zn

Which substance is oxidised?

A magnesium
B magnesium oxide
C zinc
D zinc oxide

17 The diagram shows an experiment.

aqueous P

tap

solid Q

A small volume of aqueous P is poured on to solid Q and the tap of the funnel closed.

Which pairs of substances cause the syringe to fill with gas?

HNO3 HCl H2SO4


and and and
Mg Cu Na2CO3

A   
B   
C   
D   

© UCLES 2022 0620/21/O/N/22 [Turn over


PMT

18 Ethanoic acid reacts with water to produce an acidic solution.

Which row describes the roles of ethanoic acid and water in this reaction?

ethanoic acid water

A accepts a proton donates a proton


B accepts an electron donates an electron
C donates a proton accepts a proton
D donates an electron accepts an electron

19 Aqueous ammonium sulfate is made by reacting aqueous ammonia with dilute sulfuric acid.

How is solid ammonium sulfate obtained from the resulting solution?

A crystallisation
B distillation
C filtration
D solvent extraction

20 Carbon forms two oxides: carbon monoxide, CO, and carbon dioxide, CO2.

Which row describes these two oxides?

CO CO2

A acidic acidic
B acidic neutral
C neutral acidic
D neutral neutral

21 Group II elements show the same trends as Group I elements.

Which statement about elements in Group II is correct?

A The melting point of barium is higher than the melting point of calcium.
B Barium is more reactive than beryllium.
C Strontium would not react with oxygen.
D Magnesium is more dense than barium.

© UCLES 2022 0620/21/O/N/22


PMT

22 Some information about properties of Group I elements is shown.

melting point density


element
/ C in g / cm3

lithium 181 0.53


sodium 98 0.97
potassium X
rubidium Y Z

What are the values for X, Y and Z?

X Y Z

A 63 252 0.26
B 63 39 0.26
C 39 63 1.53
D 63 39 1.53

23 Which statements describe properties of transition elements?

1 They form coloured compounds.


2 They have variable oxidation states.
3 They have low densities.
4 They are volatile.

A 1 and 2 B 1 and 4 C 2 and 3 D 3 and 4

24 Which statement about the extraction of aluminium by electrolysis is correct?

A Aluminium is extracted from its ore, cryolite.


B Aluminium is formed at the positive electrode.
C Bauxite is used to lower the temperature of the extraction process.
D Graphite is used for both the positive and negative electrodes.

© UCLES 2022 0620/21/O/N/22 [Turn over


PMT

10

25 Copper(II) nitrate and zinc carbonate are heated strongly in separate test-tubes.

Which row identifies the gases produced?

copper(II) nitrate zinc carbonate

A oxygen and nitrogen dioxide carbon dioxide only


B oxygen and nitrogen dioxide carbon dioxide and oxygen
C nitrogen dioxide only carbon dioxide and oxygen
D nitrogen dioxide only carbon dioxide only

26 Iron from a blast furnace can be converted to steel.

Which statements about steel are correct?

1 Steel contains more carbon than the iron obtained from the blast furnace.
2 Steel is produced by blowing oxygen through the iron.
3 Calcium oxide is added to molten iron to remove basic oxides.

A 1 and 2 B 1 and 3 C 2 and 3 D 2 only

27 Which metal is used to galvanise steel?

A copper
B lead
C tin
D zinc

© UCLES 2022 0620/21/O/N/22


PMT

11

28 The diagram shows a stage in the purification of dirty water.

dirty water
sand
pot with holes
fine gravel in bottom

coarse gravel

Which process does this apparatus show?

A chlorination
B condensation
C distillation
D filtration

29 Which substance in polluted air damages stonework and kills trees?

A carbon dioxide
B carbon monoxide
C lead compounds
D sulfur dioxide

30 Which row explains why a high temperature and an iron catalyst are used in the manufacture of
ammonia by the Haber process?

high temperature iron catalyst

A increases the rate of the reaction increases the equilibrium yield of ammonia
B increases the rate of the reaction increases the rate of the reaction
C increases the equilibrium yield of ammonia increases the equilibrium yield of ammonia
D increases the equilibrium yield of ammonia increases the rate of the reaction

© UCLES 2022 0620/21/O/N/22 [Turn over


PMT

12

31 The scheme shows four stages in the conversion of sulfur to sulfuric acid.

In which stage is a catalyst used?

stage A sulfur stage B sulfur


sulfur
air dioxide air trioxide

concentrated
stage C
sulfuric acid

concentrated stage D
oleum
sulfuric acid water

32 Which element has an oxide that is used as a food preservative?

A helium
B hydrogen
C iron
D sulfur

33 Which substance gives off carbon dioxide on heating?

A lime
B limestone
C limewater
D slaked lime

34 Which formula represents ethanol?

A CH3CH3 B CH2CH2 C CH3CH2OH D CH3COOH

35 Which statement about structural isomers is correct?

A They have the same structure but different reactivity.


B They have the same general formula but a different number of carbon atoms in their
molecules.
C They have the same structure but different relative molecular masses.
D They have different structures but the same numbers of each type of atom.

© UCLES 2022 0620/21/O/N/22


PMT

13

36 Which formula is the same in methanol, ethanol and propanol?

A empirical formula
B general formula
C molecular formula
D structural formula

37 Ethene reacts with water under suitable conditions.

Which statement about this reaction is correct?

A The product of this reaction has an Mr of 46.


B The reaction produces two different products.
C The reaction occurs when ethene gas is bubbled into cold water in the presence of an acid
catalyst.
D The reaction is a redox reaction.

38 Ethanoic acid is made by reacting ethanol with acidified potassium manganate(VII).

Which type of reaction occurs when ethanol reacts with acidified potassium manganate(VII)?

A displacement
B fermentation
C oxidation
D neutralisation

© UCLES 2022 0620/21/O/N/22 [Turn over


PMT

14

39 Which structure represents Terylene?

H O O O

A N C N C N C

H H

B O O O

C C O O C
C
O O O

H H O O

D N C N C N C

O H

40 The equation shows the formation of a polymer called Kevlar.

n HOOC COOH + n H 2N NH2

– H2 O

O O

C C N N

H H n

Which row describes Kevlar?

how the polymer is formed type of polymer

A addition polymerisation polyamide


B addition polymerisation polyester
C condensation polymerisation polyamide
D condensation polymerisation polyester

© UCLES 2022 0620/21/O/N/22


PMT

15

BLANK PAGE

Permission to reproduce items where third-party owned material protected by copyright is included has been sought and cleared where possible. Every
reasonable effort has been made by the publisher (UCLES) to trace copyright holders, but if any items requiring clearance have unwittingly been included, the
publisher will be pleased to make amends at the earliest possible opportunity.

To avoid the issue of disclosure of answer-related information to candidates, all copyright acknowledgements are reproduced online in the Cambridge
Assessment International Education Copyright Acknowledgements Booklet. This is produced for each series of examinations and is freely available to download
at www.cambridgeinternational.org after the live examination series.

Cambridge Assessment International Education is part of Cambridge Assessment. Cambridge Assessment is the brand name of the University of Cambridge
Local Examinations Syndicate (UCLES), which is a department of the University of Cambridge.

© UCLES 2022 0620/21/O/N/22


The Periodic Table of Elements
Group
I II III IV V VI VII VIII

© UCLES 2022
1 2

H He
hydrogen helium
Key 1 4
3 4 atomic number 5 6 7 8 9 10

Li Be atomic symbol B C N O F Ne
lithium beryllium name boron carbon nitrogen oxygen fluorine neon
7 9 relative atomic mass 11 12 14 16 19 20
11 12 13 14 15 16 17 18
Na Mg Al Si P S Cl Ar
sodium magnesium aluminium silicon phosphorus sulfur chlorine argon
23 24 27 28 31 32 35.5 40
19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36
K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr
potassium calcium scandium titanium vanadium chromium manganese iron cobalt nickel copper zinc gallium germanium arsenic selenium bromine krypton
39 40 45 48 51 52 55 56 59 59 64 65 70 73 75 79 80 84
37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54

Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe
rubidium strontium yttrium zirconium niobium molybdenum technetium ruthenium rhodium palladium silver cadmium indium tin antimony tellurium iodine xenon
85 88 89 91 93 96 – 101 103 106 108 112 115 119 122 128 127 131
16

55 56 57–71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86
lanthanoids
Cs Ba Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn

0620/21/O/N/22
caesium barium hafnium tantalum tungsten rhenium osmium iridium platinum gold mercury thallium lead bismuth polonium astatine radon
133 137 178 181 184 186 190 192 195 197 201 204 207 209 – – –
87 88 89–103 104 105 106 107 108 109 110 111 112 114 116
actinoids
Fr Ra Rf Db Sg Bh Hs Mt Ds Rg Cn Fl Lv
francium radium rutherfordium dubnium seaborgium bohrium hassium meitnerium darmstadtium roentgenium copernicium flerovium livermorium
– – – – – – – – – – – – –

57 58 59 60 61 62 63 64 65 66 67 68 69 70 71
lanthanoids La Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu
lanthanum cerium praseodymium neodymium promethium samarium europium gadolinium terbium dysprosium holmium erbium thulium ytterbium lutetium
139 140 141 144 – 150 152 157 159 163 165 167 169 173 175
89 90 91 92 93 94 95 96 97 98 99 100 101 102 103
actinoids Ac Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No Lr
actinium thorium protactinium uranium neptunium plutonium americium curium berkelium californium einsteinium fermium mendelevium nobelium lawrencium
– 232 231 238 – – – – – – – – – – –

The volume of one mole of any gas is 24 dm3 at room temperature and pressure (r.t.p.).
PMT
PMT

Cambridge IGCSE™

CHEMISTRY 0620/22
Paper 2 Multiple Choice (Extended) October/November 2022
45 minutes

You must answer on the multiple choice answer sheet.


*7173935082*

You will need: Multiple choice answer sheet


Soft clean eraser
Soft pencil (type B or HB is recommended)

INSTRUCTIONS
 There are forty questions on this paper. Answer all questions.
 For each question there are four possible answers A, B, C and D. Choose the one you consider correct
and record your choice in soft pencil on the multiple choice answer sheet.
 Follow the instructions on the multiple choice answer sheet.
 Write in soft pencil.
 Write your name, centre number and candidate number on the multiple choice answer sheet in the
spaces provided unless this has been done for you.
 Do not use correction fluid.
 Do not write on any bar codes.
 You may use a calculator.

INFORMATION
 The total mark for this paper is 40.
 Each correct answer will score one mark.
 Any rough working should be done on this question paper.
 The Periodic Table is printed in the question paper.

This document has 16 pages.

IB22 11_0620_22/4RP
© UCLES 2022 [Turn over
PMT

1 The rate of diffusion of three gases, ammonia, carbon dioxide and methane, is measured.

What is the order of the rate of diffusion of the gases from slowest to fastest?

A CO2  NH3  CH4

B CO2  CH4  NH3

C CH4  NH3  CO2

D NH3  CH4  CO2

2 Which description of Brownian motion is correct?

A random movement of particles due to bombardment by larger particles


B random movement of particles due to bombardment by smaller particles
C random movement of particles from a high concentration to a low concentration
D random movement of particles from a low concentration to a high concentration

3 The chromatogram obtained using four substances, J, K, L and M, is shown.

solvent front

baseline
J K L M

Which statement about M is correct?

A It is a mixture of J and K only.


B It is a pure substance.
C It is a mixture of J, K and L.
D It is a mixture of J, K and an unknown substance.

© UCLES 2022 0620/22/O/N/22


PMT

4 Which statements about isotopes of the same element are correct?

1 They are atoms which have the same chemical properties because they have the
same number of electrons in their outer shell.
2 They are atoms which have the same number of electrons and neutrons but
different numbers of protons.
3 They are atoms which have the same number of electrons and protons but different
numbers of neutrons.

A 1 and 2 B 1 and 3 C 2 only D 3 only

5 Which statement about solid magnesium oxide is correct?

A It is a giant structure made up of magnesium and oxygen atoms bonded covalently.


B It is an electrical conductor with mobile magnesium ions and oxygen ions.
C Magnesium loses electrons and these electrons move freely through a lattice.
D Oxygen ions and magnesium ions are attracted to each other in a giant lattice.

6 Which molecule contains only three shared pairs of electrons?

A CH3OH B Cl 2 C H2O D N2

7 Which particles are present in the structure of metals?

1 positive ions
2 negative ions
3 shared pairs of electrons
4 mobile electrons

A 1 and 2 B 1 and 4 C 2 and 3 D 2 and 4

© UCLES 2022 0620/22/O/N/22 [Turn over


PMT

8 Caffeine is a stimulant found in coffee.

O CH3

H 3C C N
N C
C H
C C
N
O N

CH3

caffeine

Which formula represents caffeine?

A C7H10N4O2 B C8H10N3O2 C C8H10N4O2 D C8H11N4O2

9 Which sample does not contain a number of atoms equal to the Avogadro constant?

A 14 g of nitrogen, N2
B 6 g of water, H2O
C 4 g of helium, He
D 28 g of carbon monoxide, CO

© UCLES 2022 0620/22/O/N/22


PMT

10 The electrolysis of concentrated aqueous sodium chloride and molten sodium chloride is shown.

+ –

electrode 1 + – + – electrode 2

concentrated aqueous molten


sodium chloride sodium chloride

What are the products at electrodes 1 and 2?

electrode 1 electrode 2

A chlorine chlorine
B hydrogen chlorine
C hydrogen sodium
D sodium sodium

11 When an acid is added to an alkali, the temperature of the reaction mixture rises.

Which words describe this reaction?

A decomposition and endothermic


B decomposition and exothermic
C neutralisation and endothermic
D neutralisation and exothermic

© UCLES 2022 0620/22/O/N/22 [Turn over


PMT

12 Some properties of four fuels are shown.

Which fuel is a gas at room temperature and makes two products when it burns in a plentiful
supply of air?

melting point boiling point


fuel formula
/ C / C

A hydrogen H2 –259 –253


B methane CH4 –182 –164
C octane C8H18 –57 126
D wax C31H64 60 400

13 The electrical energy, or voltage, of two simple cells is measured.

V V

zinc magnesium magnesium copper

electrolyte electrolyte

cell 1 cell 2

statement 1 The voltage of cell 1 is greater than cell 2.


statement 2 Zinc is more reactive than copper.
statement 3 Magnesium is oxidised in both cells.
statement 4 Magnesium atoms lose electrons to form magnesium ions.

Which option is correct?

A All the statements are correct.


B Only statements 1 and 3 are correct.
C Statement 2 is correct and explains statement 1.
D Statement 4 is correct and explains statement 3.

© UCLES 2022 0620/22/O/N/22


PMT

14 Dilute aqueous sodium chloride is electrolysed using carbon electrodes.

What is the product at the anode?

A carbon dioxide
B hydrogen
C oxygen
D sodium

15 The volume of gas given off in a chemical reaction is measured over time.

The results are shown.

100
90
80
70
volume 60
of gas 50
/ cm3 40
30
20
10
0
0 2 4 6 8 10
time / s

At which time is the rate of reaction greatest?

A 0s B 4s C 6s D 10 s

16 Dinitrogen tetroxide, N2O4, is converted into nitrogen dioxide, NO2, in a reversible reaction.

N2O4(g) 2NO2(g)

The forward reaction is endothermic.

Which conditions give the highest equilibrium yield of nitrogen dioxide?

pressure
temperature
/ atmospheres

A 2 high
B 2 low
C 50 high
D 50 low

© UCLES 2022 0620/22/O/N/22 [Turn over


PMT

17 When magnesium is heated with zinc oxide a reaction occurs.

The equation is shown.

Mg + ZnO  MgO + Zn

Which substance is oxidised?

A magnesium
B magnesium oxide
C zinc
D zinc oxide

18 X and Y are oxides of two different elements.

● X reacts with water to produce aqueous solution Z.


● Z turns universal indicator paper blue.
● An aqueous solution of Y reacts with sodium carbonate to produce carbon dioxide
gas.

Which statement is correct?

A X and Y are both the oxides of metals.


B X and Y are both the oxides of non-metals.
C X is the oxide of a metal and Y is the oxide of a non-metal.
D X is the oxide of a non-metal and Y is the oxide of a metal.

19 Ethanoic acid reacts with water to produce an acidic solution.

Which row describes the roles of ethanoic acid and water in this reaction?

ethanoic acid water

A accepts a proton donates a proton


B accepts an electron donates an electron
C donates a proton accepts a proton
D donates an electron accepts an electron

© UCLES 2022 0620/22/O/N/22


PMT

20 Copper(II) sulfate is a soluble salt.

Calcium sulfate is an insoluble salt.

Which row shows suitable reactants for preparing a pure sample of the named salt?

salt reactants

A calcium sulfate calcium carbonate + dilute sulfuric acid


B calcium sulfate aqueous calcium chloride and aqueous sodium sulfate
C copper(II) sulfate copper + dilute sulfuric acid
D copper(II) sulfate aqueous copper(II) chloride and aqueous sodium sulfate

21 Strontium displaces magnesium from molten magnesium chloride.

Bromine displaces iodine from aqueous potassium iodide.

Which row describes the change in reactivity down both Group II and Group VII of the Periodic
Table?

reactivity down the group


Group II Group VII

A decreases decreases
B decreases increases
C increases decreases
D increases increases

22 Elements J and K are in the same period in the Periodic Table.

J reacts with acids to produce a salt and hydrogen.

K reacts with sodium to form an ionic compound.

Which statement about J and K is correct?

A An atom of J has more electrons than an atom of K.


B J and K are both metals.
C J and K are both non-metals.
D J is to the left of K in the Periodic Table.

© UCLES 2022 0620/22/O/N/22 [Turn over


PMT

10

23 Part of the Periodic Table is shown.

Which element has a high density, a high melting point and forms a brown oxide?

A
D
B
C

24 The reactions of four metals, W, X, Y and Z, are listed.

● Metal W displaces metal X from the oxide of metal X.


● Metal Y has a greater tendency to form positive ions than metal W.
● Aqueous ions of metal Z are reduced by metal X.

What is the order of reactivity of the metals?

least most
reactive reactive

A Y W X Z
B Y X W Z
C Z W X Y
D Z X W Y

25 Three experiments, J, K and L, are set up to investigate rusting.

J K L

water water water

mild steel painted iron stainless steel

In which experiments does rusting occur?

J K L

A    key
B     = yes
C     = no
D   

© UCLES 2022 0620/22/O/N/22


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11

26 Silver is below copper in the reactivity series.

Which row describes the reactions of silver?

reaction with steam reaction with dilute hydrochloric acid

A no reaction no reaction
B no reaction reacts to produce hydrogen gas
C reacts to produce hydrogen gas no reaction
D reacts to produce hydrogen gas reacts to produce hydrogen gas

27 Iron is galvanised by coating it in zinc.

Brass is made by mixing copper with zinc.

Which row gives the reasons for each of these uses of zinc?

reason for galvanising iron reason for making brass

A prevents corrosion produces a softer metal


B prevents corrosion produces a harder metal
C produces a harder metal produces a softer metal
D produces a harder metal produces a harder metal

28 The diagram shows a stage in the purification of dirty water.

dirty water
sand
pot with holes
fine gravel in bottom

coarse gravel

Which process does this apparatus show?

A chlorination
B condensation
C distillation
D filtration

© UCLES 2022 0620/22/O/N/22 [Turn over


PMT

12

29 Which substance in polluted air damages stonework and kills trees?

A carbon dioxide
B carbon monoxide
C lead compounds
D sulfur dioxide

30 Ammonium nitrate, NH4NO3, is a fertiliser and is added to fields to help crops grow.

Slaked lime, Ca(OH)2, is an alkali and is added to fields to reduce the acidity of the soil.

Ammonium nitrate and slaked lime should not be added to a field at the same time because they
react with each other to form a gas, Z.

What is Z?

A ammonia
B hydrogen
C nitrogen
D oxygen

31 The scheme shows four stages in the conversion of sulfur to sulfuric acid.

In which stage is a catalyst used?

stage A sulfur stage B sulfur


sulfur
air dioxide air trioxide

concentrated
stage C
sulfuric acid

concentrated stage D
oleum
sulfuric acid water

32 Which element has an oxide that is used as a food preservative?

A helium
B hydrogen
C iron
D sulfur

© UCLES 2022 0620/22/O/N/22


PMT

13

33 Which substance gives off carbon dioxide on heating?

A lime
B limestone
C limewater
D slaked lime

34 Which compound has the most –CH2– groups in one molecule?

A butane
B butanoic acid
C butan-1-ol
D but-1-ene

35 Methane reacts with chlorine in the presence of ultraviolet light.

Which substance is not produced in this reaction?

A B C D

H Cl

H H H Cl H C Cl H C Cl

H H

36 Ethene reacts with both hydrogen and steam.

Which row about these reactions is correct?

reactant
type of reaction catalyst used
with ethene

A hydrogen substitution phosphoric acid


B hydrogen addition nickel
C steam substitution phosphoric acid
D steam addition nickel

37 Which type of reaction occurs when ethanol is converted to ethanoic acid?

A combustion
B decomposition
C neutralisation
D oxidation

© UCLES 2022 0620/22/O/N/22 [Turn over


PMT

14

38 Hydrolysis of polymer P produces the three compounds shown.

H N C O H H N C O H H N C O H

H O H O H O

What is the structure of polymer P?

H O H O

A N C N C N C

H O

H O H O

B N N C C N C

H O

H O H H

C N C N C N N

H O

O O H H

D C N C C N N

H O

39 Which statement about unsaturated hydrocarbons is correct?

A CH3CH2CH=CHCH3 is an unsaturated hydrocarbon.


B Ethene has more hydrogen atoms per molecule than ethane.
C Unsaturated hydrocarbons have double bonds between carbon and hydrogen atoms.
D Unsaturated hydrocarbons turn aqueous bromine from colourless to brown.

© UCLES 2022 0620/22/O/N/22


PMT

15

40 The equation shows the formation of a polymer called Kevlar.

n HOOC COOH + n H 2N NH2

– H2 O

O O

C C N N

H H n

Which row describes Kevlar?

how the polymer is formed type of polymer

A addition polymerisation polyamide


B addition polymerisation polyester
C condensation polymerisation polyamide
D condensation polymerisation polyester

Permission to reproduce items where third-party owned material protected by copyright is included has been sought and cleared where possible. Every
reasonable effort has been made by the publisher (UCLES) to trace copyright holders, but if any items requiring clearance have unwittingly been included, the
publisher will be pleased to make amends at the earliest possible opportunity.

To avoid the issue of disclosure of answer-related information to candidates, all copyright acknowledgements are reproduced online in the Cambridge
Assessment International Education Copyright Acknowledgements Booklet. This is produced for each series of examinations and is freely available to download
at www.cambridgeinternational.org after the live examination series.

Cambridge Assessment International Education is part of Cambridge Assessment. Cambridge Assessment is the brand name of the University of Cambridge
Local Examinations Syndicate (UCLES), which is a department of the University of Cambridge.

© UCLES 2022 0620/22/O/N/22


The Periodic Table of Elements
Group
I II III IV V VI VII VIII

© UCLES 2022
1 2

H He
hydrogen helium
Key 1 4
3 4 atomic number 5 6 7 8 9 10

Li Be atomic symbol B C N O F Ne
lithium beryllium name boron carbon nitrogen oxygen fluorine neon
7 9 relative atomic mass 11 12 14 16 19 20
11 12 13 14 15 16 17 18
Na Mg Al Si P S Cl Ar
sodium magnesium aluminium silicon phosphorus sulfur chlorine argon
23 24 27 28 31 32 35.5 40
19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36
K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr
potassium calcium scandium titanium vanadium chromium manganese iron cobalt nickel copper zinc gallium germanium arsenic selenium bromine krypton
39 40 45 48 51 52 55 56 59 59 64 65 70 73 75 79 80 84
37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54

Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe
rubidium strontium yttrium zirconium niobium molybdenum technetium ruthenium rhodium palladium silver cadmium indium tin antimony tellurium iodine xenon
85 88 89 91 93 96 – 101 103 106 108 112 115 119 122 128 127 131
16

55 56 57–71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86
lanthanoids
Cs Ba Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn

0620/22/O/N/22
caesium barium hafnium tantalum tungsten rhenium osmium iridium platinum gold mercury thallium lead bismuth polonium astatine radon
133 137 178 181 184 186 190 192 195 197 201 204 207 209 – – –
87 88 89–103 104 105 106 107 108 109 110 111 112 114 116
actinoids
Fr Ra Rf Db Sg Bh Hs Mt Ds Rg Cn Fl Lv
francium radium rutherfordium dubnium seaborgium bohrium hassium meitnerium darmstadtium roentgenium copernicium flerovium livermorium
– – – – – – – – – – – – –

57 58 59 60 61 62 63 64 65 66 67 68 69 70 71
lanthanoids La Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu
lanthanum cerium praseodymium neodymium promethium samarium europium gadolinium terbium dysprosium holmium erbium thulium ytterbium lutetium
139 140 141 144 – 150 152 157 159 163 165 167 169 173 175
89 90 91 92 93 94 95 96 97 98 99 100 101 102 103
actinoids Ac Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No Lr
actinium thorium protactinium uranium neptunium plutonium americium curium berkelium californium einsteinium fermium mendelevium nobelium lawrencium
– 232 231 238 – – – – – – – – – – –

The volume of one mole of any gas is 24 dm3 at room temperature and pressure (r.t.p.).
PMT
PMT

Cambridge IGCSE™

CHEMISTRY 0620/23
Paper 2 Multiple Choice (Extended) October/November 2022
45 minutes

You must answer on the multiple choice answer sheet.


*9155678921*

You will need: Multiple choice answer sheet


Soft clean eraser
Soft pencil (type B or HB is recommended)

INSTRUCTIONS
 There are forty questions on this paper. Answer all questions.
 For each question there are four possible answers A, B, C and D. Choose the one you consider correct
and record your choice in soft pencil on the multiple choice answer sheet.
 Follow the instructions on the multiple choice answer sheet.
 Write in soft pencil.
 Write your name, centre number and candidate number on the multiple choice answer sheet in the
spaces provided unless this has been done for you.
 Do not use correction fluid.
 Do not write on any bar codes.
 You may use a calculator.

INFORMATION
 The total mark for this paper is 40.
 Each correct answer will score one mark.
 Any rough working should be done on this question paper.
 The Periodic Table is printed in the question paper.

This document has 16 pages. Any blank pages are indicated.

IB22 11_0620_23/4RP
© UCLES 2022 [Turn over
PMT

1 Which gas diffuses the most slowly?

A CH4 B CO2 C H2 D NH3

2 The chromatogram from four different substances is shown.

Which pure substance has the largest Rf value?

A B C D

3 The structure of sodium chloride can be represented as shown.

X Y

What are X and Y?

X Y

A metal atom non-metal atom


B negative ion electron
C positive ion negative ion
D positive ion electron

© UCLES 2022 0620/23/O/N/22


PMT

4 Which two particles have the same electronic structure?

A C and O2–
B F – and Na
C K+ and S2–
D Mg and Na+

5 Which statements about isotopes of the same element are correct?

1 They are atoms which have the same chemical properties because they have the
same number of electrons in their outer shell.
2 They are atoms which have the same number of electrons and neutrons but
different numbers of protons.
3 They are atoms which have the same number of electrons and protons but different
numbers of neutrons.

A 1 and 2 B 1 and 3 C 2 only D 3 only

6 What is the total number of shared electrons in a molecule of methanol, CH3OH?

A 4 B 5 C 8 D 10

7 Which row about the structures and uses of diamond and graphite is correct?

structure use

A diamond has a giant covalent structure diamond is used to make electrodes


B diamond has a simple covalent structure diamond is used to make cutting tools
C graphite has a giant covalent structure graphite is used as a lubricant
D graphite has a simple covalent structure graphite is used to make cutting tools

© UCLES 2022 0620/23/O/N/22 [Turn over


PMT

8 Caffeine is a stimulant found in coffee.

O CH3

H 3C C N
N C
C H
C C
N
O N

CH3

caffeine

Which formula represents caffeine?

A C7H10N4O2 B C8H10N3O2 C C8H10N4O2 D C8H11N4O2

9 The equation for the reaction between hydrogen sulfide, H2S, and oxygen is shown.

2H2S + 3O2  2SO2 + 2H2O

Which mass of oxygen is required to react with 5.1 g of hydrogen sulfide?

A 2.4 g B 4.8 g C 7.2 g D 14.4 g

© UCLES 2022 0620/23/O/N/22


PMT

10 Which apparatus is used to plate a nickel object with silver?

A B

power power
supply supply

silver + – nickel nickel + – silver


object object

silver nitrate silver nitrate


solution solution

C D

power power
supply supply

silver + – nickel nickel + – silver


object object

nickel nitrate nickel nitrate


solution solution

11 When an acid is added to an alkali, the temperature of the reaction mixture rises.

Which words describe this reaction?

A decomposition and endothermic


B decomposition and exothermic
C neutralisation and endothermic
D neutralisation and exothermic

© UCLES 2022 0620/23/O/N/22 [Turn over


PMT

12 Some properties of four fuels are shown.

Which fuel is a gas at room temperature and makes two products when it burns in a plentiful
supply of air?

melting point boiling point


fuel formula
/ C / C

A hydrogen H2 –259 –253


B methane CH4 –182 –164
C octane C8H18 –57 126
D wax C31H64 60 400

13 Dinitrogen tetroxide, N2O4, is converted into nitrogen dioxide, NO2, in a reversible reaction.

N2O4(g) 2NO2(g)

The forward reaction is endothermic.

Which conditions give the highest equilibrium yield of nitrogen dioxide?

pressure
temperature
/ atmospheres

A 2 high
B 2 low
C 50 high
D 50 low

© UCLES 2022 0620/23/O/N/22


PMT

14 Dilute hydrochloric acid is reacted with excess calcium carbonate and the total volume of gas is
measured at regular intervals.

The results are shown by line W on the graph.

The experiment is repeated but with one change.

The results of the second experiment are shown by line X on the graph.

volume of
X
gas collected

0
0 time

Which change is made in the second experiment?

A A catalyst is added.
B The calcium carbonate is broken into smaller pieces.
C The concentration of the dilute hydrochloric acid is increased.
D The temperature of the dilute hydrochloric acid is decreased.

15 When hydrated copper(II) sulfate is heated, it produces white copper(II) sulfate. When water is
added, the white copper(II) sulfate turns blue.

Which type of reaction is shown by these observations?

A decomposition
B displacement
C redox
D reversible

16 When magnesium is heated with zinc oxide a reaction occurs.

The equation is shown.

Mg + ZnO  MgO + Zn

Which substance is oxidised?

A magnesium
B magnesium oxide
C zinc
D zinc oxide

© UCLES 2022 0620/23/O/N/22 [Turn over


PMT

17 The equation for the reaction between ethene and hydrogen is shown.

CH2=CH2(g) + H2(g)  CH3–CH3(g)

The bond energies are shown.

bond energy
bond
in kJ / mol

C=C 612
H–H 436
C–C 348
C–H 416

What is the overall energy change during this reaction?

A –284 kJ / mol
B –132 kJ / mol
C +132 kJ / mol
D +284 kJ / mol

18 Ethanoic acid reacts with water to produce an acidic solution.

Which row describes the roles of ethanoic acid and water in this reaction?

ethanoic acid water

A accepts a proton donates a proton


B accepts an electron donates an electron
C donates a proton accepts a proton
D donates an electron accepts an electron

© UCLES 2022 0620/23/O/N/22


PMT

19 Tests are done on an aqueous solution.

a few drops of aqueous aqueous sodium hydroxide


test
sodium hydroxide are added is added in excess
precipitate dissolves to
observation white precipitate
give a colourless solution

Which cations produce these observations?

1 aluminium, Al 3+
2 calcium, Ca2+
3 zinc, Zn2+

A 1 and 2 B 1 and 3 C 1 only D 2 and 3

20 Ammonia, NH3, dissolves in water to form a dilute solution of ammonium hydroxide, NH4OH.

The reaction is reversible and exists as an equilibrium mixture.

NH3(g) + H2O(l) NH4+(aq) + OH–(aq)

Which statement about the mixture is correct?

A All of the ammonia and water molecules have turned into ions.
B The ammonia and water molecules have stopped changing into ions.
C The concentrations of the ammonia molecules and ammonium ions are always equal.
D The rate of the formation of ammonia molecules is equal to the rate of formation of the
ammonium ions.

21 Elements E and F are in Group I of the Periodic Table.

E has a higher melting point than F.

Elements J and L are in Group VII of the Periodic Table.

J has a higher density than L.

Which elements have the highest atomic numbers in each group?

A E and J B E and L C F and J D F and L

© UCLES 2022 0620/23/O/N/22 [Turn over


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10

22 Which metal forms ions with one oxidation state?

A aluminium
B chromium
C copper
D iron

23 How does the nature of the oxides change across Period 3 from sodium to chlorine?

A basic  amphoteric  acidic

B basic  acidic  amphoteric

C amphoteric  basic  acidic

D acidic  amphoteric  basic

24 Zinc is a metal with a boiling point of 907 C.

Two methods of making zinc are shown.

heat with carbon at 1000 qC


zinc
method 1

zinc ore zinc oxide

method 2 zinc sulfate


zinc
dissolve solution electrolysis
in dilute at 35 qC
sulfuric acid

Which statement is correct?

A Carbon oxidises zinc oxide in method 1.


B Zinc vapour is produced in both methods.
C Zinc is produced at the anode in method 2.
D Zinc compounds are reduced in both methods.

25 Which statement about the reactions of metals is correct?

A Iron and carbon dioxide are produced when iron(III) oxide is heated with carbon.
B Magnesium reacts with dilute hydrochloric acid producing hydrogen and chlorine.
C Potassium reacts vigorously with water producing hydrogen and an acidic solution.
D Zinc reacts with dilute sulfuric acid producing sulfur dioxide.

© UCLES 2022 0620/23/O/N/22


PMT

11

26 12.4 g of copper(II) carbonate is heated in a test-tube. Only 50% is decomposed.

[Mr: CuCO3, 124; CuO, 80]

What will be the final mass of the substances in the test-tube?

A 9.4 g B 9.8 g C 10.2 g D 10.6 g

27 Which statement about the manufacture of ammonia is correct?

A Ammonia is manufactured by heating hydrogen and nitrogen at 50 C and 1.0 atm.


B Ammonia is obtained by heating hydrogen and nitrogen in the Contact process.
C Hydrogen for the manufacture of ammonia is extracted from air.
D The reaction between hydrogen and nitrogen to form ammonia is reversible.

28 The diagram shows a stage in the purification of dirty water.

dirty water
sand
pot with holes
fine gravel in bottom

coarse gravel

Which process does this apparatus show?

A chlorination
B condensation
C distillation
D filtration

29 Which substance in polluted air damages stonework and kills trees?

A carbon dioxide
B carbon monoxide
C lead compounds
D sulfur dioxide

© UCLES 2022 0620/23/O/N/22 [Turn over


PMT

12

30 Petrol-fuelled cars produce oxides of nitrogen.

Which statement explains how oxides of nitrogen are formed?

A In the catalytic converter, the elements nitrogen and oxygen combine.


B Oxygen and nitrogen compounds in petrol combine in the car engine.
C The high temperatures in the engine provide oxygen and nitrogen with the activation energy
needed to react.
D In the car engine, nitrogen compounds in petrol combine with oxygen.

31 The scheme shows four stages in the conversion of sulfur to sulfuric acid.

In which stage is a catalyst used?

stage A sulfur stage B sulfur


sulfur
air dioxide air trioxide

concentrated
stage C
sulfuric acid

concentrated stage D
oleum
sulfuric acid water

32 Which element has an oxide that is used as a food preservative?

A helium
B hydrogen
C iron
D sulfur

33 Which substance gives off carbon dioxide on heating?

A lime
B limestone
C limewater
D slaked lime

© UCLES 2022 0620/23/O/N/22


PMT

13

34 Which formula represents ethyl butanoate?

A CH3CH2CH2COOCH2CH3
B CH3COOCH2CH2CH2CH3
C CH3CH2CH2CH2COOCH2CH3
D CH3CH2COOCH2CH2CH2CH3

35 Methanol, CH3OH, is a member of the homologous series of alcohols.

What is the formula of the alcohol in the same homologous series which contains three carbon
atoms?

A C3H5OH B C3H6OH C C3H7OH D C3H8OH

36 Which type of compound reacts with hydrogen in an addition reaction?

A alkanes
B alkenes
C alcohols
D carboxylic acids

37 The equation for the reaction between methane and chlorine is shown.

CH4 + 4Cl 2  CCl 4 + 4HCl

Which type of reaction does methane undergo?

A substitution
B reduction
C condensation
D addition

38 Which functional groups form an amide linkage?

A H2N– and –COOH


B H2N– and H2N–
C –OH and –COOH
D –OH and H2N–

© UCLES 2022 0620/23/O/N/22 [Turn over


PMT

14

39 The structure of propene is shown.

H H H

H C C C

H H

Which diagram represents poly(propene)?

A B C D

H H
H H H H C H H H H H C H
H H
C C C C C C
C C C C
H H H n H H n
H H n H H n

40 The equation shows the formation of a polymer called Kevlar.

n HOOC COOH + n H 2N NH2

– H2 O

O O

C C N N

H H n

Which row describes Kevlar?

how the polymer is formed type of polymer

A addition polymerisation polyamide


B addition polymerisation polyester
C condensation polymerisation polyamide
D condensation polymerisation polyester

© UCLES 2022 0620/23/O/N/22


PMT

15

BLANK PAGE

Permission to reproduce items where third-party owned material protected by copyright is included has been sought and cleared where possible. Every
reasonable effort has been made by the publisher (UCLES) to trace copyright holders, but if any items requiring clearance have unwittingly been included, the
publisher will be pleased to make amends at the earliest possible opportunity.

To avoid the issue of disclosure of answer-related information to candidates, all copyright acknowledgements are reproduced online in the Cambridge
Assessment International Education Copyright Acknowledgements Booklet. This is produced for each series of examinations and is freely available to download
at www.cambridgeinternational.org after the live examination series.

Cambridge Assessment International Education is part of Cambridge Assessment. Cambridge Assessment is the brand name of the University of Cambridge
Local Examinations Syndicate (UCLES), which is a department of the University of Cambridge.

© UCLES 2022 0620/23/O/N/22


The Periodic Table of Elements
Group
I II III IV V VI VII VIII

© UCLES 2022
1 2

H He
hydrogen helium
Key 1 4
3 4 atomic number 5 6 7 8 9 10

Li Be atomic symbol B C N O F Ne
lithium beryllium name boron carbon nitrogen oxygen fluorine neon
7 9 relative atomic mass 11 12 14 16 19 20
11 12 13 14 15 16 17 18
Na Mg Al Si P S Cl Ar
sodium magnesium aluminium silicon phosphorus sulfur chlorine argon
23 24 27 28 31 32 35.5 40
19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36
K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr
potassium calcium scandium titanium vanadium chromium manganese iron cobalt nickel copper zinc gallium germanium arsenic selenium bromine krypton
39 40 45 48 51 52 55 56 59 59 64 65 70 73 75 79 80 84
37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54

Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe
rubidium strontium yttrium zirconium niobium molybdenum technetium ruthenium rhodium palladium silver cadmium indium tin antimony tellurium iodine xenon
85 88 89 91 93 96 – 101 103 106 108 112 115 119 122 128 127 131
16

55 56 57–71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86
lanthanoids
Cs Ba Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn

0620/23/O/N/22
caesium barium hafnium tantalum tungsten rhenium osmium iridium platinum gold mercury thallium lead bismuth polonium astatine radon
133 137 178 181 184 186 190 192 195 197 201 204 207 209 – – –
87 88 89–103 104 105 106 107 108 109 110 111 112 114 116
actinoids
Fr Ra Rf Db Sg Bh Hs Mt Ds Rg Cn Fl Lv
francium radium rutherfordium dubnium seaborgium bohrium hassium meitnerium darmstadtium roentgenium copernicium flerovium livermorium
– – – – – – – – – – – – –

57 58 59 60 61 62 63 64 65 66 67 68 69 70 71
lanthanoids La Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu
lanthanum cerium praseodymium neodymium promethium samarium europium gadolinium terbium dysprosium holmium erbium thulium ytterbium lutetium
139 140 141 144 – 150 152 157 159 163 165 167 169 173 175
89 90 91 92 93 94 95 96 97 98 99 100 101 102 103
actinoids Ac Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No Lr
actinium thorium protactinium uranium neptunium plutonium americium curium berkelium californium einsteinium fermium mendelevium nobelium lawrencium
– 232 231 238 – – – – – – – – – – –

The volume of one mole of any gas is 24 dm3 at room temperature and pressure (r.t.p.).
PMT

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