CLASS XI

ASSIGNMENT

GENERAL ORGANIC
CHEMISTRY

LEVEL 1

TACE - AS : 11/24 - 25/SM : 2 / SA 1 / C 07

Question 1 to 80 are MCQ WITH SINGLE OPTION CORRECT. Select the correct option

STATEMENT BASED QUESTIONS

Question number 1 to 40 are statement based MCQ. The options are given below and select the corrct
answer
Option A : Both statement I and II are correct
Option B : Statement I is correct but statement II is wrong
Option C : Statement I is wrong but statement II is correct
Option D : Both statements I and II are wrong

1) Statement I : In a long chain, functional group is placed at the highest possible number of the chain
Statement II : Alcohol group receives more priority over amine group during IUPAC nomenclature
2) Statement I : Molecular formula C4H10 shows chain isomerism
Statement II : 2 - methylpropene and butene are chain isomers
Statement II : Two show chain isomerism, minimum 3 carbon atoms are needed
3) Statement I : Butene has two geometrical isomers
Statement II : Neopentane is a chain isomer of pentane
4) Statement I : Both physical and chemical properties of the isomers are different
Statement II : Propanone and propanal are functional isomers
5) Statement I : In an organic reaction, intermediate is formed before product formation
Statement II : In case of all organic reactions, byproducts are always gaseous
6) Statement I : Hybridization of the central carbon atom of a carbocation is sp2
Statemant II : (CH3)3C+ is more stable carbocation than CH3CH2+
7) Statement I : Carbanion is formed due to the heterolytic cleavage of bonds
Statement II : Heterolytic bond cleavage is termed as polar reactions
8) Statement I : Electrophiles are always electron rich species
Statement II : Electrophiles always attack to the electron defficient centres
9) Statement I : When C6H6 reacts with CH3Cl then HCl is the byproduct
Statement II : BF3 is a Lewis acid
10) Statement I : Inductive effect cannot develop polarity in a molecule
Statement II : CH3CH = CHCH3 is a stable molecule due to resonance
11) Statement I : Ammonium cyanate is formed when urea is heated strongly
Statement II : Carbon - carbon double bond faces restricted rotation while carbon - carbon triple bons
faces free rotation
12) Statement I : In CH3CHC = C = CH2, there is 1 sp hybridized carbon atom and 2 sp2 hybridized
carbon atoms
Statement II : Dipole moment of C2H2 is more than that of HCN
13) Statement I : Quarternay carbon is absent in the compound
Statement II : Pentanal has one sp2 hybridized carbon atom
14) Statement I : The compound, CH(OH)(CN)2 cotains 4 pi bonds and three lone pairs
Statement II : There are 6 secondary carbon atoms im methylcyclohexane
15) Statement I : Tropone is an example of non-benzenoid compound
Statement II : Tetrahydrofuran is an aromatic compound
16) Statement I : Methoxy ethane is an example of symmetric ether
Statement II : 3 - pentanone is an example of a symmertic ketone
17) Statement I : 6 different alkyl groups are possible having molecular formula C5H11-
Statement II : Tertriary butyl bromide is an optically inactive molecule
18) Statement I : Correct IUPAC name of H2C(Br)CH2CH2CH2(NO2) is 4 - bromonitrobutane
Statement II : At the time of IUPAC nomenclature, ether group receives more priority then alcohol func-
tional group
19) Statement I : Both aniline and 1 - aminocyclohexane are aromatic molecules
Statement II : During IUPAC nomenclature, that is considered as the longest chain where maximum number
of carbon atoms are present
20) Statement I : The correct order of priority of the functional groups is carboxylic acid > aldehyde >
ketone
Statement II : During IUPAC nomenclature, carbon - carbon double bond receives less priority than
carbon - carbon triple bond
21) Statement I : Correct IUPAC name of CH2(SO3H)CH2CH2COOH is 3 - carboxypropylsulphonic
acid
Statement II : The correct molecular formula of ethyl ethanoate is CH3CH2COOCH2CH3
22) Statement I : In ortho - ethylanisole molecule, ethyl and ether groups are placed at the first and third
positions of the aromatic ring
NO2

Statement II : Correct IUPAC name of is 4 - nitroaniline

NH2
23) Statement I : 2,2 -dimethylpropanal does not show tautomerism
Statement II : Ethoxyethane and methoxypropane are metamers
24) Statement I : Homolytic breaking of a bond results the formation of free radicals
Statement II : Hydrogen free radical is very stable
25) Statement I : (C2H5)3C+ is more stable than (CH3)3C+
Statement II : CH3+ is more stable than CF3+
26) Statement I : NH2- is weaker nucleophile than OH-
Statement II : Methyl free radical is more stable than ethyl free radical
27) Statement I : C6H6 reacts with CH3Cl to produce C6H5CH3 and HCl and it is an example of substitu-
tion reaction
Statement II : H2C = CH2 reacts with Br2 to produce H2C(Br)CH2(Br) and it is an example of substitution
reaction
28) Statement I : BF3 acts as an electrophile
Statement II : PH3 acts as a nucleophile
29) Statement I : Both cyano and nitro groups are electron donating groups
Statement II : Both carboxy and ester groups are electron withdrawing group
30) Statement I : All carbon - carbon bond lengths in H2C = CH - CH = CH2 are equal
Statement II : Two different carbon - oxygen bond lengths are found in carbonate ion
31) Statement I : Resonance energy is defined as the energy difference between the most stable structure
and the highest energy resonance structure
Statement II : Resonance is important when the contributing structures are equivalent in energy
32) Statement I : Nitro, carboxylic acid, aldehyde, cyano all groups show negetive resonance effect
Statement II : Groups having positive resonance effect decreases the electron density in the ring
33) Statement I : Attack of HCN to CH3CH2CHO is an example of negetive electromeric effect
Statement II : In case of positive electromeric affect, the p  bonded compound attacks the reagent
34) Statement I : To separate the components having low difference of boiling point values, crystallization
method is applied
Statement II : Each successive condensation and vaporisation unit in the fractionating column is calles
theoritical plate
35) Statament I : From aniline - water mixture, the components are separated by differential extraction
method
Statement II : For differential extraction method, an organic solvent is needed
36) Statement I : Chromatography method is used to separate the components in a mixture as well as to
test the purity of the compounds
Statement II : For adsorption chromatography, silica gel is used as an adeorbent
37) Statement I : In case of column chromatography, solvent is placed at the top of the column
Statement II : Column chromatography method is not used to separate three components present in a
mixture
38) Statement I : In case of cerbon detection by qualitative analysis, the compound is heated with Fe2O3
Statement II : KCN is formed during Lassaigne’s test
39) Statement I : The colour of [Fe(CN)5NOS]4- is violet
Statement II : The colour of Fe4[Fe(CN)6]3 is yellow
40) Statement I : In case of Duma’s method, the organic compound is heated with copper oxide
Statement II : In case of Duma’s method, nitrogen gas is released

MCQ WITH SINGLE OPTION CORRECT

Question number 41 to are SINGLE OPTION CORRECT MCQ. The options are given below and
select the corrct answer NC

41) 1) Correct IUPAC name of NO 2 is

F
a) 3 - fluoro - 5 - nitrocyanobenzne b) 5 - fluoro - 3 - nitrocyanobenzne
c) 3 - fluoro - 5 - nitrophenyl isocyanide d) 5 - fluoro - 3 - nitrophenyl isocyanide
42) Among the given compounds, which contains only secondary carbon atoms ?
a) Cyclopentane b) Methyl cyclobutane
c) 1,1 - dimethylcyclopropane d) 1,2 - dimethyl cyclopropene
43) The correct order of the halogen priority at the time of IUPAC nomenclature is
a) -I > -Br > -Cl > -F b) -F > -Cl > -Br > -I
c) -Br > -Cl > -F > -I d) -Br > -F > -I > -Cl
44) The correct structure of propoxy butane is
O O
a) b)

O O
c) d)

45) Consider the following compound and select the correct number of functional groups present
H O
O CONH 2

N C CH3
NC

COCl
a) 5 b) 6 c) 4 d) 7
46) Which of the following compound contains 1o and 4o carbon atoms ?
a) 2 - methylbutane b) Pentane
c) 2,2 - dimethylpropane d) 2,2 - dimethylbutane
47) Consider the following compound and select which will be considered as the first carbon during
IUPAC nomenclature ?
CHO

Br NO 2
COOH
a) Carbon atom of -COOH group
b) Carbon atom of -CHO group
c) Carbon atom of the ring where -COOH is bonded
d) Carbon atom of the ring wheree -CHO is bonded
48) Correct order of priority of the groups at the time of IUPAC nomenclature is
a) -COOH > -CONH2 > -COOCH3 > -COCl b) -COOH > -COCl > -COOCH3 > -CONH2
c) -COOH > -COOCH3 > -COCl > -CONH2 d) -COOH > -COCl > -CONH2 > -COOCH3
49) 3 - cyanobute - 2 - ene - 1- oic acid contains
a) 4 pi bonds and 5 lone pairs b) 3 pi bonds and 6 lonepairs
c) 5 pi bonds and 5 lone pairs d) 5 pi bonds and 6 lone pairs
50) Among the given functional groups, which receives the lowest priority during IUPAC nomenclature ?
a) Amine b) Carboxylic acid c) Nitro d) Aldehyde
51) Consider the molecule hex - 1 - ene - 5 -yne and select the correct statements
(I) There are two secondary carbon atoms
(II) The molecule contains 3 pi bonds
(III) There are two carbon atoms having s - character 33.33%
a) I, II, III b) I, II c) II, III d) I, III
52) Consider the molecule 2,2,4,4 - tetramethylpentane and select the correct statements
(I) There are two quarternay carbon atoms
(II) There is one tertiary carbon atom
(III) There are 6 primary carbon atoms
a) I, II, III b) I, II c) II, III d) I, III
53) How many sp hybridized atoms are present in tropone molecule ?
2

a) 7 b) 6 c) 8 d) 5
54) Among the given molecules, which are aromatic ?
(I) Furan (II) Thiophane (III) Pyridine
a) I, II, III b) I, II c) II, III d) I, III
55) In which of the following option both molecules are not homologous to each other ?
a) 2 ,2 - dimethylbutane and 2,2 - dimethylpropane
b) Methoxy ethane and Ethoxy ethane
c) 2,2 - dimethylpropane and 2 - methylbutane
d) 2 - aminopropane and 2 - aminobutane
56) In which of the following option, both molecules are optically inactive ?
a) 2 - propanol and 3 - bromopentane
b) 2 - butanol and 2 - hexanol
c) 3 - methylpentene and 3 - methylpent 1,4 - diene
d) 3 -bromo-3-pentanol and 2-bromo-3-pentanol
57) Among the given alkenes, which is the most stable ?

a) b) c) d)

58) Find out correct statements

(I) The IUPAC group prefix of ester is alkoxycarbonyl
(II) The IUPAC group prefix of amide is carbamoyl
(III) Cyano group receives more priority than aldehyde at the time of nomenclature
a) II, III b) I, II c) I, III d) I, II, III
59) Correct IUPAC name of the given compound is
H2N

NO
a) 4 - amino - 6 - nitrosocyclohexene b) 2 - amino - 4 - nitrosocyclohex - 5 - ene
c) 1 - amino - 5 - nitrosocyclohex - 3 -ene d) 1 - amino - 3 - nitrosocyclohex - 5 - ene
60) Which molecule has the highest dipole moment value ?
a) 1, 3, 5 - trichlorobenzene b) 1, 4 - dichlorobenzene
c) 1, 3 - dichlorobenzene d) 1, 2 - dichlorobenzene
61) Which of the following carbocation is the least stable ?
 +  +
a) C NO2 3 b) CF3 c) CCH3 3 d) H 2 C CH3
62) In which of the following molecule, lone pair does not take part in resonance ?

a) b) c) O N
2
NH2 d) NH2
N N

63) Consider the molecular formula of aromatic compound C3H3F3 and select the correct statements
(I) Three positional isomers are possible by this formula
(II) All positional isomers have same dipole moment values
(III) Functional isomerism is not possible wit this formula
a) I, II b) I, III c) II, III d) I, II, III
64) Ethyl propanoate and Methyl - 2 - methylpropanoate are
a) Chain isomers b) Functional isomers c) Tautomers d) Metamers
65) Which compound does not show geometrical isomerism ?
a) 3 - methyl - 2 - butenoic acid b) 3, 4 - dimethylhex - 3 - ene
c) Pent - 2 - ene - 5 - yneoic acid d) Hex - 3 - ene - 1,5 - diyne
66) Which is the least stable free radical ?

a)

CH2 b) H 2 C = CH -CH 2
•
c) . d) (C2H5)3C+

67) Which statement is wrong ?

a) Tertiarybutyl free radical is more stable than methyl free radical
b) Hybridization of methyl free radical and methyl carbocation is same
c) Hybridization of methyl carbanion and methyl free radical is different
 
d) C CH 3 3 is more stable than H 3CC H 2
68) Among the given ions, which of the following is the weakest nucleophile ?
- -
a) O N CH 2 b) H3C CH 2
2

- -
c) CH 2 d) F 3 C CH 2

69) Tertiary butyl carbocation is more stable than methyl carbocation. Which factors are responsible to
explain this fact ?
(I) Resonance (II) Inductive effect (III) Hyperconjugation
a) I, II, III b) I, II c) I, III d) II, III
70) Which compounds do not show tautomerism ?
(I) Benzophenone (II) 2,2,4,4 - tetramethyl - 3 - pentanone
(III) 3 - phenylpropanal (IV) 2,2 - dimethylbutanal
a) I, II, III, IV b) I, II, IV c) I, II, III d) II, III, IV
71) During crystallization process, colour of the solution is removed by
a) Silica gel b) CaCl2 c) activated charcoal d) CaO
72) A mixture of chloroform and anilline is separated by
a) Steam distillation method b) Normal distillation method
c) Crystallization method d) Distillation under reduced pressure
73) The term THEORITICAL PLATE is associated with
a) Steam distillation method b) Normal distillation method
c) Crystallization method d) Fractional distillation method
74) In soap industry, glycerol is separated from spent-lye by
a) Steam distillation method b) Normal distillation method
c) Crystallization method d) Distillation under reduced pressure
75) Aniline and water mixture is separated by
a) Steam distillation method b) Normal distillation method
c) Crystallization method d) Distillation under reduced pressure
76) During Lassaigne’s test for nitrogen, the prussian blue coloured end product is
a) Fe4[Fe(CN)6]3 b) Fe(SCN)3 c) Na4[Fe(CN)6 d) No option is correct
77) In Carius method of halogen estimation, which of the following is used ?
a) Concentrated H2SO4 + AgNO3 b) Dilute H2SO4 + AgNO3
c) Dilute HNO3 + AgNO3 d) Fuming HNO3 + AgNO3
78) Which the correct working formula for Carius method of sulpher estimation is
[m = mass of compound taken and m1 = mass of sulphate formed]
 32  m1 100   32  m1 100   64 m1 100   64 m1 100 
a)   b)   c)   d)  
 233  m   256  m   233  m   256  m 
79) Consider the compound CH3CH2CH2CHO. Nucleophilic attack is the easiest at
a) First carbon b) Second carbon c) Third carbon d) Forth carbon
80) Which statements are true about metamerism ?
(I) Functional group remains unchanged
(II) Ether shows metamerism
(III) It arises due to difference of carbon atoms around the functional group
a) I, II, III b) II, III c) I, II d) I, III
 THEORITICAL QUESTIONS

1) How many 1o, 2o and 3o carbon atoms are present in the following compound ?

2) How many functional groups are present in the given compound ?

O

Cl
HO3S CN
N
O
O
O
3) Write the proper priority order of the given functional groups during IUPAC nomenclature
-NO2, -SO3H, -OH, -COOH, -Br
4) Which statement is correct about the functional group ?
a) Functional group does not contain carbon atom
b) Functional groups are responsible for the physical properties of the compound only
c) Functional groups are responsible for the chemical properties of the compound only
d) Both chemical and physical properties of the compounds are determined by functional groups
5) Consider the following compound and select the correct anwer

X = Number of 1o carbon present in the compound

Y = Number of 2o carbon present in the compound
Z = Number of 3o carbon present in the compound
P = Number of 4o carbon present in the compound
 2X  3Y 
The correct value of   will be
 Z P 
6) Give the structure of the simpliest alkane, containing 1o and 4o carbon atoms only
7) At the time of starting nomenclature, which carbon will be counted as the first carbon ?
O
b
O
a d e
H2N O

O
8) X = precentage of carbon in CH3COOH and Y = precentage of carbon in CH3CONH2. Now, what
is the value of (Y - X) ? Given that C = 12, O = 16, N = 14, H = 1
9) Among the given compounds, which has the lowest percentage of carbon ?
Given : C = 12, O = 16, Cl = 35.5, N = 14, H = 1
a) CH3COOCH3 b) CH3COCl c) CH3COOH d) CH3CONH2
10) Consider the following compound
CN CN

CHO
COOH
X = Number of lone pairs in the molecule and Y = Number of   bonds in the molecule
Now, the value of (X + Y) is
11) Detremine the correct IUPAC name of the given compounds

a) b) c) d)

O O Cl

e) f) g) h)
OH COOH
Cl Br
NO2 NH2

i) j)

O
12) Detremine the correct structures of the given compounds
a) 3,4 - diethyl - 2,5 - dimethylhexane b) hex - 1,2,3 - triene
c) 3,4 - diethylhex - 1,5 - diene d) hex - 1,4 - diyne
e) 2 - methoxy - 3 - methylbutane f) 5 - amino - 2,3 - diketopentanoicacid
g) Ethylbutanoate h) 4 - amino - 3 - hydroxypentanoic acid
i) 3,4 - dimethyl - 2 - pentenal
j) 2 - amino - 2 - bromo - 3 - chloro - 4 - nitropentane k) 4,5 - dinirobenzoic acid
l) 2,4,6 - tribromoaniline m) 3 - bromoacetophenone n) 3 - chloro - 5 - nitrobenzaldehyde
o) 4 - chlorobromobenzene p) 3 - cyano - 5 - bromobenzoic acid
q) 4 - nitro - N - methylaniline r) Phenyl benzoate s) 2 - phenylbenzoic acid
t) 2 - aminobenzaldehyde

13) Write the name and structures of

a) One non benzenoid compound
b) Heterocyclic aromatic compound
14) Give an example of homologous aldehydes
15) Write the correct priority order of the given groups in case of IUPAC nomenclature
-Br, -COOH, -NO2, -CN, -I
16) Write the structures and IUPAC names of the cyclic compounds of molecular formula C5H10
17) Write the IUPAC name of H3COCH2CH3
18) Phenyl group is bonded with two carbon atoms and five hydrogen atoms. Write the structures of the
probable compounds
19) Write the metameric ethers of molecular formula C4H10O
20) Give the correct products, when carbon - bromine bond faces heterolytic cleavage in case of
C2H5Br
21) Define : Carbocation
22) Give the correct order of stability of C2H5+, (CH3)2CH+, CH3+, (CH3)3C+
23) Define : Substrate of an organic reaction
24) Which intermediate is formed when methane faces single homolytic clevage ?
25) Which reagent attacks at the electron rich organic compounds ?
26) Give two examples of neutral nucleophilis
27) Give the equation of breaking of CH3MgBr

Question number 28 to 47 are TRUE / FALSE type. Determine the correct answer

28) Inductive effect is a temporary effect

29) Resonance is associated with only pi bond not sigma bond
30) -OC6H5 is an electron withdrawing group but -CH3 is an electron donating group
31) Due to inductive effect carbon - carbon bond length in benzene is 139 pm not 154 pm or 134 pm
32) Inductive effect is the lowest at the 4th carbon of butanoic acid
33) Higher the number of resonance structures, higher is the resonance energy value
34) In different resonance structures, position of nuclei changes
35) A stable resonance structure results when a positive charge develops over oxygen atom
36) Both -OH and -NO2 show positive resonance effect
37) If a group having negetive resonance effect is bonded with aromatic ring, then it decreases the electron
density in the ring
38) During a reaction, C = C is attacks H+ ion. It is an example of positive electromeric effect
39) Hyperconjugation is a temporary effect
40) Resonance is more contributory than hyperconjugation
41) Hyperconjugation is associated with carbon and hydrogen bond only
42) CH3+ shows lower number of hyperconjugation stability than C2H5+
43) A mixture of sand and camphor is separated by sublimation method
44) Volatile liquids from volatile impurities are separated by distillation method
45) Both -NO2 and -COOH groups are detected by Lassaigne’s test
46) Dumas method is associated with CuO and is used for quantitative estimation of nitrogen
47) HNO3 is used for Kjeldahl’s method

Question 48 to 67 are FILL IN THE BLANKS TYPE QUESTIONS. Fill in the blanks with the
proper answers

48) The acid used in Kjeldahl’s method is __________

49) In Carius method, chlorine present in an organic comound is estimated by forming ______
50) In Carius method, sulpher present in an organic comound is estimated by forming ______
51) During quantitative estimation of phosphorus, it is precipitated as ______________
52) At Lassaigne’s test for sulpher by using sodium nitropruside solution, the colour of the end product is
_________
53) During column chromatography, the stationary phase is the _________
54) Differential extraction is used when an organic compound is present in ________ medium
55) The steam volatile substances which are immiscible with water are separated by __________ method
56) If the boiling points of two componants in a mixture is very close then _______ method is used to
separate them
57) The number of hyperconjugation structures of CH3CH=CHCH3 are ______
58) Cyanide ion is attacking an organic compound having C = C part and this is known as _____
59) Lone pair donation capacity of aniline decreases due to _________
60) Among methyl aniline and methanol, more polar compound is _______

61) contains ______ tertiary and ________ quaternary carbon atoms

62) -NO2 group shows both _____ and _____ effects

63) Free radical is formed due to _______ cleavage of bonds
64) Among CH3Br and CH3I, the carbon - halogen bond is less stable in _______
65) Number of hyperconjugation structures of 2,3 - dimethyl - 2 - butene are _______
66) Nucleophiles take part only in ________ reactions
67) Butanol and methoxy propane are ________ isomers