Screenshot 2024-06-13 at 11.06.10

Document No: Rev.
Page:
AL-5153-TEST-003 03 1 of 89
Orginator: Tag no: System No: Area Code:
Techouse AS
Document Title: Chemical Cleaning Procedures

Agogo Project
Techouse Project no: 0355P
Contract No.: PO 08607
03 31/05/2024 Issued for Review L.T.H.Nhung T.N.T V.T.S n/a

Chk Appr Proj
Rev. Issue date Reason for Issue Org by
by by appr
Package No: PO No: 08607 Package Title: M40 Module Fabrication and Assembly
Supplier Document No: Supp. Rev:
Techouse Document No:
AL-5153-TEST-003 03 TH-P0355-PO08607-KA-0013
Acceptance Code:
Supplier Logo : Accepted (code 1)

Accepted with comments incl. (code 2)
Not accepted, revise and resubmit (code 3)
Issued for information (code 4)

All Interface information is
accepted and frozen (code 5)
Date: Sign:
Project AGOGO
Job title M40 MODULE
Doc Title CHEMICAL CLEANING PROCEDURE
Doc. No AL-5153-CC.001 Rev. 03
Job No AL-5153 Page Page 1 of 13
CHEMICAL CLEANING PROCEDURE
Rev Prepared by Approved by ALPHA Approved by Client Approved by C.A

ALPHA ECC ECC
01 L.T.H.Nhung N.H.Cuong
Responsible: Project Management Team Document format: A4

Document Title Document status:
Issued for Approval
Chemical Cleaning Procedure Document Number:

AL-5153-CC.001
Rev Date Lang.
03 31/05/2024 English
Project AGOGO
CONTENTS
SECTION DESCRIPTION PAGE

1. PURPOSE ..................................................................................................................................3
2. SCOPE OF WORK ....................................................................................................................3
3. REFERENCE DOCUMENTS AND STANDARD................................................................3
4. DEFINITION .............................................................................................................................4
5. CHEMICAL CLEANING REQUIREMENTS .........................................................................4
6. SAFETY CONSIDERATIONS .................................................................................................7
7. PREPARATION FOR CHEMICAL CLEANING ...................................................................8
8. CHEMICAL CLEANING MAIN STEPS .................................................................................8
9. ACCEPTANCE CRITERIA FOR CHEMICAL CLEANING ..................................................13
10. PROTECTION AFTER CHEMICAL CLEANING..................................................................13
11. APPENDICES ..........................................................................................................................13
Project AGOGO
1. PURPOSE
This procedure is an instruction for cleaning and protection of the internal surfaces of carbon steel
piping systems to acceptable levels of cleanliness for a successful start-up and operation. The procedure
also includes inspection criteria for cleaning.
It will only be used for piping systems, specified by project specifications and identified on AFC (approved
for construction) drawings for chemical cleaning. The piping lines being applied this chemical cleaning
procedure will be as below:
2. SCOPE OF WORK
This procedure includes the preparation and execution of chemical cleaning (high-pressure water jet/ water
flushing, degreasing, acid pickling, passivation/ neutralization) to the internal surface of carbon steel
piping systems to remove loose scale, rust, foreign matter, grease, etc. During the chemical cleaning
operations, care shall be taken to prevent direct contact of chemicals with items that are identified on the
P&ID and isometric drawings for chemical cleaning.
The chemical cleaning process shall be accomplished by using chemical agents (degreasing, pickling,
passivation/ neutralization) in the system and filling chemical solution with closed circulation. It also
addresses environment regulation compliance and personnel safety aspects of the work to be done.
3. REFERENCE DOCUMENTS AND STANDARD
Standard practice for cleaning, descaling, pickling and passivation/neutralization of carbon steel parts,
equipment and system.
2101-YINS-00-L-SA-00006_C3_Chemical Cleaning & Hot Oil Flushing Specification

ATSM D1125-14 Standard Test Method for Electrical Conductivity and Resistance of Water Chemical
ASTM D1293-12 Standard Test Method for pH of Water
ASTM D1067-16 Standard Test Method for Acidity or Alkalinity of Water
ASTM D1068-15 Standard Test Method for Iron in Water
Project AGOGO
4. DEFINITION
Client : AZULE ENERGY

Company : YINSON
Contractor/ Supplier : TECHOUSE
Sub-contractor/ Sub-supplier : Southern Petroleum Construction J.S. Company (ALPHA-ECC)
ASTM : American Society for Testing and Materials
PTW : Permit to Work
JSA : Job Safety Analysis
P&ID : Piping and Instrument Diagram
MSDS : Material safety data sheets
5. CHEMICAL CLEANING REQUIREMENTS
5.1. General Requirements

Lines to be cleaned shall be clearly identified on the P&ID and isometric drawings.
In-line components such as orifice plates, check valve, control valves, flow meter elements, strainer
elements, and relief valves shall be removed and replaced with temporary spools. All removed equipment
shall be shown and highlighted on drawings, removable list to be available for verificaiton. In case of 4
lines that will be applied this chemical cleaning, there is no need to remove any component.
Chemical cleaning shall take place after hydro testing of pipe work.
5.2. Chemical cleaning equipment and materials
The equipment shall be determined during the project phase and approved by TECHOUSE. As a
minimum, the following equipment/ instruments shall be used to facilitate testing:
Project AGOGO
No Equipment Q’ty
Circulation tank
Material: plastic
1. Volume: 5m3 02 ea
Protection framework and gutters to collect
chemicals are provided
Chemical Pump skid,

Achieving flow velocities: 3 m/s 02 ea
2. Max. Pressure: 10 bar
Power: Electric
Diaphragm Pump
Achieving flow velocities: 3 m/s 01 ea
3. Max. Pressure: 8.5 bar
Power: Air Compressor
4. Iron High Range ISM 01 ea
5. pH Meter 01 ea
6. Conductivity meter 01 ea
7. Water jet pump, 3000 psi 02 set

Power: Electric
Water jet pump, 4000 psi
8. 01 set
Power: Electric
Water jet pump, 6000 psi
9. 01 set
Power: Electric
10. 3KW Electrical heater with panel 02 ea
Flexible chemical suction/discharge hose,
11. corrosion- resistant: 1”, 250m

12. 250m
corrosion- resistant: 2”,
13. 250m
corrosion- resistant: 3”,
Project AGOGO
No Equipment Q’ty
14. Pressure gauge 02 ea
15. Borescope 01 ea
16. Portable eyewash station 01 ea
17. Filter System with 50 mesh screen element 02 set
18. Hand tool 02 set
19. Flange and fitting 01 lot
Connection work shall be as follows:

Connection and bypass lines have to implement to make sure cleaning chemical will not contact with all
the equipment (or instrument) were installed on the piping system. (Control valve, cylinder, pump,
sensor…)
The typical layout diagram of the flushing equipment system is enclosed in Appendix 2.
The list of chemicals is as below:

No Chemical
1 Surfactant Tween 80
2 Sodium Carbonate (Na2CO3)
3 Sodium Tripolyphosphate (P3O10Na5)
4 Trisodium phosphate (Na3PO4)
5 Citric acid
6 Phosphoric acid
7 Corrosion inhibitor (ST-UC101)
8 Caustic Soda
9 Soda ash
10 Sodium nitrite (NaNO2)
Note: Chemical concentration required for each process is described in section 8.7.
Project AGOGO
6. SAFETY CONSIDERATIONS
Most chemicals used for chemical cleaning are hazardous. All personnel involved for the work should
be familiar with all hazards and guidelines.
Personnel involved in the cleaning works should wear appropriate personal protective equipment
(P.P.E) consisting protective clothing such as:
1. Chemical suits
2. Gloves
3. Goggles
4. Face shields
5. Boots
6. Helmets
7. Hearing protection – as required
Firefighting equipment, emergency showers, eye wash station shall be installed and made available
within easily accessible locations before starting chemical cleaning operations.
Waste chemicals shall be properly neutralized prior to disposal. The waste disposal tanks shall be
performed on site at suitable position.
All vents and overflows shall be routed to waste disposal tanks or safe location away from possible
contact with personnel.
The affected areas shall be cordoned off as far as practically possible with appropriate warning signs
posted to control the access/egress of all personnel. The working area shall be cordoned off in
accordance with all local safety requirements. No unauthorized personnel are allowed to enter
cordoned off areas.
All chemicals delivered shall arrive complete with material safety data sheet (MSDS). MSDS shall
be posted at work site locations.
Only personnel with adequate training shall execute chemical cleaning operations.
Valid Permit to Work (PTW), Job Safety Analysis (JSA) and Toolbox talks shall be in place prior to
commencement of any activities.
Close monitoring by site supervisor of safety personnel is required for pickling activity carried out at
site. Briefing should be given to the workers before starting the activity.
Project AGOGO
7. PREPARATION FOR CHEMICAL CLEANING

As a minimum, the following requirement shall be checked for completion before commencement of the
chemical operations:
The water used for all the process of chemical cleaning will be obtained the resistivity of 100000
Ohm x cm and the Chloride ions maximum content of 25ppm.
Hydrostatic Testing: The hydrostatic testing and flushing of all systems involved in the chemical
cleaning process shall be completed.
Metal Temperatures: Provisions will be made to measure the metal temperaturesof boiler pressure
parts.
Drainage Hoses: Temporary vinyl hose will be installed on air vents, drains, and test connections
involved in the flushing operations. The hoses will be routed to the drainage system.
Equipment Protection: All electrical equipment and other equipment that would be damaged by
spillage or leakage of water or cleaning solutions will be protected.
Instruments: All pressure instruments in the pre-boiler piping, including those on dead-end branch
piping and all boiler pressure instruments not required for firing the boiler, will be isolated from the
instrument piping at the instrument. The primary and instrument shutoff valves will be closed. The
instrument piping blowdown valves will be closed. The instrument piping equalizer valves on all
differential transmitters, controllers, gauges, etc., will be closed. Unless specifiedotherwise, the
instruments will remain isolated until after the completion of chemical cleaning.
All valves shall be removed and replaced by dummy pipes or blind off during chemical
cleaning.
Marked up drawings (P&IDs, isometrics) attached.
Leak check and accident prevention:
- Upon completion of the temporary installation, the system shall be water testedto check for
leaks.
- Test pressure shall be maximum with pump head discharge pressure with continuous flow.
8. CHEMICAL CLEANING MAIN STEPS
The chemical cleaning has three (3) main objectives:

Degreasing: To remove grease and oil used for the preservation during transport and storage.
Acid cleaning: To remove rust from surfaces formed during shipment and construction. All
instruments if any, shall be removed prior to start pickling phase.
Passivation: To enhance the formation of a protective passive film by the formation of a
nonreactive iron oxide and to eliminate the presence of oxygen.
Project AGOGO
The overall chemical cleaning will follow the following sequence.

1. Installation of temporary piping
2. Water leak test and Flushing
3. Degreasing
4. Acid Cleaning
5. Neutralizing
6. Passivation.
7. Rinsing/ Drying
Installation of temporary piping to the system
Water leak test and Flushing
Degreasing
Acid cleaning
Neutralizing
Passivation
Rinsing/ Drying
Inspection
Waste water to collection tank
Preservation
Waste water disposal
Chemical cleaning process diagram

Project AGOGO
8.1. Installation of temporary piping

The setup of chemical cleaning system consists of many items from pump system, circulation tank,
electrical heater and hoses. Upon begin the installation, initial cleaning must be conducted to remove
all the big particle (rust and other big particles). It’s important to make sure all the piping is level to
ensure no air pockets during chemical cleaning phase and there is no solution left in the system during
draining phase. Appendix 2 show the schematic drawing for the equipment setup and process flow.
8.2. Leak test and Flushing

The cleaning circuit is filled and tested with fresh water in order to ensure the tightness of the cleaning
circuit (at the pressure of circulation which is from 5 bar to 10 bar) and permit to repair the leakages
detected at the temporary circuit or to resolve any problems of circuit arrangement, when the loop is
just filled with water (no chemicals). Leak test will be conduct with ambient temperature fresh water.
All auxiliary cleaning equipment (recirculation pumps, etc.) will be checked to ensure it is working
properly. Water fills up point will be at the circulation tank.
When the system is free from leaks, circulation is started and at the same time the system will be heated
by electrical heater attach in mixing tank. Checks are made on all circuits to ensure the systems are
circulating correctly. The duration of heating to achieve 50-70ºC is estimated at 1 hour.
8.3. Degreasing process

A grease layer may have formed during transport or storage of the equipment which may disturb.
Degreasing is to ensure that any remaining oil or grease in the internal piping system is cleaned.
Degreasing solution is a mixture of 0.2g/l surfactant Tween 80, 3g/l Sodium Carbonate (Na2CO3), 2g/l
Sodium tripolyphosphate (P3O10Na5), 1g/l Trisodium phosphate (Na3PO4).
While increasing the temperature till 50-70ºC, degreasing solution shall be added to degrease the
surfaces and ensure good wetting during the following acid cleaning stage. Fluid velocity shall be more
than 3 m/s. Once there is no oil present using oil wipe test (or indicator coupon), the degreasing phase
is considered complete.
During degreasing phase, the soda concentration should be average of 3 – 3.5% and the pH should be
more than 10. The maximum of final oil content is 25 ppm.
8.4. Acid cleaning/ Pickling process

Piping works (welding, grinding, cutting…) degrade and contaminate chromium oxide protective layer
inside piping. In order to avoid corrosion, oxide layer shall be dissolved by a chemical pickling.
Acid pickling solution is a mixture of 30g/l of citric acid, 200g/l of phosphoric acid. 2g/l of corrosion
inhibitor (ST-UC101) is used to minimize the attack of the acidic solution on the steel surfaces.
The initial pickling solution shall be tested for iron and chloride content, the total concentration of
dissolved iron must be less than 6g/l and the total concentration of chloride must be less than 5 ppm.
Project AGOGO
Before starting the pickling the cleaning solution shall be tested for inhibitor effectiveness prior to its
introduction to the relevant system. This test shall be taken as follows:
- A degreased sampled shall be immersed in the solution, which is maintained at 50 – 60 ºC
and stirred. This sample shall be the same type as piping to be treated. Effective inhibition
is indicated by the absence of hydrogen evolution.
During the cleaning the solution is monitored by chemical analysis, concentration of iron, pH and
efficiency of inhibitor. The pH of pickling solution should be less than 3.5. During acid phase,
maximum allowable total iron concentration is 1.5% (15,000 ppm), or the maximum ferric iron content
is 0.4% (4,000 ppm). In cased the iron level is exceed, the solution will be drain and new demineralized
water is refill to the system to repeat acid cleaning phase.
Acid cleaning is considered complete once iron content be constant and less than 1000 ppm.
8.5. Neutralization/ Passivation

When the acid pickling process is completed, the tank shall be filled with demin water, then either
ammonia or caustic soda and soda ash will be injected to neutralize the acid residue which remains
internal of pipeline and raise the pH to 8.5 – 9.5.
Once reach PH of 8.5 to 9.5, the passivation process will be performed to make a protection layer at
the surface of piping from corrosion. The passivation solution is used to passivate the internal surface
of the carbon steel pipes is sodium nitrite (NaNO2) 2g/l.
The duration of passivation circulation shall be from 3 to 6 hours.
Post Chemical Cleaning Boroscopic Inspection shall be carried out to verify the condition of the piping
internally.
8.6. Rinsing/ Drying

Between each cleaning step, piping will be rinsed with water. Water to the following specification
shall be used exclusively:
- Resistivity: 100 000 Ohm x Cm (before addition of NaNO3)
- Chloride ions Cl-: 25ppm maximum
- Additive: NaNO3 (3 times the ions Cl- content)
The final rinsing must be stopped only when the pH of the water and outlet are the same, average 7 –
7.5.
Air blowing will be performed to dry internal of pipeline. Dry oil-free compressed air to clean piping
of debris and contaminants. Air is blown continuously through the selected pipework from a source (air
compressor or via pressurized vessel) to bring away foreign matter (usually this method is applicable when
the flow rate capacity of the air compressor is sufficiently bigger compared to the size (diameter and length)
Project AGOGO
of the pipework, such that the flow through the pipework is bigger than the one with the process fluid at
operating conditions).
For Gas, Fuel lines the required dew point after drying must be -5 deg C or lower.
8.7. Chemical combination for each stage of the cleaning process
8.8. Inspection and Testing after Cleaning

Final visual inspection will be conduct after cleaning process. Visual inspection should be
supplemented with borescope, mirrors, and other aids, as necessary, to properly examine inaccessible
or difficult-to-see surfaces. This will establish:
- That the carbon steel piping internal surface is grey to dark grey.
- That the surface is oil and grease free
Wipe Test: Rubbing of a surface with a clean, lint free, white cotton cloth, commercial paper product,
or filter paper moistened (but not saturated) with high-purity solvent, may be used for evaluating the
cleanness of surfaces not accessible for direct visual inspection.
Project AGOGO
9. ACCEPTANCE CRITERIA FOR CHEMICAL CLEANING

Acceptance criteria for each phase of chemical cleaning as below:
10. PROTECTION AFTER CHEMICAL CLEANING

Protection of cleaned surfaces – Measures to protect cleaned surfaces should be taken as soon as final
cleaning is completed, and should be maintained during all subsequent fabrication, shipping,
inspection, storage, and installation.
Finish-cleaned materials and components should not be stored directly on the ground or floor, and
should not be permitted, insofar as practicable, to come in contact with asphalt, galvanized or carbon
steel, mercury, zinc, lead, brass, low-melting point metals, or alloys or compounds of such materials.
All 4 lines are in hydrocarbon service, they shall be purged with nitrogen and sealed with blanks before
shipping. All 4 lines will need flanged ends for flushing, testing, cleaning and nitrogen purge.
11. APPENDICES
Appendix 1: Chemicals – Material Safety Data Sheet
Appendix 2: Chemical Equipment Layout Diagram
Appendix 3: Chemical Cleaning Line List (P&ID)
Appendix 4: Chemical Cleaning JSA

Appendix 1: Chemicals – Material Safety Data Sheet
G-Biosciences, St Louis, MO, USA | 1-800-628-7730 | 1-314-991-6034 | [email protected]
A Geno Technology, Inc. (USA) brand name
Safety Data Sheet
Cat. # 786-520
think proteins! think G-Biosciences! www.GBiosciences.com

Tween 80, Regular concentration
Safety Data Sheet
according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations
Date of issue: 08/15/2016 Revision date: 05/11/2017 Version: 7.1
SECTION 1: Identification
1.1. Identification
Product form : Substance
Substance name : Tween 80, Regular concentration
CAS-No. : 9005-65-6
Product code : 367T
Formula : (C64H123O26)n
Synonyms : polsorban 80 / polyoxyethylene sorbitan monooleate (=TWEEN 80) / polysorbate 80 / TWEEN
80 A / TWEEN 80 LM (polysorbate 80) / TWEEN 80K (polysorbate 80) / TWEEN 80SD
(polysorbate 80) / value TN 80
BIG No : 25645
1.2. Recommended use and restrictions on use
Use of the substance/mixture : Surfactant
1.3. Supplier
Geno Technology, Inc./ G-Biosciences
9800 Page Avenue
Saint Louis, 63132-1429 - United States
T 800-628-7730 - F 314-991-1504
[email protected] - www.GBiosciences.com
1.4. Emergency telephone number

Emergency number : Chemtrec 1-800-424-9300 (USA/Canada), +1-703-527-3887 (Intl)
SECTION 2: Hazard(s) identification

2.1. Classification of the substance or mixture
GHS US classification
Not classified
2.2. GHS Label elements, including precautionary statements

GHS US labeling
No labeling applicable
2.3. Other hazards which do not result in classification
No additional information available
2.4. Unknown acute toxicity (GHS US)
Not applicable
SECTION 3: Composition/Information on ingredients

3.1. Substances
Name Common Name (Synonyms) Product identifier % GHS US classification
Tween 80, Regular concentration polsorban 80 / polyoxyethylene (CAS-No.) 9005-65-6 100 Not classified
(Main constituent) sorbitan monooleate (=TWEEN 80) /
polysorbate 80 / TWEEN 80 A /
TWEEN 80 LM (polysorbate 80) /
TWEEN 80K (polysorbate 80) /
TWEEN 80SD (polysorbate 80) /
value TN 80
Full text of hazard classes and H-statements : see section 16
3.2. Mixtures
Not applicable
SECTION 4: First-aid measures
4.1. Description of first aid measures
First-aid measures general : If you feel unwell, seek medical advice.
First-aid measures after inhalation : Remove the victim into fresh air. Respiratory problems: consult a doctor/medical service.
First-aid measures after skin contact : Rinse with water. Soap may be used. Take victim to a doctor if irritation persists.
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Safety Data Sheet
First-aid measures after eye contact : Rinse with water. Remove contact lenses, if present and easy to do. Continue rinsing. Take
victim to an ophthalmologist if irritation persists.
First-aid measures after ingestion : Rinse mouth with water. Immediately after ingestion: give lots of water to drink. Call Poison
Information Centre (www.big.be/antigif.htm). Consult a doctor/medical service if you feel unwell.
4.2. Most important symptoms and effects (acute and delayed)
Potential Adverse human health effects and : Non-toxic if swallowed (LD50 oral, rat > 5000 mg/kg). Slightly irritant to skin. Slightly harmful by
symptoms inhalation. Slightly irritant to eyes.
Symptoms/effects after skin contact : Slight irritation.
Symptoms/effects after eye contact : Slight irritation.
4.3. Immediate medical attention and special treatment, if necessary
Treat symptomatically.
SECTION 5: Fire-fighting measures

5.1. Suitable (and unsuitable) extinguishing media
Suitable extinguishing media : Quick-acting ABC powder extinguisher. Quick-acting BC powder extinguisher. Quick-acting
class B foam extinguisher. Quick-acting CO2 extinguisher. Class B foam (not alcohol-resistant).
Unsuitable extinguishing media : Water (quick-acting extinguisher, reel); risk of puddle expansion. Water; risk of puddle
expansion.
5.2. Specific hazards arising from the chemical
Fire hazard : DIRECT FIRE HAZARD: Combustible. INDIRECT FIRE HAZARD: Temperature above
flashpoint: higher fire/explosion hazard.
5.3. Special protective equipment and precautions for fire-fighters
Precautionary measures fire : Exposure to fire/heat: keep upwind. Exposure to fire/heat: have neighbourhood close doors and
windows.
Firefighting instructions : No specific fire-fighting instructions required.
Protection during firefighting : Heat/fire exposure: compressed air/oxygen apparatus.
SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
6.1.1. For non-emergency personnel
Protective equipment : Gloves. Protective clothing.
Emergency procedures : Mark the danger area. No naked flames. Wash contaminated clothes.
6.1.2. For emergency responders

Protective equipment : Do not attempt to take action without suitable protective equipment. For further information
refer to section 8: "Exposure controls/personal protection".
6.2. Environmental precautions
Avoid release to the environment.
6.3. Methods and material for containment and cleaning up
For containment : Contain released product, pump into suitable containers. Plug the leak, cut off the supply.
Methods for cleaning up : Take up liquid spill into absorbent material, e.g.: sand or vermiculite. Scoop absorbed
substance into closing containers. Clean contaminated surfaces with an excess of water. Wash
clothing and equipment after handling.
Other information : Dispose of materials or solid residues at an authorized site.
6.4. Reference to other sections
For further information refer to section 13.
SECTION 7: Handling and storage

7.1. Precautions for safe handling
Precautions for safe handling : Keep away from naked flames/heat. In finely divided state: use spark-/explosionproof
appliances. Finely divided: keep away from ignition sources/sparks. Carry operations in the
open/under local exhaust/ventilation or with respiratory protection. Comply with the legal
requirements. Thoroughly clean/dry the installation before use. Keep container tightly closed.
Hygiene measures : Do not eat, drink or smoke when using this product. Always wash hands after handling the
product.
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Safety Data Sheet
7.2. Conditions for safe storage, including any incompatibilities

Storage conditions : Store in a well-ventilated place. Keep cool.
Heat-ignition : KEEP SUBSTANCE AWAY FROM: heat sources.
Information on mixed storage : KEEP SUBSTANCE AWAY FROM: oxidizing agents. (strong) bases.
Storage area : Store in a dry area. Store at room temperature. Meet the legal requirements.
Special rules on packaging : SPECIAL REQUIREMENTS: closing. correctly labelled. meet the legal requirements. Secure
fragile packagings in solid containers.
SECTION 8: Exposure controls/personal protection

8.1. Control parameters
Tween 80, Regular concentration (9005-65-6)
8.2. Appropriate engineering controls

Appropriate engineering controls : Ensure good ventilation of the work station.
Environmental exposure controls : Avoid release to the environment.
8.3. Individual protection measures/Personal protective equipment
Hand protection:
Gloves
Eye protection:
Safety glasses
Skin and body protection:

Protective clothing
Respiratory protection:
Respiratory protection not required in normal conditions
SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties
Physical state : Liquid
Appearance : Liquid.
Color : Amber
Odor : Characteristic odour
Odor threshold : No data available
pH : 5 - 7 (5 %)
Melting point : Not applicable
Freezing point : No data available
Boiling point : 100 °C
Flash point : 148 °C
Relative evaporation rate (butyl acetate=1) : No data available
Flammability (solid, gas) : Not applicable.
Vapor pressure : < 1.3 hPa (20 °C)
Relative vapor density at 20 °C : >2
Relative density : 1.1
Specific gravity / density : 1080 kg/m³
Solubility : Moderately soluble in water. Soluble in ethanol. Soluble in acetone. Insoluble in oils/fats.
Soluble in methanol. Soluble in ethylacetate. Soluble in toluene.
Water: 10 g/100ml
Log Pow : No data available
Auto-ignition temperature : No data available
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Safety Data Sheet
Decomposition temperature : No data available

Viscosity, kinematic : No data available
Viscosity, dynamic : No data available
Explosion limits : No data available
Explosive properties : No data available
Oxidizing properties : No data available
9.2. Other information
Other properties : Gas/vapour heavier than air at 20°C. Slightly volatile.
SECTION 10: Stability and reactivity

10.1. Reactivity
The product is non-reactive under normal conditions of use, storage and transport.
10.2. Chemical stability
Stable under normal conditions.
10.3. Possibility of hazardous reactions
No dangerous reactions known under normal conditions of use.
10.4. Conditions to avoid
None under recommended storage and handling conditions (see section 7).
10.5. Incompatible materials
10.6. Hazardous decomposition products
Hazardous decomposition products.
SECTION 11: Toxicological information

11.1. Information on toxicological effects
Acute toxicity (oral) : Not classified
Acute toxicity (dermal) : Not classified
Acute toxicity (inhalation) : Not classified
LD50 oral rat > 10000 mg/kg (Rat, Oral)
Skin corrosion/irritation : Not classified
pH: 5 - 7 (5 %)
Serious eye damage/irritation : Not classified
pH: 5 - 7 (5 %)
Respiratory or skin sensitization : Not classified
Germ cell mutagenicity : Not classified
Carcinogenicity : Not classified
Reproductive toxicity : Not classified
Specific target organ toxicity – single exposure : Not classified

Specific target organ toxicity – repeated : Not classified
exposure
Aspiration hazard : Not classified
Potential Adverse human health effects and : Non-toxic if swallowed (LD50 oral, rat > 5000 mg/kg). Slightly irritant to skin. Slightly harmful by
symptoms inhalation. Slightly irritant to eyes.
Symptoms/effects after skin contact : Slight irritation.
Symptoms/effects after eye contact : Slight irritation.
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Safety Data Sheet
SECTION 12: Ecological information

12.1. Toxicity
Ecology - general : The product is not considered harmful to aquatic organisms or to cause long-term adverse
effects in the environment.
Ecology - air : Not classified as dangerous for the ozone layer (Regulation (EC) No 1005/2009).
Ecology - water : Mild water pollutant (surface water). No data available on ecotoxicity.
12.2. Persistence and degradability

Persistence and degradability Biodegradability in water: no data available.
12.3. Bioaccumulative potential

Bioaccumulative potential No bioaccumulation data available.
12.4. Mobility in soil

12.5. Other adverse effects

SECTION 13: Disposal considerations

13.1. Disposal methods
Waste treatment methods : Waste treatment methods.
Product/Packaging disposal recommendations : Remove to an authorized incinerator equipped with an afterburner and a flue gas scrubber with
energy recovery.
Additional information : Can be considered as non hazardous waste according to Directive 2008/98/EC, as amended
by Regulation (EU) No 1357/2014 and Regulation (EU) No 2017/997.
SECTION 14: Transport information

Department of Transportation (DOT)
In accordance with DOT
Not regulated
Transportation of Dangerous Goods
Not applicable
Transport by sea
Not regulated
Air transport
Not regulated
SECTION 15: Regulatory information

15.1. US Federal regulations
Not listed on the United States TSCA (Toxic Substances Control Act) inventory
15.2. International regulations
CANADA
EU-Regulations
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Safety Data Sheet
National regulations
15.3. US State regulations
SECTION 16: Other information

Revision date : 05/11/2017
SDS US (GHS HazCom 2012)
This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as
guaranteeing any specific property of the product.
06/28/2019 EN (English US) 6/6

Sodium Carbonate, Anhydrous
Safety Data Sheet
Date of issue: 05/13/2013 Revision date: 03/20/2018 Supersedes: 03/20/2018 Version: 1.2
1.1. Identification
Substance name : Sodium Carbonate, Anhydrous
CAS-No. : 497-19-8
Product code : LC22965
Formula : Na2CO3
1.2. Recommended use and restrictions on use
Use of the substance/mixture : For laboratory and manufacturing use only.
Recommended use : Laboratory chemicals
Restrictions on use : Not for food, drug or household use
1.3. Supplier
LabChem Inc
Jackson's Pointe Commerce Park Building 1000, 1010 Jackson's Pointe Court
Zelienople, PA 16063 - USA
T 412-826-5230 - F 724-473-0647
[email protected] - www.labchem.com

Emergency number : CHEMTREC: 1-800-424-9300 or +1-703-741-5970

GHS-US classification
Skin corrosion/irritation H315 Causes skin irritation
Category 2
Serious eye damage/eye H319 Causes serious eye irritation
irritation Category 2A
Full text of H statements : see section 16
2.2. GHS Label elements, including precautionary statements

GHS-US labeling
Hazard pictograms (GHS-US) :
GHS07
Signal word (GHS-US) : Warning
Hazard statements (GHS-US) : H315 - Causes skin irritation
H319 - Causes serious eye irritation
Precautionary statements (GHS-US) : P264 - Wash exposed skin thoroughly after handling.
P280 - Wear eye protection, protective gloves.
P302+P352 - IF ON SKIN: Wash with plenty of soap and water.
P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing
P332+P313 - If skin irritation occurs: Get medical advice/attention.
P337+P313 - If eye irritation persists: Get medical advice/attention.
P362 - Take off contaminated clothing and wash before reuse.
2.3. Other hazards which do not result in classification
Other hazards not contributing to the : None.
classification
Not applicable

Safety Data Sheet

3.1. Substances
Substance type : Mono-constituent
Name Product identifier % GHS-US classification
Sodium Carbonate, Anhydrous (CAS-No.) 497-19-8 100 Skin Irrit. 2, H315
(Main constituent) Eye Irrit. 2A, H319
3.2. Mixtures
Not applicable
SECTION 4: First-aid measures
First-aid measures general : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical
advice (show the label where possible).
First-aid measures after inhalation : Allow victim to breathe fresh air. Allow the victim to rest.
First-aid measures after skin contact : Wash with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation
occurs: Get medical advice/attention. Get medical advice/attention.
First-aid measures after eye contact : Rinse immediately with plenty of water. Obtain medical attention if pain, blinking or redness
persists.
First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention.
4.2. Most important symptoms and effects (acute and delayed)
Symptoms/effects after inhalation : Coughing.
Symptoms/effects after skin contact : Causes skin irritation.
Symptoms/effects after eye contact : Causes serious eye irritation.
Symptoms/effects after ingestion : Vomiting. Nausea.
Chronic symptoms : Not available.
4.3. Immediate medical attention and special treatment, if necessary
None.
SECTION 5: Fire-fighting measures

5.1. Suitable (and unsuitable) extinguishing media
Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand.
Unsuitable extinguishing media : Do not use a heavy water stream.
5.2. Specific hazards arising from the chemical
Fire hazard : Non combustible.
Explosion hazard : Not applicable.
Reactivity : Reacts with (some) acids.
5.3. Special protective equipment and precautions for fire-fighters
Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any
chemical fire. Prevent fire-fighting water from entering environment.
Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection.

General measures : None.

Emergency procedures : Evacuate unnecessary personnel.

Protective equipment : Equip cleanup crew with proper protection.
Emergency procedures : Ventilate area.
Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.
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Safety Data Sheet

Methods for cleaning up : On land, sweep or shovel into suitable containers. Minimize generation of dust. Store away
from other materials.
See Heading 8. Exposure controls and personal protection.

Precautions for safe handling : Wash hands and other exposed areas with mild soap and water before eating, drinking or
smoking and when leaving work. Provide good ventilation in process area to prevent formation
of vapor.
Hygiene measures : Wash exposed skin thoroughly after handling.
Storage conditions : Keep only in the original container in a cool, well ventilated place away from : incompatible
materials. Keep container closed when not in use.
Incompatible products : Strong bases. Strong acids.
Incompatible materials : Sources of ignition. Direct sunlight.

8.2. Appropriate engineering controls

Appropriate engineering controls : Emergency eye wash fountains should be available in the immediate vicinity of any potential
exposure.
8.3. Individual protection measures/Personal protective equipment

Personal protective equipment:
Gloves. Safety glasses.
Hand protection:
Wear protective gloves.
Eye protection:
Chemical goggles or safety glasses
Skin and body protection:

Wear suitable protective clothing
Respiratory protection:
Respiratory protection not required in normal
conditions
Other information:
Do not eat, drink or smoke during use.

Physical state : Solid
Appearance : White powder or lumps.
Color : white
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Safety Data Sheet
Odor : odorless
pH : 11.6
Melting point : No data available
Flash point : No data available
Flammability (solid, gas) : Non flammable.
Vapor pressure : No data available
Relative vapor density at 20 °C : No data available
Relative density : No data available
Specific gravity / density : 2.53 g/cm³
Molecular mass : 105.99 g/mol
Solubility : No data available
Explosive properties : Not applicable.
Oxidizing properties : None.

10.1. Reactivity
Reacts with (some) acids.
Not established.
Not established.
Direct sunlight. Extremely high or low temperatures.
Strong acids. Strong bases.
fume. Carbon monoxide. Carbon dioxide.

Likely routes of exposure : Inhalation; Skin and eye contact

Acute toxicity : Not classified
Sodium Carbonate, Anhydrous (497-19-8)
LD50 oral rat 4090 mg/kg
ATE US (oral) 4090 mg/kg body weight
Skin corrosion/irritation : Causes skin irritation.
pH: 11.6
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Safety Data Sheet
Serious eye damage/irritation : Causes serious eye irritation.

pH: 11.6
Based on available data, the classification criteria are not met
Specific target organ toxicity – single exposure : Not classified
Specific target organ toxicity – repeated : Not classified
exposure
Potential Adverse human health effects and : Based on available data, the classification criteria are not met.
symptoms
Symptoms/effects after inhalation : Coughing.
Symptoms/effects after skin contact : Causes skin irritation.
Symptoms/effects after eye contact : Causes serious eye irritation.
Symptoms/effects after ingestion : Vomiting. Nausea.
Chronic symptoms : Not available.

12.1. Toxicity
LC50 fish 1 300 mg/l
EC50 Daphnia 1 265 mg/l
LC50 fish 2 740 mg/l

Persistence and degradability Not established.

Bioaccumulative potential Not established.

Other information : Avoid release to the environment.

13.1. Disposal methods
Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations.
Ecology - waste materials : Avoid release to the environment.

Not regulated
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Safety Data Sheet

Listed on the United States TSCA (Toxic Substances Control Act) inventory
All components of this product are listed, or excluded from listing, on the United States Environmental Protection Agency Toxic
Substances Control Act (TSCA) inventory

CANADA
Listed on the Canadian DSL (Domestic Substances List)
EU-Regulations
Listed on the Canadian IDL (Ingredient Disclosure List)

California Proposition 65 - This product does not contain any substances known to the state of California to cause cancer,
developmental and/or reproductive harm

Other information : None.
Full text of H-phrases: see section 16:
--- H315 Causes skin irritation
---
--- H319 Causes serious eye irritation
---
NFPA health hazard : 1 - Materials that, under emergency conditions, can cause
significant irritation.
NFPA fire hazard : 0 - Materials that will not burn under typical dire conditions,
including intrinsically noncombustible materials such as
concrete, stone, and sand.
NFPA reactivity : 0 - Material that in themselves are normally stable, even
under fire conditions.
Hazard Rating
Health : 1 Slight Hazard - Irritation or minor reversible injury possible
Flammability : 0 Minimal Hazard - Materials that will not burn
Physical : 0 Minimal Hazard - Materials that are normally stable, even under fire conditions, and will NOT
react with water, polymerize, decompose, condense, or self-react. Non-Explosives.
Personal protection : B
B - Safety glasses, Gloves
SDS US LabChem
Information in this SDS is from available published sources and is believed to be accurate. No warranty, express or implied, is made and LabChem Inc assumes no liability resulting from the use of this
SDS. The user must determine suitability of this information for his application.
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Sodium Tripolyphosphate MATERIAL SAFETY DATA SHEET
CAS No 7758-29-4 SDS/MSDS
Product name : Sodium Tripolyphosphate

CAS-No. : 7758-29-4
Identified uses : Laboratory chemicals, Industrial & for professional use only.
Company : Central Drug House (P) Ltd

7/28 Vardaan House
New Delhi-10002
INDIA
Telephone : +91 11 49404040
Email : [email protected]
1.4 Emergency telephone number

Emergency Phone # : +91 11 49404040 (9:00am - 6:00 pm) [Office hours]
Not a hazardous substance or mixture according to Regulation (EC) No. 1272/2008.

This substance is not classified as dangerous according to Directive 67/548/EEC.
The product does not need to be labelled in accordance with EC directives or respective national laws.
- none
Synonyms : Sodium triphosphate pentabasic

Sodium tripolyphosphate pentabasic
Pentasodium tripolyphosphate Anhydrous
STPP
Sodium triphosphate
Formula : Na5O10P3
Molecular Weight : 367,86 g/mol
CAS-No. : 7758-29-4
EC-No. : 231-838-7
Page 1 of 6
No components need to be disclosed according to the applicable regulations.
Consult a physician. Show this safety data sheet to the doctor in attendance.
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
Wash off with soap and plenty of water. Consult a physician.
Flush eyes with water as a precaution.
Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.
The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in
section 11
no data available
Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Oxides of phosphorus, Sodium oxides
Wear self contained breathing apparatus for fire fighting if necessary.
no data available
Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Avoid
breathing dust.
For personal protection see section 8.
Do not let product enter drains.
Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed
containers for disposal.
For disposal see section 13.
Provide appropriate exhaust ventilation at places where dust is formed.

For precautions see section 2.2.
Page 2 of 6
Store in cool place. Keep container tightly closed in a dry and well-ventilated place.
hygroscopic
Apart from the uses mentioned in section 1.2 no other specific uses are stipulated
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at
the end of workday.
Use equipment for eye protection tested and approved under appropriate government standards
such as NIOSH (US) or EN 166(EU).
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique
(without touching glove’s outer surface) to avoid skin contact with this product. Dispose of
contaminated gloves after use in accordance with applicable laws and good laboratory practices.
Wash and dry hands.
Choose body protection in relation to its type, to the concentration and amount of dangerous
substances, and to the specific work-place., The type of protective equipment must be selected
according to the concentration and amount of the dangerous substance at the specific workplace.
Respiratory protection is not required. Where protection from nuisance levels of dusts are desired,
use type N95 (US) or type P1 (EN 143) dust masks. Use respirators and components tested and
approved under appropriate government standards such as NIOSH (US) or CEN (EU).
Do not let product enter drains.
a) Appearance Form: granules

Colour: white
b) Odour no data available
c) Odour Threshold no data available
d) pH 9,5 - 10,3 at 1 g/l
e) Melting point/freezing Melting point/range: 622 °C
point
f) Initial boiling point and no data available
boiling range
g) Flash point not applicable
h) Evapouration rate no data available
i) Flammability (solid, gas) no data available
j) Upper/lower no data available
flammability or
explosive limits
Page 3 of 6
k) Vapour pressure no data available
l) Vapour density no data available
m) Relative density no data available
n) Water solubility 148 g/l at 20 °C - completely soluble
o) Partition coefficient: n- no data available
octanol/water
p) Auto-ignition no data available
temperature
q) Decomposition no data available
temperature
r) Viscosity no data available
s) Explosive properties no data available
t) Oxidizing properties no data available
Dissociation constant 9,52 at 25 °C
no data available
Stable under recommended storage conditions.
no data available
Avoid moisture.
Strong acids, Strong oxidizing agents
Other decomposition products - no data available

In the event of fire: see section 5
LD50 Oral - rat - male and female - > 2.000 mg/kg

(OECD Test Guideline 401)
LC50 Inhalation - rat - male and female - 4 h - > 0,39 mg/l
LD50 Dermal - rabbit - 4.640 mg/kg
Skin - rabbit
Result: No skin irritation
Eyes - rabbit
Result: No eye irritation
Page 4 of 6
in vivo assay - mouse
Result: Did not cause sensitisation on laboratory animals.
in vitro assay
S. typhimurium
Result: negative
rat - male
Result: negative
IARC: No component of this product present at levels greater than or equal to 0.1% is identified as
probable, possible or confirmed human carcinogen by IARC.
no data available
no data available
no data available
no data available
RTECS: YK4570000
Gastrointestinal disturbance, To the best of our knowledge, the chemical, physical, and toxicological
properties have not been thoroughly investigated.
Toxicity to daphnia and EC50 - Daphnia magna (Water flea) - > 100 mg/l - 48 h
other aquatic
invertebrates
no data available
no data available
no data available
PBT/vPvB assessment not available as chemical safety assessment not required/not conducted
no data available
Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with
an afterburner and scrubber. Offer surplus and non-recyclable solutions to a licensed disposal company.
Page 5 of 6
Dispose of as unused product.
ADR/RID: - IMDG: - IATA: -
ADR/RID: Not dangerous goods

IMDG: Not dangerous goods
IATA: Not dangerous goods
ADR/RID: no IMDG Marine pollutant: no IATA: no
no data available
This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.
no data available
For this product a chemical safety assessment was not carried out
The above information is believed to be correct but does not purport to be all inclusive and shall be used
only as a guide. The information in this document is based on the present state of our knowledge and is
applicable to the product with regard to appropriate safety precautions. It does not represent any
guarantee of the properties of the product. Central Drug House (P) Ltd and its Affiliates shall not be held
liable for any damage resulting from handling or from contact with the above product. See
www.cdhfinechemical.com for additional terms and conditions of sale.
Page 6 of 6
TSP
SAFETY DATA SHEET Trisodium Phosphate
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION:
Uses: Substance used as such, in
MANUFACTURER: Griffin Bros., Inc.. formulation or in formulation of products for :
P.O. Box 7719 Detergent, Treatment of textils and leather,
Salem, OR 97303 Metal treatment, Water treatment,
Formulation Fertilizer , Laboratory
INFORMATION: (800) 456-4743
chemicals, Ceramics, Dyes etc.
EMERGENCY PHONE: CHEMTREC: (800) 424-9300
PRODUCT NAME: Trisodium Phosphate PURE: LIQUID:
PRODUCT NUMBER: G-531
DATE PREPARED: 03/03/2015
LAST REVISION: 07/18/2015 MIXTURE: X SOLID: X
2. HAZARDOUS IDENTIFICATION:
EMERGENCY OVERVIEW: Corrosive
GHS CLASSIFICATION: Skin: (Category 2), Eyes: (Category2A), STOT – Single Exposure (Category 3) Respiratory
GHS Label elements, including precautionary statements
SIGNAL WORD: Warning PICTOGRAM:
HAZARD STATEMENT(S):
H315: Causes skin irritation
H319: Causes serious eye irritation
H335: May cause respiratory irritation
PRECAUTIONARY STATEMENT(S):
P261: Avoid breathing spray, mist, fume, gas, dust, vapours
P280: Wear protective gloves, protective clothing, eye protection, face protection
P302+P352: IF ON SKIN: Wash with plenty of hands, forearms and face
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
P332+P313: IF SKIN irritation occurs: Get medical advice/attention
P337+P313: IF EYE irritation persists: Get medical advice/attention
3. COMPOSITION/INFORMATION ON INGREDIENTS:
Chemical Name CAS # Wt. Range %
TRISODIUM PHOSPHATE 10101-89-0 >= 98.5
Balance of formula is Proprietary Non-hazardous materials -- Balance
4. FIRST AID MEASURES:
GENERAL ADVICE: Consult a physician. Show this safety data sheet to the doctor in attendance. Move out of dangerous area.
EYE CONTACT: Immediately flush eyes with water for at least 15 minutes. Hold eyelids open while flushing the eyes.
INHALATION: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Get medical attention immediately.
INGESTION: If swallowed, do NOT induce vomiting. Give victim lots of water or milk. Get medical attention immediately.
Never give anything by mouth to an unconscious or convulsing person.
SKIN CONTACT: Wash with soap and water. Change contaminated clothing. Get medical attention if irritation develops or persists.
AGGRAVATED MEDICAL CONDITIONS: Pre-existing eye, skin or respiratory conditions.
SUPPLEMENTAL HEALTH INFORMATION: The effects of long-term, low-level exposure to this product have not been determined. Safe
handling of this material on a long-term basis should emphasize the avoidance of all effects from repetitive acute exposures.
5. FIRE FIGHTING MEASURES:
EXTINGUISHING MEDIA: Use extinguishing media appropriate for surrounding fire.
SPECIAL FIRE FIGHTING PROCEDURES:
Firefighters should wear proper protective equipment and self-contained breathing apparatus with full facepiece in positive pressure
mode. Move containers from fire area if it can be done without risk. Use water to keep fire-exposed containers cool.
UNUSUAL FIRE AND EXPLOSION HAZARDS: None known.
COMBUSTION PRODUCTS: None known.
6. ACCIDENTAL RELEASE MEASURES:
STEPS TO BE TAKEN IN CASE MATERIAL IS SPILLED OR RELEASED: Pick up and arrange disposal without creating dust. Sweep up and
shovel. DO NOT add water to spilled material. DO NOT use floor sweeping compounds to clean up spills. Every attempt should be made to avoid
mixing spilled material with other chemicals or debris when cleaning up. Keep in suitable, closed containers for disposal.
Page 1 of 3 G-531 TSP Trisodium Phosphate
1
7. HANDLING AND STORAGE:
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: Do not handle until all safety precautions have been read and understood.
Do not allow product to get wet. If liner is present, tie after each use. Use good personal hygiene when handling this product. Wash hands after
use, before smoking, or using the toilet. Wear personal protection as required per safety program. Follow all SDS/label precautions even after
container is emptied because it may retain product residues.
OTHER PRECAUTIONS: For industrial and institutional use only. Keep away from children. Keep containers closed while not in use.
8. EXPOSURE CONTROL/PERSONAL PROTECTION:
EXPOSURE CONTROLS:
OSHA PEL ACGIH TLV

Chemical Name TWA STEL TWA STEL
TRISODIUM PHOSPHATE Respirable: 5 mg/m³. Inhalable: 15mg/m³ Respirable: 3 mg/m³. Inhalable: 10 mg/m³
PERSONAL PROTECTIVE EQUIPMENT
RESPIRATORY PROTECTION: Use respiratory protection mask according to NIOSH/MSHA. Respiratory protection programs
must comply with 29 CFR 1910.134.
VENTILATION: Local exhaust sufficient to keep exposure below TLV.
WORK/HYGENIC PRACTICES: Use good personal hygiene when handling this product. Wash hands after use, before smoking, or using the
toilet.
EYE PROTECTION: Use chemical safety goggles and/or full face shield when splashing is possible. Contact lenses should not be
worn when working with this material. Maintain eye wash fountain and quick-drench facilities in work areas
PROTECTIVE GLOVES: Rubber, Neoprene, Nitrile, Polyvinyl chloride (PVC), Gloves must be inspected prior to use. Use proper
glove removal technique (without touching glove's outer surface) to avoid skin contact with this product.
OTHER PROTECTIVE EQUIP: Boots, apron, lab coat or coveralls of impervious material, as appropriate to avoid skin contact.
ENGINEERING CONTROLS: Facilities storing or utilizing this material should be equipped with an eye wash facility and safety shower.
9. PHYSICAL AND CHEMICAL PROPERTIES:
INFORMATION ON BASIC PHYSICAL AND CHEMICAL PROPERTIES:
a) Appearance: White granular powder k) Vapor pressure (mm/hg): No data available

b) Odor: Odorless l) Vapor density (Air = 1): No data available
d) pH: 11.7 - 12.5 at 50 g/l at 20 °C (68 °F) m) Relative density (Specific Gravity): Not applicable
e) Melting point/freezing point: No data available n) Water solubility: 21g / 100g saturated solution @ 25 °C
f) Initial boiling point and boiling range: Not applicable p) Auto-ignition temperature: n/a
g) Flash point: n/a Method Used: n/a r) Viscosity: n/a
h) Evaporation rate: No data available -) Pounds Per Gallon: Not applicable
j) Upper/lower flammability or explosive limits: UEL: n/a LEL: n/a OTHER: No other data is available for this product. . . . .
10. STABILITY AND REACTIVITY:

STABLE: Stable under recommended storage conditions.
INCOMPATIBILITY: Take care when using on aluminum.This material could be corrosive to aluminum surfaces because of the high pH.
HAZARDOUS DECOMPOSITION OR BY-PRODUCTS: oxides of carbon
HAZARDOUS POLYMERIZATION: Will Not Occur
CONDITIONS TO AVOID: Do not get water/moisture inside container, product is hygroscopic. Avoid contact with incompatible materials.
11. TOXICOLOGICAL INFORMATION:
Laboratory data
Data from ICL Performance LP single-dose (acute) animal studies with this material are given below:
ORAL – RAT LD50: 6,500 mg/kg; practically non-toxic
DERMAL – RABBIT LD50: > 7940 mgt/kg; practically non-toxic
EYE IRRITATION – RABBIT (4-HR EXP.): corrosive
SKIN IRRITATION – RABBIT: 3.3 / 8.0; moderately irritating
The anhydrous form of this material produced no mutagenic effects in standard assays using fruit flies.
This material has been defined as a hazardous chemical under criteria of the OSHA Hazard Communication Standard (29 CFR 1910.1200)
12. ECOLOGICAL INFORMATION:
The following data have been classified using criteria adopted by the European Economic Community (ECC) for aquatic organism toxicity.
INVERTEBRATE: 48-hr EC50 Daphnia magna: >1000 mg/L; Practically Non-toxic
WARMWATER FISH: 96-hr LC50 Bluegill sunfish: 440 mg/L; Practically Non-toxic
COLDWATER FISH: 96-hr LC50 Rainbow Trout: 260 mg/L; Practically Non-toxic
13. DISPOSAL CONSIDERATIONS: This material when discarded in pure form is not a hazardous waste as defined by 40 CFR 261, the Resource
Conservation and Recovery Act (RCRA). Dry materials may be landfilled or recycled in accordance with local, state, and federal regulations. If materials have
become contaminated with other substances, dispose of in accordance with local, state, and federal regulations.

2
14. TRANSPORT INFORMATION:
Regulation UN No. Proper Shipping Name Transport Packing Group

Hazard Class(es)
US DOT - Non-Regulated Material, Solid - -
ERG No.: N/A
15. REGULATORY INFORMATION: No data available
16. OTHER INFORMATION:

HMIS INFORMATION: HEALTH: 1 FLAMMABILITY: 0 PHYSICAL HAZARD: 0 PROTECTIVE: B
NFPA INFORMATION: TOXICITY: 1 FIRE: 0 REACTIVITY: 0 SPECIAL: N
Griffin Bros., Inc. expressly disclaims all express or implied warranties of merchantability and fitness for a particular purpose, with respect to the product or
information provided herein. All information appearing herein is based upon data obtained from the manufacturer and/or recognized technical sources.
While the information appears to be accurate, Griffin Bros., Inc. makes no representations as to its accuracy or sufficiency. Conditions of use are beyond
Griffin Bros., Inc.’s control and therefore users are responsible to verify this data under their particular purposes and they assume all risks of their use,
handling, and disposal of the product, or from the publications of use of, or reliance upon, information contained herein. This information relates only to the
product designated herein, and does not relate to its use in combination with any other material or in any other process.
3
Citric acid Monohydrate
SAFETY DATA SHEET

ACCORDING TO EC-REGULATIONS 1907/2006 (REACH); 1272/2008 & 453/2010 (CLP)
Version: 1
Date: 28/02/2011
SECTION 1: IDENTIFICATION
IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE
THE COMPANY/UNDERTAKING
1.1 Product identifier
Chemical Name Citric acid
Trade name Citric acid monohydrate
CAS No. 5949-29-1
EINECS No. 201-069-1
1.2 Relevant identified uses of the substance or mixture and uses advised against
Identified use(s) Used as a sour agent, buffering agent and antioxidant in the food
industry; a correctant in pharmaceutical industry; used in detergents,
buffering and chelating, sizing and as a sequestrant.
Uses advised against No uses advised against.
1.3 Details of the supplier of the Safety Data Sheet
Company Identification Weifang Ensign Industry Co., Ltd.
No. 1567, Changsheng
Changsheng Street, Changle, Weifang, 262400,
262400, Shandong
Shandong Province, China
Telephone 0086-536-6298198
Fax No 0086-536-6234587
Contact name Xiaoming Yi
e mail [email protected]
1.4 Emergency telephone number 0086-536-6298198

0086-536-6298198
SECTION 2: HAZARDS IDENTIFICATION

2.1 Classification of the substance or mixture
2.1.1 Regulation (EC) No. 1272/2008 (CLP) Warning.H319: Causes serious eye irritation
2.1.2 Directive 67/548/EEC & Directive 1999/45/EC Xi; Irritant.R36
2.2 Label elements
2.2.1 According to Regulation (EC) No. 1272/2008 & 453/2010 (CLP)
Hazard Pictogram
Signal word(s) Warning

Hazard statement(s) H319: Causes serious eye irritation
Precautionary statement(s) P264. Wash hands thoroughly after handling.
P280 Wear eye protection.
P305 + P351 + P338. IF IN EYES: Rinse cautiously with water for several
minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P337+P313: If eye irritation persists: Get medical advice/attention.
2.2.2 According to Directive 67/548/EEC & Directive 1999/45/EC
Hazard Symbol
Irritant
Risk Phrases R36. Irritating to eye
Safety Phrases S26. Avoid contact with eyes. In case of contact with eyes, rinse
immediately with plenty of water and seek medical advice
2.3 Other hazards Not known
2.4 Additional Information Not known
Revision:
Revision: Citric
Citric acid monohydrat
monohydrate
e Version
Version 1 Page: 1/ 5
SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS
3.1 Substance
Composition %W/W EC No. CAS No
Citric acid 99.5 –100.5 201-069-1 5949-29-1
3.2 Mixture . Not applicable
SECTION 4: FIRST AID MEASURES
4.1 Description of first aid measures

Inhalation Move to fresh air.
Skin Contact Wash off immediately with plenty of water for at least 15 minut es. If irritation
persists, call a physician.
Eye Contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a
physician.
Ingestion Do NOT induce vomiting. Drink 1 or 2 glasses of water. Never give anything by
mouth to an unconscious person. Consult a physician.
4.2 Most important symptoms and Serious eye damage/eye irritation: Eye Irrit. 2
effects, both acute and delayed
4.3 Indication of immediate medical Consult a physician.
attention and special treatment needed
SECTION 5: FIRE-FIGHTING MEASURES

5.1 Extinguishing Media
5.1.1 Suitable Extinguishing Media Use alcohol-resistant foam, carbon dioxide, dry powder or water fog.
5.1.2. Unsuitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the
surrounding environment.
5.2 Special hazards arising from the Oxides of carbon
substance or mixture
5.3 Advice for fire-fighters In the event of fire, wear self-contained breathing apparatus and wear suit able
protective clothing. Fire residues and contaminated fire extinguishing water must be
disposed of in accordance with local regulations
5.4 Additional information Explosion hazard from the generation of dust.
SECTION 6: ACCIDENTAL RELEASE MEASURES

6.1 Personal precautions, protective Use personal protective equipment.
equipment and emergency procedures
6.2 Environmental precautions Do not flush substance into surface water or sewage system.
6.3 Methods and material for containment Sweep up or vacuum up spillage and collect in suitable container for disposal.
and cleaning up
6.4 Reference to other sections Section 8
SECTION 7: HANDLING AND STORAGE

7.1 Precautions for safe handling Avoid contact with skin and eyes.
Use only in well-ventilated areas. Do not breathe vapours/dust
7.2 Conditions for safe storage, including Keep locked up or in an area accessible only to qualified staff
any incompatibilities
Storage Store in tightly closed original container in a dry, cool and well ventilated place.
Revision: Citric acid monohydrate Version 1 Page: 2/5

Keep in original container.
Incompatible materials Strong oxidising substances, strong alkalis.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION

8.1 Control parameters
8.1.1 Occupational Exposure Limits No values assigned
8.1.2 Biological limit value No values assigned
8.2 PNECs and DNELs

DNELs - Health No true DNEL for systemic toxicity can be derived. Local effects, eye irritation should
be considered.
PNEC/PEC – Environment
Compartment PNEC
Aquatic PNECaqua – freshwater (mg/l) 0.44
PNECaqua – marine water (mg/l) 0.044
PNECfreshwater-sediment (mg/kg d.w.) 3.46. (Equivalent to 0.752 mg/kg wwt)
The PNECmarine-sediment mg/kg d.w. 34.6. (Equivalent to 7.52 mg/kg wwt)
Terrestrial (PNECsoil mg/kg d.w.) 33.1
Sewage treatment plant PNEC STP (mg/l) >1000
Atmospheric Compartment Not applicable
8.3 Exposure controls Minimise the risk of dust inhalation.

83.1 Appropriate engineering controls Provide adequate ventilation.
8.3.2 Personal protection equipment
Eye/face protection Safety glasses with side-shields
Skin protection (Hand protection/ Avoid contact with skin, eyes and clothing. Wash hands before breaks and at the
Other) end of workday. Protective gloves must satisfy t he specifications of EU Directive
89/686/EEC and EN 374
Respiratory protection Provide adequate ventilation. Wear respirator where dust level exceeds 10 mg/m3.
Thermal hazards Not applicable

8.3.3 Environmental Exposure Controls Do not allow to enter drains, sewers or watercourses
8.3.4 Hygiene measures Do not smoke in the work area. Wash at the end of each work shift and before
eating, smoking and using the toilet. Wash promptly if skin becomes contaminated.
Promptly remove any clothing that becomes c ontaminated. When using do not eat,
drink or smoke.
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

9.1 Information on basic physical and chemical properties
Appearance Solid, crystalline
Colour White
Odour Odourless
pH (Value) 1.7 (100g/l)
Melting Point Approx.153 °C at 1,013 hPa
Boiling point/boiling range (°C): Decomposes before boiling
Flash Point (°C) Not known
Revision: Citric acid monohydrate Version 1 Page: 3/ 5

Authority.
SECTION 14: TRANSPORT INFORMATION

14.1 Land transport (ADR/RID) Not subject to transport regulations.
14.2 Sea transport (IMDG) Not subject to transport regulations.
14.3 Air transport (ICAO/IATA) Not subject to transport regulations.
14.4 Transport in bulk according to Annex Not known
II of MARPOL73/78 and the IBC Code
SECTION 15: REGULATORY INFORMATION

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture substance or mixture
15.1.1 EU regulations User to follow EU directives and regulations
Authorisations and/or restrictions on Not applicable
use
15.1.2 National regulations User to follow national regulations
SECTION 16: OTHER INFORMATION
The following sections contain revisions or new statements: Version 1.

LEGEND
LTEL Long Term Exposure Limit
STEL Short Term Exposure Limit
STOT Specific Target Organ Toxicity
DNEL Derived No Effect Level
PNEC Predicted No Effect Concentration
References:
Chemical Safety Report for citric acid and citrates
Regulation (EC) No. 1272/2008 & 453/2010 (CLP)
Directive 67/548/EEC & Directive 1999/45/EC
Risk Phrases and Safety Phrases
R36: Irritating to eyes
S26: Avoid contact with eyes. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
Hazard statement(s) and Precautionary statement(s)
H319: Causes serious eye irritation
P264: Wash hands thoroughly after handling.
P280: Wear eye protection.
P305 + P351 + P338. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
P337+P313: If eye irritation persists: Get medical advice/attention.
Training advice: Ensure staff and workers receive adequate training with regular updates in the handling of chemicals
Additional Information. Not known
Information contained in this publication or as otherwise supplied to users is believed to be accurate and is given in good faith, but it is for
the users to satisfy themselves of the suitability of the product for their own particular purpose. Weifang Ensign Industry Co., Ltd. gives no
warranty as to the fi tness of the product for any particular purpose and any implied warranty or condition (statutory or othe rwise) is
excluded except to the extent that exclusion is prevented by law. Weifang Ensign Industry Co., Ltd accepts no liability for loss or damage
(other than that arising from death or personal injury caused by defective product, if proved), resulting from reliance on this information.
Freedom under Patents, Copyright and Designs cannot be assumed.
Revision: Citric acid monohydrate Version 1 Page: 5/5

Phosphoric Acid, 85% w/w
Safety Data Sheet
Date of issue: 07/11/2014 Revision date: 12/21/2016 Supersedes: 07/02/2015 Version: 1.3
1.1. Identification
Substance name : Phosphoric Acid, 85% w/w
Chemical name : ortho-Phosphoric Acid
CAS No : 7664-38-2
Product code : LC18640
Formula : H3PO4
Synonyms : orthophosphoric acid, conc=85% / Phosphoric acid, solid / phosphoric syrup, conc=85%
1.2. Relevant identified uses of the substance or mixture and uses advised against
Use of the substance/mixture : Food industry: additive
Petrochemistry:
Catalyst: auxiliary substance
Pharmaceutical product: component
Recommended use : Laboratory chemicals
Restrictions on use : Not for food, drug or household use
1.3. Details of the supplier of the safety data sheet
LabChem Inc
Jackson's Pointe Commerce Park Building 1000, 1010 Jackson's Pointe Court
Zelienople, PA 16063 - USA
T 412-826-5230 - F 724-473-0647
[email protected] - www.labchem.com

Emergency number : CHEMTREC: 1-800-424-9300 or 011-703-527-3887

GHS-US classification
Skin corrosion/irritation Category 1B H314
Serious eye damage/eye irritation Category 1 H318
Full text of H statements : see section 16
2.2. Label elements

GHS-US labeling
Hazard pictograms (GHS-US) :
GHS05
Signal word (GHS-US) : Danger
Hazard statements (GHS-US) : H314 - Causes severe skin burns and eye damage
Precautionary statements (GHS-US) : P260 - Do not breathe mist, vapors, spray
P264 - Wash exposed skin thoroughly after handling
P280 - Wear protective gloves, protective clothing, eye protection, face protection
P301+P330+P331 - IF SWALLOWED: rinse mouth. Do NOT induce vomiting
P303+P361+P353 - IF ON SKIN (or hair): Remove/Take off immediately all contaminated
clothing. Rinse skin with water/shower
P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing
P310 - Immediately call a poison center or doctor/physician
P363 - Wash contaminated clothing before reuse
P405 - Store locked up
P501 - Dispose of contents/container to comply with local, state and federal regulations
If inhaled: Remove person to fresh air and keep comfortable for breathing

Safety Data Sheet
2.3. Other hazards

Other hazards not contributing to the : None.
classification
Not applicable

3.1. Substance
Substance type : Multi-constituent
Name Product identifier % GHS-US classification
Phosphoric Acid, 85% w/w (CAS No) 7664-38-2 100 Skin Corr. 1B, H314
(Main constituent) Eye Dam. 1, H318

3.2. Mixture
Not applicable
SECTION 4: First aid measures
First-aid measures general : Check the vital functions. Unconscious: maintain adequate airway and respiration. Respiratory
arrest: artificial respiration or oxygen. Cardiac arrest: perform resuscitation. Victim conscious
with labored breathing: half-seated. Victim in shock: on his back with legs slightly raised.
Vomiting: prevent asphyxia/aspiration pneumonia. Prevent cooling by covering the victim (no
warming up). Keep watching the victim. Give psychological aid. Keep the victim calm, avoid
physical strain. Depending on the victim's condition: doctor/hospital.
First-aid measures after inhalation : Remove the victim into fresh air. Respiratory problems: consult a doctor/medical service.
First-aid measures after skin contact : Wash immediately with lots of water (15 minutes)/shower. Do not apply (chemical) neutralizing
agents. Remove clothing while washing. Do not remove clothing if it sticks to the skin. Cover
wounds with sterile bandage. Consult a doctor/medical service. If burned surface > 10%: take
victim to hospital.
First-aid measures after eye contact : Rinse immediately with plenty of water for 15 minutes. Do not apply neutralizing agents. Take
victim to an ophthalmologist.
First-aid measures after ingestion : Rinse mouth with water. Immediately after ingestion: give lots of water to drink. Do not induce
vomiting. Do not give activated charcoal. Call Poison Information Centre
(www.big.be/antigif.htm). Take the container/vomit to the doctor/hospital. Immediately consult a
doctor/medical service. Ingestion of large quantities: immediately to hospital. Do not give
chemical antidote. Doctor: gastric lavage is not recommended.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms/injuries after inhalation : Coughing. Dry/sore throat. Irritation of the respiratory tract. Irritation of the nasal mucous
membranes. FOLLOWING SYMPTOMS MAY APPEAR LATER: Respiratory difficulties. Risk of
lung edema.
Symptoms/injuries after skin contact : Caustic burns/corrosion of the skin.
Symptoms/injuries after eye contact : Corrosion of the eye tissue.
Symptoms/injuries after ingestion : Burns to the gastric/intestinal mucosa. Nausea. Abdominal pain. Blood in vomit. AFTER
ABSORPTION OF LARGE QUANTITIES: Shock.
Chronic symptoms : ON CONTINUOUS/REPEATED EXPOSURE/CONTACT: Dry skin. Red skin.
4.3. Indication of any immediate medical attention and special treatment needed
SECTION 5: Firefighting measures

5.1. Extinguishing media
Suitable extinguishing media : Adapt extinguishing media to the environment.
Unsuitable extinguishing media : No unsuitable extinguishing media known.
5.2. Special hazards arising from the substance or mixture
Fire hazard : DIRECT FIRE HAZARD. Non combustible. INDIRECT FIRE HAZARD. Reactions involving a
fire hazard: see "Reactivity Hazard".
Explosion hazard : INDIRECT EXPLOSION HAZARD. Reactions with explosion hazards: see "Reactivity Hazard".
12/21/2016 EN (English US) 2/8

Safety Data Sheet
Reactivity : Reacts exothermically with water (moisture). Decomposes on exposure to temperature rise:
release of toxic and corrosive gases/vapours (phosphorus oxides). Reacts on exposure to
temperature rise with (some) metals: release of highly flammable gases/vapours (hydrogen).
Violent exothermic reaction with (some) bases. Violent to explosive reaction with many
compounds e.g.: with (strong) oxidizers and with (strong) reducers.
5.3. Advice for firefighters
Precautionary measures fire : Exposure to fire/heat: keep upwind. Exposure to fire/heat: consider evacuation. Exposure to
fire/heat: seal off low-lying areas. Exposure to fire/heat: have neighbourhood close doors and
windows.
Firefighting instructions : Cool tanks/drums with water spray/remove them into safety. Dilute toxic gases with water
spray. Take account of toxic fire-fighting water. Use water moderately and if possible collect or
contain it.
Protection during firefighting : Heat/fire exposure: compressed air/oxygen apparatus.

Protective equipment : Gloves. Face-shield. Corrosion-proof suit. Dust cloud production: compressed air/oxygen
apparatus. See "Material-Handling" to select protective clothing.
Emergency procedures : Mark the danger area. Prevent dust cloud formation. No naked flames. Wash contaminated
clothes. Large spills/in confined spaces: consider evacuation. In case of hazardous reactions:
keep upwind. In case of reactivity hazard: consider evacuation.
Measures in case of dust release : In case of dust production: keep upwind. In case of dust production: consider evacuation. Dust
production: have neighbourhood close doors and windows.

Protective equipment : Equip cleanup crew with proper protection.
Emergency procedures : Ventilate area.
Prevent soil and water pollution. Prevent spreading in sewers.
For containment : Contain released substance, pump into suitable containers. Consult "Material-handling" to
select material of containers. Plug the leak, cut off the supply. Dam up the solid spill.
Hazardous reaction: measure explosive gas-air mixture. Reaction: dilute combustible
gas/vapour with water curtain. Take account of toxic/corrosive precipitation water. Heat
exposure: dilute toxic gas/vapour with water spray.
Methods for cleaning up : Prevent dust cloud formation. Scoop solid spill into closing containers. See "Material-handling"
for suitable container materials. Carefully collect the spill/leftovers. Take collected spill to
manufacturer/competent authority. Wash clothing and equipment after handling.
See Heading 8. Exposure controls and personal protection.

Precautions for safe handling : Comply with the legal requirements. Remove contaminated clothing immediately. Clean
contaminated clothing. Keep the substance free from contamination. Thoroughly clean/dry the
installation before use. Do not discharge the waste into the drain. Keep away from naked
flames/heat. Observe strict hygiene. Keep container tightly closed. Measure the concentration
in the air regularly. Carry operations in the open/under local exhaust/ventilation or with
respiratory protection.
Hygiene measures : Wash exposed skin thoroughly after handling. Wash contaminated clothing before reuse.
Technical measures : Comply with applicable regulations.
Storage conditions : Keep only in the original container in a cool, well ventilated place away from : incompatible
materials. Keep container closed when not in use.
Incompatible products : Strong bases. Strong acids. metals.
Incompatible materials : Sources of ignition. Direct sunlight.
Storage temperature : > 20 °C
Heat-ignition : KEEP SUBSTANCE AWAY FROM: heat sources.
12/21/2016 EN (English US) 3/8

Safety Data Sheet
Prohibitions on mixed storage : KEEP SUBSTANCE AWAY FROM: reducing agents. (strong) bases. metals. many substances.
Storage area : Ventilation at floor level. Keep locked up. Unauthorized persons are not admitted. Meet the
legal requirements.
Special rules on packaging : SPECIAL REQUIREMENTS: closing. corrosion-proof. dry. clean. correctly labelled. meet the
legal requirements. Secure fragile packagings in solid containers.
Packaging materials : SUITABLE MATERIAL: stainless steel. polyethylene. glass. MATERIAL TO AVOID: steel.
aluminium. iron.

Phosphoric Acid, 85% w/w (7664-38-2)
OSHA OSHA PEL (TWA) (mg/m³) 1 mg/m³
IDLH US IDLH (mg/m³) 1000 mg/m³
NIOSH NIOSH REL (TWA) (mg/m³) 1 mg/m³
NIOSH NIOSH REL (STEL) (mg/m³) 3 mg/m³
8.2. Exposure controls

Appropriate engineering controls : Emergency eye wash fountains and safety showers should be available in the immediate
vicinity of any potential exposure. Provide local exhaust or general room ventilation.
Personal protective equipment : Safety glasses. Gloves. Protective clothing. Face shield.
Materials for protective clothing : GIVE EXCELLENT RESISTANCE: butyl rubber. natural rubber. neoprene. nitrile rubber.
polyethylene. viton. PVC. GIVE POOR RESISTANCE: PVA.
Hand protection : Gloves.
Eye protection : Face shield. In case of dust production: protective goggles.
Skin and body protection : Corrosion-proof clothing. In case of dust production: head/neck protection.
Respiratory protection : Dust production: dust mask with filter type P3.
Other information : Do not eat, drink or smoke during use.

Physical state : Liquid
Appearance : Clear, colorless liquid.
Color : Colourless
Odor : Odorless
pH : No data available
Melting point : 21 °C
Flash point : Not applicable
Flammability (solid, gas) : Non flammable.
Vapor pressure : 2.2 hPa (20 °C)
Relative vapor density at 20 °C : No data available
Relative density : 1.7
Specific gravity / density : 1685 kg/m³
Molecular mass : 98 g/mol
Solubility : Soluble in ethanol.
Water: Complete
12/21/2016 EN (English US) 4/8
Safety Data Sheet

Auto-ignition temperature : Not applicable
Explosive properties : Not applicable.
Oxidizing properties : None.
Minimum ignition energy : Not applicable
VOC content : Not applicable
Other properties : Substance has acid reaction.

10.1. Reactivity
Reacts exothermically with water (moisture). Decomposes on exposure to temperature rise: release of toxic and corrosive gases/vapours (phosphorus
oxides). Reacts on exposure to temperature rise with (some) metals: release of highly flammable gases/vapours (hydrogen). Violent exothermic reaction
with (some) bases. Violent to explosive reaction with many compounds e.g.: with (strong) oxidizers and with (strong) reducers.
Stable under normal conditions.
Not established.
Direct sunlight. Extremely high or low temperatures.
Strong acids. Strong bases.
Phosphorus oxides. Carbon monoxide. Carbon dioxide. Thermal decomposition generates : Corrosive vapors.

Likely routes of exposure : Skin and eye contact

Acute toxicity : Not classified
Skin corrosion/irritation : Causes severe skin burns and eye damage.

Serious eye damage/irritation : Causes serious eye damage.
Specific target organ toxicity (single exposure) : Not classified
Specific target organ toxicity (repeated : Not classified
exposure)
Potential Adverse human health effects and : Based on available data, the classification criteria are not met.
symptoms
Symptoms/injuries after inhalation : Coughing. Dry/sore throat. Irritation of the respiratory tract. Irritation of the nasal mucous
membranes. FOLLOWING SYMPTOMS MAY APPEAR LATER: Respiratory difficulties. Risk of
lung edema.
Symptoms/injuries after skin contact : Caustic burns/corrosion of the skin.
12/21/2016 EN (English US) 5/8

Safety Data Sheet
Symptoms/injuries after eye contact : Corrosion of the eye tissue.

Symptoms/injuries after ingestion : Burns to the gastric/intestinal mucosa. Nausea. Abdominal pain. Blood in vomit. AFTER
ABSORPTION OF LARGE QUANTITIES: Shock.
Chronic symptoms : ON CONTINUOUS/REPEATED EXPOSURE/CONTACT: Dry skin. Red skin.

12.1. Toxicity
Ecology - air : Not classified as dangerous for the ozone layer (Regulation (EC) No 1005/2009). Air pollutant.
Ecology - water : Mild water pollutant (surface water). May cause eutrophication. Toxic to plankton. Slightly
harmful to bacteria. Slightly harmful to aquatic organisms. pH shift.
LC50 fish 1 138 mg/l (LC50)

Persistence and degradability Biodegradability: not applicable. No test data on mobility of the components available.
Biochemical oxygen demand (BOD) Not applicable
Chemical oxygen demand (COD) Not applicable
ThOD Not applicable

Bioaccumulative potential Not bioaccumulative.

Other information : Avoid release to the environment.

13.1. Waste treatment methods
Waste disposal recommendations : Remove waste in accordance with local and/or national regulations. Hazardous waste shall not
be mixed together with other waste. Different types of hazardous waste shall not be mixed
together if this may entail a risk of pollution or create problems for the further management of
the waste. Hazardous waste shall be managed responsibly. All entities that store, transport or
handle hazardous waste shall take the necessary measures to prevent risks of pollution or
damage to people or animals. Recycle/reuse. Remove for physico-chemical/biological
treatment.
Additional information : LWCA (the Netherlands): KGA category 01. Hazardous waste according to Directive
2008/98/EC.
Ecology - waste materials : Avoid release to the environment.

Transport document description : UN1805 Phosphoric acid solution, 8, III
UN-No.(DOT) : UN1805
Proper Shipping Name (DOT) : Phosphoric acid solution
Transport hazard class(es) (DOT) : 8 - Class 8 - Corrosive material 49 CFR 173.136
Packing group (DOT) : III - Minor Danger
12/21/2016 EN (English US) 6/8

Safety Data Sheet
Hazard labels (DOT) : 8 - Corrosive
DOT Packaging Non Bulk (49 CFR 173.xxx) : 203

DOT Packaging Bulk (49 CFR 173.xxx) : 241
DOT Special Provisions (49 CFR 172.102) : A7 - Steel packaging must be corrosion-resistant or have protection against corrosion.
IB3 - Authorized IBCs: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite
(31HZ1 and 31HA2, 31HB2, 31HN2, 31HD2 and 31HH2). Additional Requirement: Only liquids
with a vapor pressure less than or equal to 110 kPa at 50 C (1.1 bar at 122 F), or 130 kPa at 55
C (1.3 bar at 131 F) are authorized, except for UN2672 (also see Special Provision IP8 in Table
2 for UN2672).
N34 - Aluminum construction materials are not authorized for any part of a packaging which is
normally in contact with the hazardous material.
T4 - 2.65 178.274(d)(2) Normal............. 178.275(d)(3)
TP1 - The maximum degree of filling must not exceed the degree of filling determined by the
following: Degree of filling = 97 / 1 + a (tr - tf) Where: tr is the maximum mean bulk temperature
during transport, and tf is the temperature in degrees celsius of the liquid during filling.
DOT Packaging Exceptions (49 CFR 173.xxx) : 154
DOT Quantity Limitations Passenger aircraft/rail : 5 L
(49 CFR 173.27)
DOT Quantity Limitations Cargo aircraft only (49 : 60 L
CFR 175.75)
DOT Vessel Stowage Location : A - The material may be stowed ‘‘on deck’’ or ‘‘under deck’’ on a cargo vessel and on a
passenger vessel.
Other information : No supplementary information available.

Listed on the United States TSCA (Toxic Substances Control Act) inventory
Not subject to reporing requirements of the United States SARA Section 313
RQ (Reportable quantity, section 304 of EPA's List of Lists) 5000 lb
All components of this product are listed, or excluded from listing, on the United States Environmental Protection Agency Toxic
Substances Control Act (TSCA) inventory
This product or mixture does not contain a toxic chemical or chemicals in excess of the applicable de minimis concentration as specified in 40
CFR §372.38(a) subject to the reporting requirements of section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986
and 40 CFR Part 372.

CANADA
WHMIS Classification Class E - Corrosive Material
EU-Regulations

California Proposition 65 - This product does not contain any substances known to the state of California to cause cancer,
developmental and/or reproductive harm
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Safety Data Sheet

Other information : None.
Full text of H-phrases: see section 16:
------ H314 Causes severe skin burns and eye damage
------ H318 Causes serious eye damage
NFPA health hazard : 3 - Short exposure could cause serious temporary or
residual injury even though prompt medical attention was
given.
NFPA fire hazard : 0 - Materials that will not burn.
NFPA reactivity : 0 - Normally stable, even under fire exposure conditions,
and are not reactive with water.
HMIS III Rating

Health : 3 Serious Hazard - Major injury likely unless prompt action is taken and medical treatment is
given
Flammability : 0 Minimal Hazard - Materials that will not burn
Physical : 0 Minimal Hazard - Materials that are normally stable, even under fire conditions, and will NOT
react with water, polymerize, decompose, condense, or self-react. Non-Explosives.
Personal protection : H
H - Splash goggles, Gloves, Synthetic apron, Vapor respirator
SDS US LabChem
Information in this SDS is from available published sources and is believed to be accurate. No warranty, express or implied, is made and LabChem Inc assumes no liability resulting from the use of this
SDS. The user must determine suitability of this information for his application.
12/21/2016 EN (English US) 8/8

Section 01 - Product And Company Identification
Product Identifier ST-UC101
Other Means of Identification None
Product Use and Restrictions on Acid corrosion inhibitor.

Use
Initial Supplier Identifier TLC VIET NAM, Import

Export Service Trading CO, LDT
- –
Section 02 - Hazard Identification
-
GHS-Classification
Acute Toxicity-Oral Category 3
Acute Toxicity-Dermal Category 3
Skin Corrosion/Irritation Category 1B
Serious Eye Damage/Irritation Category 1
STOT-Single Exposure Category 1
STOT-Repeated Exposure Category 2
Physical Hazards
Flammable Liquid Category 2
Danger
Hazards Statements
H301 – Toxic if swallowed.
H310 – Fatal in contact with skin.
H331 – Toxic if inhaled.
H314 – Causes severe skin burns and eye damage.
H370 – Causes damage to central nervous system through inhalation and ingestion.
H373 – May cause damage to liver and kidneys through prolonged or repeated inhalation and ingestion.
H225 – Highly flammable liquid and vapour.
Pictograms
Page 1 of 7
Precautionary Statements
P405 – Store locked up.
P403 + P235 – Store in a well-ventilated place. Keep cool.
P210 – Keep away from heat, sparks, open flames, and hot surfaces. — No smoking.
P223 – Keep away from any possible contact with water, because of violent reaction and possible flash fire.
P240 – Ground/bond container and receiving equipment.
P241 – Use explosion-proof electrical, ventilating, lighting, and equipment.
P242 – Use only non-sparking tools.
P243 – Take precautionary measures against static discharge.
P370 + P378 – In case of fire: Use foam, dry chemical or carbon dioxide for extinction.
P308 + P311 – IF exposed or concerned: Call a POISON CENTER or doctor/physician.
P260 – Do not breathe mist, vapours or spray.
P304 + P340 – IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P270 – Do not eat, drink or smoke when using this product.
P301 +P330 + P331 – IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P280 – Wear protective gloves, protective clothing, eye protection, and face protection.
P303 + P361 + P353 – IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin.
P363 – Wash contaminated clothing before reuse.
P310 – Immediately call a POISON CENTER or doctor/physician.
P305 + P351 + P338 – IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing.
P501 – Dispose of contents/container in accordance with all federal, provincial, and/or local regulations including the Canadian
Environmental Protection Act.
Section 03 - Composition / Information on Ingredients

Chemical Name CAS Number Weight % Unique Identifiers
Polyethylene glycol MW 600 25322-68-3 25-62%
Ethylene glycol 107-21-1 7-12%
1,3-Diethyl-2-thiourea 105-55-5 3-8%
1-(benzyl)quinolinium chloride 15619-48-4 6-9%
Quinolinium chloride 530-64-3 1-4%
Section 04 - First Aid Measures

Inhalation Remove victim to fresh air. Give artificial respiration only if breathing has stopped. If
breathing is difficult, give oxygen. Seek medical attention.
Skin Contact / Absorption Remove contaminated clothing. Rinse skin with lukewarm, gently flowing water for at
least 30 minutes. If irritation persists, repeat flushing. Seek medical attention if irritation
persists. Wash contaminated clothing before reuse or discard.
Eye Contact Immediately rinse eye(s) with lukewarm, gently flowing water for at least 30 minutes.
Forcibly hold the eyelids apart to ensure complete irrigation of eye tissue. Seek
immediate medical attention.
Ingestion Do not induce vomiting unless instructed to do so by medical personnel. Never give
anything by mouth to a victim that is convulsing or unconsicous. Seek immediate medical
attention.
Additional Information Not Available
Section 05 - Fire Fighting Measures

Suitable Extinguishing Media Foam, dry chemical or carbon dioxide.
Unsuitable Extinguishing Media Not Available
Page 2 of 7
Specific Hazards Arising From the Carbon oxides, nitrogen oxides, Sulphur oxides.
Chemical
Special Protective Equipment and Wear NIOSH-approved self-contained breathing apparatus and protective clothing. Fight
Precautions for Fire-Fighters fire from safe distance. Water spray may be used to keep exposed containers cool.
Vapours may form an ignitable mixture in the air. Vapours may travel a considerable
distance and flashback if ignited.
Further Information Static discharges can cause ignition or explosion when container is not bonded.
Section 06 - Accidental Release Measures
Personal Precautions / Protective Wear appropriate personal protective equipment. Ventilate area. Only enter area with
Equipment / Emergency PPE. Stop or reduce leak if safe to do so. Flush with water to remove any residue.
Procedures Approach release from upwind.
Environmental Precautions Prevent material from entering sewers.
Methods and Materials for Contain spilled material out of waterways. Dike large spills and use a nonsparking or
Containment and Cleaning Up explosion-proof means to transfer material to an appropriate container for disposal. For
small spills, add absorbent (soil may be used in the absence of other suitable materials).
Scoop up material and place insealed, liquid-proof container. Note that flammable
vapours may form an ignitable mixture with air. Vapours may travel considerable
distances from spill and flash back if ignited. Waste must be disposed of in accordance
with federal, provincial/state, and local environmental control regulations.
Section 07 - Handling and Storage
Precautions for Safe Handling Use proper equipment for lifting and transporting all containers. Use sensible industrial
hygiene and housekeeping practices. Wash thoroughly after handling. Avoid all situations
that could lead to harmful exposure.
Conditions for Safe Storage Store in well-ventilated area in tightly closed containers in a cool area separate from work
areas. No sources of heat, flam or sparks should be present in storage area. Use properly
grounded electrical equipment when working with this product.
Incompatibilities Oxidizers and acids.
Section 08 - Exposure Controls and Personal Protection
Engineering Control(s)
Ventilation Requirements Mechanical ventilation (dilution or local exhaust), process or personnel enclosure and
control of process conditions must be provided in accordance with all fire codes and
regulatory requirements. Supply sufficient replacement air to make up for air removed by
exhaust systems.
Other Emergency shower and eyewash must be available and tested in accordance with
regulations and be in close proximity.
Protective Equipment
Eyes/Face Chemical goggles, full-face shield, or a full-face respirator should be worn when product
is being handled. Contact lenses should not be worn as they may contribute to severe eye
injury.
Hand Protection Impervious gloves of chemically resistant material (neoprene or Viton) should be worn at
all times. Wash contaminated clothing and dry thoroughly before reuse.
Page 3 of 7
Skin and Body Protection Body suits, aprons, and/or coveralls of chemical resistant material should be worn at all
times. Wash contaminated clothing and dry thoroughly before reuse.
Respiratory Protection A NIOSH approved full-face respiratory should be worn if exposure limits will be
exceeded and/or in poorly ventilated work areas.
Thermal Hazards Not Available
Section 09 - Physical and Chemical Properties

Appearance
Physical State Liquid
Colour Clear, amber
Odour Aromatic
Odour Threshold Not Available
Property
pH 3.5-4.7(10% solution)
Melting Point/Freezing Point Not Available
Initial Boiling Point and Boiling Not Available

Range
Flash Point 9-16.2°C
Evaporation Rate 16 mbar(20°C (68°F))
Flammability Very flammable liquid
Upper Flammable Limit Not Available
Lower Flammable Limit Not Available
o
Vapour Pressure (mm Hg, 20 C) 82.7 @ 21°C
Vapour Density (Air=1) Not Available
Relative Density Not Available
Solubility(ies) Not Available
Partition Coefficient: n- Not Available

octanol/water
Auto-ignition Temperature Not Available
Page 4 of 7
Decomposition Temperature Not Available
Viscosity Not Available
Explosive Properties Static discharges can cause ignition or explosion when container is not bonded.
Specific Gravity (Water=1) 0.885-0.897 @ 16°C
% Volatiles by Volume Not Available
Formula Not Available
Molecular Weight Not Available
Section 10 - Stability and Reactivity
Reactivity Not Available
Stability Stable under normal conditions.
Possibility of Hazardous Polymerization will not occur.

Reactions
Conditions to Avoid Not Available
Incompatible Materials Oxidizers and acids.
Hazardous Decomposition Carbon oxides, nitrogen oxides and Sulphur oxides.
Products
Section 11 - Toxicological Information

Acute Toxicity Estimate
Component Oral LD50 Dermal LD50 Inhalation LC50

ST-UC101 265 mg/kg 219mg/kg 6842 ppm
This product has been classified in accordance with the Hazardous Products Regulations using ATE formula documented in the
GHS standard.
Chronic Toxicity – Carcinogenicity

Component IARC
ST-UC101 None of the components present in this material at
concentrations equal to or greater than 0.1% are listed by
IARC, NTP, or OSHA, as a carcinogen.
Skin Corrosion/Irritation Repeated or prolonged contact causes irritation including burns, dermatitis and dryness.
May be toxic if absorbed through skin.
Ingestion May be harmful if ingested. May be accompanied by chemical irritation, pulmonary
edema and hemorrhaging.
Inhalation May be severely irritating to lungs. May cause effects on the central nervous system if
inhaled.
Serious Eye Damage/Irritation Vapour can irritate the eyes. Liquid can cause severe irritation and burns.
Respiratory or Skin Sensitization Not Available
Germ Cell Mutagenicity Laboratory testing indicates that methanol may have mutagenic properties. Chromosome
aberrations may occur from methanol exposure.
Page 5 of 7
Reproductive Toxicity Laboratory testing indicates the methanol exposure may result in birth defects.
STOT-Single Exposure May cause central nervous system effects such as nausea, vomiting, apathy, lack of
coordination, stupor and in severe cases death when inhaled or ingested.
STOT-Repeated Exposure Long term exposure may cause inflammation and defatting of the skin. Liver and kidney
damage may also occur with long term exposure. Product may have cumulative toxicity
with repeated exposure being methanol is more slowly eliminated from the body than
ethanol.
Aspiration Hazard Not Available
Synergistic Materials Not Available
Section 12 – Ecological Information

Ecotoxicity
Component Toxicity to Algae Toxicity to Fish Toxicity to Daphnia and
Other Aquatic Invertebrates
Methanol EC50(Green algae, 24hr): LC50(Lepomis macrochirus, LC50(Ceriodaphnia dubia,
3.01mg/L 96hr): 15400mg/L 48hr): 11mg/L
Propargyl Alcohol Not Available LC50(Pimephales promelas, LC50(Daphnia magna, 24hr):
96hr): 1.44mg/L 11mg/L
Biodegradability Not Available

Bioaccumulation Not Available
Mobility Not Available
Other Adverse Effects Not Available
Section 13 – Disposal Considerations
Waste From Residues/Unused Dispose in accordance with all federal, provincial, and/or local regulations including the
Products Canadian Environmental Protection Act.
Contaminated Packaging Dispose in accordance with all federal, provincial, and/or local regulations including the
Canadian Environmental Protection Act.
Section 14 – Transport Information
UN Number UN1993
UN Proper Shipping Name FLAMMABLE LIQUID, N.O.S. (Methanol)
Transport Hazard Class(es) 3
Packaging Group II
Environmental Hazards Not listed as a marine pollutant under Canadian TDG Regulations, schedule III.
Special Precautions Not Available
Transport in Bulk Not Available
Additional Information Packing Group Limited Quantity Index
I 0
II 1L
III 5L
TDG
Other Secure containers (full and/or empty) with suitable hold down devises during shipment and
ensure all caps, valves, or closures are secured in the closed position.
TDG PRODUCT CLASSIFICATION: This product has been classified on the preparation date specified at section 14 of this
MSDS / SDS, for transportation in accordance with the requirements of part 2 of the Transportation of Dangerous Goods
Regulations. If applicable, testing and/or published test data regarding the classification of this product are listed in the
references at section 16 of this MSDS / SDS.
Page 6 of 7
Section 15 – Regulatory Information
NOTE: THE PRODUCT LISTED ON THIS SDS HAS BEEN CLASSIFIED IN ACCORDANCE WITH THE HAZARD CRITERIA OF
THE CANADIAN CONTROLLED PRODUCTS REGULATIONS. THIS SDS CONTAINS ALL INFORMATION REQUIRED BY
THOSE REGULATIONS.
Section 16 – Other Information
Preparation Date October 16, 2015
Note: The responsibility to provide a safe workplace remains with the user. The user should consider the health hazards and
safety information contained herein as a guide and should take those precautions required in an individual operation to instruct
employees and develop work practice procedures for a safe work environment. The information contained herein is, to the best of
our knowledge and belief, accurate. However, since the conditions of handling and use are beyond our control, we make no
guarantee of results, and assume no liability for damages incurred by the use of this material. It is the responsibility of the user to
comply with all applicable laws and regulations.
Attention: Receiver of the chemical goods / SDS coordinator
As part of our commitment to the Canadian Association of Chemical Distributors (CACD) Responsible Distribution ® initiative,
ClearTech Industries Inc. and its associated companies require, as a condition of sale, that you forward the attached Safety Data
Sheet(s) to all affected employees, customers, and end-users. ClearTech will send any available supplementary handling, health,
and safety information to you at your request.
If you have any questions or concerns please call our customer service center.
References:
1) CHEMINFO
2) eChemPortal
3) TOXNET
4) Transportation of Dangerous Goods Canada
5) HSDB
6) ECHA
7) PAN
Page 7 of 7
Safety Data Sheet
CAUSTIC SODA SOLID
Version 1.5 Revision Date: 04/30/2021
SECTION 1. PRODUCT AND COMPANY IDENTIFICATION
Product name : CAUSTIC SODA SOLID

Recommended use of the chemical and restrictions on use
Recommended use : Reserved for industrial and professional use.
Manufacturer or supplier's details

Company : Univar Solutions USA, Inc.
Address 3075 Highland Pkwy Suite 200
Downers Grove, IL 60515
United States of America (USA)
Emergency telephone number:
Transport North America: CHEMTREC (1-800-424-9300)
CHEMTREC INTERNATIONAL Tel # 703-527-3887
Additional Information: : Responsible Party: Product Compliance Department

E-mail: [email protected]
SDS Requests: 1-855-429-2661
Website: www.univarsolutions.com
SECTION 2. HAZARDS IDENTIFICATION
GHS Classification
Corrosive to metals : Category 1
Skin corrosion : Category 1A
Serious eye damage : Category 1
GHS label elements

Hazard pictograms :
Signal word : Danger
Hazard statements : H290 May be corrosive to metals.

H314 Causes severe skin burns and eye damage.
Precautionary statements : Prevention:

P234 Keep only in original container.
P260 Do not breathe dust or mist.
P264 Wash skin thoroughly after handling.
P280 Wear protective gloves/ protective clothing/ eye protection/
face protection.
Response:
P301 + P330 + P331 IF SWALLOWED: Rinse mouth. Do NOT
induce vomiting.
P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately
SDS Number: 100000041439 1 / 11 CAUSTIC SODA SOLID

Safety Data Sheet
CAUSTIC SODA SOLID
all contaminated clothing. Rinse skin with water/shower.

P304 + P340 + P310 IF INHALED: Remove person to fresh air
and keep comfortable for breathing. Immediately call a POISON
CENTER/doctor.
P305 + P351 + P338 + P310 IF IN EYES: Rinse cautiously with
water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing. Immediately call a POISON
CENTER/doctor.
P363 Wash contaminated clothing before reuse.
P390 Absorb spillage to prevent material damage.
Storage:
P405 Store locked up.
P406 Store in corrosive resistant container with a resistant inner
liner.
Disposal:
P501 Dispose of contents/ container to an approved waste dis-
posal plant.
Other hazards
None known.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance / Mixture : Mixture
Hazardous components
CAS-No. Chemical name Weight percent
1310-73-2 Sodium hydroxide 90 - 100
497-19-8 Sodium carbonate 0 -5
Actual concentration is withheld as a trade secret
Any Concentration shown as a range is due to batch variation.
SECTION 4. FIRST AID MEASURES
General advice : Move out of dangerous area.

Consult a physician.
Show this safety data sheet to the doctor in attendance.
Do not leave the victim unattended.
If inhaled : If unconscious, place in recovery position and seek medical

advice.
If symptoms persist, call a physician.
In case of skin contact : Immediate medical treatment is necessary as untreated

wounds from corrosion of the skin heal slowly and with difficul-
ty.
If on skin, rinse well with water.
If on clothes, remove clothes.
In case of eye contact : Small amounts splashed into eyes can cause irreversible tis-
sue damage and blindness.

Safety Data Sheet
CAUSTIC SODA SOLID
In the case of contact with eyes, rinse immediately with plenty

of water and seek medical advice.
Continue rinsing eyes during transport to hospital.
Remove contact lenses.
Protect unharmed eye.
Keep eye wide open while rinsing.
If eye irritation persists, consult a specialist.
Take victim immediately to hospital.
If swallowed : Keep respiratory tract clear.

Do NOT induce vomiting.
Do not give milk or alcoholic beverages.
Never give anything by mouth to an unconscious person.
If symptoms persist, call a physician.
Take victim immediately to hospital.
SECTION 5. FIREFIGHTING MEASURES
Suitable extinguishing media : Use an extinguishing media appropriate for surrounding fire.
Unsuitable extinguishing : High volume water jet

media
Specific hazards during fire- : Do not allow run-off from fire fighting to enter drains or water
fighting courses.
Hazardous combustion prod- : Carbon oxides

ucts toxic fumes
metal oxides
Further information : Collect contaminated fire extinguishing water separately. This

must not be discharged into drains.
Fire residues and contaminated fire extinguishing water must
be disposed of in accordance with local regulations.
Special protective equipment : Wear self-contained breathing apparatus for firefighting if nec-
for firefighters essary.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protec- : Use personal protective equipment.

tive equipment and emer- Avoid dust formation.
gency procedures Avoid breathing dust.
Environmental precautions : Prevent product from entering drains.

Prevent further leakage or spillage if safe to do so.
If the product contaminates rivers and lakes or drains inform
respective authorities.
Methods and materials for : Neutralise with acid.

containment and cleaning up Keep in suitable, closed containers for disposal.

Safety Data Sheet
CAUSTIC SODA SOLID
SECTION 7. HANDLING AND STORAGE
Advice on protection against : Avoid dust formation. Provide appropriate exhaust ventilation
fire and explosion at places where dust is formed.
Advice on safe handling : Avoid formation of respirable particles.

Do not breathe vapours/dust.
Avoid contact with skin and eyes.
For personal protection see section 8.
Smoking, eating and drinking should be prohibited in the ap-
plication area.
Dispose of rinse water in accordance with local and national
regulations.
Conditions for safe storage : Keep container tightly closed in a dry and well-ventilated
place.
Containers which are opened must be carefully resealed and
kept upright to prevent leakage.
Observe label precautions.
Electrical installations / working materials must comply with
the technological safety standards.
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Components with workplace control parameters

CAS-No. Components Value type Control parame- Basis
(Form of ters / Permissible
exposure) concentration
1310-73-2 Sodium hydroxide C 2 mg/m3 ACGIH
C 2 mg/m3 NIOSH REL
TWA 2 mg/m3 OSHA Z-1
C 2 mg/m3 OSHA P0
Personal protective equipment
Respiratory protection : General and local exhaust ventilation is recommended to
maintain vapor exposures below recommended limits. Where
concentrations are above recommended limits or are un-
known, appropriate respiratory protection should be worn.
Follow OSHA respirator regulations (29 CFR 1910.134) and
use NIOSH/MSHA approved respirators. Protection provided
by air purifying respirators against exposure to any hazardous
chemical is limited. Use a positive pressure air supplied respi-
rator if there is any potential for uncontrolled release, expo-
sure levels are unknown, or any other circumstance where air
purifying respirators may not provide adequate protection.
Hand protection
Remarks : The suitability for a specific workplace should be discussed

with the producers of the protective gloves.

Safety Data Sheet
CAUSTIC SODA SOLID
Eye protection : Eye wash bottle with pure water

Tightly fitting safety goggles
Wear face-shield and protective suit for abnormal processing
problems.
Skin and body protection : Choose body protection according to the amount and concen-
tration of the dangerous substance at the work place.
Hygiene measures : When using do not eat or drink.

When using do not smoke.
Wash hands before breaks and at the end of workday.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance : Beads, pellets
Colour : No data available
Odour : No data available
Odour Threshold : No data available
pH : 14
Freezing Point () : 318 °C (604 °F)
Boiling Point : No data available
Flash point : No data available
Evaporation rate : No data available
Flammability (solid, gas) : No data available
Upper explosion limit : No data available
Lower explosion limit : No data available
Vapour pressure : No data available
Relative vapour density : No data available
Relative density : No data available
Density : 17.74 lb/gal
Water solubility : No data available
Solubility in other solvents : No data available
Partition coefficient: n- : No data available

octanol/water

Safety Data Sheet
CAUSTIC SODA SOLID
Thermal decomposition : No data available
SECTION 10. STABILITY AND REACTIVITY
Reactivity : No dangerous reaction known under conditions of normal use.
Chemical stability : Stable under normal conditions.
Possibility of hazardous reac- : No data available

tions
Conditions to avoid : No data available
Incompatible materials : Acids

Alkali metals
Alkaline earth metals
Ammonia
Bases
bromine trifluoride
Copper
Copper alloys
fluorides
Fluorine
Halogenated compounds
hydrogen peroxide
lithium
Metals
Nickel
organic nitro compounds
Phosphorus compounds
Strong oxidizing agents
Zinc
Aluminium
SECTION 11. TOXICOLOGICAL INFORMATION
Skin corrosion/irritation
Product:
Remarks: Extremely corrosive and destructive to tissue.
Components:
1310-73-2:
Species: Rabbit

Safety Data Sheet
CAUSTIC SODA SOLID
Result: Causes severe burns.
Serious eye damage/eye irritation
Product:
Remarks: May cause irreversible eye damage.
Components:
1310-73-2:
Species: Rabbit
Result: Risk of serious damage to eyes.
497-19-8:
Species: Rabbit
Result: Irritating to eyes.
Carcinogenicity
IARC No component of this product present at levels greater than or
equal to 0.1% is identified as probable, possible or confirmed
human carcinogen by IARC.
OSHA No component of this product present at levels greater than or

equal to 0.1% is on OSHA’s list of regulated carcinogens.
NTP No component of this product present at levels greater than or

equal to 0.1% is identified as a known or anticipated carcinogen
by NTP.
Further information
Product:
Remarks: No data available
SECTION 12. ECOLOGICAL INFORMATION
Ecotoxicity
No data available
Persistence and degradability
No data available
Bioaccumulative potential
No data available
Mobility in soil
No data available

Safety Data Sheet
CAUSTIC SODA SOLID
Other adverse effects
Product:
Ozone-Depletion Potential : Regulation: 40 CFR Protection of Environment; Part 82 Pro-
tection of Stratospheric Ozone - CAA Section 602 Class I
Substances
Remarks: This product neither contains, nor was manufac-
tured with a Class I or Class II ODS as defined by the U.S.
Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B).
Additional ecological infor- : No data available

mation
SECTION 13. DISPOSAL CONSIDERATIONS
Disposal methods
Waste from residues : Dispose of in accordance with all applicable local, state and
federal regulations.
For assistance with your waste management needs - including
disposal, recycling and waste stream reduction, contact Uni-
var Solutions ChemCare: 1-800-637-7922
Contaminated packaging : Empty remaining contents.

Dispose of as unused product.
Do not re-use empty containers.
SECTION 14. TRANSPORT INFORMATION
DOT (Department of Transportation):

UN1823, Sodium hydroxide, solid, 8, II
IATA (International Air Transport Association):

UN1823, Sodium hydroxide, solid, 8, II
IMDG (International Maritime Dangerous Goods):

UN1823, SODIUM HYDROXIDE, SOLID, 8, II
SECTION 15. REGULATORY INFORMATION
EPCRA - Emergency Planning and Community Right-to-Know Act
CERCLA Reportable Quantity

Components CAS-No. Component RQ Calculated product RQ
(lbs) (lbs)
Sodium hydroxide 1310-73-2 1000 1000
SARA 304 Extremely Hazardous Substances Reportable Quantity
This material does not contain any components with a section 304 EHS RQ.

Safety Data Sheet
CAUSTIC SODA SOLID
SARA 311/312 Hazards : Corrosive to metals

Skin corrosion or irritation
Serious eye damage or eye irritation
SARA 302 : This material does not contain any components with a section
302 EHS TPQ.
SARA 313 : This material does not contain any chemical components with
known CAS numbers that exceed the threshold (De Minimis)
reporting levels established by SARA Title III, Section 313.
Clean Air Act
This product does not contain any hazardous air pollutants (HAP), as defined by the U.S. Clean Air Act Sec-
tion 112 (40 CFR 61).
This product does not contain any chemicals listed under the U.S. Clean Air Act Section 112(r) for Accidental
Release Prevention (40 CFR 68.130, Subpart F).
This product does not contain any chemicals listed under the U.S. Clean Air Act Section 111 SOCMI Inter-
mediate or Final VOC's (40 CFR 60.489).
Clean Water Act
The following Hazardous Substances are listed under the U.S. CleanWater Act, Section 311, Table 116.4A:
1310-73-2 Sodium hydroxide
The following Hazardous Chemicals are listed under the U.S. CleanWater Act, Section 311, Table 117.3:
This product does not contain any toxic pollutants listed under the U.S. Clean Water Act Section 307
Massachusetts Right To Know
Pennsylvania Right To Know
497-19-8 Sodium carbonate
7647-14-5 Sodium chloride (NaCl)
California Prop 65 : This product does not contain any chemicals known to State
of California to cause cancer, birth defects, or any other re-
productive harm.
The components of this product are reported in the following inventories:
TSCA : On TSCA Inventory
DSL : All components of this product are on the Canadian DSL
AICS : Not in compliance with the inventory
NZIoC : Not in compliance with the inventory
ENCS : Not in compliance with the inventory
KECI : Not in compliance with the inventory
PICCS : Not in compliance with the inventory

Safety Data Sheet
CAUSTIC SODA SOLID
IECSC : Not in compliance with the inventory
SECTION16. OTHER INFORMATION
NFPA: HMIS III:

Flammability
HEALTH 3/
1
Instability
Health
3 0 FLAMMABILITY 1
PHYSICAL HAZARD 0
0 = not significant, 1 =Slight,

Special hazard. 2 = Moderate, 3 = High
4 =Extreme, * = Chronic
The information accumulated is based on the data of which we are aware and is believed
to be correct as of the date hereof. Since this information may be applied under conditions
beyond our control and with which we may be unfamiliar and since data made become
available subsequently to the date hereof, we do not assume any responsibility for the
results of its use. Recipients are advised to confirm in advance of need that the information
is current, applicable, and suitable to their circumstances. This SDS has been prepared by
Univar Solutions Product Compliance Department (1-855-429-2661)
[email protected].
Revision Date : 04/30/2021
Material number:
16145450, 16142121, 16142419, 16140993, 16147759, 124136, 16156050, 16162350,
16161483, 16147305, 16133148, 16160208, 16142321, 16141289, 16140760
Key or legend to abbreviations and acronyms used in the safety data sheet
ACGIH American Conference of Govern- LD50 Lethal Dose 50%
ment Industrial Hygienists
AICS Australia, Inventory of Chemical LOAEL Lowest Observed Adverse Effect
Substances Level
DSL Canada, Domestic Substances List NFPA National Fire Protection Agency
NDSL Canada, Non-Domestic Substanc- NIOSH National Institute for Occupational
es List Safety & Health
CNS Central Nervous System NTP National Toxicology Program
CAS Chemical Abstract Service NZloC New Zealand Inventory of Chemi-
cals
EC50 Effective Concentration NOAEL No Observable Adverse Effect
Level
EC50 Effective Concentration 50% NOEC No Observed Effect Concentration

Safety Data Sheet
CAUSTIC SODA SOLID
EGEST EOSCA Generic Exposure Scenar- OSHA Occupational Safety & Health
io Tool Administration
EOSCA European Oilfield Specialty Chem- PEL Permissible Exposure Limit
icals Association
EINECS European Inventory of Existing PICCS Philippines Inventory of Commer-
Chemical Substances cial Chemical Substances
MAK Germany Maximum Concentration PRNT Presumed Not Toxic
Values
GHS Globally Harmonized System RCRA Resource Conservation Recovery
Act
>= Greater Than or Equal To STEL Short-term Exposure Limit
IC50 Inhibition Concentration 50% SARA Superfund Amendments and
Reauthorization Act.
IARC International Agency for Research TLV Threshold Limit Value
on Cancer
IECSC Inventory of Existing Chemical TWA Time Weighted Average
Substances in China
ENCS Japan, Inventory of Existing and TSCA Toxic Substance Control Act
New Chemical Substances
KECI Korea, Existing Chemical Inventory UVCB Unknown or Variable Composi-
tion, Complex Reaction Products,
and Biological Materials
<= Less Than or Equal To WHMIS Workplace Hazardous Materials
Information System
LC50 Lethal Concentration 50%

Sodium Nitrite Solution, Technical
Safety Data Sheet
According to U.S. Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations and according to Canada’s
Hazardous Products Regulation, February 11, 2015.
Revision Date: 09/14/2018 Date of Issue: 05/11/2015 Version: 4.0
SECTION 1: IDENTIFICATION
Product Identifier
Product Form: Mixture
Product Name: Sodium Nitrite Solution, Technical
Intended Use of the Product
For professional use only.
Name, Address, and Telephone of the Responsible Party
Manufacturer
CHEMTRADE LOGISTICS INC.
155 Gordon Baker Road
Suite 300
Toronto, Ontario M2H 3N5
For SDS Info: (416) 496-5856
www.chemtradelogistics.com
Emergency Telephone Number
Emergency Number : Canada: CANUTEC +1-613-996-6666 / US: CHEMTREC +1-800-424-9300
INTERNATIONAL: +1-703-741-5970
Chemtrade Emergency Contact: (866) 416-4404
For Chemical Emergency, Spill, Leak, Fire, Exposure, or Accident, call CHEMTREC – Day or Night
SECTION 2: HAZARDS IDENTIFICATION
Classification of the Substance or Mixture
GHS Classification
Acute Tox. 3 (Oral) H301
Eye Irrit. 2A H319
Aquatic Acute 1 H400
Label Elements
GHS Labeling
Hazard Pictograms :
GHS06 GHS07 GHS09
Signal Word : Danger

Hazard Statements : H301 - Toxic if swallowed.
H319 - Causes serious eye irritation.
H400 - Very toxic to aquatic life.
Precautionary Statements : P264 - Wash hands, forearms, and other exposed areas thoroughly after handling.
P270 - Do not eat, drink or smoke when using this product.
P273 - Avoid release to the environment.
P280 - Wear protective gloves, protective clothing, and eye protection.
P301+P310 - IF SWALLOWED: Immediately call a POISON CENTER or doctor.
P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P321 - Specific treatment (see section 4 on this SDS).
P330 - Rinse mouth.
P337+P313 - If eye irritation persists: Get medical advice/attention.
P391 - Collect spillage.
P405 - Store locked up.
09/14/2018 EN (English US) SDS#: CHE-2022S 1/9

Safety Data Sheet
According to U.S. Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules And Regulations and according to Canada’s Hazardous Products Regulation, February 11, 2015.
P501 - Dispose of contents/container in accordance with local, regional, national, and

international regulations.
Other Hazards
Exposure may aggravate those with pre-existing eye, skin, or respiratory conditions. Ingestion may cause methemoglobinemia. Initial
manifestation of methemoglobinemia is cyanosis, characterized by navy lips, tongue and mucous membranes, with skin color being
slate grey. Further manifestation is characterized by headache, weakness, dyspnea, dizziness, stupor, respiratory distress and death
due to anoxia. If ingested, nitrates may be reduced to nitrites by bacteria in the digestive tract. Signs and symptoms of nitrite
poisoning include methemoglobinemia, nausea, dizziness, increased heart rate, hypotension, fainting and, possibly shock.
Unknown acute toxicity
No data available
SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS
Mixture
Name Product Identifier %* GHS Ingredient Classification
Water (CAS No) 7732-18-5 47 - 72 Not classified
Sodium nitrite (CAS No) 7632-00-0 28 - 44+ Ox. Sol. 2, H272
Acute Tox. 3 (Oral), H301
Eye Irrit. 2A, H319
Aquatic Acute 1, H400
Sodium nitrate (CAS No) 7631-99-4 0 - 17+ Ox. Sol. 3, H272
Eye Irrit. 2A, H319
Full text of H-phrases: see section 16
+The actual concentration of the ingredient(s) is withheld as a trade secret in accordance with Regulations Amending the Hazardous
Products Regulations (HPR) SOR/2018-68 and 29 CFR 1910.1200.
*Percentages are listed in weight by weight percentage (w/w%) for liquid and solid ingredients. Gas ingredients are listed in volume
by volume percentage (v/v%).
SECTION 4: FIRST AID MEASURES
Description of First-aid Measures
General: Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label if possible).
Inhalation: Remove to fresh air and keep at rest in a position comfortable for breathing. Obtain medical attention if breathing
difficulty persists.
Skin Contact: Rinse immediately with plenty of water. Obtain medical attention if irritation develops or persists.
Eye Contact: Rinse cautiously with water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Obtain medical attention.
Ingestion: Do NOT induce vomiting. Rinse mouth. Immediately call a POISON CENTER or doctor/physician.
Most Important Symptoms and Effects Both Acute and Delayed
General: Toxic if swallowed. Causes serious eye irritation.
Inhalation: May cause respiratory irritation.
Skin Contact: May cause skin irritation.
Eye Contact: Causes serious eye irritation. Redness, pain.
Ingestion: Ingestion may cause methemoglobinemia. Initial manifestation of methemoglobinemia is cyanosis, characterized by navy
lips, tongue and mucous membranes, with skin color being slate grey. Further manifestation is characterized by headache,
weakness, dyspnea, dizziness, stupor, respiratory distress and death due to anoxia. If ingested, nitrates may be reduced to nitrites
by bacteria in the digestive tract. Signs and symptoms of nitrite poisoning include methemoglobinemia, nausea, dizziness, increased
heart rate, hypotension, fainting and, possibly shock.
Chronic Symptoms: None expected under normal conditions of use.
Indication of Any Immediate Medical Attention and Special Treatment Needed
If you feel unwell, seek medical advice (show the label where possible).
SECTION 5: FIRE-FIGHTING MEASURES
Extinguishing Media
Suitable Extinguishing Media: Water spray, fog.

Safety Data Sheet
Unsuitable Extinguishing Media: Do not use carbon dioxide. Do not use ABC dry chemical agents. Do not use a heavy water stream.
Use of heavy stream of water may spread fire.
Special Hazards Arising From the Substance or Mixture
Fire Hazard: Not flammable.
Explosion Hazard: Risk of explosion if heated under confinement.
Reactivity: Hazardous reactions will not occur under normal conditions.
Advice for Firefighters
Precautionary Measures Fire: Exercise caution when fighting any chemical fire.
Firefighting Instructions: Use water spray or fog for cooling exposed containers. In case of major fire and large quantities: Evacuate
area. Fight fire remotely due to the risk of explosion.
Protection During Firefighting: Do not enter fire area without proper protective equipment, including respiratory protection.
Hazardous Combustion Products: Nitrogen oxides.
Other Information: Refer to Section 9 for flammability properties.
Reference to Other Sections
Refer to Section 9 for flammability properties.
SECTION 6: ACCIDENTAL RELEASE MEASURES
Personal Precautions, Protective Equipment and Emergency Procedures
General Measures: Avoid all contact with skin, eyes, or clothing. Avoid breathing (vapor, mist, spray).
For Non-Emergency Personnel
Protective Equipment: Use appropriate personal protective equipment (PPE).
Emergency Procedures: Evacuate unnecessary personnel.
For Emergency Personnel
Protective Equipment: Equip cleanup crew with proper protection.
Emergency Procedures: Upon arrival at the scene, a first responder is expected to recognize the presence of dangerous goods,
protect oneself and the public, secure the area, and call for the assistance of trained personnel as soon as conditions permit.
Environmental Precautions
Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters.
Methods and Materials for Containment and Cleaning Up
For Containment: Contain any spills with dikes or absorbents to prevent migration and entry into sewers or streams.
Methods for Cleaning Up: Clean up spills immediately and dispose of waste safely. Spills should be contained with mechanical
barriers. Transfer spilled material to a suitable container for disposal. Contact competent authorities after a spill.
Reference to Other Sections
See Heading 8. Exposure controls and personal protection. For further information refer to section 13.
SECTION 7: HANDLING AND STORAGE
Precautions for Safe Handling
Hygiene Measures: Handle in accordance with good industrial hygiene and safety procedures. Wash hands and other exposed areas
with mild soap and water before eating, drinking or smoking and when leaving work.
Conditions for Safe Storage, Including Any Incompatibilities
Technical Measures: Comply with applicable regulations. Do not pressurize, cut, or weld containers.
Storage Conditions: Store in a dry, cool and well-ventilated place. Keep container closed when not in use. Keep/Store away from
extremely high or low temperatures and incompatible materials.
Incompatible Materials: Strong acids. Strong bases. Strong oxidizers.
Specific End Use(s)
For professional use only.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
Control Parameters
For substances listed in section 3 that are not listed here, there are no established Exposure limits from the manufacturer, supplier,
importer, or the appropriate advisory agency including: ACGIH (TLV), AIHA (WEEL), NIOSH (REL), OSHA (PEL), Canadian provincial
governments, or the Mexican government.

Safety Data Sheet
Exposure Controls
Appropriate Engineering Controls: Ensure adequate ventilation, especially in confined areas. Emergency eye wash fountains and
safety showers should be available in the immediate vicinity of any potential exposure. Ensure all national/local regulations are
observed.
Personal Protective Equipment: Protective goggles. Gloves. Protective clothing. Insufficient ventilation: wear respiratory protection.
Materials for Protective Clothing: Chemically resistant materials and fabrics.

Hand Protection: Wear chemically resistant protective gloves.
Eye Protection: Chemical safety goggles.
Skin and Body Protection: Wear suitable protective clothing.
Respiratory Protection: In case of insufficient ventilation, wear suitable respiratory equipment.
Environmental Exposure Controls: Do not allow the product to be released into the environment.
Consumer Exposure Controls: Do not eat, drink or smoke during use.
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Information on Basic Physical and Chemical Properties
Physical State : Liquid
Appearance : Clear, pale-yellow colored
Odor : Odorless
Odor Threshold : Not available
pH : 9 - 9.5 (1% solution)
Evaporation Rate : Not available
Melting Point : Not available
Freezing Point : Not available
Boiling Point : Not available
Flash Point : Not applicable
Auto-ignition Temperature : Not applicable
Decomposition Temperature : Not available
Flammability (solid, gas) : Not flammable
Lower Flammable Limit : Not applicable
Upper Flammable Limit : Not applicable
Vapor Pressure : Not available
Relative Vapor Density at 20°C : Not available
Relative Density : Not available
Specific Gravity : 1.306 - 1.43
Solubility : Water: 100% in water
Partition Coefficient: N-Octanol/Water : Not available
Viscosity : Not available
SECTION 10: STABILITY AND REACTIVITY
Reactivity: Hazardous reactions will not occur under normal conditions.
Chemical Stability: Stable under recommended handling and storage conditions (see section 7).
Possibility of Hazardous Reactions: Hazardous polymerization will not occur.
Conditions to Avoid: Extremely high or low temperatures. Incompatible materials.
Incompatible Materials: Strong acids. Strong bases. Strong oxidizers.
Hazardous Decomposition Products: None expected under normal conditions of use.
SECTION 11: TOXICOLOGICAL INFORMATION
Information on Toxicological Effects - Product
Safety Data Sheet
Acute Toxicity (Oral): Oral: Toxic if swallowed.

Acute Toxicity (Dermal): Not classified
Acute Toxicity (Inhalation): Not classified
LD50 and LC50 Data:
ATE (Oral) 193.18 mg/kg body weight
Skin Corrosion/Irritation: Not classified
pH: 9 - 9.5 (1% solution)
Eye Damage/Irritation: Causes serious eye irritation.
pH: 9 - 9.5 (1% solution)
Respiratory or Skin Sensitization: Not classified
Germ Cell Mutagenicity: Not classified
Carcinogenicity: Not classified
Specific Target Organ Toxicity (Repeated Exposure): Not classified
Reproductive Toxicity: Not classified
Specific Target Organ Toxicity (Single Exposure): Not classified
Aspiration Hazard: Not classified
Symptoms/Effects After Inhalation: May cause respiratory irritation.
Symptoms/Effects After Skin Contact: May cause skin irritation.
Symptoms/Effects After Eye Contact: Causes serious eye irritation. Redness, pain.
Symptoms/Effects After Ingestion: Ingestion may cause methemoglobinemia. Initial manifestation of methemoglobinemia is
cyanosis, characterized by navy lips, tongue and mucous membranes, with skin color being slate grey. Further manifestation is
characterized by headache, weakness, dyspnea, dizziness, stupor, respiratory distress and death due to anoxia. If ingested, nitrates
may be reduced to nitrites by bacteria in the digestive tract. Signs and symptoms of nitrite poisoning include methemoglobinemia,
nausea, dizziness, increased heart rate, hypotension, fainting and, possibly shock.
Chronic Symptoms: None expected under normal conditions of use.
Information on Toxicological Effects - Ingredient(s)
LD50 and LC50 Data:
Sodium nitrite (7632-00-0)
LD50 Oral Rat 85 mg/kg
LC50 Inhalation Rat 5.5 mg/l/4h
Sodium nitrate (7631-99-4)
LD50 Oral Rat > 2000 mg/kg
SECTION 12: ECOLOGICAL INFORMATION

Toxicity
Ecology - General: This material is hazardous to the aquatic environment. Keep out of sewers and waterways.
Ecology - Water: Very toxic to aquatic life.
LC50 Fish 1 0.19 mg/l (Exposure time: 96 h - Species: Oncorhynchus mykiss [flow-through])
LC50 Fish 2 0.092 - 0.13 mg/l (Exposure time: 96 h - Species: Oncorhynchus mykiss [flow-through])
LC50 Fish 1 2000 mg/l (Exposure time: 96 h - Species: Lepomis macrochirus [static])
LC50 Fish 2 994.4 - 1107 mg/l (Exposure time: 96 h - Species: Oncorhynchus mykiss [static])
Persistence and Degradability
Persistence and Degradability Readily biodegradable in water.
Bioaccumulative Potential
Log Pow -3.7 (at 25 °C)

Safety Data Sheet

Log Pow -3.8 (at 25 °C)
Bioaccumulative Potential Not expected to bioaccumulate.
Mobility in Soil Not available
Other Adverse Effects
Other Information: Avoid release to the environment.
SECTION 13: DISPOSAL CONSIDERATIONS
Waste Disposal Recommendations: Dispose of waste material in accordance with all local, regional, national, and international
regulations.
Ecology - Waste Materials: Avoid release to the environment.
SECTION 14: TRANSPORT INFORMATION
The shipping description(s) stated herein were prepared in accordance with certain assumptions at the time the SDS was authored,
and can vary based on a number of variables that may or may not have been known at the time the SDS was issued.
*When shipped in accordance with US DOT 49 CFR part 171.4(c) and other appropriate sections/provisions this material is not
designated as a marine pollutant when transported by road or rail.
**When shipped in accordance with the Canada Transport of Dangerous Goods Regulations part 1.45.1 and other appropriate
sections/provisions this material is not designated as a marine pollutant when transported by road or rail
TRANSPORTATION DOT TDG IMDG IATA
CLASSIFICATION
Identification Number UN3287 UN3287 UN3287 UN3287
Proper Shipping Name TOXIC LIQUID, TOXIC LIQUID, TOXIC LIQUID, TOXIC LIQUID,
INORGANIC, N.O.S. INORGANIC, N.O.S. INORGANIC, N.O.S. INORGANIC, N.O.S.
(CONTAINS SODIUM (CONTAINS SODIUM (CONTAINS SODIUM (CONTAINS SODIUM
NITRITE, SODIUM NITRITE, SODIUM NITRITE, SODIUM NITRITE, SODIUM
NITRATE) NITRATE) NITRATE) NITRATE)
Transport Hazard 6.1 6.1 6.1 6.1
Class(es)
Packing Group III III III III

Environmental Hazards Marine Pollutant : Yes* Marine Pollutant : Marine Pollutant : Yes Marine Pollutant:
Yes** N/A
Emergency Response ERG Number : 151 ERAP Index: Not EMS: F-A, S-A ERG code (IATA):
applicable 6L
Additional Information Not applicable Not applicable Not applicable Not applicable
SECTION 15: REGULATORY INFORMATION
US Federal Regulations
Chemical Name (CAS No.) CERCLA RQ EPCRA 304 RQ SARA 302 TPQ SARA 313
Sodium nitrite (7632-00-0) 100 lb Not applicable Not applicable Yes
Sodium nitrate (7631-99-4) Not applicable Not applicable Not applicable No
SARA 311/312
Immediate (acute) health hazard
US TSCA Flags
Chemical Name (CAS No.) US TSCA Flags/ Other Information
Sodium nitrite (7632-00-0) S - S - indicates a substance that is identified in a proposed or final Significant New Uses Rule
US State Regulations
California Proposition 65

Safety Data Sheet
Chemical Name (CAS No.) Carcinogenicity Developmental Female Reproductive Male Reproductive
Toxicity Toxicity Toxicity
Sodium nitrite (7632-00-0) No No No No
Sodium nitrate (7631-99-4) No No No No
State Right-To-Know Lists
U.S. - Massachusetts - Right To Know List - Yes
U.S. - New Jersey - Right to Know Hazardous Substance List - Yes
U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List - Yes
U.S. - Pennsylvania - RTK (Right to Know) - Special Hazardous Substances - No
U.S. - Pennsylvania - RTK (Right to Know) List - Yes
U.S. - Massachusetts - Right To Know List - Yes
U.S. - New Jersey - Right to Know Hazardous Substance List - No
U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List - No
U.S. - Pennsylvania - RTK (Right to Know) - Special Hazardous Substances - No
U.S. - Pennsylvania - RTK (Right to Know) List - Yes
Canadian Regulations
Not listed on the Canadian NDSL (Non-Domestic Substances List)
Not listed on the Canadian NDSL (Non-Domestic Substances List)
International Inventories/Lists
Chemical Name (CAS No.) Australia Turkey Korea EU EU EU EU Mexico
AICS CICR ECL EINECS ELINCS SVHC NLP INSQ
Sodium nitrite (7632-00-0) Yes Yes Yes Yes No No No Yes
Sodium nitrate (7631-99-4) Yes Yes Yes Yes No No No Yes
Chemical Name (CAS No.) China Japan Japan Japan Japan Philippines New US
IECSC ENCS ISHL PDSCL PRTR PICCS Zealand TSCA
NZIOC
Sodium nitrite (7632-00-0) Yes Yes No Yes No Yes Yes Yes
Sodium nitrate (7631-99-4) Yes Yes No No No Yes Yes Yes
SECTION 16: OTHER INFORMATION, INCLUDING DATE OF PREPARATION OR LAST REVISION
Revision Date : 09/14/2018
Revision Summary
Section Change Date Changed
3 HPR Statement 09/14/2018
14 ERG revision 09/14/2018
Other Information : This document has been prepared in accordance with the SDS requirements of the OSHA
Hazard Communication Standard 29 CFR 1910.1200 and Canada’s Hazardous Products
Regulations (HPR).
GHS Full Text Phrases:
------ Acute Tox. 3 (Oral) Acute toxicity (oral) Category 3
------ Aquatic Acute 1 Hazardous to the aquatic environment - Acute Hazard Category 1
------ Eye Irrit. 2A Serious eye damage/eye irritation Category 2A
------ Ox. Sol. 2 Oxidizing solids Category 2
------ Ox. Sol. 3 Oxidizing solids Category 3

Safety Data Sheet
------ H272 May intensify fire; oxidizer

------ H301 Toxic if swallowed
------ H319 Causes serious eye irritation
------ H400 Very toxic to aquatic life
NFPA 704
NFPA Health Hazard : 3 - Short exposure could cause serious temporary or
residual injury even though prompt medical attention was
given.
NFPA Fire Hazard : 0 - Materials that will not burn.
NFPA Reactivity Hazard : 0 - Normally stable, even under fire exposure conditions,
and are not reactive with water.
HMIS Rating
Health : 3 Serious Hazard - Major injury likely unless prompt action is taken and medical treatment is
given
Flammability : 0 Minimal Hazard
Physical : 0 Minimal Hazard
PPE See Section 8
Abbreviations and Acronyms
AICS – Australian Inventory of Chemical Substances ISHL - Japan Industrial Safety and Health Law
ACGIH – American Conference of Governmental Industrial Hygienists LC50 - Median Lethal Concentration
AIHA – American Industrial Hygiene Association LD50 - Median Lethal Dose
ATE - Acute Toxicity Estimate LOAEL - Lowest Observed Adverse Effect Level
BCF - Bioconcentration factor LOEC - Lowest-observed-effect Concentration
BEI - Biological Exposure Indices (BEI) NFPA 704 – National Fire Protection Association - Standard System for the
CAS No. - Chemical Abstracts Service number Identification of the Hazards of Materials for Emergency Response
CERCLA RQ - Comprehensive Environmental Response, Compensation, and NIOSH - National Institute for Occupational Safety and Health
Liability Act - Reportable Quantity NLP - Europe No Longer Polymers List
CICR - Turkish Inventory and Control of Chemicals NOAEL - No-Observed Adverse Effect Level
DOT – 49 CFR – US Department of Transportation – Code of Federal NOEC - No-Observed Effect Concentration
Regulations Title 49 – Transportation. NZIOC - New Zealand Inventory of Chemicals
EC50 - Median effective concentration OEL - Occupational Exposure Limits
ECL - Korea Existing Chemicals List OSHA – Occupational Safety and Health Administration
EINECS - European Inventory of Existing Commercial Chemical Substances PEL - Permissible Exposure Limits
ELINCS - European List of Notified Chemical Substances PICCS - Philippine Inventory of Chemicals and Chemical Substances
EmS - IMDG Emergency Schedule Fire & Spillage PDSCL - Japan Poisonous and Deleterious Substances Control Law
ENCS - Japanese Existing and New Chemical Substances Inventory PPE – Personal Protective Equipment
EPA – Environmental Protection Agency PRTR - Japan Pollutant Release and Transfer Register
EPCRA 304 RQ – EPCRA 304 Extremely Hazardous Substance Emergency REL - Recommended Exposure Limit
Planning and Community Right-to-Know-Act – Reportable Quantity SADT - Self Accelerating Decomposition Temperature
ERAP Index – Emergency Response Assistance Plan Quantity Limit SARA - Superfund Amendments and Reauthorization Act
ErC50 - EC50 in Terms of Reduction Growth Rate SARA 302 - Section 302, 40 CFR Part 355
ERG code (IATA) - Emergency Response Drill Code as found in the International SARA 311/312 - Sections 311 and 312, 40 CFR Part 370 Hazard Categories
Civil Aviation Organization (ICAO) SARA 313 - Section 313, 40 CFR Part 372
ERG No. - Emergency Response Guide Number SRCL - Specifically Regulated Carcinogen List
HCCL - Hazard Communication Carcinogen List STEL - Short Term Exposure Limit
HMIS – Hazardous Materials Information System SVHC – European Candidate List of Substance of Very High Concern
IARC - International Agency for Research on Cancer TDG – Transport Canada Transport of Dangerous Goods Regulations
IATA - International Air Transport Association – Dangerous Goods Regulations TLM - Median Tolerance Limit
IDLH - Immediately Dangerous to Life or Health TLV - Threshold Limit Value
IECSC - Inventory of Existing Chemical Substances Produced or Imported in TPQ - Threshold Planning Quantity
China TSCA – United StatesToxic Substances Control Act
IMDG - International Maritime Dangerous Goods Code TWA - Time Weighted Average
INSQ - Mexican National Inventory of Chemical Substances WEEL - Workplace Environmental Exposure Levels

Safety Data Sheet
Handle product with due care and avoid unnecessary contact. This information is supplied under U.S. OSHA’S “Right to Know” (29 CFR
1910.1200) and Canada’s WHMIS regulations. Although certain hazards are described herein, we cannot guarantee these are the only
hazards that exist. The information contained herein is based on data available to us and is believed to be true and accurate but it is
not offered as a product specification. No warranty, expressed or implied, regarding the accuracy of this data, the hazards connected
with the use of the product, or the results to be obtained from the use thereof, is made and Chemtrade and its affiliates assume no
responsibility. Chemtrade is a member of the CIAC (Chemistry Industry Association of Canada) and adheres to the codes and principles
of Responsible Care™.
Chemtrade NA GHS SDS 2015

Appendix 2: Cleaning Equipment Layout Diagram
CHEMICAL EQUIPMENT DIAGRAM
H V
TANK
HEATER
INLET
PIPING
SYSTEM
FLOW DIRECTION
FILTER OUTLET
H THERMOMETER
V FOLOW METER
APPENDIX 3
Chemical Cleaning Line List
Sequence Isometric Drawing N
STT Line Number P&ID Number
Number
1 0600-GF-45-9301-DC21S-ET 9301 2101-TECH-00-P-XB-00002_01 0600-GF-45-9301-DC21S-ET
2 0600-GF-45-9302-DC21S-ET 9302 2101-TECH-00-P-XB-00002_01 0600-GF-45-9302-DC21S-ET
3 0200-GF-45-9303-AC21 9303 2101-TECH-00-P-XB-00002_01 0200-GF-45-9303-AC21
4 0200-GF-45-9304-AC21 9304 2101-TECH-00-P-XB-00002_01 0200-GF-45-9304-AC21
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17
M42 MODULE
HEATING MEDIUM FROM 41HW991
A A
2101-WA02-80-P-XB-00006_01
2101-WA02-80-P-XB-00006_01
2101-WA02-80-P-XB-00005_01
2101-WA02-80-P-XB-00005_01
2101-TEC1-41-P-XB-00002_01
2101-TEC1-55-P-XB-00014_01
2101-TEC1-55-P-XB-00016_01
2101-WA02-80-P-XB-00006
2101-TEC1-55-P-XB-00013_01
2101-TEC1-41-P-XB-00001_01
STEAM FROM SUPERHEATER 55HW994
FEED WATER TO ECONOMIZER 55HW992
AMMONIA TO STEAM DRUM 55VA991
GENERAL NOTES:
HEATING MEDIUM TO 41TW991
1. TIE-IN SPOOLS BETWEEN MODULE M33 AND MODULE M40 DESIGNED AND SUPPLIED BY TECHOUSE.
COOLING MEDIUM RETURN
COOLING MEDIUM SUPPLY
2. TIE-IN SPOOLS BETWEEN MODULE M40 AND MODULE M41 DESIGNED AND SUPPLIED BY OTHERS.
TO LP FLARE HEADER
3. MARINE TIE-IN PIPING TO M40 MODULE BY OTHERS.

FUEL GAS TO GTS'S
4. LOW POINT DRAIN.

5. CONDENSATE PUMP SKID LOCATED ON FPSO DECK.
B B
1200-SP-55-9922-EX62-HC
0400-SC-55-9901-DC21-HC
1000-WH-41-9902-BC21-HC
1000-WH-41-9901-BC21-HC
0050-CJ-42-9011-TS01
0050-CJ-42-9902-TS01
HOLDS:
1. TP NUMBERS FROM MODULE M33 CONTRACTOR.
2. LINE NUMBERS FROM MODULE M41/M42 CONTRACTOR.
0050-CJ-42-9011-TS01
C C
M41 M33
TP TP
9027 M40 8407

TP
M40 INTEGRATED PIPERACK M40
TP
M33 INTEGRATED PIPERACK
9304 M40 M33
0600-GF-45-8807-AC21
TP 9303 TP FUEL GAS FROM M10
0600-GF-45-9051-DC21S-ET. 0600-GF-45-9015-DC21S-ET 0600-GF-45-9301-DC21S-ET
ET 9301 8812 2101-WA01-40-P-XB-00015
HC
NOTE 2 NOTE 1
M41 M40 HEATING MEDIUM FROM M26
TP TP 1400-WH-41-9312-BC21-HC
9030
HC 2101-VME1-41-P-XB-00009
9308 M40 NOTE 1
TP
D 1600-WC-40-9057-BC21 1600-WC-40-9349-AC21 3/4" 1400-WH-41-9314-BC21-HC TO HEATING MEDIUM SUPPLY HEADER D
9314 HC 2101-VME1-41-P-XB-00009
NOTE 2 41GTV9317 M40 NOTE 1 M33
TP COOLING MEDIUM SUPPLY
C4 NOTE 4 TP M33
TP
M40 8111 2101-HCR1-40-P-XB-00005_01
M40 9307 TP
TP 8432
16"x24"
0050-CJ-42-9011-TS01
COOLING MEDIUM REURN

HC
M41 NOTE 2 2400-WC-40-9348-AC21 9339 2400-WC-40-9353-AC21

M41
TP
TP
9048
C4 9341 M40
TP M40
TP 2101-HCR1-40-P-XB-00005_01
9342 M33 TO MP COMPRESSION INLET COOLER (M10)
9050 0200-VA-48-9003-BD20 9302 0200-VA-48-9301-BD20-PP 0200-VA-48-9302-BD20-PP TP
8408 2101-HCR1-00-P-XB-00001_07
C4 0200-GF-45-9018-AC21. 0200-GF-45-9303-AC21 0200-GF-45-9304-AC21 LP FUEL GAS SUPPLY C4
M40 M33 2101-HCR1-00-P-XB-00001_07
1400-WC-40-9065-AC11 TP NOTE 1 TP
9309 8433 TO LP FLARE HEADER
M41 0300-VF-43-9054-AC11 0300-VF-43-9301-AC21 0300-VF-43-9302-AC21
E TP M33
2101-WA01-43-P-XB-00014 E
HOLD 2 M40 TP
M40
TP
M40
TP
M40
TP
NOTE 1 TP M33
9021
16"x24" 8404 TP
9306 9310 1600-WC-40-9347-AC21 2400-WC-40-9346-AC21 9340 9305
1600-WC-40-9065-AC21. 2400-WC-40-9352-AC21 8469
0800-WC-40-9345-AC21
1400-WH-41-9311-BC21-HC.
0800-WC-40-9301-AC21
M41 M40
TP TP
9029 9316
1400-SP-55-9063-EX22-HC 1400-SP-55-9301-EX22-HC
M41
TP
9032 M40
M41 TP M40 M33
TP TP TP
C4 TS01 DS20 9044
C4 9328
9329 8401 WARM UP HP FLARE HEADER FROM M41
PIPERACK
0050-CJ-42-9010-DS20 0600-VF-43-9304-AC11
F 2101-WA01-43-P-XB-00012 F
M41 INTEGRATED PIPERACK
M40 M33
M41 TP TP
TP M40 FROM SKID 42XX699C TO M28 (WATER
TP 0050-CJ-42-9305-DS20 9330 8465 INJECTION SCALE INHIBITOR), NO POCKETS
9055 0100-CD-42-9302-AS20
9331 2101-VME1-42-P-XB-00001_02
C4 0050-CJ-42-9005-DS20 0050-CJ-42-9304-DS20 0100-CD-42-9301-AS20 M33
TP
M40
0050-CJ-42-9802-DS20
TP
0600-VF-43-9057-AC11
8463 FROM SKID 42XX699E TO M28 (WATER

M41
TP C4 M40
TP 9331 0100-CB-42-9302-AS20 INJETION BIOCIDE), NO POCKETS
9022 9332 MODULE M40 2101-VME1-42-P-XB-00001_02
0100-CB-42-9301-AS20
2101-TECH-55-P-XB-00005_01
2101-TECH-42-P-XB-00001_01
2101-TECH-55-P-XB-00007-01
2101-TECH-42-P-XB-00001_01
2101-TECH-40-P-XB-00013-01
2101-TECH-40-P-XB-00013-01
M33
M40 TP
TP
HEATING MEDIUM FROM HM HEATER
8461 FROM SKID 42XX699F TO M28 (OXYGEN/

AMMONIA FROM CHEMICAL DOSING
AMMONIA FROM CHEMICAL DOSING
9332 CHLORINE SCAVENGER), NO POCKETS

M40
0100-CO-42-9302-AS20
M41
TP TP 2101-VME1-42-P-XB-00001_02
0100-CO-42-9301-AS20
G G
COOLING MEDIUM RETURN
9031 9315
M40 M33
TP
HP STEAM TO STG
TP
0600-SC-55-9355-DC21-HC 8459 FROM SKID 42XX699G TO M28 (BIOCIDE
0600-SC-55-9071-DC61-HC 9333 DISPENSER), NO POCKETS
2101-VME1-42-P-XB-00001_02
0100-CB-42-9303-AS20
M33
M40 TP LEGEND:
C4 TP
8457 FROM SKID 42XX699H TO M28 (SRU SCALE
2101-TECH-55-P-XB-00012_01
9334 INHIBITOR), NO POCKETS

0100-CD-42-9304-AS20 - WELDED CONNECTION
2101-VME1-42-P-XB-00001_02
FROM STEAM CONDENSOR COOLING
0100-CD-42-9303-AS20
M33 - FLENGED CONNECTION
2101-TECH-56-P-XB-00001-01
TP
SEAWATER SUPPLY TO STEAM CONDENSOR
2101-TECH-55-P-XB-00004_01
M40
2101-TECH-00-P-XB-00002_01
2101-TECH-56-P-XB-00001-01
2101-TECH-00-P-XB-00002_01
2101-TECH-55-P-XB-00004_01
2101-TECH-00-P-XB-00002_01
2101-TECH-00-P-XB-00002_01
2101-TEC1-55-P-XB-00005-01
2101-TECH-56-P-XB-00001-01
FROM FEED WATER PUMPS
2101-TECH-80-P-XB-00001_01
2101-TECH-56-P-XB-00001-01
2101-TECH-80-P-XB-00001_01
2101-TECH-80-P-XB-00001_01
2101-TECH-80-P-XB-00001_01
2101-TECH-80-P-XB-00001_01
M41 TP 8455 FROM SKID 42XX699B TO M28 (NaOH), NO

TP 9335 POCKETS
H 0100-CR-42-9302-AS20 H
NON-HAZARDUOS DRAINS HEADER
NON HAZARDOUS DRAINS HEADER
INSTRUMENT AIR TO DISTRIBUTION
9023 2101-VME1-42-P-XB-00001_02
FRESH WATER TO DISTRIBUTION
M020-CR-42-9301-TS01
DEMIN WATER TO DISTRIBUTION
1200-SP-55-9822-EX62-HC
HAZARDOUS DRAINS HEADER

0400-SC-55-9801-DC61-HC
FIRE WATER TO DISTRIBUTION

1000-WH-41-9802-BC21-HC
0300-VF-43-9054-AC21
HEATING MEDIUM FROM WHRU

1000-WH-41-9801-BC21-HC
M33
PLANT AIR TO DISTRIBUTION
0050-CJ-42-9802-DS20
TP
NITROGEN TO DISTRIBUTION
FROM STEAM CONDENSOR
M40
TP
TO EJECTOR CONDENSOR
8453 FROM SKID 42XX699A TO M28 (HCI), NO

TO EXPANSION BOTTLE
OVERBOAD HEADER
9336 0075-CR-42-9304-AN50 POCKETS

2101-VME1-42-P-XB-00001_01
0075-CR-42-9303-AP13 M33
M41 TP
TP M40
1400-WH-41-9058-BC21-HC
TP 8451 FROM SKID 42XX699D TO M28 (NaOCI), NO

9033
9337 POCKETS
0075-CS-42-9302-AT70
2101-VME1-42-P-XB-00001_01 {StampHere}
0075-CS-42-9301-AT70
2400-WS-50-9302-AP04
M33
C4
0600-DN-56-9304-AC21
2400-WS-50-9301-AP04.
0600-DO-56-9301-AC21
0600-DN-56-9301-AC21
0600-DN-56-9316-AC21
0200-SC-55-9375-AC21
0200-WD-53-9311-AS20
0800-SC-55-9373-AC21
1200-SC-55-9301-AC21
TP
0200-GN-64-9301-AC21
0200-AI-63-9301-AS20
0200-AP-63-9301-AC21
M40
NOTE 2
1400-WH-41-9301-BC21-HC.
TP 8449 FROM SKID 42XX699I TO M28 (MEMBRANE

L L
HEATING MEDIUM TO 41HW981
9338 BIOCIDE), NO POCKETS

0100-CB-42-9306-AT70
2101-VME1-42-P-XB-00001_01
0100-CB-42-9305-AT70
2101-WA02-80-P-XB-00006_01
2101-WA02-80-P-XB-00006_01
2101-TEC1-41-P-XB-00002_01
2101-TEC1-55-P-XB-00002_01
2101-TEC1-55-P-XB-00001_01
2101-TEC1-55-P-XB-00004_01
FEED WATER TO ECONOMIZER 55HW982
2101-WA02-80-P-XB-00005
2101-TEC1-41-P-XB-00001_01
2101-WA02-80-P-XB-00005
STEAM FROM SUPERHEATER 55HW984
AMMONIA TO STEAM DRUM 55VA981
HEATING MEDIUM FROM 41HW981

COOLING MMEDIUM SUPPLY
FUEL GAS TO GTG'S

TO LP FLARE HEADER
0200-WD-53-0354-AS30
M40 M40
TP TP M33
TP 2400-WS-50-8427-AP04
9313 9322 C4*
M40 8540 SEAWATER SUPPLY
M TP 2400-WS-50-9303-AP04 C4 EX-DE 05 24-JAN-2024 Re-issued for Construction BT LT PKL --- --- M
HC 2101-HCR1-50-P-XB-00001
9354
M40 2400-WS-50-9304-AP04 SEAWATER RETURN C3 EX-DE 04 05-01-2024 Re-issued for Construction BT LT PKL
TP 2101-HCR1-50-P-XB-00001
M40 M40 M40 M40 M40 M40 M40 M40 M40 M40 M40 M40 M33 C2 EX-DE 03 21-AUG-2023 Re-issued for Construction BT LT PKL --- ---
TP 9352 TP TP TP TP TP TP TP TP TP TP TP TP 2400-WS-50-8702-AP04
9350 9327 9326 9325 9324 9317 9318 9320 9321 9311 9339 9323 8542 C1 EX-DE 02 26-MAY-2023 Issued for Construction BT LT PKL --- ---
M33 MODULE
Company Validity Revision Date Description Prepared by Checked by Approved by Company Client
M41 MODULE M40
TP 1200-SC-55-9370-AC21
S02 S02 S02 S02 S02 S02 S02 S02 Rev. No. Status Number Approved Approved
9351 TP TP TP TP TP TP TP TP Index Revision
0800-SC-55-9372-AC21 Client Logo and Business Name LCI Activity Code Client Document ID:
M40 0051 0436 0037 0239 0238 0052 0035 0184
TP
LCI-AO-2022-0006 363006DPFM00480
9349 M40
55PA462A/B1200-SC-55-9371-AC21
TP Azule Energy Angola S.p.A. LCI Activity Code

0200-SC-55-9374-AC21
0200-WF-71-0188-AK31
MARINE S02
0800-SC-55-9303-AC21
000576 Job No.: -

0200-WD-53-0348-AS30
0200-WD-53-0352-AS30
0600-DN-56-0094-AG33
CONDENSATE PUMPS NOTE 5
0200-GN-64-0048-AS30
9353
0400-WF-71-0188-AP31
0600-DN-56-0023-AG33
S02 S02
0200-AP-63-0101-AS30
TP TP
NOTE 3
Company Logo and Business Name Company Document ID:

N 0183 N
2101-OSMO-00-P-XB-00005-01
2101-OSMO-00-P-XB-00005-01
2101-TECH-00-P-XB-00002_01
2101-OSMO-00-P-XB-00005-01
2101-OSMO-00-P-XB-00005-01
2101-OSMO-00-P-XB-00005-01
2101-TECH-55-P-XB-00001_01
2101-TECH-55-P-XB-00001_01
2101-OSMO-00-P-XB-00005-01
2101-OSMO-00-P-XB-00005-01
2101-OSMO-00-P-XB-00005-01
2101-OSMO-00-P-XB-00005-01
2101-TECH-55-P-XB-00001_01
2101-OSMO-00-P-XB-00005-01
FRESH FIRE WATER SUPPLY AND DRAINS
Yinson Azalea Production Pte. Ltd.

Contract No.: -
Contractor/Vendor Logo and Business Name Contractor/Vendor Document ID:
TO NON HAZARDOUS DRAINS
TH-P0355-P-XB-0041-01
TO NON-HAZARDOUS DRAINS
OVERBOARD TO DISPOSAL
FROM CONDENSATE PUMPS
TO CONDENSATE PUMPS
FROM CONDENSATEPUMPS
TO HAZARDOUS DRAINS
TECHOUSE AS
INSTRUMENT AIR HEADER
DENIM WATER SUPPLY
Unit/Package RFQ No.: -

FIRE WATER SUPPLY
PLANT AIR SUPPLY
NITROGEN SUPPLY
Facility and Sub Facility Name Project and SoW Description Scale: Sheet of Sheets:
Agogo Integrated West Hub - FPSO Agogo Integrated West Hub Development 1 1 of 1
Document Title: Superseded No.: -
P Superseded by No.: - P
P&ID INTEGRATION P&ID M40/M41/M42 Plant Area Functional Unit
- -
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17
This document is property of Azule Energy Angola S.pA., formely Eni Angola S.p.A. It shall neither be shown to Third Parties nor used for purposes other than those for which it has been sent. A1
A B C D E F G H I J
FABRICATION MATERIALS
T.U.W.:TOTAL UNIT WEIGHT
PT N.S. QTY COMPONENT DESCRIPTION ITEM CODE T.U.W (kg)

NO (INS)
1 6 25550MM PIPE ASME B36.10M BE SCH80 ASTM A106 Gr B PIP-TUB-A106-6in 1087.41

1 1
SUPPORTS
2 6 1 PIPE SHOE SH03B-150-138-350 ANCI/AT503-150mm 11.58

3 6 2 WEAR PLATE WP01-150-300 ANCI/AT05-150mm 5.15
4 6 3 GUIDE FOR PIPE SHOE G05-150-3 ANCI/GT500-150mm 2.62
5 6 1 PIPE SHOE SH03B-150-100-350 ANCI/AT503-150mm 10.77
6 6 1 AXIAL STOP FOR SHOE AS02-150-3 ANCI/ST501-150mm 1.47
MISCELLANEOUS COMPONENTS
CONT. ON ERECTION MATERIALS

2 0600-GF-45-9302-DC21S-ET 2
E 132700 PT N.S. QTY COMPONENT DESCRIPTION ITEM CODE T.U.W (kg)
S 2750 NO (INS)
EL +46721
SUPPORTS
S2
M40-GF-PS-0006
M40TP9303 8 6 1 RIGHT ANGLE SUPPORT TYPE A RAB01A-5-592/250/611 FT04-C-1-5.6 0.00
ORI = D 292 9 6 3 GUIDE WITH VERTICAL RESTRAIN FOR PIPE SHOE G06-150-3-3 ANCI/GT501-150mm 3.07
S9 10 6 4 CLAMPED SHOE SH04-150-100-200 ANCI/AT03-150mm 70.79
M40-GF-PS-0006 6" 11 6 4 RIGHT ANGLE SUPPORT TYPE A RAB01A-5-637/263/645 FT04-C-1-5.6 0.00
ORI = D 12 6 1 RIGHT ANGLE SUPPORT TYPE A RAB01A-5-682/250/573 FT04-C-1-5.6 0.00
S8
3 550
0
S3/7
CUT PIPE LENGTH 3
M40-GF-PS-0006 PIECE CUT N.S. REMARKS PIECE CUT N.S. REMARKS
ORI = D NO LENGTH (INS) NO LENGTH (INS)
S10 <1> 6000 6
M40-GF-PS-0005 <1A> 6000 6
ORI = D
<1B> 6000 6
S4 <1C> 6000 6
M40-GF-PS-0005 <1D> 1550 6
M40-GF-45-9301-01
ORI = D
S11
0
550
4 4
S10
M40-GF-PS-0004
ORI = D
50 S11
255
M40-GF-45-9301-02
8 S4
5 550 M40-GF-PS-0004 5
ORI = D
S10
M40-GF-PS-0003
ORI = D
S11
6 S3/7
550
0 6
M40-GF-PS-0001 S9
ORI= D M40-GF-PS-0003
ORI = D
3 S10
M40-GF-PS-0002
ORI = D
S6
M40-GF-PS-0001
ORI= D
0 S11
300
S5
M40-GF-PS-0001
ORI= D
7 S9 S4 7
M40-GF-PS-0001 M40-GF-PS-0002
ORI= D ORI = D
CONT. ON 0600-GF-45-9015-DC21S-ET S12
M40TP9304 <1> 1
E 107150 6"
S 2750
EL +46721
8 8
03 12/03/2024 ISSUED FOR CONSTRUCTION HTĐ PP VTS

9 01 30/10/2023 ISSUED FOR CONSTRUCTION HTĐ PP VTS 9
3 REV. DATE DESCRIPTION PREP. CHK. APPR.
CLIENT LOGO and BUSINESS NAME: COMPANY LOGO and BUSINESS NAME: CONTRACTOR/VENDOR LOGO and BUSINESS NAME:
NOTES: HOLDS: MIN MAX INSULATION CLASS ET STRESS CATEGORY (Y/N) Y FLANGE MNGT (Y/N) Y PROJECT AND SOW DESCRIPTION PROJECT PROJECT
AGOGO INTEGRATED WEST HUB DEVELOPMENT CODE: ID:
1. ALL DIMENSIONS ARE IN MILLIMETER, (mm). 1. DESIGN TEMP. in (°C) 0 160 INSULATION THICK. in (mm) 38 STRESS CALC. No: 2101-TECH-45-L-CA-00027 TOTAL WEIGHT in (kg) 1087.41
AGOGO FULL FIELD - FPSO 000576 YAG
2. ALL MATERIALS SHALL COMPLY TO NACE MR0175 / ISO 15156. 2. DESIGN PRESS. in (barg) 0 60 INSU.TRACE (Heat/Steam) N CHEMICAL CLEANING (Y/N) N PID NUMBER 2101-TECH-00-P-XB-00002_01
10 CLIENT DOCUMENT ID: THIS DOCUMENT IS PROPERTY OF ENI S.P.A.
IT SHALL NEITHER BE SHOWN TO THIRD PARTIES, SCALE: 10
3. 3. OPERATING TEMP. in (°C) 17 70 PAINT SYSTEM 1D PWHT (Y/N) NA NOR USED FOR PURPOSES OTHER THAN
THOSE FOR WHICH IT HAS BEEN SENT. N.T.S
4. 4. OPERATING PRESS. in (barg) 0 43.5 RAL CODE RAL 7038 NR13 (A/B/C/D) N.A COMPANY DOCUMENT ID: ISOMETRIC DRAWING No.: SIZE:
NA 0600-GF-45-9301-DC21S-ET-WM A3
5. 5. TEST TYPE/PRESS. in (barg) H.T. 153.15 COLOR METALLIC GREY NDT Class in (%) 1
CONTRACTOR/VENDOR DOCUMENT ID: AREA CODE: LINE SIZE: SER. CODE: SYS. No: PIPE CLASS: SHEET: REV.:
6. 6. TEST MEDIUM/DURATION in mins WATER 60 INTERNAL COATING N.A SOUR SERVICE (Y/N) Y TH-P0355-L-XN-0042-01/AFC REV 02 M40 6" GF 45 DC21S 1/ 1 03
THIS DRAWING DOES NOT RELIEVE THE CONTRACTOR THE RESPONSIBILITY OF ENSURING THE CORRECTNESS OF DIMENSIONS CONTAINED THERE IN
A B C D E F G H I J
A B C D E F G H I J

NO (INS)

1 1
FITTINGS
2 6 2 ELBOW 90DEG LR ASME B16.9 BW SCH80 ASTM A234 WPB ELBO-90L-6in 30.70
CUT PIPE LENGTH
PIECE CUT N.S. REMARKS PIECE CUT N.S. REMARKS

NO LENGTH (INS) NO LENGTH (INS)
<1> 1217 6 FF WELD <2> 2642 6 (Extra +100)
2 2
E 135700
S 1226
3 EL +46721 3
6"
M33TP8807
229
2 M40-GF-45-9302-02
CONT.ON 0600-GF-45-8807-AC21
1296
4 4
<1>
1
FFW
229
M40-GF-45-9302-01
5 5
1
<2>
1
6" 277
M40TP9303
6 CONT. ON 6
0600-GF-45-9301-DC21S-ET
E 132700
S 2750
EL +46721
FFW
7 7
8 8

4 REV. DATE DESCRIPTION PREP. CHK. APPR.
HOOK-UP CLIENT LOGO and BUSINESS NAME: COMPANY LOGO and BUSINESS NAME: CONTRACTOR/VENDOR LOGO and BUSINESS NAME:
NOTES: HOLDS: MIN MAX INSULATION CLASS ET STRESS CATEGORY (Y/N) Y FLANGE MNGT (Y/N) Y PROJECT AND SOW DESCRIPTION PROJECT PROJECT
1. ALL DIMENSIONS ARE IN MILLIMETER, (mm). 1. DESIGN TEMP. in (°C) 0 160 INSULATION THICK. in (mm) 38 STRESS CALC. No: 2101-TECH-45-L-CA-00027 TOTAL WEIGHT in (kg) 184.305
2. ALL MATERIALS SHALL COMPLY TO NACE MR0175 / ISO 15156. 2. DESIGN PRESS. in (barg) 0 60 INSU.TRACE (Heat/Steam) N CHEMICAL CLEANING (Y/N) N PID NUMBER 2101-TECH-00-P-XB-00002_01
4. 4. OPERATING PRESS. in (barg) 0 43.5 RAL CODE RAL 7038 NR13 (A/B/C/D) N.A COMPANY DOCUMENT ID: ISOMETRIC DRAWING No.: SIZE:
NA 0600-GF-45-9302-DC21S-ET-WM A3
6. 6. TEST MEDIUM/DURATION in mins WATER 60 INTERNAL COATING N.A SOUR SERVICE (Y/N) Y TH-P0355-L-XN-0043-01/AFC REV 02 M40 6" GF 45 DC21S 1/ 1 04
A B C D E F G H I J
A B C D E F G H I J

NO (INS)

1 1
FITTINGS
2 2 3 ELBOW 90DEG LR ASME B16.9 BW SCH160 ASTM A234 WPB ELB-90L-2in 4.50
SUPPORTS
M40TP9340
3 2 2 GUIDE FOR PIPE SHOE G05-50-3 ANCI/GT500-50mm 1.75
CONT. ON 4 2 1 PIPE SHOE SH02B-50-250-500 ANCI/AT501-50mm 17.04
0200-GF-45-9304-AC21 5 2 1 WEAR PLATE WP01-50-450 ANCI/AT05-50mm 1.47
E 132124
6 2 1 AXIAL STOP FOR SHOE AS02-50-3 ANCI/ST501-50mm 7.11
S5/7 >1 S 3100
<3D EL +45824
M40-GF-PS-0007 2" MISCELLANEOUS COMPONENTS
ORI = D
2 S6
7 2 450MM PIPE ASME B36.10M BE SCH160 ASTM A106 Gr B PIP-TUB-A106-2in 5.00 2
M40-GF-PS-0007 ERECTION MATERIALS
ORI = D
S4
M40-GF-PS-0007
NO (INS)
ORI = D
70
44 SUPPORTS
S9
M40-GF-PS-0007
8 2 4 CLAMPED SHOE SH04-50-100-200 ANCI/AT03-50mm 19.40
ORI = D
S3 9 2 3 GUIDE WITH VERTICAL RESTRAIN FOR PIPE SHOE G06-50-3-3 ANCI/GT501-50mm 3.00
M40-GF-PS-0008
ORI = D
3 M40-GF-45-9303-02 CUT PIPE LENGTH 3

S8 PIECE CUT N.S. REMARKS PIECE CUT N.S. REMARKS
M40-GF-PS-0008 NO LENGTH (INS) NO LENGTH (INS)
ORI = D <1> 673 2 <2> 591 2
> 1 <3> 758 2
<3C <3A> 5800 2
0
568 <3B> 6000 2
<3C> 6000 2
<3D> 6000 2
S9
634
M40-GF-PS-0009 24
4 ORI = D 4
S8
M40-GF-PS-0009
>1 ORI= D
<3B
0
568
5 S3 5
M40-GF-PS-0010
ORI = D
S8
M40-GF-PS-0010
ORI = D
>1
<3A
0
568
6 6
S9
M40-GF-PS-0011
ORI = D 1 M40-GF-45-9303-01
<3>
318
2
EL +45824 S8
M40-GF-PS-0011
ORI= D
7 7
<2> 1
743
<1> 1
E 107414
S 3925
8 825 EL +45080
8
2
M41TP9050
76
CONT. ON M41 0200-GF-45-9018-AC21
2"
9 01 07/03/2024 ISSUED FOR CONSTRUCTION HTĐ PP VTS

9
REV. DATE DESCRIPTION PREP. CHK. APPR.

CLIENT LOGO and BUSINESS NAME: COMPANY LOGO and BUSINESS NAME: CONTRACTOR/VENDOR LOGO and BUSINESS NAME:
NOTES: HOLDS: MIN MAX INSULATION CLASS N.A. STRESS CATEGORY (Y/N) N FLANGE MNGT (Y/N) Y PROJECT AND SOW DESCRIPTION PROJECT PROJECT
1. ALL DIMENSIONS ARE IN MILLIMETER, (mm). 1. TIE-IN LOCATION FOR M41. DESIGN TEMP. in (°C) 0 120 INSULATION THICK. in (mm) 0 STRESS CALC. No: TOTAL WEIGHT in (kg) 291.383
2. 2. DESIGN PRESS. in (barg) 0 12.5 INSU.TRACE (Heat/Steam) N CHEMICAL CLEANING (Y/N) Y PID NUMBER 2101-TECH-00-P-XB-00002_01
4. 4. OPERATING PRESS. in (barg) 0 8 RAL CODE RAL 7038 NR13 (A/B/C/D) N.A COMPANY DOCUMENT ID: ISOMETRIC DRAWING No.: SIZE:
NA 0200-GF-45-9303-AC21-WM A3
6. 6. TEST MEDIUM/DURATION in mins WATER 60 INTERNAL COATING N.A SOUR SERVICE (Y/N) Y TH-P0355-L-XN-1063 -01/AFC REV 01 M40 2" GF 45 AC21 1/ 1 01
A B C D E F G H I J
A B C D E F G H I J

NO (INS)

1 1
FITTINGS
2 2 4 ELBOW 90DEG LR ASME B16.9 BW SCH160 ASTM A234 WPB ELB-90L-2in 6.00
CUT PIPE LENGTH
PIECE CUT N.S. REMARKS PIECE CUT N.S. REMARKS

NO LENGTH (INS) NO LENGTH (INS)
<1> 1094 2 FF WELD <2> 2748 2
M33TP84XX <3> 1523 2 FF WELD <4> 674 2 FF WELD
2 FFW 2
600 4>
1
<
2"
NOTE 2
2
M40-GF-45-9304-03
3 3
144
9
HOLD <3>
E 135700 1
S 875
EL +46667
FFW
76
4 4
0
290 1
<2>
5 M40-GF-45-9304-02
5
76
2
6 EL +46667 FFW 6
M40-GF-45-9304-01
<1>
1
844
1020
7 7
700
2
2"
NOTE 2
76
M40TP9340
CONT. ON
0200-GF-45-9303-AC21
E 132124
S 3100
EL +45824
8 8

REV. DATE DESCRIPTION PREP. CHK. APPR.
HOOK-UP CLIENT LOGO and BUSINESS NAME: COMPANY LOGO and BUSINESS NAME: CONTRACTOR/VENDOR LOGO and BUSINESS NAME:
NOTES: HOLDS: MIN MAX INSULATION CLASS N.A. STRESS CATEGORY (Y/N) N FLANGE MNGT (Y/N) Y PROJECT AND SOW DESCRIPTION PROJECT PROJECT
1. ALL DIMENSIONS ARE IN MILLIMETER, (mm). 1. TIE-IN LOCATION FOR M33. DESIGN TEMP. in (°C) 0 120 INSULATION THICK. in (mm) 0 STRESS CALC. No: TOTAL WEIGHT in (kg) 68.092
2. TEMPORARY FLANGE TO BE ADDED FOR TEST. 2. CONNECTION LINE FOR M33. DESIGN PRESS. in (barg) 0 12.5 INSU.TRACE (Heat/Steam) N CHEMICAL CLEANING (Y/N) Y PID NUMBER 2101-TECH-00-P-XB-00002_01
4. 4. OPERATING PRESS. in (barg) 0 8 RAL CODE RAL 7038 NR13 (A/B/C/D) N.A COMPANY DOCUMENT ID: ISOMETRIC DRAWING No.: SIZE:
NA 0200-GF-45-9304-AC21-WM A3
6. 6. TEST MEDIUM/DURATION in mins WATER 60 INTERNAL COATING N.A SOUR SERVICE (Y/N) Y TH-P0355-L-XN-1062 -01/AFC REV 01 M40 2" GF 45 AC21 1/ 1 01
A B C D E F G H I J
Appendix 6: Chemical Cleaning JSA
www.alpha-ecc.com HSEQ Integrated Management System Form
S Phi u JSA No.: AL5153-JSA-01

PHI U PHÂN TÍCH AN TOÀN CÔNG VI C VÀ R I RO
Job Safety Analysis and Risk Assessment Quy trình/ Procedure: AL-5153-CC.001
D / Project: AGOGO – M40 MODULE T / Team: Chemical cleaning
CÔNG
Mã s Công vi c/ Job No. AL-5153 Chemical cleaning internal pipe
VI C/ Work:
A M/ Location: Site 5 TH I GIAN / Time: d uXn u ng xuyên"/ Check X in box if "Routine":
LO I C.VI C/ Work Type: Hành chính/ Admininstrative: Ngày gi d ki n t / Date, Time From:
(Ghi d u X vào ô thích h p S n xu t/ Production: Ngày gi d ki n n/ Date, Time To:
Check X if applicable) Nguy hi m/ Dangerous: Gi y phép làm vi c (n u có) S /PTW No. (if needed):
THI T B S DÙNG/ Equipment To Be Used Mã s / ID No. Ch ng ch k. nh, hi u chu n s :/Attached Safety Inspection, Calibration Cert. No.
1
2
H ch ng ch kèm / Other attached records, certificates:
R I RO/ How to assess risk by calculation of risk rating:

M C R I RO R = LxS: RISK RATING R = LxS:
M c th p (1--4): ch p nh n c, không c n hành ng n a m t khi nó c Low risk (1--4): Acceptable risk and no further action required as long as risk has been
gi m thi u t i m c có th c. R i ro này c n c nh k xem xét. minimised as possible. Risk needs to be reviewed periodically.
M c v a (5--8): có th ch p nh n mi n là có thêm hành ng gi m thi u nó. R i ro Moderate risk (5--8): Tolerable with further action required to minimise risk. Risk needs to be
này c n c nh k xem xét. M c cao (9--12): có th ch p nh n mi n là có thêm reviewed periodically.
hành ng gi m thi u nó. R i ro này c n c liên t c xem xét. M c r t cao (15-- High risk (9--12): Tolerable with further action required to minimise risk. Risk needs to be
16): không c ch p nh n và ph i hành ng ngay gi m thi u nó. reviewed continuously.
M c c bi t cao (20--25): không c ch p nh n và ph i hành ng kh n c p Critical risk (15--16): Unacceptable risk and further action required immediately to minimise risk.
gi m thi u nó. Catastrophic (20--25): Unacceptable risk and urgent action required to minimise risk.
L-M C M T N SU T XU T HI N: L - LIKELIHOOD RATING:
Hi m khi x y ra (1): hi m khi x y ra tình hu ng này; Ít x y ra (2): khi có th x y Rare (1): the event may occur in exceptional circumstances; Unlikely (2): the event could occur
ra; V a ph i (3): th nh tho ng có x y ra; D x y ra (4): có kh x y ra trong sometimes; Moderate (3): the event should occur sometimes; Likely (4): the event will probably
s ng h p; H ch c ch n (5): s x y ra trong h u h ng h p. occur in most circumstances; Almost Certain (5): the event is expected to occur in most
S - H U QU C A TÌNH HU NG: circumstances.
Không k (1): không tích, không gây b nh; Nh (2): ch c n c u; S - SEVERITY RATING:
V a (3): ph i u tr y t , ti m b LTI; L n (4): tr thành i khuy t t t Insignificant (1): no injuries or health issues; Minor (2): first aid treatment; Moderate (3):
ho c m c b nh vi n; Nghiêm tr ng (5): t vong. medical treatment. potential LTI; Major (4): permanent disability or disease; Extreme (5): death.
JSA Form .xls Page 1/6

M I NGUY/ HAZARD L S R KI M / CONTROLS L S R T? / OK?
m b o m i thi t b dây th y l c, dây khí, m c

ki m tra và ki m nh (v i các thi t b
su t quá trình s d ng m b o thi t b trong tình
tr ng t t
Ensure tools/ equipment such as hydraulic
Thi t b không phù h p ho c b l i
hoses, air hoses, pumps are certified and must
Un proper, or defect tools and
be inspected (electrical and mechanical) prior to
Equipment
use to Ensure they are in good condition
Các thi t b ph i có ch ng ch và luôn s n sàng All

equipment certificates must be valid and
available
Quá trình chu n b , l p t v t thi t m b o kh ch u áp l c c a thi t b vàph ki n

b , máy móc và an toàn công ng phù h p v i yêu c u
Thi t b có kh i ng l n
c khi r a hóa ch t Set up and Ensure pressure capacity of equipment/
Heavy object lifting
hook up materials, tools, accessories comply to the requirement of test
equipments, and site safety pack
preparation before the chemical
cleaning operation.
i v i công vi c ph i th c hi n th công thì kh i
t i cho phép là 20kg
Thi t b có kh i ng l n
Apply manual handling technique, maximum
Heavy object lifting
allowable weight is 20kg per person. Two
persons per load max
Ki m tra các thi t b r i an toàn c khi

nâng h và tuân th quy trình nâng h , l p t
Các tai n n do t, v p
Check for loose objects on equipment and
ngã
secure before lifting and followed to the lifting
Slip, tripping, falling incident
and rigging procedure for all lifting activities
Ki m tra an toàn công ng c khi b t u công

Tai n n trong quá trình làm vi c
vi c
Personal injury due to manual
Site safety inspection to be carried out before
handling
start work

Trang b b o h lao ng (g ng tay, m b o h , qu n

Tai n n trong quá trình làm vi c áo chông hóa ch t, m t n c…) Used
Personal injury due to manual proper PPE (safety glove, safety helmet, safety
handling shoes, coverall, and chemical resistant suit, toxic
mask, boot)
Quá trình chu n b , l p t v t thi t

b , máy móc và an toàn công ng Ô nhi m môi tr ng do dò r Ch t h p th hóa h c/ gi lau/ khay c n chu n b s n
c khi r a hóa ch t Set up and hóa ch t phòng tr ng h p rò r hóa ch t Chemical
hook up materials, tools, Environment damage due to absorbents/ rags/ drip trays are available at site
equipments, and site safety chemical leaking, spills for use in case of spills
preparation before the chemical
cleaning operation. Giám sát và nhân viên an toàn c n có m t toàn
th i gian t i công ng
Phân công i không Site supervisors and Site safety officer are
công vi c hu n luy n No required full time at Site
competent person for the task
Giao nhi m v v i chuyên môn

Assigned person for the task only
Các thi t b c n c ki m tra c khi b t u công vi c.

S d a thi t b Hand tools shall
be inspected before start job. Only sufficient tool
Làm vi c v i thi t b c m tay to be used and right purpose.
Working with hand tools and
equipment
Ph i dùng tay cao su khi làm vi c v i hóa ch t
Ki m tra rò r và n c Rubber gloves will be worn when working with
Leak Test and Water Flushing chemical
Ch ý n v trí c th . Gi tay và chân xa các

khu v c nguy hi m.
Góc k t
Be aware of body placement. Keep hands and
Pinch point
feet away from areas that may have the potential
to crush or trap them

MSDS c dán công ng phòng nh ng ng

h p nguy hi m, x lý và c p c u.
i lao ng s c làm quen và t o làm vi c
v i hóa ch t
MSDS’s will be on the job site for hazard,
handling, disposal and first aid information.
Làm vi c và x lý hóa ch t Workers will be familiar and trained with the
T yd um chemicals they are working with
Chemical handling and
Degreasing
chemical disposal
Hóa ch t s c x lý theo xu t c a nhà s n xu t

và quy nh c a chính quy n a
Chemical will be disposed of according to
manufacture recommendations and local
authority regulations
T t c các kh p, m t bích, van c n c ki m tra trong

su t quá trình c và t y d u m và s a ch a
Rò r ngay khi tìm th y
Leaking All joints, flanges, valve shall be inspected for
leak during water flushing and degreasing and
corrected when found.

v i hóa ch t
Pickling MSDS’s will be on the job site for hazard,
Workers will be familiar and trained with the
Làm vi c và x lý hóa ch t
chemicals they are working with
chemical disposal
Hóa ch t s c x lý theo xu t c a nhà s n xu t

và quy nh c a chính quy n a
Chemical will be disposed of according to
manufacture recommendations and local
authority regulations


Làm vi c và x lý hóa ch t
Th ng và trung hòa v i hóa ch t
Passivation / neutralization MSDS’s will be on the job site for hazard,
chemical disposal
Workers will be familiar and trained with the
chemicals they are working with
ng tr c ti p v i hóa ch t ph i m c
ch ng hóa ch t, ng cao su, bao tay cao su
i b tai n n, nh ng b i kính trong su t quá trình làm vi c People
Th ng và trung hòa
hóa ch t directly working with cleaning chemical must
Passivation / neutralization
Personal injury, chemical impact wear plastic coverall, rubber boots, rubber
gloves and goggles at all time when working
near chemical
Ch ý v trí làm vi c, gi tay và chân xa các v trí

góc k t và tránh nh ng có kh có v t th
Không ng gi a t i và nh ng v t c nh
Be aware of body placement when working,
V trí nguy hi m và v t th r
keep hands and feet away from pinch point and
Pinch point, drop object
drop object areas that may have the potential to
crush or trap them. Never stand between a load
and a stationary object
Hoàn thành công vi c và d n d p

công ng
Complete job, clear site and Luôn s d ng pháp nâng h phù h p khi di
carried out house keeping Nâng h thi t b chuy n v t thi t b
Lifting Always use proper lifting technique moving
material and equipment
Di chuy n rác th i, bi n báo an toàn, v thi t

b ra kh i công ng và ti n hành v sinh làm
X lý ch t th i và hóa ch t vi c
Waste and Chemical disposal Remove barricade, safety sign, material,
equipment from site to sufficient place and
carried out good housekeeping

THI T B B O V NHÂN B T BU C (thêm ho c b t logo cho phù h p)/ Compulsory PPE (add or drop logos as appropriate)
XEM XÉT / HSE REVIEW:

Phi u JSA c so n phù h p v i Quy trình nh n bi t m i nguy và qu n lý r i ro, PL-01-009. Tôi xem xét và ng ý v i n i dung c a nó.
This JSA was prepared in accordance with the Procedure for Hazard Identification and Risk Management, PL-01-009. I have reviewed and agree with this JSA.
i xem xét/ Review by hàng / Customer
(Nhân viên an toàn/ HSE Officer) (N u có quy nh/ If specified)
[H tên]
[Ch ký]
[Ngày tháng]
I TH C HI N CÔNG VI C/ Workers (Those performing the Work):

Tôi hi u và s tuân theo c, m i nguy và bi n ki m ghi trong phi u JSA này. Tôi hi u r ng vi c th c hi n sai trình t c có th gây nên m i nguy
t ng c và phê chu n. N u ph m vi công vi c thay i ho c xu t hi n m i nguy m i, tôi s h i ý ki n i phê chu n c khi ti p t c th c hi n. Tôi
hi u quy n và v c a mình n u ph i d ng công vi c./ I understand and will adhere to the steps, hazards, and controls in this JSA. I understand that performing steps out of
sequence may pose hazards that have not been evaluated nor authorized. I will contact the person who authorized my work prior to continuing, if the scope of work changes or new
hazards are introduced. I understand my stop work authority and responsibility.
H tên/ Name Ký tên/ Signature Ngày/ Date H tên/ Name Ký tên/Sign. Ngày/ Date
I CHO TI N HÀNH CÔNG VI C (PH KHU V C)/ Releaser (Area

I PHÊ CHU N (CH HUY) CÔNG VI C / Authoriser (Supervisor):
Manager)
Tôi trao i thông tin v nh ng m i nguy c thù c a khu v c v i i phê
Tôi cùng m i i th c hi n công vi c có tên nêu trên ti n hành xem xét chu n công vi c / nh ng i th c hi n công vi c có tên nói trên và cho u
c, m i nguy và bi n ki m ghi trong phi u JSA này. Tôi phê duy t cho ph i công vi c này v i nh ng i ch u nh ng xung quanh. Nh ng i
h c th c hi n công vi c này. H có trình chuyên môn (ho c có ch ng ch th c hi n công vi c có tên nêu trên c tôi cho phép ti n hành công vi c này
c n thi t) và c ch ng nh n hoàn thành hu n luy n b t bu c v an toàn theo trong ph m vi nêu. Chú thích: Gi y phép làm vi c s ........ (n u ph i có).
quy nh c a nhà c, th c hi n công vi c này./ I have communicated unique area hazards with the authorizer or listed worker(s) and have
I have reviewed the steps, hazards and controls described in this JSA with all workers coordinated this job with affected occupants. Listed workers are released to perform
listed above and authorize them to perform the work. Workers are qualified (that is, described scope of work. Notes: PTW No ........(if specified).
licensed or certified, as appropriate, and in full compliance with compulsory training
requirements) to perform this activity.
H tên/ Name Ký tên/ Signature Ngày/ Date H tên/ Name Ký tên/Sign. Ngày/ Date

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Document No: Rev.

Document Title: Chemical Cleaning Procedures

Contract No.: PO 08607

03 31/05/2024 Issued for Review L.T.H.Nhung T.N.T V.T.S n/a

Supplier Logo : Accepted (code 1)

Not accepted, revise and resubmit (code 3)

Issued for information (code 4)

CHEMICAL CLEANING PROCEDURE

Rev Prepared by Approved by ALPHA Approved by Client Approved by C.A

Responsible: Project Management Team Document format: A4

Chemical Cleaning Procedure Document Number:

SECTION DESCRIPTION PAGE

3. REFERENCE DOCUMENTS AND STANDARD

2101-YINS-00-L-SA-00006_C3_Chemical Cleaning & Hot Oil Flushing Specification

Client : AZULE ENERGY

5. CHEMICAL CLEANING REQUIREMENTS

5.1. General Requirements

5.2. Chemical cleaning equipment and materials

Chemical Pump skid,

4. Iron High Range ISM 01 ea

7. Water jet pump, 3000 psi 02 set

Flexible chemical suction/discharge hose,

14. Pressure gauge 02 ea

16. Portable eyewash station 01 ea

17. Filter System with 50 mesh screen element 02 set

18. Hand tool 02 set

19. Flange and fitting 01 lot

Connection work shall be as follows:

The list of chemicals is as below:

7. PREPARATION FOR CHEMICAL CLEANING

8. CHEMICAL CLEANING MAIN STEPS

The chemical cleaning has three (3) main objectives:

The overall chemical cleaning will follow the following sequence.

Water leak test and Flushing

Chemical cleaning process diagram

8.1. Installation of temporary piping

8.2. Leak test and Flushing

8.3. Degreasing process

8.4. Acid cleaning/ Pickling process

8.5. Neutralization/ Passivation

8.6. Rinsing/ Drying

8.7. Chemical combination for each stage of the cleaning process

8.8. Inspection and Testing after Cleaning

9. ACCEPTANCE CRITERIA FOR CHEMICAL CLEANING

10. PROTECTION AFTER CHEMICAL CLEANING

Appendix 1: Chemicals – Material Safety Data Sheet

Appendix 2: Chemical Equipment Layout Diagram

Appendix 3: Chemical Cleaning Line List (P&ID)

Appendix 4: Chemical Cleaning JSA

A Geno Technology, Inc. (USA) brand name

Safety Data Sheet

think proteins! think G-Biosciences! www.GBiosciences.com

1.4. Emergency telephone number

SECTION 2: Hazard(s) identification

2.2. GHS Label elements, including precautionary statements

SECTION 3: Composition/Information on ingredients

06/28/2019 EN (English US) Page 1

SECTION 5: Fire-fighting measures

SECTION 6: Accidental release measures

6.1.2. For emergency responders