CLASS : XII

SUBJECT: MATHEMATICS, PHYSICS AND CHEMISTRY

TOPIC : JEE
DATE : 25.10.2024
MAX.MARKS:300

( x– )
1. (d) a
Given, equation of hyperbola 2x2 + 5xy + 2y2 + 4x + 5y = 0 2
and equation of asymptotes  y = 2ax – a  y = 2a
2 2 2

2x2 + 5xy + 2y2 + 4x + 5y +  = 0 ...... (i)  y = 4AX

2
{4A = 2a , A = a/2}
which is the equation of a pair of straight line. We know that which is parabola with directrix X = – A
the standard equation of a pair of straight lines is ax 2 + 2hxy + x – a/2 = – a/2  x = 0
by2 + 2gx + 2fy +c = 0. Comparing equation (i) with standard
equation, we get a = 2, b = 2, h = 5/2, g = 2, f = 5/2 and c = . 6. (c)
We also known that the condition for a pair of straight lines is Here PS = RS = 2
abc + 2fgh - af2 - bg2 - ch2 = 0.  PQ is major Axis
25 25
Therefore 4 + 25 - 2 - 8 - 4  = 0.
9λ 9
− + =0
or 4 2 or  = 2. Substituting value of  in
equation (i), we get
2x2 + 5xy + 2y2 + 4x + 5y + 2 = 0. 7. (c)
x y
2. (b) a b
Equation tangent at the point  is sec  – tan  = 1. It
A(a, 2a)
meets the transverse axis y = 0 and the tangent at vertex x =

V VB = AB
a in the point Q (a cos , 0) and R
[ a,
b (1−cosθ )
sin θ ]
. If (h, k) is
mid point of QR then 2h = a + a cos 
B(at2, 2at)
2h−a b(1−cos θ )
cos  = a and 2k = θsin
3. (a) 
Extremities of the latus-rectum are (2, 4) and (2, –4).
ab(1−cos2 θ )
Since any circle drawn with any focal chord as it’s
and 4hk = sin θ = ab sin 
diameter touches the directrix. Thus equation of  16h2k2 = a2b2 (1 – cos2 )

[ ( )]
required circle is (x – 2) 2 + (y – 4) (y + 4) = 0, i.e., x 2 + 2
2 h−a
y2 – 4x – 12 = 0, it’s radius is 1−
a
√ 4 +12 = 4. 2 2
b
=a
4.
(a)  4hk2 + b2h = b2a locus x(4y2 + b2) = ab2
  = 1, k = 4, m = 1
2
The parabola is y = k
( x– )
6
K &
k2 – ( + m)2 = (4)2 – (1 + 1)2 = 16 – 4 = 12.

6 K 6 K 8. (d)
– –
Dirctrix x – K = 4 x = K 4 
( x−1 )2 ( y −2)2
Which coincides with line x = ½ + =1
6 K 1 9 4 Equation of normal to ellipse
2 2
 K – 4 = 2  K2 + 2K – 24 = 0 X Y
 (K + 6) (K – 4) = 0  K = – 6, K = 4
+ =1
9 4
3X sec - 2Y cosec = 5
5. (c) 3
The focus of the parabola y2 = 4ax is S(a, 0).
Let P(at2, 2at) be any point on the parabola. The Slope of normal 2 tan = 3  tan = 2
mid-point of SP is given by 2 1
a(t 2 +1 ) 2 at+0  = √ 5 , cos = √ 5
x= 2 , y= 2 = at sin

[ ] √ √
2
y y2 So normal is 3 5 X - 5 Y = 5
2
+1
 2x = a a = a +a Now X = x - 1, Y = y - 2.
So 3 √ 5 (x - 1) - √ 5 (y - 2) = 5
64A, SAKTHI NAGAR, GANDHIGRAMAM SOUTH, KARUR-639004. MOBILE ; 8838315600
 CLASS : XII
SUBJECT: MATHEMATICS, PHYSICS AND CHEMISTRY
TOPIC : JEE
DATE : 25.10.2024
MAX.MARKS:300

√ 5 (3x - y) = 5(√ 5 + 1) i.e., 4 x+8 y−9 a=0 .

3x – y = √ 5 (√ 5 + 1).
( x +1)2 ( y +2 )2
+ =1
9. (a) 225 225
x2 y 2 15. (a) 25 9
a2 – b2 = 1 a=
√ 225 15
25
= , b=
5 9
=
√
225 15
3 
9 4
e= 1− =
25 5 √
Focus
(
= −1 ,−2±
15 4
)
. =(−1 ,−2±4 )
3 5 =(–1,2); (–1,–6) .

16. (a)
The coordinates of the ends of the latus rectum of the
Locus of the point of intersection of two  tangent is director 2
circle. parabola y =4 ax are (a, 2a) and (a,−2a) respectively.
equation of director circle x2 + y2 = a2 – b2 The equation of the normal at (a, 2a) to y 2 =4 ax is

10. (b)Tangent at P (x1 , y1) on xy = c2 is

y−2a=
−2 a
2a {
(x −a ) using y− y 1 =
− y1
2a
( x−x 1 ) }
Or x + y−3 a=0 .....(i)
Similarly the equation of the normal at (a, –2a) is
+ =2 x− y −3 a=0 .....(ii)
 Q = (2x1, 0), R = (0, 2y1)
The combined equation of (i) and (ii) is
Now OQR is a right  and QR is the hypotenuse.
 circumcentre = mid pt, of QR = (x1, y1) x 2 − y 2−6 ax+9 a2 =0
17.(a)
y
=t 2 y−1
11. (d) Here 2 and x−2=t 2
= x – 1, t = 2
( )  y =4 ( x−2 ).
2
y
( x−2 )= 2 t
2
( )
 y−1 2
=( x−1)⇒( y −1)2 =4 ( x−1)
2
12. (c) ( x+2)2 =−2( y−2 ) 
1 3  The equation directrix is x – 1 = -1 x = 0.
y−2=− y=
Equation of latus rectum is 2  2.
18. (b)
Tangent of parabola y2 = 4ax is y = mx + a/m, which also
13. (a) m=tan θ=tan 60 °= √3 touches to the parabola
2 x2 = 4by a/m = – bm2  m = –(a/b)1/3
The equation of tangent at (h,k ) to y =4 ax is
yk=2 a( x +h ) 19. (d)
2a Let coordinates of P be (a cos, b sin ),
2a k=
m= √ 3= SS' = 2ae, PS = a (1-e cos) and PS' = a(1+e cos)
Comparing, we get k or √3 and  Coordinates of the incentre is given by
a 2 ae. a cosθ−aea ( 1−e cosθ ) +ae. a (1+e cosθ )
h=
3. x= 2 a ( 1+e ) =
a2 e [ 2 cosθ−1+e cosθ+1+e cosθ ]
=ae cos θ
2a ( 1+e )
14. (b)
x+2 y=4 . 2 ae . b sinθ be
= sin θ
and y =

a 9a 9a 2 a ( 1+e ) 1+e  Locus of the incentre of the

2 y + x=2 a+ = 2 y +x− =0
 4 4  4 triangle PS'S is

64A, SAKTHI NAGAR, GANDHIGRAMAM SOUTH, KARUR-639004. MOBILE ; 8838315600

 CLASS : XII
SUBJECT: MATHEMATICS, PHYSICS AND CHEMISTRY
TOPIC : JEE
DATE : 25.10.2024
MAX.MARKS:300

x2 y 2 ( 1+ e )2 m2 =  –2
+ Now, (m2 – )2 + 4m2 = 8
a2 e 2 b2 e2 =1 so ( – 2 – )2 + 4( – 2) = 8
x2 y 2 ( 1+e )2 =3
2 2
+ 2 2 So  +  = 3 + 0
or a e a e ( 1+e ) (1−e ) =1
( 1−e ) x 2 + ( 1+e ) y 2=a2 e 2 22.1
or 1
y = mx + is tangent to y2 = 4x
m
20.(b) x2-y2 = a2+ b2
1 32
Now,x2+ 32(mx+ ) = 0 ⇒x2+ 32mx +
m m
=0
2 4 × 32 1
⇒ ( 32 m ) − =0 ⇒ m=
m 2
Equation of the tangent is x- 2y + 4 = 0
⇒| sin-1 (sin 1) + sin-1 (sin(-2)) + sin-1 (sin
4) |
=|1+2- π + π -4|=1

Let the equation of tangents are

8 4
y = m1x + C1, and 3 a +3 b
23.(b) Minimum value of ∀a,b∈R
y = m2x+ C2 4 2
a b
which cuts the coordinate axes at E, F, G, Given, a2=25 and b2=16

√ √
H as shown in the figure
Now, OE x OG = OF x OH b2 16 3
∴ e= 1− 2 = 1− =
25 5
( )( )
−C1 +C 2 a
⇒ × = ( C1 ) (−C 2 ) ⇒ m1 m2=1 2
Given, a =25 and b = 16 2
m1 m2
Let P be (h, k) and equation of the tangent
through P on the hyperbola is
y=mx ± √ a 2 m2−b 2
∴ e= 1−
√ √ b2
a
2
16 3
= 1− =
25 5
So, the coordinates of foci S and S' are (3,
⇒(k2-mh)2= (a2m2-b2) 0) and (-3, 0) respectively.
Let, P (5 cos θ , 4 sin θ ) be a variable point
⇒(h2- a2)m2- 2khm + k2+ b2= 0
2 2 on the ellipse.
k +b Then, Δ = area of Δ PSS' =
whose roots are m1and m2¿ 2 =1

| |
2
h −a 3 0 1
⇒locus is x2 - y2 = a2 + fr2 1
−3 0 1 =12 sinθ
2
5 cos θ 4 sin θ 1
21. Ans. 0003
Since the value of sin θ lies between -1
Sol. and 1
By symmetry, circle must be centred on x axis. So, the maximum value of area of Δ PSS' is
so  = 0 12 sq. units
Also, a8 + b4≥2a462 (since, A.M ≥ G.M)
3 ( a8 + b4 )
⇒ 4 2
≥6
a b

24.1.5

Now, normal to y2 = 4x at p(m2, –2m) is

y = mx – 2m – m3
(, 0) must lie on it  m( – 2) – m2 = 0
64A, SAKTHI NAGAR, GANDHIGRAMAM SOUTH, KARUR-639004. MOBILE ; 8838315600
 CLASS : XII
SUBJECT: MATHEMATICS, PHYSICS AND CHEMISTRY
TOPIC : JEE
DATE : 25.10.2024
MAX.MARKS:300
3 5 5
n1 c v + n2 c v 2× R+1× R 3 R+ R
1 2 2 2 2
n 1 +n2 = (cv)mix = 2+1 = 3
11 R
6
=

27. (d)
PdV
C=C V +
dT
PdV α
( ) ( )
1
Let A= t , & B= , t
t
1
t
ndT = T
nRT dV α
{ ∵ Both curves aresymmetric about line y=x } nv dT = T

( ) ( )
2 2
2 1 1 dV α dT
then, ( AB ) = t− + −t =14 ∫ V = R∫ T2
t t

( )
2 1
⇒ 2 t + 2 =14+ 4 ⇒ t + 2 =9
t
2 1

t nV = – RT
α
+ n C
2 2 1 2
V
Now, ( OA ) =t + 2 =9 ⇒ ( 2 r ) =9 C = e–/RT
t
Ve/RT = C
⇒|2r|=3 ⇒|r|=1.5
28. (a)
Work done by the system = Area of shaded portion on
25.(20)
Let common tangents are P-V diagram
= (300 – 100) 10–6 × (200 – 10) × 103 = 20 J

29. (a)
So, 4m2 + 9 = 42m2 - 143 From calorimetry principle Qice = Qwater
mL + m (T– 0) = m (100 – T)
80 + T = 100 – T
& 2T = 20 , T = 10
For given tangent not pass through 4th
quadrant
T:y = 2x + 5 30. (a)
IV P = Constant & III  isothermal

Now, comparing with 31. (c)

Average degree of freedom
We get, 2×3+1×5 11
=
fav = 2+3 5
1 5 16
2x-y = -5 we nave
f
mix = 1 + av = 1 + 11 = 11 = 1.4
Hence, C is correct Answer.

So, 32. (b)

Work done )
26. (b)

64A, SAKTHI NAGAR, GANDHIGRAMAM SOUTH, KARUR-639004. MOBILE ; 8838315600

 CLASS : XII
SUBJECT: MATHEMATICS, PHYSICS AND CHEMISTRY
TOPIC : JEE
DATE : 25.10.2024
MAX.MARKS:300
π
πr 1 r 2 39.(d)
= 2 = 2 ×1 × 1 atm-litre
π
= 2 atm –litre

33. (a)
From A : Q > 0, U = 0, W > 0
From B : Q < 0, U = 0, W < 0

34. (a)
Both are molar specific heat
40.(c)
that's why x = y
An isothermal process is a thermodynamic
process in which the temperature of a system
35. (c) remains constant. The transfer of heat into or
(slope )adi Cp out of the system happens so slowly that
=γ =
( slope)isothernal Cv thermal equilibrium is maintained.
 .
According to first law of thermodynamics,
36. (b): Mass of the gas ¿ m .
At a fixed temperature and pressure,
= PΔV
41. (b): Work done, W
volume is fixed. Density of the gas
m m m = 2×105 (150−50)×10−3
P= =≻ = =x
V V . P nRT ¿2×10 4 J
xT =¿ constant.
42. (c)For an ideal gas, the no of molecules in 1 mole of all gas at
At 1 0o C i. e., 283 K ,
is same .
xT =x 283 K
At 110 o C , xT =x ' 383 K
283 43. (b) W = Area unden P –V curre
'
¿≻ x = x
383 W = P –V
= (P2 – P1) × (V2 – V1)
37.(b)
PVr = const.TV[−1const = P V for contant pressure
= P V
const = 105 (2 – 1) m3
= 105 J

38.(a)
PV - nRT 44. (a)

45. (b)

64A, SAKTHI NAGAR, GANDHIGRAMAM SOUTH, KARUR-639004. MOBILE ; 8838315600

 CLASS : XII
SUBJECT: MATHEMATICS, PHYSICS AND CHEMISTRY
TOPIC : JEE
DATE : 25.10.2024
MAX.MARKS:300

< 1 or C 1< C 2 Give C2 = 1M.

 C1 should be the minimum conc. of H+.
46. Ans.0001
(b) is the right answer.
Sol. Work done by gas

π.
( 400
π
×10 )
3

×
(20×10 –6
)
J
54. (d)

= 2 2
=1J

(P) EºFe3+, Fe
47. Ans.0500
Sol.U = n CvT  1 × 0.77 + 2 × (– 0.44) = 3 × x

48.(25)  x=– V ~ – 0.04 V.

Pressure is not changing isobaric (Q) 4H2O 4H+ + 4OH–
process
2H2O  O2 + 4H+ + 4e– –
1.23 V
+ O2 + 2H2O + 4e–4OH– + 0.4 V
and

_____________________________________
49.3 4H2O 4H+ + 4OH–
– 0.83 V
(R) Eº(Cu2+ + Cu  2Cu+)

x × 1 + 0.52 × 1 = 0.34 × 2
x = 0.16 V.
 Cu2+ + e–  Cu+ 0.16 V
+ CuCu+ + e– – 0.52 V
50.(1400)
______________________________________________________________

Cu2+ + Cu 2Cu+ – 0.36 V

51. (c) However, in the given option, – 0.18 V is
1 1 printed.
κ= ×cell constant= ×0 . 47=0 . 015 S cm−1 .
R 31 .6

52. (c)
In the molten state ICl3 ionises as follows (s) Eº(Cr3+, Cr2+)
x × 1 + 2 × (– 0.91) = 3 × (– 0.74)
2ICl3 ICl2+ + ICl4–
Hence both I2 and Cl2 are produced at both the electrodes. x – 1.82 = – 2.22
 x = – 0.4 V
Hence, most appropriate is (d).
(P) – (c) ; (Q) – (d) ; (R) – (a) ; (S) – 2.
53. (b)Ecell = 0.059 log
55. (c)
For Ecell to be +ve and maximum
64A, SAKTHI NAGAR, GANDHIGRAMAM SOUTH, KARUR-639004. MOBILE ; 8838315600
 CLASS : XII
SUBJECT: MATHEMATICS, PHYSICS AND CHEMISTRY
TOPIC : JEE
DATE : 25.10.2024
MAX.MARKS:300
56. (a)
Rest all show less tendency to donate electron pair due to
resonance.
65. (b):
57. (b)
Total current passed in 30 sec.
1 1 ohm
= 2 × 100 × 10 + 100 × 10 + 100 × 10 + 2
× 100 × 10 Cell Constant
= 3 × 100 × 10 mA × s
= 3000 × 10–3 amp s = 3 C
EQ W E m
F or Q = F = Z = 3
W= 66. (c) :
Al 2 O3 →2 Al
2 Al 3+ + 6 e− →2 Al
58. (c)
Equivalent of Al = Equivalent of Cu = Equivalent of ∴ Al 3+ + 3 e− → Al
Na Thus, 3 F of charge is required to obtain 1 mole of Al from
1 1 Al 2 O3
or mole Al = 2 mole Cu = 1 mole Na
3
or 2 : 3 : 6 or 1 : 1.5 : 3 mole ratio 67. (b) : Lower the value of reduction potential stronger is the
reducing agent i.e., undergoes oxidation most easily.
59. (a)E0 is intensive property and it does not depend on mass of Cr →Cr 3+ +3 e− (oxidation)
F2 taking part. Hence, Cr is the strongest reducing agent.

Eº
MnO−
4 2+
60. (a)Ecell +  68. (d) : |Mn has highest reduction potential hence,
2+
0.15 — 0.77 = – 0.62 V Mn is the most stable reduced species.

69. (c)
61. (b) HCl is an electrolyte. 70. (c)
71. 0.059 volt
62. (c) According to Faraday’s law.
Sol. H2 2H+ + 2e–
0 . 059 ( Zn++ ) 0.1M and = 1 atm
E cell =Eocell − log
63. (a) 2 (Cu++ )
0 .059 0.1 Eoxidation= 0 – log ( )2 = + 0.0591 × 1 =
=1 . 10− log =1. 10 V
2 0.1 . 0.0591 volt

72. Ans.– 13.842 kJ mol–1

64. (d): Mn;
67 . 2
;
73. Sol. Moles of H2 reacting = 22 . 4 = 3
For the cell,  Equivalent of H2 used = 3 × 2 = 6
; w i t
Now, E = 96500
Since the value is negative, so the i×15×60
process is non‐spontaneous.
 6 = 96500

64A, SAKTHI NAGAR, GANDHIGRAMAM SOUTH, KARUR-639004. MOBILE ; 8838315600

 CLASS : XII
SUBJECT: MATHEMATICS, PHYSICS AND CHEMISTRY
TOPIC : JEE
DATE : 25.10.2024
MAX.MARKS:300
i = 643.33 ampere
Also, equivalent of H2 = equivalent of Cu formed
 Equivalent of Cu deposited = 6
63 . 5
 wCu = 6 × 2 = 190.5 g
Thus, wt. of Cu deposited = 190.5 g

74. Ans. Increased by 0.01 V.

75.(10)
Pt(s)|H2(g, latm)|
H+ (aq, lM) || Fe3+ (aq), Fe2+ (aq) | Pt (s)
at anode H2 2H+ +2e-
At cathode

64A, SAKTHI NAGAR, GANDHIGRAMAM SOUTH, KARUR-639004. MOBILE ; 8838315600