Latihan Chapter 1

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MODUL 1

CHM3233
KETONE AND ALDEHYDE

1. Give the IUPAC name for the following compounds

O O O

O
O
O

H OH Cl
H H
O NH2
O NH2 O

NH2 OH
O
Br O Br O

OH OH
H

O
Cl O Cl O

O
O Br O

O
O O NH2

H H

O O
O
Br
H Br Br
H
Br O
OH O OH O

2. Draw the product of the following compounds.

NaBH4
CH3NH2

LiAlH4
CH3MgBr
H2O
1 eq CH3OH
O
ex CH3OH

-CN Ph3P-CHCH3
HCl

NH(CH3)2

NaBH4
CH3NH2

LiAlH4
CH3MgBr
H2O H
1 eq CH3OH
ex CH3OH O

-CN Ph3P-CHCH3
HCl

NH(CH3)2
NaBH4
CH3NH2

LiAlH4
CH3MgBr O
H2O
1 eq CH3OH
ex CH3OH

-CN Ph3P-CHCH3
HCl

NH(CH3)2

NaBH4
CH3NH2

LiAlH4
CH3CH2MgBr O
H2O
H 1 eq CH3CH2OH
ex CH3OH

-CN Ph3P-CHCH3
HCl

NH(CH3)2

3. Draw the reaction mechanism of the following compounds.


O O

H 1 eq. CH3CH2OH 1 eq. CH3CH2OH


H+ H+

O O

H 2 eq. CH3CH2OH HO OH
H+ H+

O O

H
NH(CH3)2 NH(CH3)2
H+ H+

O O

H NH2CH2CH3 NH2CH2CH3
H+ H+

O H3CO OCH3

1 eq. CH3CH2OH H2O


H+ H+

O O

HO OH PH3P-CHCH3

H+

O O

NH(CH3)2 NH(CH2CH3)2
H+ H+

NH2CH2CH3 O H2O
O
H+ H+

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