SafetyDataSheet (SDS) BONDERITEL-MRB-415 EnglishUnitedStates 08152022

Download as pdf or txt
Download as pdf or txt
You are on page 1of 5

Safety Data Sheet

Revision Number: 002.0 Issue date: 08/15/2022

1. PRODUCT AND COMPANY IDENTIFICATION


Product name: BONDERITE L-MR B-415 IDH number: 1916190
Product type/use: Water Soluble Cooling Lubricants for
Metal Working
Restriction of Use: None identified Region: United States
Company address: Contact information:
Henkel Corporation Telephone: +1 (860) 571-5100
One Henkel Way MEDICAL EMERGENCY Phone: Poison Control Center
Rocky Hill, Connecticut 06067 1-877-671-4608 (toll free) or 1-303-592-1711
TRANSPORT EMERGENCY Phone: CHEMTREC
1-800-424-9300 (toll free) or 1-703-527-3887
Internet: www.henkelna.com

2. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
DANGER: CAUSES SKIN IRRITATION.
MAY CAUSE AN ALLERGIC SKIN REACTION.
CAUSES SERIOUS EYE DAMAGE.

HAZARD CLASS HAZARD CATEGORY


SKIN IRRITATION 2
SERIOUS EYE DAMAGE 1
SKIN SENSITIZATION 1

PICTOGRAM(S)

Precautionary Statements

Prevention: Avoid breathing vapors, mist, or spray. Wash affected area thoroughly after handling.
Contaminated work clothing should not be allowed out of the workplace. Wear protective
gloves, eye protection, and face protection.
Response: IF ON SKIN: Wash with plenty of water. IF IN EYES: Rinse cautiously with water for several
minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If skin irritation or
rash occurs: Get medical attention. Take off contaminated clothing.
Storage: Not prescribed
Disposal: Dispose of contents and/or container according to Federal, State/Provincial and local
governmental regulations.

Classification complies with OSHA Hazard Communication Standard (29 CFR 1910.1200) and is consistent with the provisions of the
United Nations Globally Harmonized System of Classification and Labeling of Chemicals (GHS).

See Section 11 for additional toxicological information.

3. COMPOSITION / INFORMATION ON INGREDIENTS


Hazardous Component(s) CAS Number Percentage*
Distillates (petroleum), hydrotreated
64742-52-5 10 - 30
heavy naphthenic
Boric acid compound with
860382-11-2 5 - 10
dicyclohexylamine (1:1)
N,N,N',N'-Tetramethyl-2,2'-
3033-62-3 1-5
oxybis(ethylamine)
Monoethanolamine 141-43-5 0.1 - 1
IDH number: 1916190 Product name: BONDERITE L-MR B-415
Page 1 of 5
Preservative Proprietary 0.1 - 1

* Exact percentages may vary or are trade secret. Concentration range is provided to assist users in providing appropriate protections.

4. FIRST AID MEASURES


Inhalation: If inhaled, immediately remove the affected person to fresh air. If symptoms
develop and persist, get medical attention.

Skin contact: Immediately wash skin thoroughly with soap and water. If symptoms develop
and persist, get medical attention.

Eye contact: In case of contact with the eyes, rinse immediately with plenty of water for 15
minutes, and seek immediate medical attention.

Ingestion: Get medical attention. DO NOT induce vomiting unless directed to do so by


medical personnel.

Symptoms: See Section 11.

Notes to physician: This material, if aspirated into the lungs, may cause chemical pneumonitis;
treat the affected person appropriately.

5. FIRE FIGHTING MEASURES


Extinguishing media: Water spray (fog), foam, dry chemical or carbon dioxide.

Special firefighting procedures: Wear full protective clothing. Wear self-contained breathing apparatus.

Unusual fire or explosion hazards: This product is an aqueous mixture and although it will exhibit a flash point, it
will not support combustion.

Hazardous combustion products: Upon decomposition, this product may yield gaseous nitrogen oxides, carbon
monoxide, carbon dioxide and/or low molecular weight hydrocarbons.

6. ACCIDENTAL RELEASE MEASURES


Use personal protection recommended in Section 8, isolate the hazard area and deny entry to unnecessary and
unprotected personnel.

Environmental precautions: Prevent further leakage or spillage if safe to do so. Wear appropriate
protective equipment and clothing during clean-up. Do not allow product to
enter sewer or waterways.

Clean-up methods: Absorb spill with inert material. Shovel material into appropriate container for
disposal. Dispose of according to Federal, State and local governmental
regulations.

7. HANDLING AND STORAGE


Handling: Avoid contact with eyes, skin and clothing. Wash thoroughly after handling.
Avoid breathing vapors or mists of this product. For industrial use only. Do not
mix this product with fluids which contain NITRITES/NITRATES.
NITROSAMINE may be formed.

Storage: For safe storage, store between 5 °C (41°F) and 38 °C (100.4 °F)

For information on product shelf life, please review labels on container or check the Technical Data Sheet.

IDH number: 1916190 Product name: BONDERITE L-MR B-415


Page 2 of 5
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Employers should complete an assessment of all workplaces to determine the need for, and selection of, proper
exposure controls and protective equipment for each task performed.

Hazardous Component(s) ACGIH TLV OSHA PEL AIHA WEEL OTHER


5 mg/m3 PEL Mist.
Distillates (petroleum), hydrotreated 5 mg/m3 TWA
500 ppm (2,000 None None
heavy naphthenic Inhalable fraction.
mg/m3) PEL
Boric acid compound with
None None None None
dicyclohexylamine (1:1)
0.05 ppm TWA
N,N,N',N'-Tetramethyl-2,2'-
0.15 ppm STEL None None None
oxybis(ethylamine)
(SKIN)
6 ppm STEL 3 ppm (6 mg/m3)
Monoethanolamine None None
3 ppm TWA PEL
Preservative None None None None

Engineering controls: Provide local and general exhaust ventilation to effectively remove and
prevent buildup of any vapors or mists generated from the handling of this
product.

Respiratory protection: If ventilation is not sufficient to effectively prevent buildup of aerosols, mists or
vapors, appropriate NIOSH/MSHA respiratory protection must be provided.

Eye/face protection: Wear safety glasses; chemical goggles (if splashing is possible).

Skin protection: Chemical resistant, impermeable gloves. Gloves should be tested to


determine suitability for prolonged contact. Use of impervious apron and boots
are recommended.

9. PHYSICAL AND CHEMICAL PROPERTIES


Physical state: Liquid
Color: Amber
Odor: Amine
Odor threshold: Not available.
pH: 9.67
Vapor pressure: Not determined
Boiling point/range: 100 °C (212°F)calculated
Melting point/ range: Not applicable
Specific gravity: 0.970
Vapor density: Not determined
Flash point: Not determined
Flammable/Explosive limits - lower: Not determined
Flammable/Explosive limits - upper: Not determined
Autoignition temperature: Not determined
Flammability: Not applicable
Evaporation rate: Not applicable
Solubility in water: Disperses in water as emulsion
Partition coefficient (n-octanol/water): Not determined
VOC content: Not determined
Viscosity: 240 mPa.s
Decomposition temperature: Not available.

10. STABILITY AND REACTIVITY


Stability: Stable at normal conditions.

Hazardous reactions: None under normal processing.

Hazardous decomposition Upon decomposition, this product may yield gaseous nitrogen oxides, carbon monoxide,
products: carbon dioxide and/or low molecular weight hydrocarbons.

Incompatible materials: Nitrites may react with organic amines to form nitrosamines which can cause cancer.

Reactivity: This product may react with strong acids or oxidizing agents.

Conditions to avoid: Keep away from heat, ignition sources and incompatible materials.

IDH number: 1916190 Product name: BONDERITE L-MR B-415


Page 3 of 5
11. TOXICOLOGICAL INFORMATION
Relevant routes of exposure: Skin, Inhalation, Eyes, Ingestion

Potential Health Effects/Symptoms

Inhalation: This product is irritating to the respiratory system.


Skin contact: This product is irritating to the skin. May cause skin sensitization.
Eye contact: This product is severely irritating to the eyes and may cause irreversible damage including
burns and blindness.
Ingestion: Ingestion may cause gastrointestinal irritation, nausea, vomiting and diarrhea.

Hazardous Component(s) LD50s and LC50s Immediate and Delayed Health Effects
Inhalation LC50 (Rat, 4 h) = > 4.026 mg/l
Inhalation LC50 (Rat, 4 h) = 2.18 mg/l
Distillates (petroleum), hydrotreated
Inhalation LC50 (Rat, 4 h) = 10.5 mg/l Irritant
heavy naphthenic
Inhalation LC50 (Rat, 4 h) = > 5.2 mg/l
Inhalation LC50 (Rat, 4 h) = < 5.7 mg/l
Irritant, Skin, Gastrointestinal, Central
Boric acid compound with
None nervous system, Reproductive,
dicyclohexylamine (1:1)
Developmental, Blood
Inhalation LC50 (Rat, 4 h) = 4 mg/l
N,N,N',N'-Tetramethyl-2,2'-
Inhalation LC50 (Rat, 4 h) = 16 mg/l Irritant, Kidney, Eyes
oxybis(ethylamine)
Inhalation LC50 (Rat, 4 h) = > 2.204 mg/l
Oral LD50 (Rat) = 10.2 g/kg
Irritant, Kidney, Liver, Corrosive, Respiratory,
Monoethanolamine Oral LD50 (Mouse) = 700 mg/kg
Developmental
Dermal LD50 (Rabbit) = 1,025 mg/kg
Preservative Inhalation LC50 (Rat, 4 h) = 1.08 mg/l Irritant

OSHA Carcinogen
Hazardous Component(s) NTP Carcinogen IARC Carcinogen
(Specifically Regulated)
Distillates (petroleum), hydrotreated
No No No
heavy naphthenic
Boric acid compound with
No No No
dicyclohexylamine (1:1)
N,N,N',N'-Tetramethyl-2,2'-
No No No
oxybis(ethylamine)
Monoethanolamine No No No
Preservative No No No

12. ECOLOGICAL INFORMATION


Ecological information: Do not empty into drains, soil or bodies of water.

13. DISPOSAL CONSIDERATIONS


Information provided is for unused product only.

Recommended method of disposal: Dispose of according to Federal, State and local governmental regulations.

14. TRANSPORT INFORMATION


The transport information provided in this section only applies to the material/formulation itself, and is not specific to any
package/configuration.

U.S. Department of Transportation Ground (49 CFR)

Proper shipping name: Not regulated


Hazard class or division: None
Identification number: None
Packing group: None

International Air Transportation (ICAO/IATA)

IDH number: 1916190 Product name: BONDERITE L-MR B-415


Page 4 of 5
Proper shipping name: Not regulated
Hazard class or division: None
Identification number: None
Packing group: None

Water Transportation (IMO/IMDG)

Proper shipping name: Not regulated


Hazard class or division: None
Identification number: None
Packing group: None

15. REGULATORY INFORMATION


United States Regulatory Information

TSCA 8 (b) Inventory Status: All components are listed as active or are exempt from listing on the Toxic Substances
Control Act (TSCA) inventory.
TSCA 12 (b) Export Notification: None above reporting de minimis

CERCLA/SARA Section 302 EHS: None above reporting de minimis.


CERCLA/SARA Section 311/312: Immediate Health, Delayed Health
CERCLA/SARA Section 313: None above reporting de minimis.

California Proposition 65: This product contains a chemical known in the State of California to cause cancer. This
product contains a chemical known to the State of California to cause birth defects or other
reproductive harm.

Canada Regulatory Information

CEPA DSL/NDSL Status: One or more components are not listed on, and are not exempt from listing on either the
Domestic Substances List or the Non-Domestic Substances List.

16. OTHER INFORMATION


This safety data sheet contains changes from the previous version in sections: New Safety Data Sheet format.

Prepared by: Regulatory Affairs

Issue date: 08/15/2022

DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel
Corporation and its affiliates (“Henkel”) does not assume responsibility for any results obtained by persons over whose methods
Henkel has no control. It is the user’s responsibility to determine the suitability of Henkel’s products or any production methods
mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and
persons against any hazards that may be involved in the handling and use of any Henkel’s products. In light of the foregoing,
Henkel specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular
purpose, arising from sale or use of Henkel’s products. Henkel further disclaims any liability for consequential or incidental damages
of any kind, including lost profits.

This Safety Data Sheet has been generated based on OSHA Hazard Communication Standard (29 CFR 1910.1200) and provides
information in accordance with U.S. federal law only. No warranty or representation of any kind is given with respect to the
substantive or export laws of any other jurisdiction or country. Please confirm that the information provided herein conforms to the
substantive export or other law of any other jurisdiction prior to export. Please contact Henkel Product Safety and Regulatory
Affairs for additional assistance.

IDH number: 1916190 Product name: BONDERITE L-MR B-415


Page 5 of 5

You might also like