Bonds, Vespr

Download as pdf or txt
Download as pdf or txt
You are on page 1of 3

Hybridization

Metal/Non-Metal

Steal e-

Brings ions together, releases


Creates Lattice
energy that's greater than
lattice Energy
IE & EA to create ions

1 low IE + 1 High EA
Ionic Bonds
Electronic
Lose e-
Geometry Cation
Look @ atoms and all e- (+) charge

Gain e-
Anion
Molecular VSEPR (-) charge
Geometry
Only look 2 atoms High MP/BP, dissolve polar solvents

Lone pairs REPEL


Non-metal + Non-metal
more than Bonding e-
Share e-
Underachiever Bonds With Non-Polar
Lewis Dot Always Non-Polar
Molecules with Bonds
Overachiever Covalent Bonds
Exceptions
Odd Ball With Polar Bonds Depends

σ Allows for free rotation


B/w molecules
π No FREE rotation
H-Bond in
Phase Changes
Metallic Bonds Sea of e-
Strong Interaction 1. Ion-Ion

You can have a non- Intermolecular Both e- came Typically Lewis


polar molecule with Interactions Coordinate from 1 atom Base + Acid Reaction
polar bonds Covalent Bonds Lone pair +
2. Dipole-Dipole unhybridized orb
1. Need an EN (NOF) attached to H

2. Needed EN with lone pair Hydrogen


Bonding
With an EN stripping an e-, H Types
basically becomes a proton.

Interactions

3. London Disperson/
randomly more e- found on
Van Der Waals
one side → induce charge

non-polar molecule induces "


temporary" dipole on another
non-polar molecule

Within same Intramolecular


molecule Interactions
V = normal # of e-

# of shared e- pairs
More Positive = Look @ |#'s| &
Formal Charge Bond Order
More Imbalanced Add

FC: underestimates EN

Oxidation State: More bonds = Shorter


overestimates EN effects
Bond Length
Bond Length

Covalent
H, N, O, F, Cl, Br, I Non-Polar Covalent Non Polar vs. Polar More energy needed =
Bonds
Covalent Energy required More shared e-
Dipole Moment Polar Covalent Bond Energy
to break bonds Higher bond energy =
Stronger bond

Lewis Relative difference in EN


Structure Polarity
More EN = More e- density
VSEPR Chart

You might also like