RYESTION DANK SECTION-A Multiple-Choice Questions Amides can be converted j ines by th nto ami i : i ’y the reaction named by Castilaenice (b) Ammonolysis . (A) Diazotisati i Which of the following Sola ‘isation (CBSE Delhi 2023) (@) LiAlH, not be a good a rues nitrobenzene to aniline? (©) Feand HCl : @ i In the reaction Sn and HCl (CBSE Delhi 2023) CHsNH + CHCl; + 3 KOH ——> A + 3B + 3C the product A is } (a) CgHsNC (b) CsH,CN | (©) CcH,Cl @) CGH,NHCH, (CBSE Delhi 2023) CH,CONH, on reaction with NaOH and Bry in alcoholic medium gives: | (a) CH,COONa () CH,NH, (c) CH,CH,Br (d) CH,CH,NH, (CBSE 2023) Which of the following is least basic? | (a) (CH,),NH () NHy | | © Cn (a) (CH,),N (CBSE 2023) CH,CONH, on reaction with LiAIH, gives | (a) CHjCH:NH2 ) as | a) a | (c) CH,NH, (@) OHy (CBSE Delhi 2020) . i Out o' wing, the strongest base in aqueous So tion is f it of the following, ig nee i 7 | (a) Methylamine (a) Aniline (CIBSE 2020) (©) Trimethylamine | KOH |, i holic gives foul smell of ( )-cHN on heating with CHC], and alcol © C prone | @) CoH cher 2000) @ Cp-oHe! @ scanned with OKEN Scanneruestion See MBD Sure Shot CBSE 8, Which of the following does not react with Hinsbers reugonit “f@) CgHgNH, (6) (CgH NH fe) (Cys! 10. The IUPAC name of CHy CH is (a) CHANH, 2 methylbenzenamine Nb) N-Mothyl N-othylbonzenamine (gd) N.N-Methy! ethyl benzenamine (a) N-Ethy (¢) N, N-Ethyl methyl benzenamine 11. CHC #N ESP, P will be? I (a) CHjCH,NC _()-CH,CH NH, (©) CHNHCH, — @) CHyNH, 12. Which of the following compound i is the most basic? NH, NH, CH,NH, 6G -G.00 13, Which one of the aie aise sanded be prepared by Gabriel phthalimide synthesis) (@) Ethylamine (6) Isopropylamine (c) n-Propylamine (dq) Ethylmethylamine 14, The best reagent for converting 2-phenylpropanamide into 2-pheny’ lpropanamine i is 48) Bry in aqueous NaOH — (8) excess of Hy RRS Cyr ee ene (©) iodine in the presence of red phospkorus i | 4d} LiAIH, in ether ae 15, Amongst the following, the strongest base in aqueous medium is (a) CH;NH, — (@) NCCH,NH, ~— LX) (CH,)NH_ —d) C,H; NHCH, (NCERT Exemplar Problem 16. In the chemical reactions The compounds ‘A’ and ‘B’ respectively are : 4) benzene diazonium chloride and fluorobenzene () nitrobenzene and chlorobenzene (©) nitrobenzene and fluorobenzene (@)_ phenol and benzene 17. In the reaction : NO, NO, Oy 4. oO. (A) is ‘Br he ‘cr @ scanned with OKEN Scanner307) (@44,PO, and H,0 ’) Ht (©) HgS0,/H,S0, a es on 3, Aniline undergoes condensation to fi iff base on form Schiff b: ing wi (a) acetyl chloride (6) ammonia e) acetone es : . : (ec) acetone ) benzaldehyde. » we ana le eee is given by only primary amines? ee # Reaction with chloroform and alcoholic KOH eaction with acetyl chloride @p Reaction with Grignard reagent. . Hoffmann degradation of m-bromobenzamide gives (a) aniline m-bromoaniline (c) bromobenzene (d)_m-bromoethyl benzene. , Aniline when diazotized in cold and then treated with dimethyl aniline gives a coloured product. Its structure would be (a) cu<_\- NEN. 4 \- ay ain n(_\- aa) ©) cuign{_Y-vi-€ Vf (ad) can(_\-Nan-(_)-nuctty Y pound will dissolve in an alkali solution after it undergoes . Which of the following com} reaction with Hinsberg’s reaeent! (o-CHNt iy ie tible to oxidation by HNOs, ‘Amino (-NH,) group is susceptible the presence of: : (a) dil HySO4 (6) CS, at 0 = A 4, Nitration of aniline in strongly acidic Hine Fe (a) inspite of gubstituents, nitro group always & ne i pailic substitution reactions, amin er ae Oe ante f substituents, nitro grouP always goes to m-P0 oid aoe trong) medium, aniline is present as anilinium ion. (d) in acidic 5, Aniline reacts with Bro water to give NH NH, ee Br © © Ea (a) (©) CgHjNHO Hs (@) (CHy)3N therefore, nitration is done in () CH,COC! —_—@) Water. m also gives m-nitroaniline because nly m-position is meta directive major product: NH, @ Br Br @ scanned with OKEN Scanner- Glycogen is a polysaccharide of a-D-g rege’ i s ee Understanding Concepts through Questions . Maltose is made up of (a) o-D-glucose (6) D-fructose ; (c) a-D-glucose and B-D-glucose (d) glucose and fructose. s. (a) . Glucose reacts with HNOs to give (a) Gluconic acid (b) Sorbitol (c) Saccharic acid (d) Hexanoic acid 1s. (c) ives n-hexane. This suggests the presence of 3. Glucose on reaction with HI and red P gi (a) one primary —OH group. (6) straight chain of six C atoms (c) one aldehydic group (d) one double bond as. (b) @ scanned with OKEN Scanner336 MBD Sure Shot VR Or Me eae Q4. Which of the following is not reducing sugar ? iItose (b) ribose to lucoce (a) sucrose Ans. (d) : 5. Glucose and fructose are : : s @. structural isomers (b) functional isomers (c) anomers (d) geometrical isomers Ans. (b) Explanation : Ghucose and fructose have same molecular formula CoHs.0 but have different functional groups (-CHO, glucose) and (>C=0, fructose). Q6. a-D-glucose and B-D-glucose are (a) enantiomers (b) geometrical isomers (c) anomers (d)_ epimers Ans. (c) Explanation : o-D-glucose and (D-glucose differ in the configuration only around C; atom and are called anomers. Q7. Which of the following is not true about glucose? (a) It is an aldohexose. (6) On heating with HI, it forms n-hexane (©) It does not give 2, 4-DNP test. (@)_Itis present in furanose form. Ans.(d) Explanation : Glucose is present in pyranose form and it is never present in furanose form. Q8. An example of disaccharide is : (a) glucose (b) ribose (c) cellulose (d) lactose. Ans.(d) Q9. Name the sugar present in milk. How many monosaccharide units are present in itt What are such oligosaccharides called? ‘Ans. Lactose is present is milk. It has two monosaccharide units : glucose and galactose. These are called disaccharides. QUO. (i) Why are carbohydrates generally optically active ? (ii) Name the linkage connecting monosaccharide units in polysaccharides. ‘Ans. (i) Carbohydrates are generally optically active because they have one or more chiral carbon atoms. ; (ii) Glycosidic linkage. Q.11. What are the hydrolysis products of (i) sucrose and (ii) lactose? Ans. (i) Glucose and fructose CyHog033 + HO seinem? CoHiy0g + CoH y20g Saston Ghaas _“Fredies (i) D-glucose and D-galactose CrgHaOn1 + HO SEE CyHyy0, + OH y,0y Lactose Glucose Galactose © Proteins, amino acids and structure of proteins @ scanned with OKEN Scannerred on boiling. in their side chains. ‘s characteristic of proteins containing phenolic groups in their side 3) Understanding Concepts through Questions 12. Denaturation of (a) 1 of primary Structure (o) Joss of primary and se (loss of secondary (@) formation of am: as. (c) planation : Durin; Protein leads to loss of its biological activity by condary structure and tertiary structure ‘ino acids. ng denaturation of proteins, the secondary and tertiary structures get Timary structure re mains as such. '8.In a basic medium, glycine predo: (a) Zwitter ion 18. (c) 4. Which of the following is not an fa) Alanine (6) Leucine minantly exists as (8) cationic 6) anionic (@) covalent form essential amino acid ? (c) Valine (d)_ Lysine. 18. (a) '5.Proteins on complete hydrolysis give : 4a) a-amino acids (6) lipids (c) peptides (@) nucleic acids. 18. (a) '6.An example of fibrous protein is : (2) Albumin (6) Keratin (c) Fibroin (d) Haemoglobin, as. (b) \7. State differences between primary and secondary structure of proteins, ts. The order in which the amino acids are joined in one or more polypeptide chains of a Protein is called primary structure. It gives its function and is critical of its biological activity. ‘ ees fain ets eit y ture determines the manner in which the protein chain is folded. It ce eyo ia ppiie ad eal ohne eee Tegion of the backbone to another. ee @ scanned with OKEN ScannerUnderstanding Concepts through Questions =—§_——————___ 221. Vitamin Ais called : 4 (@) Ascorbic acid 4b) Retinol 4 () Calciferol (d) None of these s.(b) ca22.Deficiency of vitamin D leads to disease | (a) Rickets~” (0) Beri-beri (c) Scurvy (d) Night-blindness “Ans. (a) 323. Which of the following B-group vitamin can be stored in our body a. ® Vitamin B, (0) Vitamin B, (c) Vitamin B, (@ Vitamin Byy 3s (d) 224. Most appropriate source of vitamin C is (a) cereals (6) egg yolk (©) citrus fruits (@) milk “‘Ans.(c) 25. What is the chemical name of vitamin C and which disease is caused by its deficiency? __tns. Ascorbic acid; deficiency disease : Scurvy. ‘a 26.Why must vitamin C be supplied regularly in diet? What is chemical name of vitamin C? . Vitamin C is water soluble and therefore, excess of it is readily excreted in urine. Hence it cannot be stored in our body. : Chemical name of vitamin C : Ascorbic acid Name the vitamins in each case whose deficiency causes ‘| @night blindness (i) poor coagulation of the blood. +"8.(i) Vitamin A (ji) Vitamin K GQ im a © Nucleic acids : DNA and RNA @ scanned with OKEN Scanner* Protein synthesis ta © Replication: DNA has a unique ability to duplicate or replicate i about the synthesis of another DNA copy of itself using certain enzymes. © Mutation: It is a chemical change in a DNA molecule that could lead to proteins with different amino acid sequence. Mutations may result into de: and can cause abnormalities or diseases. Understanding Concepts through Questions §=—__ Q28. Which of the following statement is not correct? (a) Cytosine and thymine are pyrimidines. (0) DNA differs from RNA in sugar as well as nitrogenous base. (c)_ In RNA, heterocyclic amine base is bonded to C-1' of sugar and the ph is bonded to C-5' sugar position. (d) In double helix structure of DNA, thymine can bond to cytosine by two hydrog Ans. (d) Explanation: Thymine can bond to adenine by 2 hydrogen bonds. Q29. Which of the following is not a pyrimidine ? (a) Thymine (6) Guanine (c) Uracil (a) Cytos Ans. (b) Q30.In a polynucleotide, the bond which joins two nucleotides is called (a) glycosidic bond (6) aminoester bond (0. phosphodiester bond (d) disulphide linkage Ans. (c) Q31.Structure of a DNA molecule is : (a) Linear (6) Branched (©) Single helix (d) Double Ans. (d) Q82. (i) What type of linkages hold together monomers of DNA? (ii) What products would be formed when a nucleotide from DNA containing hydrolysed? Ans. (i) Hydrogen bonds. (ii) 2-deoxy-D-ribose, thymine and phosphoric acid. Q33. What is the difference between DNA and RNA o Ans Both DNA and RNA contain two bases deriv base derived from pyrimidine cytosine. Ho contains thymine whereas RNA contains n the basis of bases they cont ed from purine; guanine and adenine wever, they have fourth different base : uracil. @ scanned with OKEN Scanneri~ Question Bank SECTION-A -\ yo Multiple-Choice Questions —_ 4 1. Which of the following statement is not true about glucose? (a) It isan aldohexos (by On heating with HI it forms n-hexane, (©) It is present in pyranose form. (a) It gives 2, 4 DNP test : (CBSE Dethi 2023 2. f-pleated sheet structure in proteins refers to (a)_ primary structure (b) secondary structure () tertiary structure (d) quaternary structure (CBSE Delhi 2023 8. Hydrolysis of sucrose is called ta) inversion (@ hydration (c)_ esterification (a) saponification (CBSE Delhi 2023 4. An ochelix is a structural feature of: (a) Sucrose (6) Starch _() Polypeptides (a) Nucleotides (CBSE 2028 5. The glycosidic linkage involved in linking the glucose units in amylose part of starch is: (a) C,-Cg « linkage (6) C,-Ce B linkage _(o): Cy-Cy@ linkage (a) C,-C, B linkage (CBSE 2023 6. Which of the following is a non-reducing sugar? — (a) Sucrose " “ (b) Maltose | (c) Glucose (d) Lactose (CBSE 2028, 7. a-D-Glucose and B-D-Glucose differ from each other with respect to the: (a) Number of - OH groups (6) Configuration at the C-1 carbon (c) Size of the hemiacetal ring (d) Configuration at the C-5 carbon (CBSE 2021-22: 8. Nucleotides are composed of a: i (a) pentose sugar and phosphoric acid (8) nitrogenous base and phosphoric acid (c)_ nitrogenous base and a pentose sugar +(d) nitrogenous base, a pentose sugar and phosphoric acid 9. The functional unit that is repeated in a protein molecule is: (a) Anester linkage (b) Aglycosidic linkage (c) A peptide linkage (@) Anether linkage (CBSE 2021-23) (CBSE 2021-22) @ scanned with OKEN Scanner1, Amino acids wh are known ag (@) Acidic ami i no acids (c) Basic amino acids DMA Or A 2 Nucleic acids are /@ amino acids 2° nucleotides 3. Glucose on reaction with Br, (a) Saccharic acid (©) Gluconie acid 4. Complete the following analogy: Curdling of milk : Ax a-helix: B Polymer of '2 Water gives: (@) ‘ich cannot be Synthesized in the (b) @ (b) (@) (b) (d) » Guanine and Thymine ©, Uracil and Thymine (CBSE 2021.29) ined through diet Guanin body and must be obtaii Essential amino acids Non-essential amino acids (CBSE 2021.22) nucleosides glucose (CBSE 2021.22) Hexanoic acid Salicylic acid (CBSE 2021-22) (a) A: Primary structure B : Secondary structure (6) A: Denatured protein B : Primary structure (ec) A: Secondary structure B : Denatured protein 44Y" A: Denatured protein B : Secondary structure 5. An a-helix is a structural feature of td: Sucrose oY Nucleotides (CBSE 2021.22) AG Polypeptides Mfd¥- Starch (CBSE 2020) 6. Which one is the complementary base of cytosine in one strand to that in other strand of au “©) Guan is ‘uanine ig sec ioe (CBSE 2020) 1. In which of the following order base, phosphate and sugar are arranged in the nucleotide . Inw of DNA? (a) , Base-phosphate-sugar Phosphate-base-sugar (6) @ Base-sugar-phosphate Sugar-base-phosphate (CBSE 2020) ino acids molecules are linked through hydrogen bonds in the secondary 8. Which part of amino ai structure of proteins 2 (a) NH, group (©) _—C— and —NH— groups Tt 19. Curdling of milk is an example oft (a) breaking of peptide linkage : a Gede (©) breaking of protein into amino aci c (b) (d) ) {d) COOH group None of the above (CBSE 2020) hydrolysis of lactose | re cation of protein ae CSE Sample Paper 2020-21) @ scanned with OKEN Scanner(saa) MBD Sure Shot CBSE Quest" Bank Chermisty. 20. Which of the following is not an essential amino acid? (a) Lysine (0) Glycine (c) Phenylalanine (d) Valine. 21. The sequence in which amino acids are arranged in a protein is called (a) primary structure (b) secondary structure (c) tertiary structure (d)_ tetrahedral structure. 22, Glucose on treatment with sodium amalgam gives (a) n-heptanoic acid 6) sorbitol (c)_ gluconic acid (@) _glucaric acid 28. Which amino acid has no asymmetric carbon atom ? (a) Histidine -(b) Glycine (c) a-Alanine (d) Threonine 24. The bond that determines the secondary structure of protein is : (a) Covalent bond (6) Sulphur linkage -(c) Hydrogen bond (@)_ Tonic bond 25. Mutation in DNA occurs due to changes in the sequence of (a) nitrogenous bases (6) ribose units (c) phosphate units (@ _ hydrogen bonds. 26. The chemical change in DNA molecule that could lead to synthesis of proteins with ar altered amino acids sequence is called (a) Replication (6) Lipid formation () Cellular membrane -d) Mutation. 27, In DNA, the complementary bases are: Aa) adenine and thymine; guanine and cytosine (6) adenine and thymine; guanine and uracil (c) adenine and guanine; thymine and cytosine (@)_ uracil and adenine; cytosine and guanine 28, The number of primary OH group present in glucose is (a) 2 () 4 fe) 1 @ 5 29, An example of a disaccharide made up of two units of the same monosaccharides is: (a) Sucrose 46S Maltose (©) Lactose (d) Starch 30. Guanine is held by three hydrogen bonds with the base : (a) Thymine (6) Adenine ) Cytosine (d) Uracil. (SERED & ints / Explanations 4 1. (d) : Glucose does not give 2, 4-DNP test because —CHO group is not free but is preset in cyclic structure. 4 2.(6) 3 @ 4.) 5.(c) 6a) 7.(6) 8d) 9%) 10, (a) 11. () 12, (c) 13. (c) 14. (d) 15. (©) 16. (c) 17. (c) 18.(c) 19. (d) 20. (6) 21. (a) 22, (b); CHO CH,OH (CHO), + 2(H) —Ns_, (CHOH), CH,OH CH,OH @ scanned with OKEN Scanner