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COMMON PERIODIC TEST Answer Key 3

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44 views4 pages

COMMON PERIODIC TEST Answer Key 3

Uploaded by

athiyanathiyanaathi
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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COMMON PERIODIC TEST – II

CHEMISTRY
XII STD ANSWER KEY
MARKS:40
SECTION – A (8 X 1 = 8)
Directions (Q.Nos. 1-8): The following questions are multiple choice questions with one
correct answer. Each question carries 1 mark.

1) b) 3 X 10-4 mol L -1 s -1

2) c) Half.
[𝑅𝑜]
3) d)
2𝑘
4) d) (CH3)2C=CH2
5) a) 10 > 20 > 30
6) a) Phenoxide is stablised by resonance
7) c) A is true but R is false.
8) a) Both A and R are true and R is the correct explanation of A
SECTION – B (3 X 2 = 6)

9) Order of a reaction
(i) It is the sum of powers of molar concentrations of reaction species
in the rate equation of reaction.
r = k[A]x [B]y and order = X + Y

1 𝑑[𝑁𝑂2 ] 1 −𝑑[𝑁2 𝑂5 ]
10)
4 𝑑𝑡
=
2 𝑑𝑡
2
= x 2.8 x10 -3 Ms-1
4
= 1.4 x 10 -3 Ms-1

11) O – nitro phenol is more steam volatile due to intramolecular hydrogen


bonding present in it. While p-nitro phenol is less volatile due to
intermolecular H – bonding.
(or)

SECTION – C (3 x 3 = 9)

12) a) r = k[A]1/2 [B]2


Order = 2+ ½ = 2 ½
(or)
b) A B
Rate = k [A] 2

Rate = k [3A]2
= 9k[A]2
Rate increased by 9 times.

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13)
𝑘
Slope =
2.303

14) Diborane is made to react with an alkene to form an addition product. This
product is then treated with hydrogen peroxide in the presence of sodium
hydroxide, alcohol is obtained. It follows anti Markovnikov’s rule.

15) Reimer – Tiemann reaction. Phenol with chloroform in the presence of aqueous alkali
introduces a – CHO group at the ortho position. Further acidification yields salicylaldehyde.

SECTION – D 4 MARKS
16) a) First order (1mark)
b) rate = k [CH2 = CH2 ] (1 mark)
0.693 0.693
c) t½= = = 2.7 X 1014 s (2 mark)
𝑘 2.5 𝑥10−15
(or)
t=5
[𝑅𝑜]
= 3
[𝑅]
2.303 [𝑅𝑜]
K= log [𝑅]
𝑡
2.303
= log 3
5
= 0.2197 min-1

SECTION – E 5 marks
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17) a) i) activation energy decreases. (1 mark)
ii) an increase in temperature No change in activation energy.The activation energy
remains same. (1 mark)
(b)
[R] = 100
[R] = 75
T = 40 min
2.303 [𝑅𝑜]
K= log
𝑡 [𝑅]

2.303 [100]
K= log
𝑡 [75]
2.303 [4]
= log
𝑡 [3]
2.303
= (0.60 – 0.48)
40
= 0.06909 min -1
2.303 100
T= log
0.069 20
2.303
= x 0.69
0.069
= 23.03 min. (3 mark)
(or)
(c.) Pseudo first order reaction:
If a reaction is not truly of the first order but under certain conditions
becomes reaction of first order is called pseudo first order reaction.
eg. Acidic hydrolysis of ester.
CH3 COOC2 H5 + H2O H+ CH3COOH + C2H5OH (2 mark)

(d). K = 0.0030 mol l-1 s-1


[𝑨𝒐]−[𝑨] 𝟎.𝟏−𝟎.𝟎𝟕𝟓
T= =
𝒌 𝟎.𝟎𝟎𝟑𝟎
0.025 25 𝑥10−3
= = = 8.33 s (3 mark)
0.0030 3 𝑥10−3

18) a) Ethers have low polarity and as a result do not show any association by
intermolecular H-bonding. Therefore ethers have low boiling points than
that isomeric alcohols. So, Butan – 1 – ol has a higher boiling point than
diethyl ether. (2 mark)

b) (i) phenol picric acid

(1 mark)

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(ii) 2 – methyl propanol 2 – methyl propene

(1 mark )
(iii) propan -2- ol propanone

(1 mark)

(or)
a) Propan – 1 – ol < 4 – methyl phenol < phenol < 3 – nitrophenol < 3 , 5 – dinitrophenol
< 2,4,6 – trinitrophenol. (2 mark)
b) (i) acid catalysed dehydration of 1-methyl cyclohexanol

(1 ½ mark)

(ii) acid catalysed dehydration of butan-1-ol

(1 ½ mark)

*************

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